JPH0644971B2 - 脱硫方法 - Google Patents
脱硫方法Info
- Publication number
- JPH0644971B2 JPH0644971B2 JP62003098A JP309887A JPH0644971B2 JP H0644971 B2 JPH0644971 B2 JP H0644971B2 JP 62003098 A JP62003098 A JP 62003098A JP 309887 A JP309887 A JP 309887A JP H0644971 B2 JPH0644971 B2 JP H0644971B2
- Authority
- JP
- Japan
- Prior art keywords
- bed
- temperature
- absorbent
- molecular sieve
- feedstock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 15
- 238000006477 desulfuration reaction Methods 0.000 title claims description 11
- 230000023556 desulfurization Effects 0.000 title claims description 11
- 239000002250 absorbent Substances 0.000 claims description 33
- 230000002745 absorbent Effects 0.000 claims description 33
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 239000002808 molecular sieve Substances 0.000 claims description 12
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 11
- 238000010521 absorption reaction Methods 0.000 claims description 7
- 230000008929 regeneration Effects 0.000 claims description 6
- 238000011069 regeneration method Methods 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- 230000003009 desulfurizing effect Effects 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 150000003464 sulfur compounds Chemical class 0.000 description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 238000011282 treatment Methods 0.000 description 4
- 239000003463 adsorbent Substances 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- 238000007655 standard test method Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- -1 hydrogen sulfide Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 102200118166 rs16951438 Human genes 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB868600574A GB8600574D0 (en) | 1986-01-10 | 1986-01-10 | Desulphurisation |
| GB8600574 | 1986-01-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62183833A JPS62183833A (ja) | 1987-08-12 |
| JPH0644971B2 true JPH0644971B2 (ja) | 1994-06-15 |
Family
ID=10591191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62003098A Expired - Lifetime JPH0644971B2 (ja) | 1986-01-10 | 1987-01-09 | 脱硫方法 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0230146B1 (no) |
| JP (1) | JPH0644971B2 (no) |
| CA (1) | CA1299341C (no) |
| DE (1) | DE3677945D1 (no) |
| GB (1) | GB8600574D0 (no) |
| NO (1) | NO168837C (no) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0262849B1 (en) * | 1986-10-01 | 1992-07-29 | Imperial Chemical Industries Plc | Desulphurisation |
| GB8805351D0 (en) * | 1988-03-07 | 1988-04-07 | Ici Plc | Desulphurisation |
| US7655135B2 (en) | 2006-03-14 | 2010-02-02 | Syntroleum Corporation | Process for removing solid particles from a hydroprocessing feed |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3313722A (en) * | 1964-03-04 | 1967-04-11 | Universal Oil Prod Co | Continuous thermal diffusion process employing fixed beds of adsorbent and moving inlets and outlets |
| US4204947A (en) * | 1978-04-03 | 1980-05-27 | Chevron Research Company | Process for the removal of thiols from hydrocarbon oils |
| US4224191A (en) * | 1979-03-05 | 1980-09-23 | Chevron Research Company | High-copper-level comulled sulfur sorbent |
-
1986
- 1986-01-10 GB GB868600574A patent/GB8600574D0/en active Pending
- 1986-12-30 EP EP19860310206 patent/EP0230146B1/en not_active Expired
- 1986-12-30 DE DE8686310206T patent/DE3677945D1/de not_active Expired - Lifetime
-
1987
- 1987-01-09 NO NO870100A patent/NO168837C/no not_active IP Right Cessation
- 1987-01-09 JP JP62003098A patent/JPH0644971B2/ja not_active Expired - Lifetime
- 1987-01-09 CA CA000527088A patent/CA1299341C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE3677945D1 (de) | 1991-04-11 |
| NO168837C (no) | 1992-04-08 |
| GB8600574D0 (en) | 1986-02-19 |
| NO168837B (no) | 1991-12-30 |
| EP0230146A3 (en) | 1989-01-18 |
| JPS62183833A (ja) | 1987-08-12 |
| NO870100D0 (no) | 1987-01-09 |
| NO870100L (no) | 1987-07-13 |
| EP0230146A2 (en) | 1987-07-29 |
| EP0230146B1 (en) | 1991-03-06 |
| CA1299341C (en) | 1992-04-28 |
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