JPH0680207B2 - Polyester thick yarn and method for producing the same - Google Patents
Polyester thick yarn and method for producing the sameInfo
- Publication number
- JPH0680207B2 JPH0680207B2 JP58178232A JP17823283A JPH0680207B2 JP H0680207 B2 JPH0680207 B2 JP H0680207B2 JP 58178232 A JP58178232 A JP 58178232A JP 17823283 A JP17823283 A JP 17823283A JP H0680207 B2 JPH0680207 B2 JP H0680207B2
- Authority
- JP
- Japan
- Prior art keywords
- yarn
- thick
- polyester
- thin
- woven
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000728 polyester Polymers 0.000 title claims description 41
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 238000009835 boiling Methods 0.000 claims description 31
- 230000009477 glass transition Effects 0.000 claims description 3
- 239000004744 fabric Substances 0.000 description 39
- 230000000694 effects Effects 0.000 description 17
- 238000002474 experimental method Methods 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 238000004043 dyeing Methods 0.000 description 11
- 238000009991 scouring Methods 0.000 description 10
- 239000002759 woven fabric Substances 0.000 description 10
- 238000009998 heat setting Methods 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000005259 measurement Methods 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000001788 irregular Effects 0.000 description 4
- 238000009941 weaving Methods 0.000 description 4
- 235000009508 confectionery Nutrition 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 238000002788 crimping Methods 0.000 description 2
- -1 diol compound Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical group O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
Description
【発明の詳細な説明】 〔技術分野〕 本発明は糸長手方向に太細を有し、特に甘撚、または無
撚で生糸織編物とした場合に良好な外観、品位および風
合を発揮させることのできるポリエステル太細糸及びそ
の製造方法に関する。Description: TECHNICAL FIELD The present invention has a large and small thickness in the longitudinal direction of the yarn, and particularly when it is made into a raw yarn woven or knitted fabric with a soft twist or no twist, it exhibits a good appearance, quality and feel. The present invention relates to a polyester thick yarn and a method for producing the same.
ポリエステル未延伸糸を不均一延伸して糸長手方向に太
細のある糸とすることは公知の技術である。しかしなが
ら単に不均一延伸して得られた太細糸は通常沸水収縮率
が50〜80%と極めて大きくこのままで織編物とした場合
には精練染色仕上などの際の収縮が大きすぎて異常に高
密度の硬い風合のものしか得られない。It is a well-known technique to non-uniformly draw a polyester unstretched yarn to make a yarn thick and thin in the longitudinal direction of the yarn. However, the thick yarns obtained by simply non-uniform stretching usually have an extremely high boiling water shrinkage rate of 50 to 80%, and when used as a woven or knitted fabric, the shrinkage during scouring and dyeing is too large and abnormally high. Only the texture with a hard density can be obtained.
すなわち適正な織編物とするには、より低収縮率化する
ことが必要であり、このために本発明者は特開昭57-112
428号公報、特開昭57-139514号公報および特開昭57-143
515号公報などで太細を有するポリエステルマルチフィ
ラメント糸をリラックス熱処理することにより低収縮率
化技術を提案した。しかしながらこれらの技術を詳細に
検討してみると糸長手方向の沸水収縮率のバラツキが大
きくそのため生糸織編物としてから精練する際にパッカ
リング状のシボムラが多発し、織編物品位が不良となる
ことが判明した。リラックス熱処理においては加熱体上
での糸道規制のために加熱体入口ガイドが必須であり、
加熱体上で数十%の沸水収縮率の大巾な低下を行なう際
にこのガイド上で延伸に供給する未延伸糸の解舒撚の間
欠的なタマリに基づく加熱体への糸の接触状態の長さ方
向の変化があること、及び加熱体上での糸ゆれが大きい
ことが糸長手方向の沸水収縮率のバラツキが大きい原因
となっている。糸長手方向の沸水収縮率バラツキは異型
断面糸において特に顕著である。That is, in order to obtain a proper woven or knitted fabric, it is necessary to further reduce the shrinkage ratio, and for this reason, the present inventor has proposed that the method disclosed in JP-A-57-112.
428, JP-A-57-139514 and JP-A-57-143
In Japanese Patent No. 515, etc., a technique for reducing the shrinkage ratio has been proposed by subjecting a polyester multifilament yarn having a large thickness to a relax heat treatment. However, when these technologies are examined in detail, the boiling water shrinkage in the longitudinal direction of the yarn greatly varies, and therefore, when the raw silk woven or knitted product is refined, puckering ring-shaped unevenness frequently occurs, resulting in poor woven or knitted article position. It has been found. In the relaxation heat treatment, the heating body inlet guide is indispensable to regulate the yarn path on the heating body,
The contact state of the yarn to the heating element due to the intermittent tamari of the untwisting of the undrawn yarn supplied to the drawing on this guide when the boiling water shrinkage rate of the heating element is drastically reduced by several tens of percent. Of the boiling water shrinkage in the longitudinal direction of the yarn is large due to the change in the length direction of the yarn and the large fluctuation of the yarn on the heating body. The variation in boiling water shrinkage in the longitudinal direction of the yarn is particularly remarkable in the modified cross-section yarn.
また特開昭51-147616号公報にはポリエステル太細糸を
0.95〜1.15の緊張率で緊張熱処理し、仮撚加工糸とした
場合には太細効果の明瞭な糸とする技術、特開昭57-191
340号公報にはポリエステル太細糸を0.95〜1.05の延伸
比で熱処理し熱劣化の小さい糸とする技術が開示されて
いる。しかしながら緊張熱処理といえども加熱体上での
糸ゆれ防止のため糸道規制ガイドは必須であり、緊張率
1.05程度以下では実質的にリラックス熱処理と大差なく
前記した欠点は避けられず、一方緊張率が1.05程度以上
では緊張熱処理に供給する太細糸の太部が細部に変化し
て太細効果が減少するばかりでなく、太部が間欠的に伸
長し、新たな太細構造が形成され糸長手方向の沸水収縮
率バラツキが大きい点は避けられない。In addition, Japanese Patent Laid-Open No. 51-147616 discloses polyester thick yarn.
Technology for producing a yarn having a clear thick and thin effect when a false twisted yarn is obtained by performing a tension heat treatment at a tension ratio of 0.95 to 1.15, and JP-A-57-191.
Japanese Unexamined Patent Publication No. 340 discloses a technique in which a thick polyester yarn is heat-treated at a draw ratio of 0.95 to 1.05 to form a yarn having a small thermal deterioration. However, even in the tension heat treatment, the yarn path regulation guide is indispensable to prevent the yarn fluctuation on the heating body.
If it is less than about 1.05, it is substantially the same as the relaxation heat treatment, and the above-mentioned drawbacks cannot be avoided.On the other hand, if the tension ratio is about 1.05 or more, the thick part of the thick yarn supplied to the tension heat treatment changes in detail and the thinning effect decreases. In addition to the above, it is unavoidable that the thick portion is intermittently elongated, a new thick and thin structure is formed, and the variation in boiling water shrinkage in the longitudinal direction of the yarn is large.
特公昭58-4092号公報には各フィラメント長さ方向に沿
って未延伸部がランダムに分布し、かつ任意の断面にお
いて未延伸部が5〜80%あるポリエステルマルチフィラ
メントが開示されている。未延伸部がランダムに分布
し、糸条全体としては必ずどの部分にも未延伸部が存在
しているために、糸長さ方向の染濃淡差が小さく、編織
物とした場合に染濃淡差に基づく霜降効果が小さい欠点
がある。また該公報に示される技術では糸条の長手方向
の沸水収縮率の変動率が大きく、織編物、特に生糸織編
物においてはシボムラが発生し、品位が悪い欠点があ
る。該公報には織編物を染色すると微妙なシボが発現
し、あたかもスパンが如き風合を有すると説明している
が、生糸織編物ではこの微妙なシボが品位をそこない欠
点となるのである。Japanese Patent Publication No. 58-4092 discloses a polyester multifilament in which unstretched parts are randomly distributed along the length direction of each filament and the unstretched parts are 5 to 80% in an arbitrary cross section. Since the unstretched parts are randomly distributed and there are always unstretched parts in every part of the entire yarn, the difference in dyeing density in the yarn length direction is small, and the difference in dyeing density in knitted fabrics is small. There is a drawback that the frost effect based on is small. Further, the technique disclosed in this publication has a large fluctuation rate of boiling water shrinkage in the longitudinal direction of the yarn, and causes unevenness in the woven or knitted fabric, particularly in the raw yarn woven or knitted fabric, resulting in poor quality. The publication describes that when a woven or knitted fabric is dyed, a delicate grain appears, and the span has a texture like that. However, in the raw silk woven or knitted fabric, this delicate grain becomes a defect that the quality is not impaired.
特開昭57-171717号公報にはシルク調の自然な斑を有す
る織編物を得るために、長手方向に不規則に斑部があ
り、斑部には延伸された単糸が多いポリエステルマルチ
フィラメント斑糸が開示されている。斑部は延伸された
繊維本数が45%以上、未延伸繊維本数が30%以下と規定
されており、斑部における未延伸繊維の割合いが少ない
ために斑部でない正常部との染濃淡差が小さく、織編物
として染色しても良好な霜降り調が得られない。更にこ
の発明では斑部の個数は1〜900m当り1個と長手方向に
はきわめて少ない斑部の数を指向しており、この点から
も霜降り調は得られない。またこの斑糸は2段延伸に製
造することが開示されているが、記載された延伸方法で
は熱収縮率の変動が大きく、生糸編織物とした場合には
シボムラが出る欠点ががある。Japanese Unexamined Patent Publication (Kokai) No. 57-171717 discloses a polyester multifilament having irregular irregularities in the longitudinal direction and a large number of stretched single yarns in order to obtain a woven or knitted fabric having natural irregularities of silk tone. Plaques are disclosed. It is specified that the number of stretched fibers is 45% or more and the number of unstretched fibers is 30% or less in the spots, and because the proportion of unstretched fibers in the spots is small, the difference in dyeing density from the normal spots that are not spots Is small, and good marbling tone cannot be obtained even when dyed as a woven or knitted fabric. Further, in the present invention, the number of spots is one per 1 to 900 m, which is extremely small in the longitudinal direction, and from this point, the marbling tone cannot be obtained. Further, it is disclosed that this fluff yarn is produced in a two-stage drawing, but in the described drawing method, there is a drawback that the fluctuation of the heat shrinkage is large, and when a raw yarn knitted woven fabric is produced, unevenness in texture occurs.
すなわち従来技術では糸長手方向に太細を有し、良好な
染霜降調外観効果力を有し、かつ糸長手方向に沸水収縮
率バラツキの小さいポリエステルマルチフィラメント糸
は得られていなかったのである。That is, in the prior art, a polyester multifilament yarn having a large thickness in the yarn longitudinal direction, a good frost-dyeing appearance effect and a small boiling water shrinkage variation in the yarn longitudinal direction has not been obtained.
本発明の目的は仮撚、強撚−熱セットなど特別の加工を
せずに無撚または甘撚で生糸織編物とした場合に製編機
の際の熱処理工程での異常収縮ムラの発生がなく、品
位、霜降り調外観、風合の良好な編織物とするのに好適
なポリエステル太細糸及びその製造方法を提供するもの
である。The object of the present invention is to produce abnormal shrinkage unevenness in the heat treatment step of the knitting machine when the raw yarn woven or knitted fabric is untwisted or sweet twisted without special processing such as false twisting, strong twisting-heat setting. In addition, the present invention provides a polyester thick and thin yarn suitable for producing a knitted fabric having a good quality, a marbling appearance, and a good texture, and a method for producing the same.
本発明の第一の発明は、ポリエステルマルチフィラメン
ト糸を構成する各フィラメントに太細があり、全フィラ
メントの2/3以上が太部である部分が少なくとも糸1m当
り2コ、全フィラメントの4/5以上が細部である部分が
少なくとも糸1m当り2コ存在し、マルチフィラメント糸
の繊度変動率U%値が3.1〜11.8%、沸水収縮率が4.2〜
19.8%、糸長手方向の沸水収縮率の変動率が5%以下で
あるポリエステル太細糸である。1st invention of this invention WHEREIN: Each filament which comprises a polyester multifilament thread | yarn is thick and thin, and the part where 2/3 or more of all filaments is a thick part is at least 2 per 1m of thread | yarn, 4 / of all filaments. There are at least 2 parts with 5 or more details per 1 m of yarn, the fineness variation rate U% of the multifilament yarn is 3.1 to 11.8%, and the boiling water shrinkage is 4.2 to
It is a polyester thick and thin yarn having a boiling water shrinkage rate of 5% or less in the yarn longitudinal direction of 19.8%.
本発明のポリエステル太細糸は構成する各フィラメント
に太細があり、全フィラメント2/3以上が太部である部
分が少なくとも糸1m当り2コ、全フィラメントの4/5以
上が細部である部分が少なくとも糸1m当り2コ存在する
必要がある。The polyester thick and thin yarn of the present invention has thick and thin filaments, and at least 2/3 or more of all filaments are thick portions and at least 2/5 / m of the entire filaments are fine portions. Must exist at least 2 per 1 m of yarn.
本発明のポリエステル太細糸の糸形状を模式的に第1図
に示した。各フィラメントは長さ方向に太部huと細部ho
の繰り返した形状である。糸全体の断面方向に全フィラ
メントの2/3以上が太部である部分(糸太部分Hu)が糸1
m当り2コあること及び、全フィラメントの4/5以上が細
部である部分(糸細部分Ho)が少なくとも糸1m当り2コ
存在することが良好な霜降り調効果を所持するために必
要なのである。第1図には太部Huと細部Hoも示した。The yarn shape of the polyester thick and thin yarn of the present invention is schematically shown in FIG. Each filament has a thick hu and a fine ho in the length direction.
Is a repeated shape. Thread 1 is the portion where 2/3 or more of all filaments are thick in the cross-sectional direction of the whole thread (thick thread Hu)
In order to have a good marbling effect, it is necessary that there are 2 pieces per m and that there are at least 2 parts (thin portion Ho) where 4/5 or more of all filaments are fine (thread fine part Ho) per 1m of thread. . Figure 1 also shows the thick Hu and Ho details.
本発明のポリエステル太細糸の糸長手方向の太細ムラの
程度は後述するU%値測定法で測定して繊度変動率U%
が3.1〜11.8%の範囲にある必要がある。U%値が3.1%
未満である染色織編物において太部に対応する濃染部が
点在したものかまたは太細コントラストに対応する霜降
調効果が充分でなく、更に織編物のふくらみが小さい欠
点があるのでU%値の下限は4%以上が好ましく、5%
以上がより好ましい。U%値が11.8%を越えると染色織
編物全体が濃色となり霜降調効果が充分でない。良好な
霜降調効果を付与するにはU%の値が10%以下であるこ
とが好ましい。The degree of thick and thin unevenness of the polyester thick and thin yarn of the present invention in the yarn longitudinal direction is measured by a U% value measuring method described later, and the fineness variation rate is U%.
Should be in the range of 3.1 to 11.8%. U% value is 3.1%
In the dyed woven or knitted fabric which is less than the above, there is a defect that the deeply dyed part corresponding to the thick part is scattered or the frost reduction effect corresponding to the thick and thin contrast is not sufficient, and further the bulge of the woven and knitted fabric is small, so the U% value is The lower limit of 4% or more is preferable, and 5%
The above is more preferable. If the U% value exceeds 11.8%, the entire dyed woven or knitted fabric becomes deeply colored, and the defrosting effect is not sufficient. The U% value is preferably 10% or less in order to impart a good frost-decreasing effect.
本発明になる太細糸の沸水収縮率は特に生糸織編物用に
は重要な特性が4.2〜19.8%であることが必要である。
沸水収縮率が4.2%未満になると生糸織編物とした場合
でのふくらみ付与効果が出し難く、19.8%を越えると織
編物とした場合の精練、染色などの熱処理する際に異常
に収縮し風合が硬いものしか得られない欠点、更に収縮
が大き過ぎて織編物を規定の巾に仕上げ難くなる欠点が
ある。沸水収縮率を5〜18%とするとよりふくらみがあ
り、より柔軟で良好な風合の織編物が得られる。The boiling water shrinkage of the thick and thin yarn according to the present invention is required to be 4.2 to 19.8%, which is an important characteristic especially for raw silk woven or knitted fabrics.
If the boiling water shrinkage is less than 4.2%, it will be difficult to obtain the swelling effect when the raw silk woven or knit is used, and if it exceeds 19.8%, the woven and knitted fabric will abnormally shrink during heat treatment such as scouring or dyeing. However, there is a defect that only a hard product can be obtained, and further, the shrinkage is too large and it is difficult to finish the woven or knitted product to a specified width. When the boiling water shrinkage ratio is 5 to 18%, the woven and knitted fabric has more bulge and is softer and has a good texture.
糸長手方向の沸水収縮率の変動率(以下ws-cv%と言
う)は後述する測定方法に基づいて5%以下とする必要
がある。糸長手方向に太細がある糸においてws-cv%が
小さいことが本発明のポリエステル太細糸の最大の特徴
である。ws-cv%が5%を越えると生糸織編物として精
練する際にパッカリング状のシボムラとなり、仕上げ時
に伸長してパッカリングを消去しようとすると、織編物
のふくらみが減少する欠点及び織編物中で大きく収縮し
た糸がより伸長されてスジムラとなる欠点がある。ws-c
v%が小さい程良好であり、4%以下とすることが好ま
しく、3.5%以下とすることがより好ましい。The fluctuation rate of boiling water shrinkage in the yarn longitudinal direction (hereinafter referred to as ws-cv%) must be 5% or less based on the measurement method described later. The greatest feature of the polyester thick and thin yarn of the present invention is that ws-cv% is small in a yarn having a fineness in the longitudinal direction of the yarn. If ws-cv% exceeds 5%, puckering-like unevenness will occur when scouring as a raw silk woven or knitted fabric, and the bulge of the woven or knitted fabric will decrease when trying to erase the puckering by stretching at the time of finishing. There is a drawback that the yarn that has been greatly contracted by is stretched and becomes uneven. ws-c
The smaller v% is, the better the better, and preferably 4% or less, more preferably 3.5% or less.
糸長手方向の沸水収縮率のレンジRも小さい程好まし
く、後述する測定方法でレンジRは4%以下であること
が好ましく、3%以下とすることがより好ましい。The smaller the range R of boiling water shrinkage in the longitudinal direction of the yarn, the more preferable, and the range R is preferably 4% or less and more preferably 3% or less in the measuring method described later.
本発明のポリエステル太細糸を形成するポリエステルと
はテレフタル酸、イソフタル酸、フタル酸、ナフタリン
‐2,6-ジカルボン酸、などの芳香族ジカルボン酸もしく
はアジピン酸、セバシン酸などの脂肪族ジカルボン酸ま
たはこれらのエステル類と、エチレングリコール、ジエ
チレングリコール、1,4-ブタンジオール、ネオペチルグ
リコール、シクロヘキサン‐1,4-ジメタノールなどのジ
オール化合物とから合成されるポリエステルであり、特
に構成単位の80モル%以上がエチレンテレフタレート単
位であるポリエステルが好ましい。The polyester forming the polyester thick yarn of the present invention is an aromatic dicarboxylic acid such as terephthalic acid, isophthalic acid, phthalic acid, naphthalene-2,6-dicarboxylic acid, or an aliphatic dicarboxylic acid such as adipic acid or sebacic acid, or A polyester synthesized from these esters and a diol compound such as ethylene glycol, diethylene glycol, 1,4-butanediol, neopetyl glycol, and cyclohexane-1,4-dimethanol, especially 80 mol% of the constitutional unit. The polyester having ethylene terephthalate units as described above is preferable.
また、上記ポリエステル成分にポリアルキレングリコー
ル、ペンタエリスリトール、メトキシポリアルキレング
リコール、ビスフェノールA、スルホイソフタル酸など
を添加あるいは共重合しても良い。Further, polyalkylene glycol, pentaerythritol, methoxypolyalkylene glycol, bisphenol A, sulfoisophthalic acid, etc. may be added to or copolymerized with the above polyester component.
ポリエステル太細糸を構成するフィラメントの横断面形
状は特に異形断面の場合に好ましく適応される。異形断
面形状としては格別の制限はないが、T型あるいはY型
としシルキーな特徴を付与することがより好ましく適応
される。The cross-sectional shape of the filaments constituting the polyester thick yarn is preferably adapted especially in the case of an irregular cross section. There is no particular limitation as to the modified cross-sectional shape, but it is more preferable to adopt a T-type or Y-type to impart a silky characteristic.
また本発明のポリエステル太細糸は仮撚などの捲縮加
工、強撚−熱セットなどの特別の糸加工をすることなく
甘撚または無撚で生糸織編物とする場合に、ws-cv%が
小さい効果がいかんなく発揮できる。When the polyester thick and thin yarn of the present invention is a raw silk woven or knitted fabric without twisting or crimping such as false twisting and special twisting such as strong twist-heat setting, ws-cv% However, the small effect can be demonstrated without any limitation.
なお本発明において甘撚とは撚糸後熱セットしないで製
編織できる範囲の撚であり、通常500T/M以下である。In the present invention, the sweet twist is a twist within a range that can be knitted and woven without heat setting after twisting, and is usually 500 T / M or less.
本発明の第二の発明は前記したポリエステル糸を好適に
製造するためのものであって、ポリエステルマルチフィ
ラメント未延伸糸を(1+定応力伸長域伸度×0.6)倍
〜(1+定応力伸長域伸度×1.2)倍の延伸倍率で加熱
ピンを用いて延伸し、加熱延伸ローラ上でTg+20℃〜Tg
+60℃(但しTgはポリエステル未延伸糸のガラス転移点
温度)で加熱処理後、常温のローラに0.03〜0.4g/dで給
糸捲回し、特許請求の範囲(1)項記載のポリエステル
太細糸として巻取ることを特徴とするポリエステル太細
糸の製造方法である。A second invention of the present invention is to suitably produce the above-mentioned polyester yarn, which comprises a polyester multifilament undrawn yarn (1 + constant stress elongation region elongation × 0.6) times to (1 + constant stress elongation region). Elongation x 1.2) Stretching with a heating pin at a draw ratio of Tg + 20 ° C to Tg on a heating stretching roller
After heat treatment at + 60 ° C (where Tg is the glass transition temperature of the polyester unstretched yarn), the yarn is wound around a roller at room temperature at 0.03 to 0.4 g / d, and the polyester thick and thin film according to claim (1) is used. A method for producing a polyester thick and thin yarn, which comprises winding the yarn as a yarn.
ポリエステルマルチフィラメント未延伸糸としては、そ
の強力伸長曲線において定応力伸長域を示すことが太細
糸とするために必要なことである。定応力伸長域が小さ
過ぎる未延伸糸を使用して得られる太細糸を織編物にし
た場合には、染色すると濃淡のコントラストが低くな
り、霜降り調の外観が得難いので、0.20以上であること
が好ましく、0.30以上あることがより好ましい。定応力
伸長域が大き過ぎる未延伸糸を使用して得られる太細糸
を織編物にした場合には、太細の断面積比が大きくなり
過ぎ、染色すると濃淡のコントラストが強くなり過ぎる
ので1.0以下であることが好ましく、0.80以下であるこ
とがより好ましい。It is necessary for the polyester multifilament undrawn yarn to exhibit a constant stress extension region in its tenacity extension curve in order to obtain a thick and thin yarn. When the thick and thin yarn obtained by using undrawn yarn whose constant stress elongation region is too small is used as a woven or knitted product, the contrast of light and shade becomes low when dyed, and it is difficult to obtain a marbling appearance, so 0.20 or more. Is preferable, and 0.30 or more is more preferable. When a thick and thin yarn obtained by using unstretched yarn with a too large constant stress elongation region is used as a woven or knitted fabric, the cross-sectional area ratio of thick and thin becomes too large, and when dyed, the contrast of shade becomes too strong. It is preferably below, and more preferably 0.80 or below.
なお紡糸工程に連続して延伸することも可能であるが紡
出直後の未延伸糸は定応力伸長域が明瞭でなく、延伸し
てもマルチフィラメント糸全体に実質的に太細を形成し
難いので一担巻取った未延伸糸を延伸することが好まし
い。It is also possible to draw continuously in the spinning process, but the constant-strength extension region is not clear in the undrawn yarn immediately after spinning, and it is difficult to form a thick or thin shape in the entire multifilament yarn even if it is drawn. Therefore, it is preferable to draw the undrawn yarn that has been wound up.
また、ポリエステルマルチフィラメント未延伸糸を構成
するフィラメントの横断面形状は特に異形断面の場合に
従来方法では達成できない小さな沸水収縮率バラツキの
太細糸とすることが可能であり、異形断面において好適
に適応できる。Further, the cross-sectional shape of the filaments constituting the polyester multifilament undrawn yarn can be made into a thin yarn having a small variation in boiling water shrinkage that cannot be achieved by the conventional method, particularly in the case of an irregular cross section, and is suitable for an irregular cross section. Can be adapted.
以上説明したポリエステルマルチフィラメント未延伸糸
を使用して延伸する方法について図面を用いて以下詳細
に説明する。第2図は本発明の一実施態様を示す製造工
程図である。A method of drawing using the polyester multifilament undrawn yarn described above will be described in detail below with reference to the drawings. FIG. 2 is a manufacturing process diagram showing an embodiment of the present invention.
第2図において、1はポリエステルマルチフィラメント
未延伸糸でフィードローラ2と加熱延伸ローラ4の間で
加熱ピン3を介して(1+定応力伸長域伸度×0.6)倍
〜(1+定応力伸長域伸度×1.2)倍の延伸倍率で延伸
し、加熱延伸ローラ4上で加熱セットする。次いで常温
のローラ5に捲回し巻取機6にて巻取るものである。In FIG. 2, reference numeral 1 is a polyester multifilament unstretched yarn, which is (1 + constant stress elongation region elongation × 0.6) times (1 + constant stress elongation region) between the feed roller 2 and the heating stretching roller 4 via the heating pin 3. Stretching is performed at a stretch ratio of 1.2) times and set by heating on the heating stretching roller 4. Then, it is wound around the roller 5 at room temperature and wound by the winder 6.
延伸倍率は得られる太細糸のU%値を3.1%以上とする
ために(1+定応力伸長域伸度×1.2)倍以下とするも
ので、U%値を4%以上、5%以上とするためには延伸
倍率はそれぞれ(1+定応力伸長域伸度×1.1)倍以
下、(1+定応力伸長域伸度×1.0)倍以下とすること
が良い。またU%値を11.8%以下とするために(1+定
応力伸長域伸度×0.6)倍以上とするもので、U%値を1
0%以下とするためには(1+定応力伸長域伸度×0.8)
倍以上とすることが良い。The draw ratio is (1 + constant stress elongation zone elongation 1.2) times or less in order to obtain a U% value of the obtained thick and thin yarn of 3.1% or more, and a U% value of 4% or more and 5% or more. In order to achieve this, the draw ratio is preferably (1 + constant stress extension zone elongation × 1.1) times or less and (1 + constant stress extension zone elongation × 1.0) times or less, respectively. Also, in order to keep the U% value at 11.8% or less, it is (1 + constant stress extension zone elongation x 0.6) times or more, and the U% value is 1
To achieve 0% or less (1 + constant stress elongation zone elongation x 0.8)
It is better to double or more.
良好な霜降調を得るために糸長手方向に前記したように
特定の糸太部分と糸細部分が存在することが必要で、こ
のために延伸領域に加熱ピンを使用することが必要であ
る。加熱ピンの温度Tg−20℃〜Tg+30℃の範囲であるこ
とが好ましい。In order to obtain a good defrosting condition, it is necessary that there are specific thick and thin portions in the longitudinal direction of the yarn as described above, and it is necessary to use a heating pin in the drawing region for this purpose. The temperature of the heating pin is preferably in the range of Tg-20 ° C to Tg + 30 ° C.
加熱ピンの温度がTg−20℃未満であると、太細の発生が
分散されず、太い部分が長く存在し、得られた太細糸で
構成される織編物を染色すると長い濃染部が存在し、か
つ周期性を呈し、いわゆるモアレ調となり編織物の品位
が著しく低下するので好ましくない。When the temperature of the heating pin is less than Tg-20 ° C, the occurrence of thick and thin is not dispersed, and the thick portion is present for a long time. It is present and presents periodicity, and becomes a so-called moire tone, which is not preferable because the quality of the knitted fabric is significantly deteriorated.
一方加熱ピンの温度Tg+30℃を越えると得られる太細糸
のU%値が低下し、織編物として染色すると濃淡差が低
下し良好な霜降り調外観が得難く、好ましくない。また
延伸領域において加熱板を使用すると太部と細部が分散
し、糸太部分と糸細部分が形成されなくなるので加熱板
は使用しないことが好ましい。On the other hand, when the temperature of the heating pin exceeds Tg + 30 ° C., the U% value of the obtained thick and thin yarn decreases, and when dyed as a woven or knitted product, the difference in shade is reduced, and it is difficult to obtain a good marbling appearance, which is not preferable. Further, when a heating plate is used in the stretching region, the thick portion and the detail are dispersed, and the thick portion and the thin portion are not formed. Therefore, it is preferable not to use the heating plate.
加熱延伸ローラの温度は得られる太細糸の沸水収縮率を
4.2〜19.8%とするためにTg+20℃〜Tg+60℃の範囲と
することが必要である。沸水収縮率を5〜18%とするに
はTg+25℃〜Tg+50℃とすることが良い。なお目標とす
る沸水収縮率レベルを安定して得るために加熱延伸ロー
ラにおけるの接触時間は0.01〜0.4秒が好ましく、0.05
〜0.3秒がより好ましい。なお本発明の太細糸の糸長手
方向に沸水収縮率バラツキが極めて小さいのは延伸おけ
る延伸ローラ上で定長状態で加熱する効果である。The temperature of the heating / drawing roller determines the boiling water shrinkage of the obtained thick yarn.
In order to obtain 4.2 to 19.8%, it is necessary to set the temperature in the range of Tg + 20 ° C to Tg + 60 ° C. In order to make the boiling water shrinkage rate 5 to 18%, it is preferable to set it to Tg + 25 ° C to Tg + 50 ° C. Note that the contact time in the heating and stretching roller is preferably 0.01 to 0.4 seconds in order to stably obtain the target boiling water shrinkage level, and 0.05 to 0.05 seconds.
~ 0.3 seconds is more preferred. The fact that the variation in boiling water shrinkage in the yarn longitudinal direction of the thick and thin yarn of the present invention is extremely small is the effect of heating in a constant length state on the stretching roller in stretching.
加熱延伸ロールより直接巻取機にて巻取ることも可能で
あるが巻取張力変動が巻取った太細糸に影響し、織編物
とした場合にヒケムラやスジムラを発生し易いので、加
熱延伸ローラで加熱処理後常温のローラに給糸、捲回し
てから巻取ることが必要である。この場合に加熱延伸ロ
ーラと常温のローラの間の張力は走行安定性の点で0.03
g/d以上、太部減少防止の点より0.4g/d以上とすること
が必要である。It is possible to wind directly from the heating draw roll with a winder, but the change in take-up tension affects the thick and thin yarns that are wound, and when a woven or knitted product is likely to cause sink marks or uneven streaks, heat drawing After heat treatment by the roller, it is necessary to supply the yarn to the roller at room temperature, wind it, and then wind it. In this case, the tension between the heating and stretching roller and the roller at room temperature is 0.03 in terms of running stability.
It is required to be g / d or more and 0.4 g / d or more from the viewpoint of preventing thick part reduction.
本発明のポリエステル太細糸は上述したようにフィラメ
ントの太部が集合した糸太部分とフィラメント糸細部が
集合した糸細部分が糸長手方向に交互に存在することに
もかかわらず、糸長手方向の沸水収縮率バラツキが極め
て小さいので、織編物製造工程において精練の際のパッ
カリング状のシボムラの発生はなく、またあったとして
も軽微であり、染色、仕上により品位、ふくらみ、霜降
り調外観の良好な生織編物とすることができる。As described above, the polyester thick thin yarn of the present invention has the yarn thick portion in which the thick portion of the filament gathers and the thin portion in which the filament yarn detail gathers alternately in the yarn longitudinal direction, Since the variation in boiling water shrinkage is extremely small, there is no puckering ring-like unevenness during scouring in the woven and knitting manufacturing process, and even if there is, it is slight, and quality, swelling, and marbling appearance due to dyeing and finishing. A good raw woven fabric can be obtained.
従い仮撚などの捲縮加工、強撚−熱セットなどの特別の
糸加工をすることなく甘撚または無撚で織編物とする場
合に本発明の効果を発揮することができる。Therefore, the effect of the present invention can be exhibited in the case where a woven or knitted fabric is obtained by sweet twisting or non-twisting without performing crimping processing such as false twisting and special thread processing such as strong twisting-heat setting.
また製造方法においては特殊な装置を使用することなく
簡単な糸道でコンパクトな装置で加工できるものであ
る。Further, in the manufacturing method, a simple yarn path can be used for processing with a compact device without using a special device.
以下本発明を実施例により、さらに詳細に説明する。な
お沸水収縮率、繊度変動率、U%値、定応力伸長域伸
度、Tg関係の測定方法について以下に述べる。Hereinafter, the present invention will be described in more detail with reference to Examples. The methods for measuring boiling water shrinkage, fineness variation, U% value, constant stress extension zone elongation, and Tg relationship are described below.
A.沸水収縮率 1周1mの10周巻を1カセとし、0.1g/d荷重下で原長を測
定し、0.2mg/d荷重下98℃の水中で15分間処理し、0.1g/
d荷重下で処理長を測定し、 とし、これを一標本の沸水収縮率とする。測定試料の任
意の50個所について測定を繰り返し、平均値を試料の沸
水収縮率、最大値と最小値の差を沸水収縮率のレンジ
R、標準偏差を試料の沸水収縮率で除して100倍し%表
示したものをws-cv%とする。A. Boiling water shrinkage rate 1 round of 1 m 10 rounds is used as 1 case, and the original length is measured under a load of 0.1g / d, and treated in 98 ° C water for 15 minutes under a load of 0.1mg / d, 0.1g / d
d Measure the processing length under load, And this is the boiling water shrinkage of one sample. Repeat the measurement at any 50 points in the measurement sample, divide the average value by the boiling water shrinkage ratio of the sample, the difference between the maximum and minimum values in the range R of the boiling water shrinkage ratio, and divide the standard deviation by the boiling water shrinkage ratio of the sample and multiply by 100. The% displayed is ws-cv%.
B.繊度変動率U%値の測定方法 測定機としては市販のUster Eveness Tester(計測器工
業株式会社製)を使用する。糸のトータル繊度により使
用する測定用スロットを選択し、糸速を4m/mmとし撚糸
機で約1500rpmの回転を与え撚糸しつつノルマルテスト
にて測定する。U%値は3分間の測定を1回として、測
定試料の任意の5個所について測定しその平均値で表わ
す。B. Method for measuring U% value of fineness variation rate A commercially available Uster Eveness Tester (manufactured by Keisokuki Kogyo Co., Ltd.) is used. The measurement slot to be used is selected according to the total fineness of the yarn, the yarn speed is set to 4 m / mm, and the yarn is twisted by applying a rotation of about 1500 rpm with a twisting machine to perform the normal test. The U% value is measured at any 5 points on the measurement sample, with one measurement for 3 minutes, and is expressed as an average value.
C.定応力伸長域伸度 インストロン型引張試験機で得た第3図に示すチヤート
上のAの伸度を読みとり、例えば40%であれば0.40とし
て表わす。定応力伸長域伸度は測定試料の任意の5個所
について測定し、その平均値で表わす。C. Elongation of constant stress elongation zone The elongation of A on the chart shown in Fig. 3 obtained by an Instron type tensile testing machine is read, and if it is 40%, it is expressed as 0.40. The constant stress elongation zone elongation is measured at arbitrary 5 points on the measurement sample and is represented by the average value.
D.Tg ガラス転移点は比熱測定法より求めたものとしてポリエ
チレンテレフタレートは69℃〔Kolloidzeilshrift165、
40(1959)〕である。The D.Tg glass transition point is 69 ° C [Kolloidzeilshrift165,
40 (1959)].
実施例1 25℃オルトクロロフェノール中の固有粘度が0.63のポリ
エチレンテレフタレート未延伸糸120デニール36フィラ
メントを第2図に示す装置にて延伸、加熱処理を行なっ
た、未延伸糸の定応力伸長域伸度は0.62、断面形状はY
断面である。加熱ピンは80℃、延伸速度500m/minで表1
に示す延伸倍率で延伸し、加熱延伸ローラ温度は115℃
で接触時間0.15秒とし、0.15g/dの張力で常温のローラ
に給糸、捲回し巻取った。Example 1 Polyethylene terephthalate unstretched yarn of 120 denier 36 filaments having an intrinsic viscosity of 0.63 in orthochlorophenol at 25 ° C. was stretched and heat-treated in the apparatus shown in FIG. The degree is 0.62, the cross-sectional shape is Y
It is a cross section. The heating pin is 80 ℃ and the drawing speed is 500m / min.
Stretched at the stretching ratio shown in, and the heating stretching roller temperature is 115 ° C
The contact time was 0.15 seconds, and the yarn was fed, wound and wound on a roller at room temperature with a tension of 0.15 g / d.
得られた太細糸の特性は表1に示すとおりであり、いず
れもマルチフィラメント糸全体としての実質的に太細が
存在するもので糸太部分、糸細部分の個数は、それぞれ
表1に示す太細糸あった。これらの太細糸を経糸として
は200T/Mの撚を施こし織密度127本/インチ、緯糸とし
てはそのままで織密度83本/インチで2/2ツイルとし、9
8℃水中でリラクッス精練、200℃乾熱セット、アルカリ
減量10%を行なった後、染料アマクロンブルー(Americ
a Color & Chemica Corp製)1.0%owf、助剤サンソル
ト(日華化学製)1.0%owfの条件で染色を行なった。織
物の精練工程でのパッカリング状のシボムラ発生はいず
れも軽微であり、最終仕上織物ではムラは全くなく品位
は良好であった。各延伸倍率に対応する織物の風合と霜
降効果を表1に併記したが、比較例である実験No1の織
物は織物全体に濃色が強過ぎて不良であり、比較例であ
る実験No7の織物はふくらみと霜降り効果が小さ過ぎて
不良であった。また実験No6の太細糸はふくらみが小さ
く適度なふくらみのある良好な風合の織物が得られたが
ふくらみを強調する織編物には不向きである。The characteristics of the obtained thick and thin yarns are as shown in Table 1. In each case, there is substantially thick and thin as the whole multifilament yarn. The numbers of thick and thin portions are shown in Table 1, respectively. There was a thick thread to show. These thick yarns were twisted at 200T / M as warp and weaving density was 127 yarns / inch, and as weft yarns, weaving density was 83 yarns / inch and 2/2 twill.
Relax scouring in water at 8 ℃, dry heat setting at 200 ℃, alkali weight loss 10%, and then dye Amacron Blue (American
a Color & Chemica Corp.) 1.0% owf and the auxiliary agent Sun Salt (Nichika Kagaku) 1.0% owf. The occurrence of puckering unevenness was slight in the scouring process of the woven fabric, and the final finished woven fabric had no unevenness and was of good quality. The texture and frost effect of the fabric corresponding to each draw ratio are also shown in Table 1. The fabric of Experiment No. 1 which is a comparative example is poor because the dark color is too strong over the entire fabric, and the fabric of Comparative Experiment 7 is comparatively poor. The woven fabric was poor because the bulging and marbling effects were too small. In addition, the thick and thin yarn of Experiment No. 6 has a small bulge and a good woven fabric with a moderate bulge was obtained, but it is not suitable for a woven or knitted fabric that emphasizes the bulge.
実施例2 実施例1において、延伸倍率を1.52倍とし、加熱延伸ロ
ーラ温度を表2に示す条件とした以外は実施例1に準じ
延伸、加熱処理し、得られた太細糸を製織、精練、乾熱
セット、アルカリ減量、染色を行なった。Example 2 In Example 1, drawing and heat treatment were carried out according to Example 1 except that the draw ratio was 1.52 times and the heating and drawing roller temperature was set to the conditions shown in Table 2, and the obtained thick and thin yarn was woven and scoured. , Dry heat setting, alkali weight loss, and dyeing were performed.
得られた太細糸の特性は表2に示すとおりであり、いず
れもマルチフィラメント糸全体として実質的に太細が存
在するもので糸太部分、糸細部分の個数はそれぞれ表2
に示す太細糸であった。織物の精練工程でのパッカリン
グ状のシボムラ発生は実験No.8を除きいずれも軽微であ
り、最終仕上織物ではムラは全くなく品位は良好であ
り、霜降り効果も良好であった。The characteristics of the obtained thick and thin yarns are as shown in Table 2. In each case, the multifilament yarn as a whole has substantially thick and thin yarns.
It was the thick thin yarn shown in. Except for Experiment No. 8, the occurrence of puckering unevenness was slight in the scouring process of the woven fabric, and the final finished woven fabric had no unevenness and had good quality and good marbling effect.
実験No.8のシボムラはやや目立ち、最終仕上織物でも若
干ムラが残った。各加熱延伸ローラ温度に対応する織物
の風合を表2に併記したが、比較例である実験No.8の織
物は硬い風合で不良であり、比較例である実験No.14織
物はふくらみが小さ過ぎて不良であった。なお実験No.9
の織物は風合がやや硬いが良好であった。実験No.9の太
細糸はソフトな風合を強調する織編物には不向きであ
る。実験No.13の織物はふくらみが小さいが良好であっ
た。実験No.13の太細糸はふくらみを強調する織編物に
は不向きである。The Shibomura of Experiment No. 8 was slightly conspicuous, and some unevenness remained in the final finished fabric. The textures of the fabrics corresponding to the respective temperatures of the heating and stretching rollers are also shown in Table 2. The fabrics of Experiment No. 8 which is a comparative example are poor in a hard texture, and the fabrics of Experiment No. 14 which is a comparative example are bulged. Was too small and bad. Experiment No. 9
The fabric had a slightly hard texture, but was good. The thick yarn of Experiment No. 9 is not suitable for woven and knitted fabrics that emphasize soft texture. The woven fabric of Experiment No. 13 had a small bulge but was good. The thick yarn of Experiment No. 13 is not suitable for woven and knitted fabrics that emphasize the bulge.
実施例3 実施例2の実験No.11の条件の延伸条件を880m/minとし
て延伸、加熱処理し、得られた太細糸を製織、精練、乾
熱セット、アルカリ減量、染色を行った。得られた太細
糸の特性、織物特徴は実験No.15として表2に示した。Example 3 The stretching conditions of Experiment No. 11 of Example 2 were set to 880 m / min and heat-treated, and the obtained thick yarn was woven, scoured, dry-heat set, alkali-reduced and dyed. The characteristics and the fabric characteristics of the obtained thick thin yarn are shown in Table 2 as Experiment No. 15.
風合い霜降り効果は良好であった。パッカリング状のシ
ボムラが微かにあるが実用上使用可能なレベルであっ
た。The texture and marbling effect were good. There was a slight puckering unevenness, but it was at a practically usable level.
比較例1 実施例1で使用した未延伸糸を使用して延伸してから熱
板で加熱処理した。装置としては第2図において加熱延
伸ローラ4を加熱することなく使用し、ローラ4とロー
ラ5の間に25cmの熱板を使用し、熱板入口部にアルミナ
セラミック製のバーガイドを使用した場合と使用しない
場合の両者とした。延伸速度を500/min、加熱ピンを80
℃、延伸倍率を1.52倍とし、加熱処理は表3に示す温
度、緊張率とした。Comparative Example 1 The unstretched yarn used in Example 1 was used for drawing and then heat treated with a hot plate. As the apparatus, in FIG. 2, the heating and stretching roller 4 is used without heating, a 25 cm hot plate is used between the rollers 4 and 5, and a bar guide made of alumina ceramic is used at the hot plate inlet. And both when not used. Drawing speed 500 / min, heating pin 80
C., the draw ratio was 1.52 times, and the heat treatment was carried out at the temperature and strain rate shown in Table 3.
得られた太細糸の特性は表3に示すとおりであり、いず
れも糸長手方向の沸水収縮率バラツキが大きい。実施例
1に準じ製織、精練、乾熱セット、アルカリ減量、染色
を行なった。織物の特徴も表3に示した。精練上りでの
パッカリング状シボムラはいずれも大きく、特にws-cv
%が大きい程顕著であり、いずれの織物も以降の工程で
ムラを消すことができなかった。The characteristics of the obtained thick and thin yarns are as shown in Table 3, and all have large variations in boiling water shrinkage in the yarn longitudinal direction. Weaving, scouring, dry heat setting, alkali weight loss, and dyeing were carried out according to Example 1. The characteristics of the woven fabric are also shown in Table 3. The puckering shibomura after refining is large, especially ws-cv
The larger the percentage, the more remarkable it was, and it was not possible to eliminate unevenness in any of the subsequent steps in any of the fabrics.
比較例2 本比較例では未延伸部がランダムに分布したポリエステ
ル太細糸を本願発明の太細糸と比較する。Comparative Example 2 In this comparative example, a polyester thick yarn in which unstretched portions are randomly distributed is compared with the thick yarn of the present invention.
実施例1で使用した未延伸糸を予熱ロール75℃、加熱板
140℃、延伸倍率1.50倍、延伸速度500m/minで延伸し、
巻取った。The undrawn yarn used in Example 1 was preheated to 75 ° C. with a heating plate.
Stretched at 140 ° C, stretching ratio 1.50 times, stretching speed 500 m / min,
I wound up.
得られた太細糸は各フィラメントに未延伸部がランダム
に分布するもので、本発明の糸太部分、糸細部分はなか
った。U%値は4.2%、沸水収縮率は4.9%であった。In the obtained thick and thin yarn, unstretched portions were randomly distributed in each filament, and neither the thick portion nor the thin portion of the present invention was present. The U% value was 4.2%, and the boiling water shrinkage ratio was 4.9%.
実施例1に準じ製織、精練、乾熱セット、アルカリ減
量、染色を行なったが、精練におけるシボムラ発生が大
きく、仕上織物の風合は良好であったが品位が悪く、染
外観も染濃淡がこなれすぎて霜降り調効果が得られなか
った。Weaving, scouring, dry heat setting, alkali reduction, and dyeing were carried out in accordance with Example 1, but the occurrence of unevenness in the scouring was large, and the finished fabric had a good texture, but the grade was poor and the dyeing appearance was also dyed with light and shade. I didn't get the marbling effect because I was too familiar with it.
第1図は本発明の太細糸形状の模式図、第2図は本発明
で好ましく用いられる製造工程の概略図、第3図は定応
力伸長域伸度を説明するための強力伸長曲線図である。 1:ポリエステル未延伸糸 2:フィードローラ 3:加熱ピン 4:加熱延伸ローラ 5:常温ローラ 6:巻取機 hu:フィラメント太部 ho:フィラメント細部 Hu:糸太部分 Ho:糸細部分FIG. 1 is a schematic diagram of the shape of a thick and thin yarn of the present invention, FIG. 2 is a schematic diagram of a manufacturing process preferably used in the present invention, and FIG. 3 is a strong elongation curve diagram for explaining constant stress elongation zone elongation. Is. 1: Polyester unstretched yarn 2: Feed roller 3: Heating pin 4: Heating stretching roller 5: Room temperature roller 6: Winding machine hu: Filament thick part ho: Filament detail Hu: Thread thick part Ho: Thread thin part
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭57−133233(JP,A) 特開 昭57−171717(JP,A) 特公 昭58−4092(JP,B2) ─────────────────────────────────────────────────── ─── Continuation of the front page (56) Reference JP-A-57-133233 (JP, A) JP-A-57-171717 (JP, A) JP-B-58-4092 (JP, B2)
Claims (2)
する各フィラメントに太細があり、全フィラメントの2/
3以上が太部である部分が少なくとも糸1m当り2コ、全
フィラメントの4/5以上が細部である部分が少なくとも
糸1m当り2コ存在し、マルチフィラメント糸の繊度変動
率U%値が3.1〜11.8%、沸水収縮率が4.2〜19.8%、糸
長手方向の沸水収縮率の変動率が5%以下であるポリエ
ステル太細糸。1. Each of the filaments constituting the polyester multifilament yarn is thick and thin,
There are at least 2 parts per 1 m of yarn with 3 or more thick parts, and at least 2 parts with 4/5 or more of all filaments per minute, and the fineness variation rate U% of multifilament yarn is 3.1. ~ 11.8%, boiling water shrinkage is 4.2 ~ 19.8%, the fluctuation rate of boiling water shrinkage in the longitudinal direction of the yarn is 5% or less polyester thick yarn.
を(1+定応力伸長域伸度×0.6)倍〜(1+定応力伸
長域伸度×1.2)倍の延伸倍率で加熱ピンを用いて延伸
し、加熱延伸ローラ上でTg+20℃〜Tg+60℃(但しTgは
ポリエステル未延伸糸のガラス転移点温度)で加熱処理
後、常温のローラに0.03〜0.4g/dで給糸捲回し、特許請
求の範囲(1)項記載のポリエステル太細糸として巻取
ることを特徴とするポリエステル太細糸の製造方法。2. A polyester multifilament undrawn yarn is drawn with a heating pin at a draw ratio of (1 + constant stress extension zone elongation × 0.6) times to (1 + constant stress extension zone elongation × 1.2) times and heated. After heat treatment at Tg + 20 ° C. to Tg + 60 ° C. (where Tg is the glass transition temperature of the polyester unstretched yarn) on a stretching roller, the yarn is wound at 0.03 to 0.4 g / d on a roller at room temperature, The method for producing a polyester thick and thin yarn, characterized in that the polyester thick and thin yarn is wound up.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58178232A JPH0680207B2 (en) | 1983-09-28 | 1983-09-28 | Polyester thick yarn and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58178232A JPH0680207B2 (en) | 1983-09-28 | 1983-09-28 | Polyester thick yarn and method for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6071712A JPS6071712A (en) | 1985-04-23 |
| JPH0680207B2 true JPH0680207B2 (en) | 1994-10-12 |
Family
ID=16044900
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58178232A Expired - Lifetime JPH0680207B2 (en) | 1983-09-28 | 1983-09-28 | Polyester thick yarn and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0680207B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0726271B2 (en) * | 1985-11-14 | 1995-03-22 | 東洋紡績株式会社 | Polyester multifilament yarn and method for producing the same |
| JPS62133111A (en) * | 1985-12-02 | 1987-06-16 | Teijin Ltd | Polyester uneven yarn |
| JPS62133118A (en) * | 1985-12-04 | 1987-06-16 | Teijin Ltd | Combined polyester slub yarn |
| JPS62133117A (en) * | 1985-12-04 | 1987-06-16 | Teijin Ltd | Antistatic polyester slub yarn |
| JPS62268817A (en) * | 1986-05-15 | 1987-11-21 | Mitsubishi Rayon Co Ltd | Polyester marbled fine filament yarn |
| JPH0682230U (en) * | 1993-05-10 | 1994-11-25 | 利昭 大原 | Partition wall panel |
| JP3686308B2 (en) * | 2000-05-18 | 2005-08-24 | 正子 岡 | Irregular fabric and method for producing the same, irregular fiber product and method for producing the same |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57133233A (en) * | 1981-02-09 | 1982-08-17 | Mitsubishi Rayon Co | Production of polyester special yarn |
| JPS57171717A (en) * | 1981-04-13 | 1982-10-22 | Kuraray Co Ltd | Polyester filament uneven yarn and its production |
| JPS584092A (en) * | 1981-06-26 | 1983-01-11 | 日本国有鉄道 | Hydraulic rock drill |
-
1983
- 1983-09-28 JP JP58178232A patent/JPH0680207B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6071712A (en) | 1985-04-23 |
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