JPH07100332A - High temperature regenerative heating device - Google Patents
High temperature regenerative heating deviceInfo
- Publication number
- JPH07100332A JPH07100332A JP5245407A JP24540793A JPH07100332A JP H07100332 A JPH07100332 A JP H07100332A JP 5245407 A JP5245407 A JP 5245407A JP 24540793 A JP24540793 A JP 24540793A JP H07100332 A JPH07100332 A JP H07100332A
- Authority
- JP
- Japan
- Prior art keywords
- heat storage
- exhaust gas
- combustion exhaust
- denitration
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
Landscapes
- Air Supply (AREA)
- Chimneys And Flues (AREA)
- Treating Waste Gases (AREA)
Abstract
(57)【要約】
【目的】 燃焼排ガスの温度が非常に高温であっても、
脱硝機能を十分に発揮することができる高温用蓄熱式加
熱装置を提供する。
【構成】 加熱部１と、交互に燃焼させて加熱部１に熱
風を供給する２基のバ−ナ−２ａ，２ｂと、燃焼排ガス
中の窒素酸化物を除去する２基の脱硝反応室１６ａ，１
６ｂと、この脱硝反応室に連設された蓄熱部よりなる蓄
熱式加熱装置である。上記蓄熱部が二分されており、脱
硝反応室１６ａ，１６ｂの上流側に上部蓄熱部２０ａ，
２０ｂが設けられ、下流側に下部蓄熱部２１ａ，２１ｂ
が設けられている。脱硝反応室１６ａ，１６ｂに導入さ
れる燃焼排ガスは上部蓄熱部２０ａ，２０ｂで適正の温
度範囲まで冷却されるので、燃焼排ガスの温度が非常な
高温になる場合でも、脱硝機能を十分に発揮する。脱硝
反応後の燃焼排ガスは下部蓄熱部２１ａ，２１ｂで再度
熱回収される。
(57) [Summary] [Purpose] Even if the temperature of combustion exhaust gas is extremely high,
Provided is a high temperature heat storage type heating device capable of sufficiently exerting a denitration function. [Structure] A heating unit 1, two burners-2a and 2b for alternately burning and supplying hot air to the heating unit 1, and two denitration reaction chambers 16a for removing nitrogen oxides in combustion exhaust gas. , 1
6b, and a heat storage type heating device comprising a heat storage section connected to the denitration reaction chamber. The heat storage section is divided into two parts, and the upper heat storage section 20a, 20a is provided upstream of the denitration reaction chambers 16a, 16b.
20b is provided, and lower heat storage units 21a and 21b are provided on the downstream side.
Is provided. The combustion exhaust gas introduced into the denitration reaction chambers 16a and 16b is cooled to an appropriate temperature range in the upper heat storage sections 20a and 20b, so that the denitration function is sufficiently exhibited even when the temperature of the combustion exhaust gas becomes extremely high. . The combustion exhaust gas after the denitration reaction is heat-recovered again in the lower heat storage parts 21a and 21b.
Description
【０００１】[0001]
【産業上の利用分野】本発明は、排ガス中の窒素酸化物
を除去する機能（脱硝機能）を有する蓄熱式加熱装置に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heat storage type heating device having a function of removing nitrogen oxides in exhaust gas (denitration function).
【０００２】[0002]
【従来の技術】脱硝機能を有する蓄熱式加熱装置として
は、実開平３−１２１３０９号公報に開示されたものが
ある。図２はその装置の概念図である。図２において、
１は被加熱物を装入する加熱部であり、この加熱部１に
連設させて、燃料ガス供給管４ａ，４ｂとバ−ナ−タイ
ル３ａ，３ｂからなり、交互に燃焼させる２基のバ−ナ
−２ａ，２ｂが設けられている。そして、バ−ナ−２
ａ，２ｂにそれぞれ連設させて脱硝反応室１６ａ，１６
ｂが設けられており、この脱硝反応室１６ａ，１６ｂに
は、それぞれアンモニア供給配管１８ａ，１８ｂが接続
されている。更に、脱硝反応室１６ａ，１６ｂに連設さ
せてそれぞれセラミックス等の蓄熱体６ａ，６ｂが充填
された蓄熱部５ａ，５ｂが設けられている。2. Description of the Related Art A heat storage type heating device having a denitration function is disclosed in Japanese Utility Model Laid-Open No. 3-121309. FIG. 2 is a conceptual diagram of the device. In FIG.
Reference numeral 1 is a heating section for charging an object to be heated. The heating section 1 is connected to the heating section 1 and is composed of fuel gas supply pipes 4a and 4b and burner tiles 3a and 3b. Burners-2a and 2b are provided. And burner-2
a denitration reaction chambers 16a, 16 connected to a and 2b, respectively.
b is provided, and ammonia supply pipes 18a and 18b are connected to the denitration reaction chambers 16a and 16b, respectively. Further, heat storage parts 5a and 5b are provided so as to be connected to the denitration reaction chambers 16a and 16b and filled with heat storage bodies 6a and 6b such as ceramics, respectively.
【０００３】図中、７は燃料ガスを示し、８ａ、８ｂは
燃料ガスの切替弁である。１７はアンモニアを示し、１
９ａ，１９ｂはアンモニアの切替弁である。９は燃焼用
空気を示し、１０は空気を送り込む経路を変える三方
弁、１１ａ，１１ｂは燃焼用空気ダクトである。そし
て、１４は排ガスを示し、１３は排ガスの排出経路を変
える三方弁、１２ａ，１２ｂは排ガスダクトである。In the figure, 7 is a fuel gas, and 8a and 8b are fuel gas switching valves. 17 is ammonia and 1
9a and 19b are ammonia switching valves. Reference numeral 9 denotes combustion air, 10 is a three-way valve that changes the route for feeding the air, and 11a and 11b are combustion air ducts. Reference numeral 14 denotes exhaust gas, 13 is a three-way valve that changes the exhaust gas discharge path, and 12a and 12b are exhaust gas ducts.
【０００４】バ−ナ−２ａ，２ｂは、燃料ガスの切替弁
８ａ、８ｂを一定時間毎に交互に開閉させることによっ
て、交互燃焼するようになっている。この燃焼中におけ
る各流体は、バ−ナ−２ａで燃焼が行われている場合、
図中に矢印で示す経路を流れる。バ−ナー２ａにおいて
は、切替弁８ａが開にされて燃料ガス供給管４ａに供給
された燃料ガス７が、蓄熱部５ａを通過して高温に予熱
された燃焼用空気９と混合され燃焼する。この際の燃焼
温度は非常に高温になるので、多量の窒素酸化物が発生
する。燃焼ガスは加熱部１へ送られて被加熱物を加熱し
た後、バ−ナ−タイル３ｂを経由して脱硝反応室１６ｂ
へ送り出される。この脱硝反応室１６ｂにおいては、切
替弁１９ｂが開にされてアンモニア１７が供給され、無
触媒脱硝反応が行われる。脱硝反応が終了した燃焼排ガ
スは蓄熱部５ｂに送られ、蓄熱体６ｂを加熱して冷却さ
れる。蓄熱体６ｂによって熱回収された燃焼排ガスは、
排ガスダクト１２ｂから三方弁１３を経て排気される。The burners-2a and 2b are configured to alternately burn by switching the fuel gas switching valves 8a and 8b alternately at regular intervals. Each fluid during this combustion is burned by the burner-2a,
It flows along the path indicated by the arrow in the figure. In the burner 2a, the switching valve 8a is opened and the fuel gas 7 supplied to the fuel gas supply pipe 4a is mixed with the combustion air 9 preheated to a high temperature through the heat storage section 5a and burned. . Since the combustion temperature at this time becomes extremely high, a large amount of nitrogen oxide is generated. The combustion gas is sent to the heating unit 1 to heat the object to be heated, and then passes through the burner tile 3b to remove the denitration reaction chamber 16b.
Sent to. In the denitration reaction chamber 16b, the switching valve 19b is opened and the ammonia 17 is supplied to carry out the non-catalytic denitration reaction. The combustion exhaust gas after the denitration reaction is sent to the heat storage section 5b, and heats the heat storage body 6b to cool it. The combustion exhaust gas whose heat is recovered by the heat storage body 6b is
The exhaust gas is discharged from the exhaust gas duct 12b through the three-way valve 13.
【０００５】バ−ナ−２ｂで燃焼が行われている場合に
おいては、各流体は上述の経路とは逆の方向に流れる。
そして、バ−ナ−２ｂには、蓄熱体６ｂ（バ−ナ−２ａ
で燃焼が行われた際に蓄熱された）によって予熱された
高温の燃焼用空気９が供給され、燃焼が行われる。When the burner-2b is burning, each fluid flows in the direction opposite to the above-mentioned path.
Then, the burner-2b has a heat storage body 6b (burner-2a).
The high-temperature combustion air 9 preheated by the heat is accumulated when the combustion is performed in (1), and the combustion is performed.
【０００６】[0006]
【発明が解決しようとする課題】無触媒脱硝反応におけ
る反応温度と脱硝率の関係は図３の如くであることが知
られている。すなわち、反応温度が約１０００℃を超え
たり、又は約７００℃を下回ると、脱硝率が著しく低下
する。このため、１０００℃を超える温度の燃焼排ガス
又は７００℃未満の温度の燃焼排ガスにおいては、実用
的な脱硝処理を行うことができない。It is known that the relationship between the reaction temperature and the denitration rate in the catalyst-free denitration reaction is as shown in FIG. That is, when the reaction temperature exceeds about 1000 ° C. or falls below about 700 ° C., the denitration rate remarkably decreases. Therefore, a practical denitration treatment cannot be performed on the combustion exhaust gas having a temperature higher than 1000 ° C. or the combustion exhaust gas having a temperature lower than 700 ° C.
【０００７】しかし、上記従来の加熱装置においては、
脱硝反応室１６ａ，１６ｂに導入される燃焼排ガスの温
度は加熱部１における加熱温度（加熱部１内の燃焼ガス
温度）によって一義的に決まってしまうので、加熱装置
の使用条件によっては、脱硝反応室１６ａ，１６ｂに導
入される燃焼排ガスの温度が非常に高温になることもあ
る。そして、燃焼排ガスの温度が約１０００℃を超える
ような場合には、上記従来の加熱装置は脱硝機能を発揮
することができない。従って、このような高温条件で使
用する加熱装置としては、上記従来の加熱装置は適用で
きない。However, in the above conventional heating device,
The temperature of the combustion exhaust gas introduced into the denitration reaction chambers 16a and 16b is uniquely determined by the heating temperature in the heating unit 1 (the combustion gas temperature in the heating unit 1). The temperature of the combustion exhaust gas introduced into the chambers 16a and 16b may become extremely high. When the temperature of the combustion exhaust gas exceeds about 1000 ° C., the conventional heating device cannot exhibit the denitration function. Therefore, the conventional heating device described above cannot be applied as a heating device used under such high temperature conditions.
【０００８】本発明は、燃焼排ガスの温度が非常な高温
になる場合でも、脱硝機能を十分に発揮することができ
る高温用蓄熱式加熱装置を提供することを目的とする。[0008] It is an object of the present invention to provide a high temperature regenerative type heating device capable of sufficiently exhibiting the denitration function even when the temperature of combustion exhaust gas becomes extremely high.
【０００９】[0009]
【課題を解決するための手段及び作用】上記の目的を達
成するために、本発明においては、燃焼排ガスの流れ方
向における脱硝反応室の上流側及び下流側に蓄熱部を設
けている。上記のように、蓄熱部が二分されて、脱硝反
応室の前後（上流側及び下流側）に設けられていると、
燃焼排ガスは加熱部から上流側の蓄熱部（以下、上部蓄
熱部と言う）を経由して脱硝反応室に送られてくるの
で、加熱部から送り出された燃焼排ガスの温度が非常な
高温であっても、燃焼排ガスは蓄熱部を通過する間に蓄
熱体に顕熱を奪われ、その温度が降下する。In order to achieve the above object, in the present invention, heat storage sections are provided on the upstream side and the downstream side of the denitration reaction chamber in the flow direction of combustion exhaust gas. As described above, when the heat storage section is divided into two parts and is provided before and after the denitration reaction chamber (upstream side and downstream side),
The flue gas is sent from the heating section to the denitration reaction chamber via the upstream heat storage section (hereinafter referred to as the upper heat storage section), so the temperature of the flue gas sent out from the heating section is extremely high. However, the combustion exhaust gas is deprived of sensible heat by the heat storage body while passing through the heat storage unit, and the temperature thereof drops.
【００１０】この際、燃焼排ガスの温度を降下させる度
合は蓄熱体の充填量を変えることによって設定すること
ができので、加熱装置の使用条件に基づいて、適量の蓄
熱体を充填すれば、脱硝反応室へ導入する燃焼排ガスの
温度を適正の範囲にすることができる。そして、脱硝反
応させた燃焼排ガスは下流側の蓄熱部（以下、下部蓄熱
部と言う）で十分に熱回収される。At this time, since the degree of lowering the temperature of the combustion exhaust gas can be set by changing the filling amount of the heat storage body, if the proper amount of the heat storage body is filled based on the usage conditions of the heating device, the denitration is performed. The temperature of the combustion exhaust gas introduced into the reaction chamber can be set within an appropriate range. Then, the combustion exhaust gas that has undergone the denitration reaction is sufficiently heat-recovered in the heat storage section on the downstream side (hereinafter referred to as the lower heat storage section).
【００１１】[0011]
【実施例】図１は本考案の一実施例の概念図である。図
１において、図２と同じ構成部分については同一の符号
を付し説明を省略する。本実施例においては、脱硝反応
室１６ａ，１６ｂの前後（燃焼排ガスの流れ方向におけ
る上流側と下流側）にそれぞれ蓄熱部が設けられてい
る。具体的に説明すると、バ−ナ−２ａと脱硝反応室１
６ａとの間及びバ−ナ−２ｂと脱硝反応室１６ｂとの間
にそれぞれ上部蓄熱部２０ａ，２０ｂが設けられてい
る。又、脱硝反応室１６ａ，１６ｂの下流側にもそれぞ
れ下部蓄熱部２１ａ，２１ｂが設けられている。２２
ａ，２２ｂは上部蓄熱部２０ａ，２０ｂに充填されてい
る蓄熱体、２３ａ，２３ｂは下部蓄熱部２１ａ，２１ｂ
に充填されている蓄熱体である。なお、上記脱硝反応室
１６ａ，１６ｂの内容積は、燃焼排ガスの滞留時間が
０．１Nsec（標準状態における燃焼排ガスの滞留時間）
以上になるようにする。DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 is a conceptual diagram of an embodiment of the present invention. In FIG. 1, the same components as those in FIG. 2 are designated by the same reference numerals and the description thereof will be omitted. In this embodiment, heat storage sections are provided in front of and behind the denitration reaction chambers 16a and 16b (upstream side and downstream side in the flow direction of combustion exhaust gas). More specifically, the burner-2a and the denitration reaction chamber 1
6a and between the burner 2b and the denitration reaction chamber 16b are provided with upper heat storage parts 20a and 20b, respectively. Further, lower heat storage units 21a and 21b are provided downstream of the denitration reaction chambers 16a and 16b, respectively. 22
a and 22b are heat storage bodies filled in the upper heat storage units 20a and 20b, and 23a and 23b are lower heat storage units 21a and 21b.
It is a heat storage body filled in. The internal volume of the denitration reaction chambers 16a and 16b is such that the combustion exhaust gas retention time is 0.1 Nsec (combustion exhaust gas retention time in a standard state).
Try to be above.
【００１２】上記のような構成になっている装置におい
ては、燃焼がバーナー３ａで行われている場合、加熱部
１から送り出された燃焼排ガスは、まず、上部蓄熱部２
０ｂに入り、顕熱が奪われて冷却される。上部蓄熱部２
０ｂの出口では、燃焼排ガスの温度は正常な脱硝反応が
行われる領域まで降下する。次いで、冷却された燃焼排
ガスは脱硝反応室１６ｂに導入される。脱硝反応室にお
いては、アンモニア供給配管１８ｂからアンモニア１７
が供給され、燃焼排ガス中の窒素酸化物とアンモニアの
反応が次式のように行われ、燃焼排ガスの脱硝処理がな
される。 ＮＯ＋ＮＨ3 ＋1/4 Ｏ2 ＝Ｎ2 ＋3/2 Ｈ2 ＯIn the apparatus having the above-mentioned structure, when the combustion is carried out by the burner 3a, the combustion exhaust gas sent from the heating section 1 is first of all the upper heat storage section 2
0b enters, sensible heat is taken away and it is cooled. Upper heat storage part 2
At the outlet of 0b, the temperature of the combustion exhaust gas drops to a region where normal denitration reaction is performed. Next, the cooled combustion exhaust gas is introduced into the denitration reaction chamber 16b. In the denitration reaction chamber, the ammonia 17 is supplied from the ammonia supply pipe 18b.
Is supplied, and the reaction of nitrogen oxides and ammonia in the combustion exhaust gas is performed as shown in the following equation, and the denitration treatment of the combustion exhaust gas is performed. NO + NH 3 +1/4 O 2 = N 2 +3/2 H 2 O
【００１３】脱硝処理された燃焼排ガスは、更に下部蓄
熱部２１ｂに送られ、再度蓄熱体によって熱回収され冷
却される。そして、熱回収された燃焼排ガスは、排ガス
ダクト１２ｂから三方弁１３を経て排気される。なお、
図１の実施例においては、加熱部１が被加熱物を装入す
るもの（加熱炉のようなもの）になっているが、加熱部
１が他の構造もの、例えば、ラジアントチュ−ブであっ
ても全く支障がない。The combustion exhaust gas subjected to the denitration process is further sent to the lower heat storage section 21b, where the heat is again recovered and cooled by the heat storage body. Then, the heat-recovered combustion exhaust gas is exhausted from the exhaust gas duct 12b through the three-way valve 13. In addition,
In the embodiment shown in FIG. 1, the heating part 1 is for charging the object to be heated (like a heating furnace), but the heating part 1 has another structure, for example, a radiant tube. There is no problem even if there is.
【００１４】又、図１の実施例においては、脱硝反応室
１６ａ，１６ｂにアンモニア供給配管１８ａ，１８ｂが
接続されている例が挙げられているが、脱硝反応を行わ
せるために供給する物質は、アンモニアに限定されるも
のではなく、アンモニアと同様に燃焼排ガス中の窒素酸
化物と反応してこれを還元しうる水素やメタンなどであ
ってもよい。Further, in the embodiment of FIG. 1, an example in which the ammonia supply pipes 18a and 18b are connected to the denitration reaction chambers 16a and 16b is given, but the substance to be supplied for carrying out the denitration reaction is However, it is not limited to ammonia, but may be hydrogen, methane, or the like that can react with and reduce nitrogen oxides in the combustion exhaust gas like ammonia.
【００１５】次に、図１の加熱装置の実施結果について
説明する。図４は上部蓄熱部と下部蓄熱部の間を流れる
燃焼排ガスの温度変化の一例を示す図である。この例に
おけるバーナー２基の燃焼切替え間隔は３０秒にしたも
のであり、図中、点線（Ａ）はバーナー切替え直後の温
度変化を示し、実線（Ｂ）はバーナー切替え末期（次の
バーナーに切替える直前）の温度変化を示す。バーナー
切替え直後の燃焼ガス（Ａ）は、上部蓄熱部入口では温
度が約１４００℃であったが、上部蓄熱部出口では、そ
の温度が脱硝処理可能領域の下限に近い７００℃付近ま
で冷却され、脱硝反応室へ導入される。Next, the results of implementation of the heating device of FIG. 1 will be described. FIG. 4 is a diagram showing an example of a temperature change of the combustion exhaust gas flowing between the upper heat storage unit and the lower heat storage unit. The combustion switching interval between the two burners in this example is 30 seconds. In the figure, the dotted line (A) shows the temperature change immediately after the burner switching, and the solid line (B) shows the final stage of the burner switching (switch to the next burner). The temperature change immediately before) is shown. The temperature of the combustion gas (A) immediately after the burner was switched was about 1400 ° C at the inlet of the upper heat storage unit, but at the outlet of the upper heat storage unit, the temperature was cooled to around 700 ° C, which is close to the lower limit of the denitrification processable range. It is introduced into the denitration reaction chamber.
【００１６】そして、下部蓄熱部で約１５０℃程度まで
冷却され、放散される。同様に、バーナー切替え末期の
燃焼ガス（Ｂ）は、約１４００℃であった上部蓄熱部入
口の温度が、上部蓄熱部出口では、その温度が脱硝処理
可能領域の上限である１０００℃近傍を超えることなく
冷却され、脱硝反応室へ導入される。その後、下部蓄熱
部で約３００℃程度まで冷却され、放散される。Then, it is cooled to about 150 ° C. in the lower heat storage section and is dissipated. Similarly, the combustion gas (B) at the final stage of burner switching has a temperature of about 1400 ° C. at the inlet of the upper heat storage portion, and at the outlet of the upper heat storage portion, the temperature exceeds about 1000 ° C. which is the upper limit of the denitration processable region. Without cooling, it is introduced into the denitration reaction chamber. After that, it is cooled to about 300 ° C. in the lower heat storage section and is dissipated.
【００１７】図４の例のように、加熱部から送り出され
る燃焼排ガスの温度（上部蓄熱部入口温度）に対し、上
部蓄熱部に充填する蓄熱体が適切な量になっていると、
バーナー切替えによる蓄熱体の温度変化があっても、脱
硝反応室内のガス温度は脱硝処理可能領域内に収まる。As shown in the example of FIG. 4, when the temperature of the combustion exhaust gas sent out from the heating section (upper heat storage section inlet temperature) is an appropriate amount of the heat storage material filled in the upper heat storage section,
Even if the temperature of the regenerator changes due to burner switching, the gas temperature in the denitration reaction chamber falls within the denitration processable region.
【００１８】[0018]
【発明の効果】本発明においては、蓄熱部が二分され、
脱硝反応室の前後（上流側及び下流側）に設けられてお
り、脱硝反応室に導入される燃焼排ガスは上部蓄熱部で
適正の温度範囲まで冷却されるので、燃焼排ガスの温度
が非常な高温になる場合でも、脱硝機能を十分に発揮す
る。又、脱硝反応室の後には下部蓄熱部が設けられてい
るので、脱硝反応後の熱回収も行われ、熱効率を損なう
こともない。According to the present invention, the heat storage section is divided into two,
The combustion exhaust gas is provided before and after the denitration reaction chamber (upstream side and downstream side), and the combustion exhaust gas introduced into the denitration reaction chamber is cooled to an appropriate temperature range in the upper heat storage part, so the temperature of the combustion exhaust gas is extremely high. Even when it becomes, the denitration function is fully exerted. Further, since the lower heat storage section is provided after the denitration reaction chamber, heat recovery after the denitration reaction is also performed, and thermal efficiency is not impaired.
【図１】本発明の一実施例の概念図である。FIG. 1 is a conceptual diagram of an embodiment of the present invention.
【図２】従来の蓄熱式加熱装置の概念図である。FIG. 2 is a conceptual diagram of a conventional heat storage type heating device.
【図３】反応域温度と脱硝率の関係を示す図である。FIG. 3 is a diagram showing a relationship between a reaction zone temperature and a denitration rate.
【図４】上部蓄熱部と下部蓄熱部の間を流れる燃焼排ガ
スの温度変化の一例を示す図である。FIG. 4 is a diagram showing an example of temperature change of combustion exhaust gas flowing between an upper heat storage unit and a lower heat storage unit.
１ 加熱部、 ２ａ，２ｂ バ−ナ− ３ａ，３ｂ バ−ナ−タイル ４ａ，４ｂ 燃料ガス供給管 ７ 燃焼ガス ８ａ，９ｂ，１９ａ，１９ｂ 切替弁 ９ 燃焼用空気 １０，１３ 三方弁 １１ａ，１１ｂ 燃焼用空気ダクト １２ａ，１２ｂ 排ガスダクト １４ 排ガス １６ａ，１６ｂ 脱硝反応室 １７ アンモニア １８ａ，１８ｂ アンモニア供給配管 ２０ａ，２０ｂ 上部蓄熱部 ２１ａ，２１ｂ 下部蓄熱部 ２２ａ，２２ｂ 上部蓄熱部に充填されている蓄熱体 ２３ａ，２３ｂ 下部蓄熱部に充填されている蓄熱体 1 heating part, 2a, 2b burner 3a, 3b burner tile 4a, 4b fuel gas supply pipe 7 combustion gas 8a, 9b, 19a, 19b switching valve 9 combustion air 10, 13 three-way valve 11a, 11b Combustion air duct 12a, 12b Exhaust gas duct 14 Exhaust gas 16a, 16b Denitration reaction chamber 17 Ammonia 18a, 18b Ammonia supply pipe 20a, 20b Upper heat storage section 21a, 21b Lower heat storage section 22a, 22b Heat storage body filled in the upper heat storage section 23a, 23b Heat storage body filled in the lower heat storage section
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｆ２３Ｌ 15/02 7704−3Ｋ Ｆ２３Ｊ 15/00 Ａ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location F23L 15/02 7704-3K F23J 15/00 A
Claims (1)
蓄熱部と、前記燃焼排ガス中の窒素酸化物を除去する脱
硝反応室とが設けられた蓄熱式加熱装置において、前記
燃焼排ガスの流れ方向における前記脱硝反応室の上流側
及び下流側に蓄熱部が設けられていることを特徴とする
高温用蓄熱式加熱装置。1. A heat storage type heating device provided with a heating part, a heat storage part for storing exhaust heat of combustion exhaust gas, and a denitrification reaction chamber for removing nitrogen oxides in the combustion exhaust gas. A heat storage type heating device for high temperature, wherein heat storage parts are provided on the upstream side and the downstream side of the denitration reaction chamber in the flow direction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5245407A JP3064760B2 (en) | 1993-09-30 | 1993-09-30 | High temperature regenerative heating device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5245407A JP3064760B2 (en) | 1993-09-30 | 1993-09-30 | High temperature regenerative heating device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07100332A true JPH07100332A (en) | 1995-04-18 |
| JP3064760B2 JP3064760B2 (en) | 2000-07-12 |
Family
ID=17133199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5245407A Expired - Fee Related JP3064760B2 (en) | 1993-09-30 | 1993-09-30 | High temperature regenerative heating device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3064760B2 (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000325743A (en) * | 1999-01-20 | 2000-11-28 | Basf Ag | Thermal decomposition of N2O |
| JP2005081234A (en) * | 2003-09-08 | 2005-03-31 | Toshiba Corp | Pollutant gas decomposition device and contaminated soil treatment device |
| JP2005265234A (en) * | 2004-03-17 | 2005-09-29 | Babcock Hitachi Kk | Ammonia containing exhaust gas treating device and method |
| JP2013064584A (en) * | 2011-09-16 | 2013-04-11 | Yu Po Lee | Heat recovery system of high-temperature exhaust |
| CN103191639A (en) * | 2013-04-17 | 2013-07-10 | 沈雁军 | Energy-saving emission-reducing denitration process as well as preparation method and application of denitration catalyst |
| CN104524959A (en) * | 2014-12-30 | 2015-04-22 | 北京华泰焦化工程技术有限公司 | Coke oven combustion waste gas denitration system and method |
| CN104772039A (en) * | 2015-04-08 | 2015-07-15 | 北京华泰焦化工程技术有限公司 | Coke oven combustion exhaust denitration system and coke oven combustion exhaust denitration method |
| CN105299687A (en) * | 2015-10-12 | 2016-02-03 | 国家电网公司 | Heat accumulating-type heat exchanger capable of removing dust and nitric oxide in smoke simultaneously |
| CN108131671A (en) * | 2018-02-13 | 2018-06-08 | 项玮 | Denitration heat-accumulating burner used for industrial furnace |
| WO2025264016A1 (en) * | 2024-06-21 | 2025-12-26 | 포스코홀딩스 주식회사 | Ammonia reforming and combustion system using direct heat storage method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3121309U (en) | 2006-02-01 | 2006-05-18 | 有限会社大石製作所 | Disaster prevention article storage pillow |
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1993
- 1993-09-30 JP JP5245407A patent/JP3064760B2/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000325743A (en) * | 1999-01-20 | 2000-11-28 | Basf Ag | Thermal decomposition of N2O |
| JP2005081234A (en) * | 2003-09-08 | 2005-03-31 | Toshiba Corp | Pollutant gas decomposition device and contaminated soil treatment device |
| JP2005265234A (en) * | 2004-03-17 | 2005-09-29 | Babcock Hitachi Kk | Ammonia containing exhaust gas treating device and method |
| JP2013064584A (en) * | 2011-09-16 | 2013-04-11 | Yu Po Lee | Heat recovery system of high-temperature exhaust |
| CN103191639A (en) * | 2013-04-17 | 2013-07-10 | 沈雁军 | Energy-saving emission-reducing denitration process as well as preparation method and application of denitration catalyst |
| CN104524959A (en) * | 2014-12-30 | 2015-04-22 | 北京华泰焦化工程技术有限公司 | Coke oven combustion waste gas denitration system and method |
| CN104772039A (en) * | 2015-04-08 | 2015-07-15 | 北京华泰焦化工程技术有限公司 | Coke oven combustion exhaust denitration system and coke oven combustion exhaust denitration method |
| CN104772039B (en) * | 2015-04-08 | 2017-12-05 | 北京华泰焦化工程技术有限公司 | A kind of coke oven combustion exhaust gas denitration system and method |
| CN105299687A (en) * | 2015-10-12 | 2016-02-03 | 国家电网公司 | Heat accumulating-type heat exchanger capable of removing dust and nitric oxide in smoke simultaneously |
| CN108131671A (en) * | 2018-02-13 | 2018-06-08 | 项玮 | Denitration heat-accumulating burner used for industrial furnace |
| WO2025264016A1 (en) * | 2024-06-21 | 2025-12-26 | 포스코홀딩스 주식회사 | Ammonia reforming and combustion system using direct heat storage method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3064760B2 (en) | 2000-07-12 |
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