JPH07187950A - Oil-in-water type cosmetic - Google Patents
Oil-in-water type cosmeticInfo
- Publication number
- JPH07187950A JPH07187950A JP34791993A JP34791993A JPH07187950A JP H07187950 A JPH07187950 A JP H07187950A JP 34791993 A JP34791993 A JP 34791993A JP 34791993 A JP34791993 A JP 34791993A JP H07187950 A JPH07187950 A JP H07187950A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- oil
- silica
- water
- cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000000843 powder Substances 0.000 claims abstract description 52
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 28
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 18
- 230000000694 effects Effects 0.000 abstract description 12
- 230000002688 persistence Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 16
- 239000000049 pigment Substances 0.000 description 14
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 11
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 10
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 206010040880 Skin irritation Diseases 0.000 description 7
- 230000036556 skin irritation Effects 0.000 description 7
- 231100000475 skin irritation Toxicity 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000010445 mica Substances 0.000 description 6
- 229910052618 mica group Inorganic materials 0.000 description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 239000011162 core material Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 5
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 5
- 230000002045 lasting effect Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000008213 purified water Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 229940058015 1,3-butylene glycol Drugs 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000004606 Fillers/Extenders Substances 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 235000019437 butane-1,3-diol Nutrition 0.000 description 4
- -1 candelilla wax Natural products 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 230000003020 moisturizing effect Effects 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 3
- 239000003974 emollient agent Substances 0.000 description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 229940099259 vaseline Drugs 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 244000020551 Helianthus annuus Species 0.000 description 2
- 235000003222 Helianthus annuus Nutrition 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 229940073609 bismuth oxychloride Drugs 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- KEHCHOCBAJSEKS-UHFFFAOYSA-N iron(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Fe+2] KEHCHOCBAJSEKS-UHFFFAOYSA-N 0.000 description 2
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- 244000247812 Amorphophallus rivieri Species 0.000 description 1
- 235000001206 Amorphophallus rivieri Nutrition 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920002752 Konjac Polymers 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- XLYOFNOQVPJJNP-DYCDLGHISA-N deuterium hydrogen oxide Chemical compound [2H]O XLYOFNOQVPJJNP-DYCDLGHISA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 210000000720 eyelash Anatomy 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000000252 konjac Substances 0.000 description 1
- 235000010485 konjac Nutrition 0.000 description 1
- 238000010303 mechanochemical reaction Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229950011087 perflunafene Drugs 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- UWEYRJFJVCLAGH-IJWZVTFUSA-N perfluorodecalin Chemical compound FC1(F)C(F)(F)C(F)(F)C(F)(F)[C@@]2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)[C@@]21F UWEYRJFJVCLAGH-IJWZVTFUSA-N 0.000 description 1
- YVBBRRALBYAZBM-UHFFFAOYSA-N perfluorooctane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YVBBRRALBYAZBM-UHFFFAOYSA-N 0.000 description 1
- 239000010702 perfluoropolyether Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、伸び広がりが良く、エ
モリエント性、しっとり感等の使用感に優れ、使用性も
簡便で化粧持続性の高い、粉体を含有する水中油型化粧
料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oil-in-water cosmetic containing a powder, which has good spreadability, excellent emollient properties, moisturizing feel, and the like, and is easy to use and has a long duration of makeup. .
【０００２】[0002]
【従来の技術】従来、水中油型の乳化化粧料を調製する
ための乳化剤として、また化粧料中に粉体を分散させる
ときの分散剤、濡れ剤としても各種界面活性剤が配合さ
れてきた。しかし、これらの系では界面活性剤による耐
水性及び耐油性低下による化粧持続性の悪化、べたつき
等が問題となっていた。一方、界面活性剤を用いずに水
と粉体だけの系があったが、これは伸び広がりの悪さ、
きしみ、水が揮発した後、つっぱり感や乾燥感が生じ
る、化粧の持続性に欠ける等の欠点があった。また、水
と油分を乳化せずに混合し粉体を分散させ、使用時に振
り混ぜる化粧料もあったが、これは使用するときに振り
混ぜるという点で使用性が簡便でなく、伸び広がり等の
使用感も必ずしも満足できるものではなかった。2. Description of the Related Art Conventionally, various surfactants have been blended as an emulsifier for preparing an oil-in-water emulsion cosmetic, a dispersant for dispersing powder in the cosmetic, and a wetting agent. . However, in these systems, problems such as deterioration of makeup persistence and stickiness due to reduction of water resistance and oil resistance due to the surfactant have been problems. On the other hand, there was a system of only water and powder without using a surfactant, but this was a
There were drawbacks such as a squeaky feeling, a feeling of dryness after evaporation of water, and lack of durability of makeup. In addition, there were cosmetics in which water and oil were mixed without emulsification and the powder was dispersed and shaken at the time of use, but this is not convenient in terms of shaking when used, and spreads and spreads. The feeling of use was not always satisfactory.
【０００３】[0003]
【発明が解決しようとする課題】上記の欠点を改良する
方法として、アルキル変性カルボキシビニルポリマーを
用いて水に油溶性紫外線吸収剤や粉体を分散させる技術
が開示されている（特開平５ー９７６４４号公報）。し
かしながら、その場合粉体が未処理または疎水化処理さ
れたものでは、少量であれば分散性は良好であるが、多
量の粉体を配合する場合は、分散性が充分ではなかっ
た。そこで、粉体による効果を充分発揮でき、凝集や使
用時の色変わりを生じることのない化粧料が望まれてい
た。As a method for improving the above-mentioned drawbacks, a technique of dispersing an oil-soluble ultraviolet absorber or powder in water using an alkyl-modified carboxyvinyl polymer has been disclosed (Japanese Patent Laid-Open No. Hei. 97644). However, in that case, if the powder was untreated or hydrophobized, the dispersibility was good if it was a small amount, but the dispersibility was not sufficient if a large amount of the powder was blended. Therefore, there has been a demand for a cosmetic that can sufficiently exhibit the effect of powder and does not cause aggregation or color change during use.
【０００４】[0004]
【課題を解決するための手段】本発明者は上記課題を解
決すべく鋭意検討を行った結果、アルキル変性カルボキ
シビニルポリマーを使用する系においてシリカ被覆粉体
を用いると、粉体の分散性が向上し、良好な使用感と簡
便性、化粧持続性を併せ持つことを見い出し、本発明を
完成した。Means for Solving the Problems As a result of intensive studies to solve the above problems, the present inventor has found that when silica-coated powder is used in a system using an alkyl-modified carboxyvinyl polymer, the dispersibility of the powder is improved. The present invention has been completed by finding out that it has improved, good usability, convenience, and durability of makeup.
【０００５】すなわち、本発明は次の成分（ａ）、
（ｂ）、（ｃ）および（ｄ）： （ａ）アルキル変性カルボキシビニルポリマー ０．０１〜３．０重量％ （ｂ）油分 １〜６０重量％ （ｃ）シリカ被覆粉体 １〜４０重量％ （ｄ）水 ３０〜９５重量％ を含有することを特徴とする水中油型化粧料を提供する
ものである。That is, the present invention provides the following component (a),
(B), (c) and (d): (a) Alkyl-modified carboxyvinyl polymer 0.01 to 3.0% by weight (b) Oil content 1 to 60% by weight (c) Silica-coated powder 1 to 40% by weight (D) An oil-in-water cosmetic, which comprises 30 to 95% by weight of water.
【０００６】本発明に用いられるアルキル変性カルボキ
シビニルポリマー（ａ）としては、通常化粧料に用いら
れるもので、特に限定されるものではないが、例えば、
カーボポール１３４２、ペミュレンＴＲＩ、ペミュレン
ＴＲＩＩ（いずれもグッドリッチ社製）として市販され
ているものを使用することができる。必要に応じて、１
種または２種以上を組み合わせて用いることができる。
本発明におけるアルキル変性カルボキシビニルポリマー
の配合量は０．０１〜３．０％、特に０．１〜１．０％
が好ましく、この範囲で用いれば油分及び粉体の分散
性、化粧持続性、系の安定性が良好となる。The alkyl-modified carboxyvinyl polymer (a) used in the present invention is usually used in cosmetics and is not particularly limited.
Commercially available products such as Carbopol 1342, Pemulen TRI, and Pemulen TRII (all manufactured by Goodrich) can be used. 1 as needed
One kind or a combination of two or more kinds can be used.
The amount of the alkyl-modified carboxyvinyl polymer used in the present invention is 0.01 to 3.0%, particularly 0.1 to 1.0%.
When used in this range, the dispersibility of oil and powder, the durability of makeup, and the stability of the system are improved.
【０００７】本発明に用いられる油分（ｂ）としては、
通常化粧料に用いられるものであればいずれでも良く、
例えば、オリーブ油、ヒマシ油等の植物油、ミツロウ、
キャンデリラロウ、木ロウ等のロウ類、流動パラフィ
ン、スクワラン、ワセリン、パラフィンワックス等の炭
化水素、セタノール、ステアリルアルコール、ベヘニル
アルコール等の高級アルコール、パーフルオロポリエー
テル、パーフルオロデカリン、パーフルオロオクタン等
のフッ素系油、グリセリン脂肪酸エステル、トリグリセ
ライド等のエステル油、その他ラノリン、シリコーン油
等を挙げることができる。これら油分の配合量は１〜６
０％が好ましい。１％未満であるとエモリエント等の使
用感、および化粧持続性等の効果が充分得られず、６０
％を超えて配合しても効果の向上は少ない。As the oil component (b) used in the present invention,
As long as it is usually used for cosmetics, any
For example, vegetable oils such as olive oil and castor oil, beeswax,
Waxes such as candelilla wax, wooden wax, hydrocarbons such as liquid paraffin, squalane, vaseline, paraffin wax, higher alcohols such as cetanol, stearyl alcohol, behenyl alcohol, perfluoropolyether, perfluorodecalin, perfluorooctane, etc. Fluorine-based oils, glycerin fatty acid esters, ester oils such as triglyceride, lanolin, silicone oils and the like can be mentioned. The amount of these oil components is 1 to 6
0% is preferable. If it is less than 1%, the feeling of use such as emollient, and the effects such as makeup lasting cannot be sufficiently obtained.
Even if it is mixed in excess of%, the effect is not improved much.
【０００８】本発明に用いられるシリカ被覆粉体（ｃ）
としては、体質顔料、着色顔料等の化粧用粉体を芯材と
しシリカを被覆したものである。本発明でいう化粧用粉
体としては、通常化粧品に用いられるものであればいず
れでも良く、例えば、タルク、マイカ、カオリン、炭酸
マグネシウム、炭酸カルシウム、ケイ酸アルミニウム、
ケイ酸マグネシウム、ケイ酸カルシウム等の体質顔料、
酸化チタン、酸化亜鉛、ベンガラ、黄酸化鉄、黒酸化
鉄、グンジョウ、コンジョウ等の無機着色顔料、タール
色素、天然色素等の有機顔料、雲母チタン、酸化鉄雲母
チタン、オキシ塩化ビスマス等のパール剤、その他ナイ
ロンパウダー、シルクパウダー等の有機粉体が挙げられ
る。必要に応じて、これらの１種または２種以上を組み
合わせて用いることができる。また、これらの粉体は、
シリカ被覆の前に、例えば、アルミナ、酸化ジルコニウ
ム等で予め表面処理したものを使用しても良い。Silica-coated powder (c) used in the present invention
As a core material, a cosmetic powder such as an extender pigment or a coloring pigment is used as a core material and coated with silica. The cosmetic powder referred to in the present invention may be any as long as it is usually used in cosmetics, for example, talc, mica, kaolin, magnesium carbonate, calcium carbonate, aluminum silicate,
Extender pigments such as magnesium silicate and calcium silicate,
Inorganic color pigments such as titanium oxide, zinc oxide, red iron oxide, yellow iron oxide, black iron oxide, sunflower, konjou, tar pigments, organic pigments such as natural pigments, pearl agents such as titanium mica, titanium iron oxide mica titanium and bismuth oxychloride. , And other organic powders such as nylon powder and silk powder. These can be used alone or in combination of two or more, if necessary. Also, these powders
Before silica coating, for example, those which have been surface-treated in advance with alumina, zirconium oxide or the like may be used.
【０００９】被覆処理に用いられるシリカは、結晶性で
も非結晶性でも良い。上記化粧用粉体にシリカを被覆す
る方法は種々あるが、例えば、化粧用粉体の水性懸濁液
に活性なシリカゾルを添加または生成させる方法、化粧
用粉体を芯材としてシリカと湿式または乾式にて混合粉
砕処理するメカノケミカル反応による方法等があげられ
る。また、シリカ被覆粉体を、さらに、シリカの特性を
妨げない範囲でポリアクリル酸等の分散剤で表面処理し
ても良い。The silica used for the coating treatment may be crystalline or amorphous. There are various methods of coating the cosmetic powder with silica, for example, a method of adding or generating an active silica sol to an aqueous suspension of the cosmetic powder, silica as a core material of the cosmetic powder and wet or A method using a mechanochemical reaction in which dry-mixing and pulverization is performed can be used. Further, the silica-coated powder may be surface-treated with a dispersant such as polyacrylic acid as long as the characteristics of silica are not impaired.
【００１０】本発明で用いられる化粧用粉体とシリカの
組成比は、被覆される粉体により任意に選択されるが、
重量比９９：１〜４０：６０が好ましく、更に好ましく
は９５：５〜６０：４０の範囲である。なお、被覆状態
は、部分的でも、完全でもいずれの状態でもよい。シリ
カ被覆粉体の配合量は、１〜４０％が好ましく、更に好
ましくは２〜３５％であり、１％未満では着色力、メー
キャップ効果、化粧持続性等が充分得られず、４０％を
超えると伸び広がり等の使用感が悪くなり、また化粧膜
が厚くなり肌への負担感が高まって好ましくない。The composition ratio of the cosmetic powder and silica used in the present invention is arbitrarily selected depending on the powder to be coated.
The weight ratio is preferably 99: 1 to 40:60, more preferably 95: 5 to 60:40. The covering state may be partial, complete, or any state. The content of the silica-coated powder is preferably 1 to 40%, more preferably 2 to 35%. If it is less than 1%, the coloring power, makeup effect, makeup lasting, etc. cannot be sufficiently obtained, and exceeds 40%. It is not preferable because the feeling of use such as stretching and spreading deteriorates, and the thickness of the cosmetic film increases to increase the burden on the skin.
【００１１】本発明に用いられる水（ｄ）の配合量は、
３０〜９５％が好ましい。The amount of water (d) used in the present invention is
30 to 95% is preferable.
【００１２】本発明の化粧料には、本発明の効果を妨げ
ない範囲で従来の化粧料に使用される香料、防腐剤、保
湿剤、薬効成分、紫外線吸収剤、界面活性剤、乳化安定
剤、水溶性高分子、水膨潤性粘土鉱物、ＰＨ調製剤等を
配合することができる。ただし、べたつき、皮膚刺激性
の観点から通常の界面活性剤は配合しないことが望まし
い。The cosmetics of the present invention include fragrances, preservatives, moisturizers, medicinal ingredients, ultraviolet absorbers, surfactants and emulsion stabilizers used in conventional cosmetics within the range that does not impair the effects of the present invention. , A water-soluble polymer, a water-swelling clay mineral, a PH adjusting agent and the like can be added. However, from the viewpoint of stickiness and skin irritation, it is desirable not to add an ordinary surfactant.
【００１３】[0013]
【実施例】以下に実施例を挙げて更に説明する。なお、
これらは本発明を何ら限定するものではない。[Examples] Examples will be further described below. In addition,
These do not limit the invention in any way.
【００１４】実施例１〜４および比較例１〜２ 表１に示す組成の水中油型化粧料を調製し、粉体分散
性、使用感、化粧膜の自然さについて官能評価を行っ
た。その結果も併せて表１に示す。なお、実施例１〜４
および比較例１〜２はリキッドファンデーションであ
る。Examples 1 to 4 and Comparative Examples 1 to 2 Oil-in-water type cosmetics having the compositions shown in Table 1 were prepared, and sensory evaluations were conducted on the powder dispersibility, the feeling of use, and the naturalness of the cosmetic film. The results are also shown in Table 1. In addition, Examples 1-4
And Comparative Examples 1 and 2 are liquid foundations.
【００１５】[0015]
【表１】 [Table 1]
【００１６】（製法） 実施例１〜４、比較例１〜２ Ａ．（２）〜（４）を加熱する。 Ｂ．（１）、（５）〜（１３）および（１５）を混合分
散し加熱する。 Ｃ．ＡとＢを混合する。 Ｄ．Ｃに（１４）を添加し、中和し、容器に充填して製
品とする。(Production Method) Examples 1 to 4, Comparative Examples 1 to 2 A. (2) to (4) are heated. B. (1), (5) to (13) and (15) are mixed and dispersed and heated. C. Mix A and B. D. (14) is added to C, neutralized, and filled in a container to obtain a product.
【００１７】（評価方法）各評価項目について、１０名
の官能パネルにより下記の７段階（０〜６）の絶対評価
を行い、その平均点をさらに４段階に分けて評価した。(Evaluation Method) For each evaluation item, a sensory panel of 10 people performed the following absolute evaluation of 7 steps (0 to 6), and the average score was further divided into 4 steps for evaluation.
【００１８】（１）絶対評価 ６：非常に良い ５：良い ４：やや良い ３：普通 ２：やや悪い １：悪い ０：非常に悪い （２）４段階評価 ５．０〜６．０：非常に良好：◎ ３．０〜４．９：良好 ：○ １．０〜２．９：やや不良 ：△ ０ 〜０．９：不良 ：×(1) Absolute evaluation 6: Very good 5: Good 4: Fairly good 3: Normal 2: Fairly bad 1: Poor 0: Very bad (2) Four-step evaluation 5.0 to 6.0: Very good Very good: ◎ 3.0 to 4.9: Good: ○ 1.0 to 2.9: Slightly bad: △ 0 to 0.9: Bad: ×
【００１９】表１の結果から明らかなように、本発明品
である実施例１〜４の水中油型化粧料は、比較例１〜２
の水中油型化粧料に比較して、粉体分散性、使用感、化
粧膜の自然さの全ての面で、はるかに優れた特性を有し
ていることが分かる。特に、本発明品は、粉体を多く配
合しても分散性が良く、良好な使用感と簡便性、化粧持
続性を併せ持ち、かつ皮膚に対して刺激が無く、安全性
の高いものが得られた。 一方、未処理の顔料を配合し
た比較例１では粉体の分散性が悪いため、粉体の凝集が
起こり、使用感が悪く、化粧膜の自然さが得られなかっ
た。また、シリカ被覆粉体の配合量の多い比較例２は伸
び広がり等の使用感が悪く、化粧膜が厚くなり自然な膜
は得られなかった。As is clear from the results shown in Table 1, the oil-in-water cosmetics of Examples 1 to 4, which are the products of the present invention, are comparative Examples 1 to 2.
It can be seen that, in comparison with the oil-in-water type cosmetics of No. 1, the powder has far superior properties in all of the powder dispersibility, the feeling of use, and the naturalness of the cosmetic film. In particular, the product of the present invention has good dispersibility even when a large amount of powder is blended, has good usability, convenience, and makeup lasting, and has no irritation to the skin, and is highly safe. Was given. On the other hand, in Comparative Example 1 in which the untreated pigment was blended, the dispersibility of the powder was poor, the powder agglomerated, the usability was bad, and the naturalness of the cosmetic film was not obtained. Further, in Comparative Example 2 in which the silica-coated powder was contained in a large amount, the feeling of use such as stretching and spreading was poor, and the cosmetic film became thick and a natural film could not be obtained.
【００２０】 実施例５ リキッドファンデーション（しっとりタイプ） （処方） 重量％ １ セチルアルコール ０．３ ２ 流動パラフィン ２０ ３ ワセリン １ ４ ミツロウ ２ ５ アルキル変性カルボキビニルポリマー １ ６ 1,3-ブチレングリコール ５ ７ ポリエチレングリコール ５ ８ ２０％シリカ被覆酸化チタン １５ ９ ２０％シリカ被覆ベンガラ １ １０ ２０％シリカ被覆黄酸化鉄 ２．５ １１ ２０％シリカ被覆黒酸化鉄 ０．８ １２ 精製水 残量 １３ 香料 適量 １４ 防腐剤 適量 １５ トリエタノールアミン １Example 5 Liquid Foundation (Moisture Type) (Formulation) 1% Cetyl Alcohol 0.3 2 Liquid Paraffin 20 3 Vaseline 1 4 Beeswax 2 5 Alkyl Modified Carboxyvinyl Polymer 1 6 1,3-Butylene Glycol 5 7 Polyethylene Glycol 5 8 20% Silica-coated titanium oxide 15 9 20% Silica-coated red iron oxide 1 10 20% Silica-coated yellow iron oxide 2.5 11 20% Silica-coated black iron oxide 0.8 12 Purified water Residual amount 13 Perfume proper amount 14 Preservative Appropriate amount 15 Triethanolamine 1
【００２１】（製法） Ａ：１〜５を加熱分散する。 Ｂ：６〜１２を混合し加熱する。 Ｃ：ＡとＢを混合する。 Ｄ：Ｃに１３〜１４を添加後、１５を添加し中和して、
容器に充填し製品とする。(Production Method) A: 1 to 5 are dispersed by heating. B: Mix 6-12 and heat. C: Mix A and B. D: Add 13 to 14 to C, then add 15 to neutralize,
Fill the container into the product.
【００２２】実施例５は、粉体および油分の分散状態が
良好で、肌上での伸び広がりが良く、エモリエント性等
の使用感、メーキャップ効果および化粧持続性に優れ、
皮膚刺激性の無い、しっとりタイプのファンデーション
である。In Example 5, the powder and oil are well dispersed, the spreadability on the skin is good, the feeling of use such as emollient property, the makeup effect and the durability of makeup are excellent.
It is a moisturizing foundation with no skin irritation.
【００２３】 実施例６ リキッドマスカラ （処方） 重量％ １ 固形パラフィン ８ ２ ラノリンワックス ８ ３ イソパラフィン系炭化水素 ３０ ４ ポリアクリル酸エステルエマルション（３０％水溶液） ３０ ５ アルキル変性カルボキシビニルポリマー ０．５ ６ 香料 適量 ７ 防腐剤 適量 ８ ５％シリカ被覆黒酸化鉄 １０ ９ 精製水 残量 １０ トリエタノールアミン ０．４Example 6 Liquid mascara (formulation) wt% 1 solid paraffin 8 2 lanolin wax 8 3 isoparaffin hydrocarbon 30 4 polyacrylic ester emulsion (30% aqueous solution) 30 5 alkyl-modified carboxyvinyl polymer 0.5 6 fragrance Appropriate amount 7 Preservative Appropriate amount 8 5% Silica-coated black iron oxide 10 9 Purified water Remaining amount 10 Triethanolamine 0.4
【００２４】（製法） Ａ：１〜３を加熱する。 Ｂ：４〜９を混合分散し加熱する。 Ｃ：ＡとＢを混合する。 Ｄ：Ｃに１０を加えて中和し、容器に充填して製品とす
る。(Production Method) A: 1 to 3 are heated. B: 4 to 9 are mixed and dispersed and heated. C: Mix A and B. D: Add 10 to C to neutralize, and fill a container to obtain a product.
【００２５】実施例６は、粉体および油分の分散状態が
良好で、肌上での伸び広がりの良い使用感で、メーキャ
ップ効果および耐水性等の化粧持続性に優れ、皮膚刺激
性の無い、マスカラである。Example 6 has a good dispersion state of powder and oil, has a good feeling of extension and spread on the skin, is excellent in make-up effect such as makeup effect and water resistance, and has no skin irritation. It is a mascara.
【００２６】 実施例７ 肌色クリーム （処方） 重量％ １ 流動パラフィン １０ ２ ワセリン １ ３ トリオクタン酸グリセリル ５ ４ 1,3-ブチレングリコール ５ ５ グリセリン ２ ６ アルキル変性カルボキシビニルポリマー ０．３ ７ カルボキシビニルポリマー ０．３ ８ ３０％シリカ被覆酸化チタン ５ ９ ベンガラ ０．３ １０ 黄酸化鉄 ０．６ １１ 黒酸化鉄 ０．１ １２ 精製水 残量 １３ トリエタノールアミン ０．５ １４ 防腐剤 適量 １５ 香料 適量Example 7 Skin Color Cream (Formulation) Weight% 1 Liquid paraffin 10 2 Vaseline 1 3 Glyceryl trioctanoate 5 4 1,3-Butylene glycol 5 5 Glycerin 2 6 Alkyl-modified carboxyvinyl polymer 0.3 7 Carboxyvinyl polymer 0 3 8 30% silica-coated titanium oxide 5 9 red iron oxide 0.3 10 yellow iron oxide 0.6 11 black iron oxide 0.1 12 purified water residual amount 13 triethanolamine 0.5 14 preservative appropriate amount 15 perfume appropriate amount
【００２７】（製法） Ａ：１〜３を加熱する。 Ｂ：４〜１２を混合分散し加熱する。 Ｃ：ＡとＢを混合する。 Ｄ：Ｃに１３を添加し中和する。 Ｅ：Ｄに１４〜１５を添加混合し、容器に充填して製品
とする。(Production Method) A: 1 to 3 are heated. B: 4 to 12 are mixed and dispersed and heated. C: Mix A and B. D: Add 13 to C to neutralize. E: Add 14 to 15 to D, mix, and fill a container to obtain a product.
【００２８】実施例７は、粉体および油分の分散状態が
良好で、肌上での伸び広がりが良く、しっとり感等の使
用感、メーキャップ効果および化粧持続性に優れ、皮膚
刺激性の無い、肌色クリームである。In Example 7, the powder and oil were well dispersed, spread well on the skin, had a feeling of use such as moisturizing feeling, were excellent in makeup effect and makeup lasting, and had no skin irritation. It is a skin color cream.
【００２９】 実施例８ 乳液 （処方） 重量％ １ ＦＯＭＢＬＩＮ ＨＣー０４（モンテフルオス社製） ２０ ２ ５％テフロン処理酸化チタン ２ ３ 1,3-ブチレングリコール １５ ４ アルキル変性カルボキシビニルポリマー ０．３ ５ ４０％シリカ被覆酸化チタン ２ ６ グリセリン ５ ７ 精製水 残量 ８ 香料 適量 ９ トリエタノールアミン ０．３Example 8 Emulsion (Formulation) Weight% 1 FOMBLIN HC-04 (manufactured by Montefluos) 20 2 5% Teflon-treated titanium oxide 2 3 1,3-butylene glycol 15 4 alkyl-modified carboxyvinyl polymer 0.3 5 40 % Silica-coated titanium oxide 2 6 Glycerin 5 7 Purified water Remaining amount 8 Perfume proper amount 9 Triethanolamine 0.3
【００３０】（製法） Ａ：１〜２を混合分散する。 Ｂ：３〜７を混合分散する。 Ｃ：ＡとＢを混合する。 Ｄ：Ｃに８を添加し９を加えて中和し、容器に充填し製
品とする。(Production Method) A: 1 and 2 are mixed and dispersed. B: 3 to 7 are mixed and dispersed. C: Mix A and B. D: Add 8 to C and add 9 to neutralize, and fill a container to obtain a product.
【００３１】実施例８は、粉体および油分の分散状態が
良好で、肌上での伸び広がりが良く、しっとり感等の使
用感および化粧持続性に優れ、皮膚刺激性の無い、乳液
である。Example 8 is a milky lotion in which the powder and oil components are well dispersed, spreads and spreads well on the skin, is excellent in the feeling of use such as moisturizing feeling and the durability of makeup, and has no skin irritation. .
【００３２】[0032]
【発明の効果】本発明の化粧料は、良好な使用感と簡便
性、粉体の分散性、化粧効果及び化粧持続性を併せ持ち
皮膚刺激性の無い優れた水中油型化粧料である。The cosmetic composition of the present invention is an excellent oil-in-water cosmetic composition which has good usability and convenience, dispersibility of powder, cosmetic effect and makeup lasting and has no skin irritation.
【手続補正書】[Procedure amendment]
【提出日】平成６年８月８日[Submission date] August 8, 1994
【手続補正１】[Procedure Amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】０００８[Correction target item name] 0008
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【０００８】本発明に用いられるシリカ被覆粉体（ｃ）
としては、体質顔料、着色顔料等の化粧用粉体を芯材と
しシリカを被覆したものである。本発明でいう化粧用粉
体としては、通常化粧品に用いられるものであればいず
れでも良く、例えば、タルク、マイカ、カオリン、炭酸
マグネシウム、炭酸カルシウム、ケイ酸アルミニウム、
ケイ酸マグネシウム、ケイ酸カルシウム等の体質顔料、
酸化チタン、酸化亜鉛、ベンガラ、黄酸化鉄、黒酸化
鉄、グンジョウ、コンジョウ、酸化チタン・酸化鉄複合
顔料等の無機着色顔料、タール色素、天然色素等の有機
顔料、雲母チタン、酸化鉄雲母チタン、オキシ塩化ビス
マス等のパール剤、その他ナイロンパウダー、シルクパ
ウダー等の有機粉体が挙げられる。必要に応じて、これ
らの１種または２種以上を組み合わせて用いることがで
きる。また、これらの粉体は、シリカ被覆の前に、例え
ば、アルミナ、酸化ジルコニウム等で予め表面処理した
ものを使用しても良い。Silica-coated powder (c) used in the present invention
As a core material, a cosmetic powder such as an extender pigment or a coloring pigment is used as a core material and coated with silica. The cosmetic powder referred to in the present invention may be any as long as it is usually used in cosmetics, for example, talc, mica, kaolin, magnesium carbonate, calcium carbonate, aluminum silicate,
Extender pigments such as magnesium silicate and calcium silicate,
Titanium oxide, zinc oxide, red iron oxide, yellow iron oxide, black iron oxide , sunflower , konjac , titanium oxide / iron oxide composite
Examples thereof include inorganic color pigments such as pigments, tar pigments, organic pigments such as natural pigments, pearl agents such as titanium mica, titanium iron oxide mica and bismuth oxychloride, and organic powders such as nylon powder and silk powder. These can be used alone or in combination of two or more, if necessary. In addition, as these powders, those which have been surface-treated in advance with, for example, alumina, zirconium oxide, etc. before silica coating may be used.
【手続補正２】[Procedure Amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００１７[Correction target item name] 0017
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００１７】（評価方法）各評価項目について、１０名
の官能検査パネルにより下記の７段階（０〜６）の絶対
評価を行い、その平均点をさらに４段階に分けて評価し
た。(Evaluation method) With respect to each evaluation item, a sensory test panel of 10 persons performed the following absolute evaluation of 7 steps (0 to 6), and the average score was further divided into 4 steps for evaluation.
【手続補正３】[Procedure 3]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２５[Name of item to be corrected] 0025
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２５】実施例６は、粉体および油分の分散状態が
良好で、睫上での伸び広がりの良い使用感で、メーキャ
ップ効果および耐水性等の化粧持続性に優れ、皮膚刺激
性の無い、マスカラである。In Example 6, the dispersion state of powder and oil was good, the spreadability on the eyelashes was good, the makeup effect and the durability of makeup such as water resistance were excellent, and there was no skin irritation. It is a mascara.
【手続補正４】[Procedure amendment 4]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２９[Name of item to be corrected] 0029
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２９】 実施例８ 乳液 （処方） 重量％ １ ＦＯＭＢＬＩＮ ＨＣ−０４（モンテフルオス社製） ２０ ２ ５％パーフルオロアルキルリン酸エステルジエタノール アミン処理酸化チタン ２ ３ １，３−ブチレングリコール １５ ４ アルキル変性カルボキシビニルポリマー ０．３ ５ ４０％シリカ被覆酸化チタン ２ ６ グリセリン ５ ７ 精製水 残量 ８ 香料 適量 ９ トリエタノールアミン ０．３[0029] Example 8 emulsion (Formulation) wt% 1 FOMBLIN HC-04 (Montefluos Co.) 20 2 5% perfluoroalkyl phosphoric acid ester diethanol amine oxide treated titanium 2 3 1,3-butylene glycol 15 4 alkyl-modified carboxy Vinyl polymer 0.3 5 40% silica-coated titanium oxide 2 6 Glycerin 5 7 Purified water Remaining amount 8 Perfume proper amount 9 Triethanolamine 0.3
【手続補正５】[Procedure Amendment 5]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００３１[Correction target item name] 0031
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００３１】実施例８は、粉体および油分の分散状態が
良好で、肌上での伸び広がりが良く、しっとり感等の使
用感に優れ、皮膚刺激性の無い、乳液である。Example 8 is a milky lotion in which the powder and oil are well dispersed, the spreadability on the skin is good, the moist feeling and the like are excellent, and the skin is not irritating.
Claims (2)
（ｄ）： （ａ）アルキル変性カルボキシビニルポリマー ０．０１〜３．０重量％ （ｂ）油分 １〜６０重量％ （ｃ）シリカ被覆粉体 １〜４０重量％ （ｄ）水 ３０〜９５重量％ を含有することを特徴とする水中油型化粧料。1. The following components (a), (b), (c) and (d): (a) alkyl-modified carboxyvinyl polymer 0.01 to 3.0% by weight (b) oil 1 to 60% by weight (C) Silica-coated powder 1 to 40% by weight (d) Water 30 to 95% by weight, An oil-in-water type cosmetic composition characterized by the above-mentioned.
用粉体とシリカの組成比が、重量比９９：１〜４０：６
０の範囲であることを特徴とする請求項１記載の水中油
型化粧料。2. The composition ratio of cosmetic powder of the silica-coated powder as the component (c) and silica is 99: 1 to 40: 6 by weight.
The oil-in-water cosmetic composition according to claim 1, which is in a range of 0.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34791993A JP3409194B2 (en) | 1993-12-24 | 1993-12-24 | Oil-in-water cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP34791993A JP3409194B2 (en) | 1993-12-24 | 1993-12-24 | Oil-in-water cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07187950A true JPH07187950A (en) | 1995-07-25 |
| JP3409194B2 JP3409194B2 (en) | 2003-05-26 |
Family
ID=18393504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP34791993A Expired - Lifetime JP3409194B2 (en) | 1993-12-24 | 1993-12-24 | Oil-in-water cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3409194B2 (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0948723A (en) * | 1995-06-01 | 1997-02-18 | Shiseido Co Ltd | Milky lotion like powdery cosmetic material |
| JPH09255529A (en) * | 1996-03-23 | 1997-09-30 | Shiseido Co Ltd | Oil-in-water type emulsion composition |
| JPH1030044A (en) * | 1996-07-15 | 1998-02-03 | Pola Chem Ind Inc | Emulsion composition containing perfluoro-polyether |
| JPH1029920A (en) * | 1996-07-12 | 1998-02-03 | Pola Chem Ind Inc | Protectant against irritation and composition for external use for skin comprising the same |
| JPH11130628A (en) * | 1997-10-28 | 1999-05-18 | Pola Chem Ind Inc | Base cosmetic for summer |
| JPH11246331A (en) * | 1997-12-13 | 1999-09-14 | Kose Corp | Oil-in-water type cosmetic |
| JPH11246351A (en) * | 1998-02-26 | 1999-09-14 | Pola Chem Ind Inc | Naturally-looking visible makeup cosmetic for sensitive skin |
| JP2001172123A (en) * | 1999-12-17 | 2001-06-26 | Pola Chem Ind Inc | Makeup-comes-off protection cosmetic |
| JP2001278772A (en) * | 2000-03-30 | 2001-10-10 | Shiseido Co Ltd | Skin care preparation |
| US6395262B1 (en) | 1996-09-20 | 2002-05-28 | L'oreal | Cosmetic composition comprising a copolymer and utilization of the copolymer in a cosmetic composition |
| JP2002241226A (en) * | 2001-02-15 | 2002-08-28 | Kose Corp | Makeup cosmetic |
| JP2012241002A (en) * | 2011-05-24 | 2012-12-10 | Kao Corp | Make-up cosmetic |
-
1993
- 1993-12-24 JP JP34791993A patent/JP3409194B2/en not_active Expired - Lifetime
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0948723A (en) * | 1995-06-01 | 1997-02-18 | Shiseido Co Ltd | Milky lotion like powdery cosmetic material |
| JPH09255529A (en) * | 1996-03-23 | 1997-09-30 | Shiseido Co Ltd | Oil-in-water type emulsion composition |
| JPH1029920A (en) * | 1996-07-12 | 1998-02-03 | Pola Chem Ind Inc | Protectant against irritation and composition for external use for skin comprising the same |
| JPH1030044A (en) * | 1996-07-15 | 1998-02-03 | Pola Chem Ind Inc | Emulsion composition containing perfluoro-polyether |
| US6395262B1 (en) | 1996-09-20 | 2002-05-28 | L'oreal | Cosmetic composition comprising a copolymer and utilization of the copolymer in a cosmetic composition |
| JPH11130628A (en) * | 1997-10-28 | 1999-05-18 | Pola Chem Ind Inc | Base cosmetic for summer |
| JPH11246331A (en) * | 1997-12-13 | 1999-09-14 | Kose Corp | Oil-in-water type cosmetic |
| JPH11246351A (en) * | 1998-02-26 | 1999-09-14 | Pola Chem Ind Inc | Naturally-looking visible makeup cosmetic for sensitive skin |
| JP2001172123A (en) * | 1999-12-17 | 2001-06-26 | Pola Chem Ind Inc | Makeup-comes-off protection cosmetic |
| JP2001278772A (en) * | 2000-03-30 | 2001-10-10 | Shiseido Co Ltd | Skin care preparation |
| JP2002241226A (en) * | 2001-02-15 | 2002-08-28 | Kose Corp | Makeup cosmetic |
| JP2012241002A (en) * | 2011-05-24 | 2012-12-10 | Kao Corp | Make-up cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3409194B2 (en) | 2003-05-26 |
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