JPH07267761A - Ornamental tile and its production - Google Patents
Ornamental tile and its productionInfo
- Publication number
- JPH07267761A JPH07267761A JP5935094A JP5935094A JPH07267761A JP H07267761 A JPH07267761 A JP H07267761A JP 5935094 A JP5935094 A JP 5935094A JP 5935094 A JP5935094 A JP 5935094A JP H07267761 A JPH07267761 A JP H07267761A
- Authority
- JP
- Japan
- Prior art keywords
- pigments
- ceramic
- pattern
- bodies
- patterns
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000000049 pigment Substances 0.000 claims abstract description 85
- 239000007788 liquid Substances 0.000 claims abstract description 45
- 239000000919 ceramic Substances 0.000 claims abstract description 44
- 239000007787 solid Substances 0.000 claims abstract description 33
- 230000002093 peripheral effect Effects 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 238000010304 firing Methods 0.000 claims abstract description 7
- 239000012466 permeate Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 10
- 239000000758 substrate Substances 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 2
- 239000011148 porous material Substances 0.000 abstract description 10
- 239000003086 colorant Substances 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 7
- 239000002245 particle Substances 0.000 abstract description 3
- -1 metal complex ions Chemical class 0.000 abstract description 2
- 229910021645 metal ion Inorganic materials 0.000 abstract description 2
- 230000000149 penetrating effect Effects 0.000 abstract description 2
- 208000007542 Paresis Diseases 0.000 abstract 1
- 235000015895 biscuits Nutrition 0.000 abstract 1
- 208000012318 pareses Diseases 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
Landscapes
- Finishing Walls (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、タイル等のセラミック
製品の表面に顔料を用いて模様を形成する方法に係り、
審美性に優れた装飾タイルの製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for forming a pattern using a pigment on the surface of a ceramic product such as a tile,
The present invention relates to a method of manufacturing a decorative tile having excellent aesthetics.
【0002】[0002]
【従来の技術】従来、タイル等のセラミック製品の表面
に液体顔料を用いて模様を形成する方法として、特開平
5−43361号公報に記載の形成方法が知られてい
る。これは、タイル等のセラミック素地の表面に、液体
顔料を塗布して浸透させることにより模様部を形成した
後、分散剤溶液を塗布するか、或いは、セラミック素地
の表面の一部又は全部に分散剤溶液を塗布した後、液体
顔料を塗布して浸透させることにより、前記模様部表面
の周縁の一部又は全部を拡散させて、ぼかし模様を形成
する方法である。2. Description of the Related Art Heretofore, as a method for forming a pattern on the surface of a ceramic product such as a tile by using a liquid pigment, a forming method described in JP-A-5-43361 is known. This is done by applying a liquid pigment to the surface of the ceramic base such as tiles to form a pattern, and then applying a dispersant solution or dispersing it on a part or all of the surface of the ceramic base. This is a method in which after applying the agent solution, a liquid pigment is applied and permeated to diffuse a part or all of the peripheral edge of the surface of the pattern portion to form a blurred pattern.
【0003】また、特願平2−41833号公報、及び
特願平1−105647号公報に記載の、液体顔料を使
用した方法が知られている。Further, there are known methods using a liquid pigment described in Japanese Patent Application Nos. 2-41833 and 1-105647.
【0004】図5の(a)は従来例における模様部の平
面図、図5の(b)は同断面図である。この例では、ま
ず中央部に液体顔料を流して深く染み込ませて模様部1
0を形成した後、分散剤溶液を塗布して模様部10の周
縁にぼかし部11を形成する。FIG. 5A is a plan view of a pattern portion in a conventional example, and FIG. 5B is a sectional view of the same. In this example, first, the liquid pigment is poured into the central portion so that the liquid pigment is deeply soaked into the pattern portion 1.
After forming 0, the dispersant solution is applied to form the blur portion 11 on the periphery of the pattern portion 10.
【0005】図6の(a)は従来例における模様中央部
の印刷版の平面図、図6の(b)は図6の(a)の外周
に接する模様周縁部の印刷版の平面図、図6の(c)は
模様中央部と模様周縁部を合成してプリントした模様の
平面図である。この例では、模様中央部12に、例えば
青のインクを通過させて、青色の着色模様を形成する。
次いで、模様周縁部13に、例えば茶色のインクを通過
させて、茶色の着色模様を形成する。FIG. 6 (a) is a plan view of a printing plate in the central portion of the pattern in the conventional example, and FIG. 6 (b) is a plan view of the printing plate in the peripheral portion of the pattern in contact with the outer periphery of FIG. 6 (a). FIG. 6C is a plan view of the pattern printed by combining the central part of the pattern and the peripheral part of the pattern. In this example, for example, blue ink is passed through the pattern central portion 12 to form a blue colored pattern.
Next, for example, brown ink is passed through the pattern peripheral portion 13 to form a brown colored pattern.
【0006】[0006]
【発明が解決しようとする課題】しかし、上記図5にお
ける従来の製造方法においては、タイル等の素地上に液
体顔料を塗布した後に分散剤を塗布するので、周縁部だ
けをぼかすのが困難であるという欠点があった。However, in the conventional manufacturing method shown in FIG. 5, the dispersant is applied after the liquid pigment is applied to the substrate such as tiles, so that it is difficult to blur only the peripheral portion. There was a drawback.
【0007】また、液体顔料の塗布作業と分散剤の塗布
作業を個別に行わなければならない為に、作業に時間を
費やすという欠点があった。Further, since the liquid pigment coating work and the dispersant coating work have to be carried out separately, there is a drawback in that time is spent in the work.
【0008】更に、図6における製造方法においては、
異なる中央部模様の外周と周縁部模様との間に隙間がで
きないように印刷することは熟練を要する。Further, in the manufacturing method shown in FIG.
It requires skill to perform printing so that there is no gap between the outer circumference and the peripheral edge pattern of different central part patterns.
【0009】[0009]
【課題を解決するための手段】本発明の装飾タイルの製
造方法は、液体顔料と固体顔料とを混合したものを、セ
ラミック生素地もしくは締焼素地上に塗布し、焼成する
ことを特徴とする。The method for producing a decorative tile according to the present invention is characterized in that a mixture of a liquid pigment and a solid pigment is applied to a ceramic green body or a fired green body and fired. .
【0010】また、液体顔料と固体顔料とを混合したも
のを、予め釉薬を施したセラミック生素地上に塗布し、
焼成する方法とすることもできる。Further, a mixture of a liquid pigment and a solid pigment is applied to a ceramic raw material pre-glazed,
A method of firing can also be used.
【0011】更に、本発明の装飾タイルは、セラミック
素地表面上の固体顔料からなる凸状模様と、この凸状模
様の真下及び周縁部に拡がり、セラミック素地表面下に
浸透する液体顔料からなる模様とで構成されたことを特
徴とする。Further, the decorative tile of the present invention is a pattern composed of a convex pattern made of a solid pigment on the surface of the ceramic base material, and a liquid pigment spreading right under and the peripheral portion of the convex pattern and penetrating under the surface of the ceramic base material. It is composed of and.
【0012】また、セラミック素地表面上に施された釉
薬と、この釉薬上に固体顔料からなる凸状模様と、この
凸状模様の真下及び周縁部に拡がり、この釉薬及び/又
はセラミック素地表面下に浸透する液体顔料からなる模
様とで構成したものとすることもできる。[0012] Further, the glaze applied on the surface of the ceramic base material, the convex pattern made of solid pigment on the glaze, and spreading right under and the peripheral portion of the convex pattern, the glaze and / or the surface of the ceramic base surface And a pattern made of a liquid pigment that permeates into.
【0013】[0013]
【作用】本発明の装飾タイルの製造方法においては、固
体顔料はセラミック素地の気孔より粒子が大きいため、
セラミック素地内に浸透できず、施釉した模様の範囲内
でセラミック素地上に留まる。それに比べ液体顔料は、
色の基となる金属イオンや金属錯体イオンがセラミック
素地の気孔より小さいため、セラミック素地の気孔を水
分と共に通過し、施釉した模様の周りを囲むように浸透
し、水分がセラミック素地内に吸収されてしまったとこ
ろで移動が停止する。In the method for producing a decorative tile of the present invention, since the solid pigment has larger particles than the pores of the ceramic base,
It cannot penetrate into the ceramic body and stays on the ceramic body within the range of the glazed pattern. Liquid pigments, on the other hand,
Since the metal ions or metal complex ions that are the basis of the color are smaller than the pores of the ceramic base material, they pass through the pores of the ceramic base material together with the water and penetrate to surround the glazed pattern, and the water content is absorbed into the ceramic base material. The movement stops at the place where it is.
【0014】[0014]
【実施例】以下、図面を参照しながら、本発明の特徴
を、実施例に基づいて、具体的に説明する。DESCRIPTION OF THE PREFERRED EMBODIMENTS The features of the present invention will be specifically described below with reference to the drawings based on the embodiments.
【0015】図1は本発明の一実施例の装飾タイルの平
面図、図2は同装飾タイルの断面図である。図におい
て、1はタイル締焼素地であって、表面部1aに固体顔
料と液体顔料を混合したものを塗布すると、液体顔料は
セラミックの気孔に浸透して施釉した模様の範囲外に拡
がった液体顔料部2を形成する。これは、セラミックの
タイル素地1の表面下の模様となっている。また、固体
顔料は、粒子が大きいためにセラミックの気孔に浸透で
きず、施釉した模様の範囲内に顔料が止まって固体顔料
部3を形成する。これは、セラミックのタイル素地1の
表面上の凸状模様となっている。FIG. 1 is a plan view of a decorative tile according to an embodiment of the present invention, and FIG. 2 is a sectional view of the decorative tile. In the figure, reference numeral 1 denotes a tile firing base, and when a mixture of a solid pigment and a liquid pigment is applied to the surface portion 1a, the liquid pigment penetrates into the pores of the ceramic and spreads outside the range of the glazed pattern. The pigment part 2 is formed. This is a pattern below the surface of the ceramic tile base 1. Further, the solid pigment cannot penetrate into the pores of the ceramic due to the large size of the particles, and the pigment stops within the range of the glazed pattern to form the solid pigment portion 3. This is a convex pattern on the surface of the ceramic tile base 1.
【0016】このとき、例えば、濃い青色の固体顔料と
薄い青色の液体顔料を、つまり、同一色の濃淡の顔料を
混合して使用すると、薄い青色の液体顔料はセラミック
の気孔に浸透して模様の周縁部まで拡がり、薄い青色に
ぼかし着色された液体顔料部2を形成する。また、模様
の範囲内には、濃い青色に着色された固体顔料部3が形
成され、1回の施釉作業で、彩色の異なる中央部と周縁
部とを同時に形成できる。即ち、外周ぼかし模様を形成
できる。At this time, for example, when a dark blue solid pigment and a light blue liquid pigment, that is, a mixture of light and dark pigments of the same color are mixed and used, the light blue liquid pigment penetrates into the pores of the ceramic to form a pattern. The liquid pigment portion 2 is spread to the peripheral portion of the liquid pigment 2 and is colored in a faint blue color. Further, the solid pigment portion 3 colored deep blue is formed within the range of the pattern, and the central portion and the peripheral portion having different colors can be simultaneously formed by one glaze operation. That is, it is possible to form a blurred outer peripheral pattern.
【0017】上記の本実施例においては、青色の液体顔
料として、硝酸コバルト53%、糖蜜14%、エタノ−
ル7%、水26%の混合物を用いた。また、青色の固体
顔料としては、酸化コバルト系固体顔料5%、粘土5
%、釉薬用フリット90%を混合したものを用いた。こ
の液体顔料と固体顔料とを混合したものをセラミックの
素地上に印刷し、更に釉薬を塗布し焼成すると、周縁部
がぼかし模様の青色模様が得られた。In the above embodiment, as the blue liquid pigment, cobalt nitrate 53%, molasses 14%, ethanol
A mixture of 7% water and 26% water was used. Further, as the blue solid pigment, 5% of cobalt oxide type solid pigment and 5% of clay
%, And a mixture of 90% glaze frit was used. When a mixture of the liquid pigment and the solid pigment was printed on a ceramic substrate, and a glaze was applied and fired, a blue pattern with a blurred peripheral edge was obtained.
【0018】この様に、焼成後の発色を基本とした同系
色の固体顔料と液体顔料を混合して使用すると、薄い色
の液体顔料はセラミックの気孔に浸透して模様の周縁部
まで拡がり、薄い色にぼかし着色されたぼかし模様が得
られる。As described above, when a solid pigment of a similar color based on the color developed after firing and a liquid pigment are mixed and used, the liquid pigment of a light color penetrates into the pores of the ceramic and spreads to the peripheral portion of the pattern, A blur pattern colored in a light color is obtained.
【0019】さらに、異なった色の固体顔料と液体顔料
を混合して使用すると、1回の施釉作業で、2色に彩色
された二色重ね模様が得られる。また、異なった色の固
体顔料や液体顔料を混合使用し、これを斑点状に施釉す
れば、審美性に優れた組合せ模様を得ることができる。Further, when solid pigments and liquid pigments of different colors are mixed and used, a two-color overlapping pattern colored in two colors can be obtained by one glaze operation. Also, by mixing and using solid pigments or liquid pigments of different colors and glazing them in spots, it is possible to obtain a combination pattern with excellent aesthetics.
【0020】図3は、本発明の他の実施例を示す印刷版
の平面図、図4は、同プリントの平面図である。図にお
いて、酸化鉄系の茶色の固体顔料と上記硝酸コバルト等
の混合物からなる青色の液体顔料とを混合し、白色の釉
薬を塗布された1枚のセラミックの印刷版4にロ−ル印
刷施釉を行えば、茶色の固体顔料部5は模様のロール印
刷をした範囲内に収まって着色され、青色の液体顔料は
白色の釉薬及び/又はセラミックの気孔に浸透して印刷
施釉した模様の周縁部に拡がって液体顔料部6が形成さ
れ、審美性の極めて優れた色相の模様が得られた。FIG. 3 is a plan view of a printing plate showing another embodiment of the present invention, and FIG. 4 is a plan view of the print. In the figure, an iron oxide-based brown solid pigment is mixed with a blue liquid pigment composed of a mixture of cobalt nitrate or the like, and roll-applied glaze is applied to one ceramic printing plate 4 coated with white glaze. By doing so, the brown solid pigment portion 5 is colored within the range where the pattern is roll-printed, and the blue liquid pigment penetrates into the white glaze and / or the pores of the ceramic and the peripheral portion of the printed glaze pattern. The liquid pigment portion 6 was spread over the surface, and a pattern with a hue having an extremely excellent aesthetic appearance was obtained.
【0021】なお、固定顔料と液体顔料の顔料の添加量
又は素地の含水率を調整することで、液体顔料の拡散範
囲を調節すれば、所望の範囲内で模様形成の操作が可能
となる。If the diffusion range of the liquid pigment is adjusted by adjusting the addition amount of the fixed pigment and the liquid pigment or the water content of the substrate, the pattern forming operation can be performed within a desired range.
【0022】[0022]
【発明の効果】以上説明したように、本発明によれば、
液体顔料と固体顔料との混合物を、セラミック生素地又
は締焼素地上に塗布し焼成することで、一度の施釉作業
で、固体顔料の外周周縁部に液体顔料の模様を同時に現
出させることができ、外周ぼかし模様や異なる色系の顔
料の2色の境界線をきれいに分けた重ね着色模様が労せ
ずして形成可能となり、作業性の向上が図れる。As described above, according to the present invention,
By applying a mixture of a liquid pigment and a solid pigment onto a ceramic green body or a sinter-fired body and firing it, the pattern of the liquid pigment can be simultaneously displayed on the outer peripheral edge of the solid pigment with one glaze operation. Therefore, it is possible to easily form an outer peripheral blurring pattern or a superposed colored pattern in which the boundary lines of two colors of pigments of different colors are neatly separated, and workability can be improved.
【0023】また、得られたタイルは、固体顔料を使用
した部分がセラミック素地上に突出して模様を形成し、
その外周周縁部は液体顔料がセラミック素地下に浸透し
て模様を形成した、遠近感のある特異な質感模様を有す
るものとなる。Further, in the obtained tile, a portion using the solid pigment is projected on the ceramic base material to form a pattern,
The outer peripheral edge portion has a peculiar texture pattern with a perspective, in which the liquid pigment penetrates into the ceramic basement to form a pattern.
【0024】更に、予め釉薬を施したセラミック素地上
に、液体顔料と固体顔料との混合物を塗布し焼成するこ
とで、下地釉薬の上に固体顔料が定着すると共に、液体
顔料が下地釉薬及び/又はセラミック素地表面下に浸透
し、深みのある審美的模様を現出させることができる。Furthermore, by applying a mixture of a liquid pigment and a solid pigment to a ceramic base which has been previously applied with a glaze, and baking the mixture, the solid pigment is fixed on the base glaze and the liquid pigment is mixed with the base glaze and / or Alternatively, it can penetrate below the surface of the ceramic base material to reveal a deep aesthetic pattern.
【図1】 本発明の一実施例の装飾タイルの平面図であ
る。FIG. 1 is a plan view of a decorative tile according to an embodiment of the present invention.
【図2】 同装飾タイルの断面図である。FIG. 2 is a cross-sectional view of the decorative tile.
【図3】 本発明の他の実施例を示す印刷版の平面図で
ある。FIG. 3 is a plan view of a printing plate showing another embodiment of the present invention.
【図4】 同プリントの平面図である。FIG. 4 is a plan view of the same print.
【図5】 従来例であって、同図の(a)は模様部の平
面図、同図の(b)はその断面図である。FIG. 5 is a conventional example, in which FIG. 5A is a plan view of a pattern portion, and FIG. 5B is a sectional view thereof.
【図6】 別の従来例であって、同図の(a)は模様中
央部の印刷版の平面図、同図の(b)は模様周縁部の印
刷版の平面図、同図の(c)は模様中央部と模様周縁部
を合成してプリントした模様の平面図である。FIG. 6 is another conventional example, in which FIG. 6A is a plan view of a printing plate in the central portion of the pattern, FIG. 6B is a plan view of a printing plate in the peripheral portion of the pattern, and FIG. FIG. 3C is a plan view of a pattern in which the central portion of the pattern and the peripheral portion of the pattern are combined and printed.
1:タイル素地 1a:表面部 2:液体顔料部 3:
固体顔料部 4:印刷版 5:固体顔料部 6:液体顔
料部 10:模様部 11:ぼかし部 12:模様中央
部 13:模様周縁部1: Tile base 1a: Surface part 2: Liquid pigment part 3:
Solid pigment part 4: Printing plate 5: Solid pigment part 6: Liquid pigment part 10: Pattern part 11: Shading part 12: Pattern central part 13: Pattern peripheral part
Claims (4)
を、セラミック生素地もしくは締焼素地上に塗布し、焼
成する装飾タイルの製造方法。1. A method for producing a decorative tile, which comprises applying a mixture of a liquid pigment and a solid pigment to a ceramic green body or a fired green body and firing the mixture.
を、予め釉薬を施したセラミック生素地上に塗布し、焼
成する装飾体の製造方法。2. A method for producing a decorative body, which comprises applying a mixture of a liquid pigment and a solid pigment to a ceramic raw material which has been previously glazeed, and firing the mixture.
る凸状模様と、この凸状模様の真下及び周縁部に拡が
り、セラミック素地表面下に浸透する液体顔料からなる
模様とで構成された装飾タイル。3. A decorative tile comprising a convex pattern made of a solid pigment on the surface of a ceramic substrate and a pattern made of a liquid pigment that spreads immediately below and around the peripheral edge of the convex pattern and permeates under the surface of the ceramic substrate. .
と、この釉薬上に固体顔料からなる凸状模様と、この凸
状模様の真下及び周縁部に拡がり、この釉薬及び/又は
セラミック素地表面下に浸透する液体顔料からなる模様
とで構成された装飾タイル。4. A glaze applied on the surface of a ceramic base material, a convex pattern composed of a solid pigment on the glaze, and a glaze and / or a peripheral part of the convex pattern, which are spread under the glaze and / or the surface of the ceramic base material. A decorative tile composed of a pattern made of liquid pigment that permeates into.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5935094A JPH07267761A (en) | 1994-03-29 | 1994-03-29 | Ornamental tile and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5935094A JPH07267761A (en) | 1994-03-29 | 1994-03-29 | Ornamental tile and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07267761A true JPH07267761A (en) | 1995-10-17 |
Family
ID=13110754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5935094A Pending JPH07267761A (en) | 1994-03-29 | 1994-03-29 | Ornamental tile and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07267761A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006219311A (en) * | 2005-02-08 | 2006-08-24 | Inax Corp | Decorative tile and method for manufacturing the same |
| CN108059486A (en) * | 2017-12-11 | 2018-05-22 | 蒙娜丽莎集团股份有限公司 | Colored Imitation Rock Porcelain Tiles and its manufacturing method and equipment are oozed in a kind of consistent ink-jet of bottom surface texture |
| CN113786043A (en) * | 2021-09-15 | 2021-12-14 | 广东顺德周大福珠宝制造有限公司 | Jewelry and surface treatment method thereof |
-
1994
- 1994-03-29 JP JP5935094A patent/JPH07267761A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006219311A (en) * | 2005-02-08 | 2006-08-24 | Inax Corp | Decorative tile and method for manufacturing the same |
| CN108059486A (en) * | 2017-12-11 | 2018-05-22 | 蒙娜丽莎集团股份有限公司 | Colored Imitation Rock Porcelain Tiles and its manufacturing method and equipment are oozed in a kind of consistent ink-jet of bottom surface texture |
| CN113786043A (en) * | 2021-09-15 | 2021-12-14 | 广东顺德周大福珠宝制造有限公司 | Jewelry and surface treatment method thereof |
| CN113786043B (en) * | 2021-09-15 | 2023-02-21 | 广东顺德周大福珠宝制造有限公司 | Jewelry and surface treatment method thereof |
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