JPH072795B2 - Magnesium halide for transition metal catalyst carrier - Google Patents
Magnesium halide for transition metal catalyst carrierInfo
- Publication number
- JPH072795B2 JPH072795B2 JP62000114A JP11487A JPH072795B2 JP H072795 B2 JPH072795 B2 JP H072795B2 JP 62000114 A JP62000114 A JP 62000114A JP 11487 A JP11487 A JP 11487A JP H072795 B2 JPH072795 B2 JP H072795B2
- Authority
- JP
- Japan
- Prior art keywords
- transition metal
- metal catalyst
- magnesium halide
- catalyst carrier
- carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 Magnesium halide Chemical class 0.000 title claims description 22
- 239000003054 catalyst Substances 0.000 title claims description 20
- 239000011777 magnesium Substances 0.000 title claims description 18
- 229910052749 magnesium Inorganic materials 0.000 title claims description 17
- 229910052723 transition metal Inorganic materials 0.000 title claims description 17
- 150000003624 transition metals Chemical class 0.000 title claims description 17
- 150000001336 alkenes Chemical class 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 9
- 238000002441 X-ray diffraction Methods 0.000 claims description 8
- SGZHLLQPCVCEDC-UHFFFAOYSA-L magnesium;bromide;chloride Chemical compound Cl[Mg]Br SGZHLLQPCVCEDC-UHFFFAOYSA-L 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 25
- 239000010936 titanium Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
- 239000007818 Grignard reagent Substances 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000004795 grignard reagents Chemical class 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical group C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- KLWZLMKMCYTORE-UHFFFAOYSA-N cyclohexane;hydrobromide Chemical compound Br.C1CCCCC1 KLWZLMKMCYTORE-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明はオレフィンの重合用遷移金属触媒担体用の新規
なハロゲン化マグネシウムに関する。詳しくは特定のＸ
線回折線を有する結晶性のハロゲン化マグネシウムから
なるオレフィン重合用遷移金属触媒担体用ハロゲン化マ
グネシウムに関する。The present invention relates to a novel magnesium halide for a transition metal catalyst carrier for olefin polymerization. See specific X
The present invention relates to a magnesium halide for a transition metal catalyst carrier for olefin polymerization, which comprises crystalline magnesium halide having a line diffraction line.
オレフィンの重合用にハロゲン化マグネシウムなどの担
体にハロゲン化チタンを担持してなる遷移金属触媒と有
機金属化合物からなる触媒を用いることは特公昭39−11
2105号で開示されて以来、種々の改良方法が提案されて
おり、優れた性能のものも知られている。It is disclosed in Japanese Examined Patent Publication No. 39-11 that a transition metal catalyst in which a titanium halide is supported on a carrier such as magnesium halide and a catalyst composed of an organometallic compound are used for the polymerization of olefins.
Since the disclosure in No. 2105, various improved methods have been proposed, and those having excellent performance are also known.
上記改良方法は主として担体を得るに際して添加物を加
えて粉砕したり、或るいは担体として用いるハロゲン化
マグネシウムを溶剤に溶解せしめ次いで析出させること
により、遷移金属を担持してオレフィン重合用の触媒と
した時、優れた性能のものとなるように、担体をＸ線回
折によって測定された回折線が明確なピークを持たずハ
ロ−として観測されるようになるように処理することが
行われている。特に、溶解し、次いで析出する方法は優
れており、高活性の触媒を製造することが出来る（例え
ば、特開昭56−11908）。しかしながらこの方法は析出
剤を多量に必要とする上に繰り返しハロゲン化チタンで
処理しないと良好な活性のものが得られないという問題
がある。又、添加物を加えて粉砕する方法は、再現性良
く優れた性能の触媒を与えるのが困難である。The above improving method is mainly to add a crusher to obtain a carrier and grind it, or dissolve magnesium halide used as a carrier in a solvent and then precipitate it to carry a transition metal and to form a catalyst for olefin polymerization. In order to obtain excellent performance, the carrier is treated so that the diffraction line measured by X-ray diffraction has no clear peak and is observed as halo-. . In particular, the method of dissolving and then precipitating is excellent, and a highly active catalyst can be produced (for example, JP-A-56-11908). However, this method has a problem that a large amount of a precipitant is required and that a product having good activity cannot be obtained unless it is repeatedly treated with titanium halide. Further, it is difficult to provide a catalyst with excellent reproducibility and excellent performance by the method of adding additives and pulverizing.
本発明者はこれらの問題を解決した新規な遷移金属触媒
担体用ハロゲン化マグネシウムついて鋭意検討したとこ
ろ、特定の結晶性の回折線を与えるハロゲン化マグネシ
ウムがオレフィン重合用遷移金属触媒担体用として極め
て優れていることを見出し本発明を完成した。The inventors of the present invention have made extensive studies on a novel magnesium halide for a transition metal catalyst carrier which has solved these problems, and a magnesium halide giving a diffraction line of specific crystallinity is extremely excellent for a transition metal catalyst carrier for olefin polymerization. Therefore, the present invention has been completed.
即ち、本発明はＸ線回折によって測定された回折線とし
て7.38Å付近に最大強度を有し7.98、5.32、3.57、3.4
7、3.26、2.90Å付近に比較的強い回折線を与える結晶
性のMgBrClからなるオレフィン重合用遷移金属触媒担体
用ハロゲン化マグネシウムである。That is, the present invention has a maximum intensity near 7.38Å as a diffraction line measured by X-ray diffraction and is 7.98, 5.32, 3.57, 3.4.
It is a magnesium halide for a transition metal catalyst carrier for olefin polymerization, which is composed of crystalline MgBrCl which gives a relatively strong diffraction line in the vicinity of 7, 3.26 and 2.90Å.
本発明において、ハロゲン化マグネシウムとしては、そ
のＸ線回折スペクトルが特定のところ、即ち、7.38Å付
近に最大強度を有し、7.98、5.32、3.57、3.26、2.90Å
付近に比較的強い回折線を有するものであるかぎり特に
その製法に制限はないが例えば次のような製法が例示で
きる。In the present invention, as the magnesium halide, its X-ray diffraction spectrum has a specific intensity, that is, it has a maximum intensity in the vicinity of 7.38Å, 7.98, 5.32, 3.57, 3.26, 2.90Å
The manufacturing method is not particularly limited as long as it has a relatively strong diffraction line in the vicinity, but the following manufacturing method can be exemplified.
一般式R1MgBr（式中、R1は炭化水素残基である。）で表
わされるグリニャール試薬（このグリニャール試薬は、
良く知られているようにR1Brであらわされる臭素化炭化
水素化合物と金属マグネシウムをエーテル等の存在下に
反応せしめることで得られる。）と一般式R2Cl（式中、
R2は炭化水素残基である。）であらわされる塩素化炭化
水素化合物を反応せしめることにより、容易に上に定義
した結晶性のMgBrClがえられる。。ここで上述の臭化炭
化水素化合物、塩素化炭化水素化合物の炭化水素残基と
しては脂肪族、脂環族、芳香族炭化水素残基等のどのよ
うなものでも良く、特に制限はないが、炭素数１〜20度
のものを用いるのが一般的である。The Grignard reagent represented by the general formula R 1 MgBr (wherein R 1 is a hydrocarbon residue) (this Grignard reagent is
As is well known, it can be obtained by reacting a brominated hydrocarbon compound represented by R 1 Br with metallic magnesium in the presence of ether or the like. ) And the general formula R 2 Cl (where
R 2 is a hydrocarbon residue. By reacting a chlorinated hydrocarbon compound represented by (1), crystalline MgBrCl defined above can be easily obtained. . Here, the above-mentioned brominated hydrocarbon compound, the hydrocarbon residue of the chlorinated hydrocarbon compound may be any of aliphatic, alicyclic, aromatic hydrocarbon residues, etc., but is not particularly limited, It is common to use one having 1 to 20 carbon atoms.
グリニャール試薬と塩素化炭化水素化合物の反応は通常
媒体として用いたエーテル類の沸点で行えば充分に反応
は進行する。反応が進行するとMgBrClは媒体に不溶化し
析出してくるので濾過、或いは静置分離することで容易
にとりだすことができる。ここで、MgBrClとしては組成
が正確に1:1:1である必要はなく、そのＸ線回折スクト
ルが上述の条件を満足すればよい。The reaction between the Grignard reagent and the chlorinated hydrocarbon compound proceeds sufficiently if it is carried out at the boiling point of the ether used as a medium. As the reaction proceeds, MgBrCl becomes insoluble and precipitates in the medium, and can be easily taken out by filtration or static separation. Here, the composition of MgBrCl does not need to be exactly 1: 1: 1 as long as the X-ray diffraction screen satisfies the above conditions.
こうして得られたMgBrClを遷移金属触媒用の担体として
用いる方法としては特に制限はないが、例えば液状のハ
ロゲン化チタンで処理することでオレフィン重合用の遷
移金属触媒とされる。ここで用いるハロゲン化チタンと
しては、好ましくは四塩化チタン、或いはエーテル等で
炭化水素溶剤に可溶化した三塩化チタン、さらには上記
チタン化合物の塩素の一部をアルコキシ基としたもの
（例えば、メトキシ、エトキシ、プロポキシ、ブトキ
シ、ペンチルオキシ等）が例示される。The method of using the MgBrCl thus obtained as a carrier for a transition metal catalyst is not particularly limited, but a transition metal catalyst for olefin polymerization can be obtained, for example, by treating with liquid titanium halide. The titanium halide used here is preferably titanium tetrachloride, or titanium trichloride solubilized in a hydrocarbon solvent with ether or the like, and further, one in which a part of chlorine of the titanium compound is an alkoxy group (for example, methoxy). , Ethoxy, propoxy, butoxy, pentyloxy and the like).
具体的には、液状のハロゲン化チタンに単に上述のMgBr
Clを分散し撹拌することで行われる。接触処理の際の温
度としては通常、常温ないし200℃である。Specifically, the above-mentioned MgBr was simply added to liquid titanium halide.
It is performed by dispersing Cl and stirring. The temperature during the contact treatment is usually room temperature to 200 ° C.
また、接触処理の際に、エーテル、エステル、アルコキ
シシランなどの含酸素有機化合物等の電子供与性化合物
を存在させることもできる。Further, during the contact treatment, an electron donating compound such as an oxygen-containing organic compound such as ether, ester or alkoxysilane can be present.
本発明のハロゲン化マグネシウムを用いて得られた遷移
金属触媒を用いて重合できるオレフィンとしてはエチレ
ン、プロピレン、ブテン−１、ペンテン−１、ヘキセン
−１、オクテン−１、スチレン、ビニルナフタレンなど
が例示され、それらの単独重合或いは相互の共重合さら
にはジエンとの共重合などに用いられる。Examples of the olefin that can be polymerized by using the transition metal catalyst obtained by using the magnesium halide of the present invention include ethylene, propylene, butene-1, pentene-1, hexene-1, octene-1, styrene and vinylnaphthalene. They are used for homopolymerization or mutual copolymerization thereof, and further for copolymerization with a diene.
以下、実施例を挙げ本発明を説明する。 Hereinafter, the present invention will be described with reference to examples.
実施例１ 300mlの丸底フラスコにマグネシウム7.4g、ジエチルエ
ーテル20ml入れ、エーテルの還流下に臭化シクロヘキサ
ン50gとジエチルエーテル50mlの混合物を２時間かけて
滴下した。その後さらに１時間還流下撹拌処理し、C6H
11MgBrのジエチルエーテル溶液を調製した。Example 1 A 300 ml round bottom flask was charged with 7.4 g of magnesium and 20 ml of diethyl ether, and a mixture of 50 g of cyclohexane bromide and 50 ml of diethyl ether was added dropwise over 2 hours under reflux of ether. After that, the mixture is further stirred for 1 hour under reflux and C 6 H
A solution of 11 MgBr in diethyl ether was prepared.
次いでジエチルエーテルの還流下に四塩化炭素15gを４
時間かけて加え、更に還流下に２時間撹拌した。Then, under reflux of diethyl ether, 4 g of carbon tetrachloride (15 g) was added.
The mixture was added over time, and the mixture was further stirred under reflux for 2 hours.
次い室温でろ過し、固形分をジエチルエーテル洗浄し、
窒素気流で乾燥して、固形分40gを得た。得られた固形
分はMg:Cl:Brがほぼ1:1:1であり、MgBrClであった。ま
たＸ線回折の測定結果を第１図に示す。Next, it is filtered at room temperature, the solid content is washed with diethyl ether,
It was dried with a nitrogen stream to obtain a solid content of 40 g. The resulting solids were MgBrCl with Mg: Cl: Br approximately 1: 1: 1. The measurement results of X-ray diffraction are shown in FIG.
上記固形分10gを200mlの丸底フラスコに入れ、四塩化チ
タン50ml、トルエン50mlを入れ、90℃で１時間撹拌処理
し、次いで静置して上澄を除去した。さらに四塩化チタ
ン50ml、トルエン50mlを入れ、90℃で１時間撹拌処理
し、次いで静置して上澄を除去し、得られた固形分をト
ルエンで７回洗浄して遷移金属触媒とした。分析の結果
はチタンを1.9wt％含有していた。10 g of the above solid content was placed in a 200 ml round bottom flask, 50 ml of titanium tetrachloride and 50 ml of toluene were placed therein, and the mixture was stirred at 90 ° C. for 1 hour and then left to stand to remove the supernatant. Further, 50 ml of titanium tetrachloride and 50 ml of toluene were added, and the mixture was stirred at 90 ° C. for 1 hour, then left standing to remove the supernatant, and the obtained solid content was washed 7 times with toluene to obtain a transition metal catalyst. As a result of the analysis, titanium was contained at 1.9 wt%.
上記操作で得た遷移金属触媒を用いてエチレンを重合し
た。内容積２のオートクレーブにｎ−ヘプタン１入
れ、上記遷移金属触媒20mg、トリエチルアルミニウム0.
5mlを加え、水素を2Kg/cm2ゲージまで入れ、さらにエチ
レンを6Kg/cm2ゲージまで加えた後75℃に昇温し、10Kg/
cm2ゲージになるようにエチレンを追加しながら75℃で
２時間重合した。その後冷却し、未反応のエチレンをパ
ージした後ろ過して、ポリエチレンパウダーを得た。乾
燥秤量したところ360gであった。このパウダーの極限粘
度数は2.56（135℃テトラリン溶液で測定した。）、か
さ比重は0.48、粘度は200メッシュ以下の微粉4.5％、10
メッシュ以上の粗粒0.3％であった。Ti当たりの収率
は、947Kg/g−Tiであり、かさ比重も良好であり、粒度
分布も比較的シャープであった。Ethylene was polymerized using the transition metal catalyst obtained by the above operation. 1 n-heptane was placed in an autoclave with an internal volume of 2, 20 mg of the above transition metal catalyst and 0.3 of triethylaluminum.
5 ml was added, hydrogen was added up to 2 kg / cm 2 gauge, ethylene was further added up to 6 kg / cm 2 gauge, and then the temperature was raised to 75 ° C. to 10 kg / cm 2.
Polymerization was carried out at 75 ° C. for 2 hours while adding ethylene to a cm 2 gauge. Then, the mixture was cooled, unreacted ethylene was purged, and then filtered to obtain polyethylene powder. It was 360 g when dried and weighed. This powder has an intrinsic viscosity of 2.56 (measured with a tetralin solution at 135 ° C), a bulk specific gravity of 0.48 and a fineness of less than 200 mesh 4.5%, 10%.
The coarse particles of the mesh or more were 0.3%. The yield per Ti was 947 Kg / g-Ti, the bulk specific gravity was good, and the particle size distribution was relatively sharp.
実施例２ 実施例１において四塩化炭素にかえて四塩化硅素を用い
たところ同様に組成としてはMgBrClのハロゲン化マグネ
シウムが得られ、Ｘ線回折スペクトルは、7.38Åに最大
ピークがあり7.987、5.32、3.57、32.47、3.26、2.90Å
に比較的強い回折線がみられた。同様の操作でえられた
遷移金属触媒は、Ti当たり965Kg/g−Tiの活性であっ
た。Example 2 In the same manner as in Example 1, except that carbon tetrachloride was replaced with silicon tetrachloride, magnesium halide MgBrCl having a similar composition was obtained, and the X-ray diffraction spectrum had a maximum peak at 7.38Å 7.987, 5.32. , 3.57, 32.47, 3.26, 2.90Å
A relatively strong diffraction line was observed at. The transition metal catalyst obtained by the same operation had an activity of 965 Kg / g-Ti per Ti.
（発明の効果） 本発明のハロゲン化マグネシウムはオレフィン重合用遷
移金属触媒用の担体として極めて優れており工業的に価
値がある。(Effects of the Invention) The magnesium halide of the present invention is extremely excellent as a carrier for a transition metal catalyst for olefin polymerization and is industrially valuable.
第１図は本発明のハロゲン化マグネシウムのＸ線回折の
スペクトルを示す図面である。FIG. 1 is a drawing showing an X-ray diffraction spectrum of the magnesium halide of the present invention.
Claims (1)
7.38Å付近に最大強度を有し7.98、5.32、3.57、3.47、
3.26、2.90Å付近に比較的強い回折線を与える結晶性の
MgBrClからなるオレフィン重合用遷移金属触媒担体用ハ
ロゲン化マグネシウム。1. Diffraction lines measured by X-ray diffraction
Has maximum strength near 7.38Å, 7.98, 5.32, 3.57, 3.47,
3.26, which gives a relatively strong diffraction line near 2.90Å
Magnesium halide for transition metal catalyst support for olefin polymerization consisting of MgBrCl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62000114A JPH072795B2 (en) | 1987-01-06 | 1987-01-06 | Magnesium halide for transition metal catalyst carrier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62000114A JPH072795B2 (en) | 1987-01-06 | 1987-01-06 | Magnesium halide for transition metal catalyst carrier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63168411A JPS63168411A (en) | 1988-07-12 |
| JPH072795B2 true JPH072795B2 (en) | 1995-01-18 |
Family
ID=11465029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62000114A Expired - Lifetime JPH072795B2 (en) | 1987-01-06 | 1987-01-06 | Magnesium halide for transition metal catalyst carrier |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH072795B2 (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5846129A (en) * | 1981-09-10 | 1983-03-17 | 帝人株式会社 | Polyester composite crimped yarn and production thereof |
-
1987
- 1987-01-06 JP JP62000114A patent/JPH072795B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63168411A (en) | 1988-07-12 |
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