JPH0812966A - Cool storage material - Google Patents
Cool storage materialInfo
- Publication number
- JPH0812966A JPH0812966A JP6171936A JP17193694A JPH0812966A JP H0812966 A JPH0812966 A JP H0812966A JP 6171936 A JP6171936 A JP 6171936A JP 17193694 A JP17193694 A JP 17193694A JP H0812966 A JPH0812966 A JP H0812966A
- Authority
- JP
- Japan
- Prior art keywords
- konjak
- bag
- water
- storage material
- cold storage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000011232 storage material Substances 0.000 title abstract description 22
- 229920002752 Konjac Polymers 0.000 claims abstract description 47
- 235000010485 konjac Nutrition 0.000 claims abstract description 47
- 150000004676 glycans Chemical class 0.000 claims abstract description 15
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 15
- 239000005017 polysaccharide Substances 0.000 claims abstract description 15
- 239000003381 stabilizer Substances 0.000 claims abstract description 12
- 235000013312 flour Nutrition 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 16
- 239000000203 mixture Substances 0.000 abstract description 14
- -1 polyethylene Polymers 0.000 abstract description 11
- 239000000499 gel Substances 0.000 abstract description 9
- 229920002472 Starch Polymers 0.000 abstract description 7
- 239000008107 starch Substances 0.000 abstract description 7
- 235000019698 starch Nutrition 0.000 abstract description 7
- 235000010418 carrageenan Nutrition 0.000 abstract description 5
- 239000000679 carrageenan Substances 0.000 abstract description 5
- 229920001525 carrageenan Polymers 0.000 abstract description 5
- 229940113118 carrageenan Drugs 0.000 abstract description 5
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 abstract description 5
- 244000215068 Acacia senegal Species 0.000 abstract description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract description 3
- 108010010803 Gelatin Proteins 0.000 abstract description 3
- 229920002907 Guar gum Polymers 0.000 abstract description 3
- 229920000084 Gum arabic Polymers 0.000 abstract description 3
- 239000004698 Polyethylene Substances 0.000 abstract description 3
- 235000010489 acacia gum Nutrition 0.000 abstract description 3
- 239000000205 acacia gum Substances 0.000 abstract description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract description 3
- 239000008273 gelatin Substances 0.000 abstract description 3
- 229920000159 gelatin Polymers 0.000 abstract description 3
- 235000019322 gelatine Nutrition 0.000 abstract description 3
- 235000011852 gelatine desserts Nutrition 0.000 abstract description 3
- 235000010417 guar gum Nutrition 0.000 abstract description 3
- 239000000665 guar gum Substances 0.000 abstract description 3
- 229960002154 guar gum Drugs 0.000 abstract description 3
- 229920001277 pectin Polymers 0.000 abstract description 3
- 235000010987 pectin Nutrition 0.000 abstract description 3
- 239000001814 pectin Substances 0.000 abstract description 3
- 229920000573 polyethylene Polymers 0.000 abstract description 3
- 229920001285 xanthan gum Polymers 0.000 abstract description 3
- 235000010493 xanthan gum Nutrition 0.000 abstract description 3
- 239000000230 xanthan gum Substances 0.000 abstract description 3
- 229940082509 xanthan gum Drugs 0.000 abstract description 3
- 239000000843 powder Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 229920003169 water-soluble polymer Polymers 0.000 description 10
- 244000247812 Amorphophallus rivieri Species 0.000 description 9
- 235000001206 Amorphophallus rivieri Nutrition 0.000 description 9
- 239000000252 konjac Substances 0.000 description 9
- 229920000715 Mucilage Polymers 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 8
- 244000061456 Solanum tuberosum Species 0.000 description 7
- 235000002595 Solanum tuberosum Nutrition 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 241000251468 Actinopterygii Species 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 235000013305 food Nutrition 0.000 description 6
- 235000015110 jellies Nutrition 0.000 description 6
- 239000008274 jelly Substances 0.000 description 6
- 244000005700 microbiome Species 0.000 description 6
- 235000018102 proteins Nutrition 0.000 description 6
- 108090000623 proteins and genes Proteins 0.000 description 6
- 102000004169 proteins and genes Human genes 0.000 description 6
- 229940032147 starch Drugs 0.000 description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 235000010443 alginic acid Nutrition 0.000 description 4
- 229920000615 alginic acid Polymers 0.000 description 4
- 238000003912 environmental pollution Methods 0.000 description 4
- 230000008014 freezing Effects 0.000 description 4
- 238000007710 freezing Methods 0.000 description 4
- 235000013372 meat Nutrition 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- 235000013311 vegetables Nutrition 0.000 description 4
- 244000062793 Sorghum vulgare Species 0.000 description 3
- 229940072056 alginate Drugs 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000019713 millet Nutrition 0.000 description 3
- SATHPVQTSSUFFW-UHFFFAOYSA-N 4-[6-[(3,5-dihydroxy-4-methoxyoxan-2-yl)oxymethyl]-3,5-dihydroxy-4-methoxyoxan-2-yl]oxy-2-(hydroxymethyl)-6-methyloxane-3,5-diol Chemical compound OC1C(OC)C(O)COC1OCC1C(O)C(OC)C(O)C(OC2C(C(CO)OC(C)C2O)O)O1 SATHPVQTSSUFFW-UHFFFAOYSA-N 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- 102000009027 Albumins Human genes 0.000 description 2
- 108010088751 Albumins Proteins 0.000 description 2
- 239000001904 Arabinogalactan Substances 0.000 description 2
- 229920000189 Arabinogalactan Polymers 0.000 description 2
- 241001474374 Blennius Species 0.000 description 2
- 108010076119 Caseins Proteins 0.000 description 2
- PTHCMJGKKRQCBF-UHFFFAOYSA-N Cellulose, microcrystalline Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC)C(CO)O1 PTHCMJGKKRQCBF-UHFFFAOYSA-N 0.000 description 2
- 229920002307 Dextran Polymers 0.000 description 2
- 229920000569 Gum karaya Polymers 0.000 description 2
- 229920000057 Mannan Polymers 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 108010073771 Soybean Proteins Proteins 0.000 description 2
- 241000934878 Sterculia Species 0.000 description 2
- 240000004584 Tamarindus indica Species 0.000 description 2
- 235000004298 Tamarindus indica Nutrition 0.000 description 2
- 229920001615 Tragacanth Polymers 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 235000021120 animal protein Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000019312 arabinogalactan Nutrition 0.000 description 2
- 239000000305 astragalus gummifer gum Substances 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 229940105329 carboxymethylcellulose Drugs 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 235000019688 fish Nutrition 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 235000010494 karaya gum Nutrition 0.000 description 2
- 239000000231 karaya gum Substances 0.000 description 2
- 229940039371 karaya gum Drugs 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 229960002900 methylcellulose Drugs 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 2
- 239000008108 microcrystalline cellulose Substances 0.000 description 2
- 229940016286 microcrystalline cellulose Drugs 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 239000004854 plant resin Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 235000012015 potatoes Nutrition 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 229940079832 sodium starch glycolate Drugs 0.000 description 2
- 239000008109 sodium starch glycolate Substances 0.000 description 2
- 229920003109 sodium starch glycolate Polymers 0.000 description 2
- 235000010491 tara gum Nutrition 0.000 description 2
- 239000000213 tara gum Substances 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
Landscapes
- Preparation Of Fruits And Vegetables (AREA)
- Jellies, Jams, And Syrups (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は物品を保冷するために用
いられる蓄冷材に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a regenerator material used for keeping articles cold.
【0002】[0002]
【従来の技術】従来蓄冷材としてはポリビニルアルコー
ル、ポリアクリル酸塩類等の合成糊料の水溶液を袋詰め
したものが提供されている。2. Description of the Related Art Conventionally, as a cold storage material, a bag in which an aqueous solution of a synthetic paste such as polyvinyl alcohol or polyacrylic acid salt is packed is provided.
【0003】[0003]
【発明が解決しようとする課題】しかしながら上記従来
の蓄冷材は、使用後に廃棄する場合、ポリビニルアルコ
ール、ポリアクリル酸塩等の合成糊料が微生物によって
分解されず環境汚染を引き起こし、また水を多量に含ん
でいるので焼却処理をすることも困難である。また従来
の灰汁、水酸化カルシウム、炭酸ナトリウム等のゲル化
剤を使用してゲル化させたコンニャクを袋詰めしたもの
を使用しても蓄冷剤として使用可能ではあるが、凍結さ
せると解凍したときに組織の荒れや離水変化のためコン
ニャク加工物は凍みた状態となり、弾性を失ってコンニ
ャク加工物としての再利用が困難である。However, when the above conventional regenerator materials are discarded after use, synthetic pastes such as polyvinyl alcohol and polyacrylate are not decomposed by microorganisms to cause environmental pollution, and a large amount of water is used. It is also difficult to incinerate because it is contained in. It is also possible to use a bag of konjak gelled with a conventional gelling agent such as lye, calcium hydroxide or sodium carbonate, but it can also be used as a cold storage agent, but when it is thawed when frozen In addition, the konjak processed product becomes frozen due to the roughness of the tissue and the change of water separation, and it loses elasticity and is difficult to reuse as the konjak processed product.
【0004】[0004]
【課題を解決するための手段】本発明は上記従来の課題
を解決するための手段としてコンニャク精粉および/ま
たはコンニャクイモの摩砕物を多糖類からなる安定剤で
ゲル化させたコンニャク加工物を袋詰めした蓄冷材を提
供するものである。Means for Solving the Problems The present invention provides a konjak processed product obtained by gelling a konjak refined powder and / or a konjak millet ground product with a stabilizer composed of a polysaccharide as a means for solving the above-mentioned conventional problems. It provides a bag of cold storage material.
【0005】本発明の蓄冷剤に使われる安定剤として
は、海草抽出物である寒天、カラギーナン、ファ−セレ
ラン、アルギン酸塩、アルギン酸プロピレン、グリコー
ルエステル、植物種子粘質物であるグァーガム、ローカ
スビーンガム、タマリンド種子多糖類、タラガム、植物
樹脂粘質物であるアラビアガム、トラガントガム、カラ
ヤガム、植物果実粘質物であるペクチン、アラビノガラ
クタン、微生物産生粘質物であるキサンタンガム、スク
レロガムブルラン、デキストラン、動物性たんぱく質で
あるゼラチン、アルブミン、カゼイン、植物性たんぱく
質である大豆たんぱく質、小麦たんぱく質セルロース及
びその誘導体であるカルボキシメチルセルロース、メチ
ルセルロース、微結晶セルロース並びに澱粉及びその誘
導体である澱粉、澱粉リン酸エステル、澱粉グリコール
酸ナトリウム等の多糖類が使用される。該多糖類は増粘
性を有することが望ましい。上記安定剤は単独で使用さ
れてもよいし、二種以上が併用されてもよい。上記多糖
類は通常5〜20重量%程度の添加量で使用される。Stabilizers used in the cold accumulating agent of the present invention include seaweed extracts such as agar, carrageenan, faserelan, alginates, propylene alginate, glycol esters, plant seed mucilages guar gum, locus bean gum, Tamarind seed polysaccharides, tara gum, plant resin mucilages gum arabic, tragacanth gum, karaya gum, plant fruit mucilage pectin, arabinogalactan, microbial mucilage xanthan gum, sclerogam vullan, dextran, animal protein Gelatin, albumin, casein, vegetable protein soybean protein, wheat protein cellulose and its derivatives carboxymethyl cellulose, methyl cellulose, microcrystalline cellulose and starch and its derivatives starch, starch Phosphoric acid esters, polysaccharides sodium starch glycolate, etc. are used. It is desirable that the polysaccharide has a thickening property. The above stabilizers may be used alone or in combination of two or more. The above-mentioned polysaccharide is usually used in an amount of about 5 to 20% by weight.
【0006】本発明の蓄冷材につかわれるコンニャク源
としては、コンニャクイモを生のまま潰した、あるいは
煮てから潰したもの、またはコンニャクイモを切断、乾
燥、摩砕して製粉した荒粉、該荒粉を更に風選してマン
ナン粒子を取り出した精粉あるいはこれらの混合物等が
使用できる。The konjak source used in the cold accumulating material of the present invention includes konjak crushed raw or smashed after crushing, or konjac yam cut, dried and ground to obtain coarse powder, It is possible to use a refined powder obtained by further wind-selecting the rough powder and taking out mannan particles, or a mixture thereof.
【0007】[0007]
【作用】本発明の蓄冷剤は水溶性高分子によってコンニ
ャク精粉またはコンニャクイモの摩砕物をゲル化したも
のであるので、取扱は容易で、またその蓄冷効果も優れ
ている。更に本発明の蓄冷材はコンニャク精粉および/
またはコンニャクイモの摩砕物と動植物性の多糖類、た
んぱく質等の水溶性高分子と水とからなるから、使用後
に廃棄する場合微生物による分解が可能であり環境汚染
を引き起こすことがない。また上記水溶性高分子は酸性
におけるたんぱく質の安定性を付与し、また粘性、結着
性を増加させたり、乳化粒子系を安定させたり、該水溶
性高分子を付加した食品のゲル化を促進したりすること
ができる。更に該水溶性高分子と水との親和性により遊
離水の割合が減少し、凍結したときの氷晶の大きさが小
さくなり、凍結解凍した時の組織の荒れや離水変化を防
止することができ、凍結前のゲル状態を維持するので、
上記蓄冷剤は凍結、解凍後も不要になれば、ゼリー、ド
リンク、あるいはコンニャク加工物として食用に供する
ことができる。The cold accumulating agent of the present invention is a gel of konjak refined powder or konjak potato milled with a water-soluble polymer, so that it is easy to handle and has an excellent cold accumulating effect. Further, the regenerator material of the present invention is konjac refined flour and /
Alternatively, since it is composed of ground material of konjac potato, water-soluble polymer such as animal and plant polysaccharides and proteins, and water, it can be decomposed by microorganisms when used and discarded without causing environmental pollution. In addition, the above water-soluble polymer imparts protein stability under acidic conditions, increases viscosity and binding property, stabilizes emulsion particle system, and promotes gelation of foods to which the water-soluble polymer is added. You can Further, the affinity of the water-soluble polymer with water reduces the proportion of free water, reduces the size of ice crystals when frozen, and prevents the roughening of tissues and the change in water separation when frozen and thawed. It can be done and maintains the gel state before freezing,
If the above-mentioned cold storage agent becomes unnecessary after freezing and thawing, it can be used as a jelly, a drink, or a konjak processed product for food.
【0008】[0008]
〔実施例1〕コンニャク精粉3重量%、水97重量%を
含む混合物を混練してコンニャク精粉を膨潤させた混合
物に、更に安定剤としてカラギーナン5重量%を添加
し、クエン酸を用いてpHを3.5に調節した。該混合
物をポリエチレン製の袋に充填し、該袋を真空パックす
る。その後該袋を湯煎して、該袋中の混合物をゲル化さ
せる。[Example 1] 5% by weight of carrageenan was added as a stabilizer to a mixture obtained by kneading a mixture containing 3% by weight of konjak refined powder and 97% by weight of water to swell the konjak refined powder, and using citric acid. The pH was adjusted to 3.5. The mixture is filled in a polyethylene bag and the bag is vacuum packed. Then, the bag is roasted to gel the mixture in the bag.
【0009】〔実施例2〕コンニャクイモ1kgを煮沸し
た後摩砕し、該摩砕されたコンニャク摩砕物に安定剤と
してファーセレラン60gを添加して混練し、ジャンプ
を用いてpHを3.0に調節した。該混練物をポリプロ
ピレン製の袋に充填し、該袋を真空パックする。その後
該袋を湯煎して、該袋中の混合物をゲル化させる。[Example 2] 1 kg of konjac potato was boiled and then ground, and 60 g of furceleran as a stabilizer was added to the ground konjak ground material and kneaded, and the pH was adjusted to 3.0 using a jump. I adjusted. The kneaded product is filled in a polypropylene bag, and the bag is vacuum-packed. Then, the bag is roasted to gel the mixture in the bag.
【0010】〔蓄冷効果〕実施例1および2で作成した
蓄冷剤に熱伝対を取付け、冷凍庫にいれて凍結させ、そ
の後室温に放置して、該蓄冷剤の温度変化を測定した。
図1にその結果を示す。図1から明らかなように実施例
1で作成した蓄冷剤は放置後30分から3時間30分後
の3時間にわたって0℃を維持し、高い蓄冷効果を示し
た。また実施例2で作成した蓄冷剤も放置後30分から
1時間30分までの1時間の間0℃付近を維持し、その
後昇温した。以上のことから本発明の蓄冷剤の蓄冷効果
は充分に満足のいくものであることが明らかになった。[Cool Storage Effect] A thermocouple was attached to the cold storage agents prepared in Examples 1 and 2, placed in a freezer to be frozen, and then allowed to stand at room temperature, and the temperature change of the cold storage agents was measured.
The result is shown in FIG. As is clear from FIG. 1, the cold accumulating agent prepared in Example 1 maintained 0 ° C. for 3 hours from 30 minutes to 3 hours 30 minutes after standing, and showed a high cold accumulating effect. Also, the cold storage agent prepared in Example 2 was maintained at around 0 ° C. for 1 hour from 30 minutes to 1 hour 30 minutes after being left to stand, and then heated. From the above, it became clear that the cold storage effect of the cold storage agent of the present invention is sufficiently satisfactory.
【0011】上記実施例1および2で製造された蓄冷剤
は、例えば家庭用冷蔵庫あるいは冷凍庫で冷却し、氷枕
として使用したり、炎症を起している患部に当てたりす
る他、クーラーボックスに野菜、魚、肉等とともに収納
すれば、該野菜、魚、肉等の鮮度を維持したままキャン
プ場等へ運搬することができるし、またクーラーボック
スに蓄冷剤を収納して釣った魚の保管箱としても使用す
ることができる。そして該蓄冷剤が不要となれば、蓄冷
剤はゼリー、ドリンク、あるいはコンニャク加工物とし
て食用に供することができる。上記の他に該蓄冷剤は種
々な用途に使用することができる。The cold storage agents manufactured in Examples 1 and 2 are cooled in, for example, a household refrigerator or a freezer and used as an ice pillow, or applied to an inflamed affected area, or vegetables in a cooler box. If it is stored together with fish, meat, etc., it can be transported to campgrounds etc. while maintaining the freshness of the vegetables, fish, meat etc. Also, as a storage box for fish caught by storing a cool storage agent in a cooler box. Can also be used. When the regenerator is no longer needed, the regenerator can be used as a jelly, a drink, or a konjak processed product for consumption. In addition to the above, the regenerator can be used for various purposes.
【0012】[0012]
【発明の効果】したがって本発明の方法においては使用
後に廃棄した場合にも微生物によって分解可能で環境を
汚染することがなく、更に使用後不要になった場合には
ゼリー、ドリンクあるいはコンニャク加工物として食用
に供することができる蓄冷剤が提供できる。Therefore, in the method of the present invention, it can be decomposed by microorganisms even when it is discarded after use and does not pollute the environment, and when it becomes unnecessary after use, it is used as a jelly, drink or konjak processed product. A regenerator that can be used for food can be provided.
【図1】本発明の蓄冷剤の蓄冷効果を示すグラフFIG. 1 is a graph showing the cold storage effect of the cold storage agent of the present invention.
─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成6年11月15日[Submission date] November 15, 1994
【手続補正3】[Procedure 3]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】全文[Correction target item name] Full text
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【書類名】 明細書[Document name] Statement
【発明の名称】 蓄冷材[Title of Invention] Regenerator material
【特許請求の範囲】[Claims]
【発明の詳細な説明】Detailed Description of the Invention
【0001】[0001]
【産業上の利用分野】本発明は物品を保冷するために用
いられる蓄冷材に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a regenerator material used for keeping articles cold.
【0002】[0002]
【従来の技術】従来蓄冷材としてはポリビニルアルコー
ル、ポリアクリル酸塩類等の合成糊料の水溶液を袋詰め
したものが提供されている。2. Description of the Related Art Conventionally, as a cold storage material, a bag in which an aqueous solution of a synthetic paste such as polyvinyl alcohol or polyacrylic acid salt is packed is provided.
【0003】[0003]
【発明が解決しようとする課題】しかしながら上記従来
の蓄冷材は、使用後に廃棄する場合、ポリビニルアルコ
ール、ポリアクリル酸塩等の合成糊料が微生物によって
分解されず環境汚染を引き起こし、また水を多量に含ん
でいるので焼却処理をすることも困難である。また従来
の灰汁、水酸化カルシウム、炭酸ナトリウム等のゲル化
剤を使用してゲル化させたコンニャクを袋詰めしたもの
を使用しても蓄冷材として使用可能ではあるが、凍結さ
せると解凍したときに組織の荒れや離水変化のためコン
ニャク加工物は凍みた状態となり、弾性を失ってコンニ
ャク加工物としての再利用が困難である。However, when the above conventional regenerator materials are discarded after use, synthetic pastes such as polyvinyl alcohol and polyacrylate are not decomposed by microorganisms to cause environmental pollution, and a large amount of water is used. It is also difficult to incinerate because it is contained in. It is also possible to use a bag of konjak gelled with a conventional gelling agent such as lye, calcium hydroxide, sodium carbonate, etc., but it can also be used as a cold storage material , but when it is thawed when frozen In addition, the konjak processed product becomes frozen due to the roughness of the tissue and the change of water separation, and it loses elasticity and is difficult to reuse as the konjak processed product.
【0004】[0004]
【課題を解決するための手段】本発明は上記従来の課題
を解決するための手段としてコンニャク精粉および/ま
たはコンニャクイモの摩砕物を多糖類からなる安定剤で
ゲル化させたコンニャク加工物を袋詰めした蓄冷材を提
供するものである。Means for Solving the Problems The present invention provides a konjak processed product obtained by gelling a konjak refined powder and / or a konjak millet ground product with a stabilizer composed of a polysaccharide as a means for solving the above-mentioned conventional problems. It provides a bag of cold storage material.
【0005】 本発明の蓄冷材に使われる安定剤として
は、海草抽出物である寒天、カラギーナン、ファ−セレ
ラン、アルギン酸塩、アルギン酸プロピレン、グリコー
ルエステル、植物種子粘質物であるグァーガム、ローカ
スビーンガム、タマリンド種子多糖類、タラガム、植物
樹脂粘質物であるアラビアガム、トラガントガム、カラ
ヤガム、植物果実粘質物であるペクチン、アラビノガラ
クタン、微生物産生粘質物であるキサンタンガム、スク
レロガムブルラン、デキストラン、動物性たんぱく質で
あるゼラチン、アルブミン、カゼイン、植物性たんぱく
質である大豆たんぱく質、小麦たんぱく質セルロース及
びその誘導体であるカルボキシメチルセルロース、メチ
ルセルロース、微結晶セルロース並びに澱粉及びその誘
導体である澱粉、澱粉リン酸エステル、澱粉グリコール
酸ナトリウム等の多糖類が使用される。該多糖類は増粘
性を有することが望ましい。上記安定剤は単独で使用さ
れてもよいし、二種以上が併用されてもよい。上記多糖
類は通常5〜20重量%程度の添加量で使用される。Examples of stabilizers used in the cold storage material of the present invention include seaweed extracts such as agar, carrageenan, faserelan, alginate, propylene alginate, glycol esters, plant seed mucilage guar gum, locust bean gum, Tamarind seed polysaccharides, tara gum, plant resin mucilages gum arabic, tragacanth gum, karaya gum, plant fruit mucilage pectin, arabinogalactan, microbial mucilage xanthan gum, sclerogam vullan, dextran, animal protein Gelatin, albumin, casein, vegetable protein soybean protein, wheat protein cellulose and its derivatives carboxymethyl cellulose, methyl cellulose, microcrystalline cellulose and starch and its derivatives starch, starch Polysaccharides such as powdered phosphoric acid ester and sodium starch glycolate are used. It is desirable that the polysaccharide has a thickening property. The above stabilizers may be used alone or in combination of two or more. The above-mentioned polysaccharide is usually used in an amount of about 5 to 20% by weight.
【0006】 本発明の蓄冷材につかわれるコンニャク
源としては、コンニャクイモを生のまま潰した、あるい
は煮てから潰したもの、またはコンニャクイモを切断、
乾燥、摩砕して製粉した荒粉、該荒粉を更に風選してマ
ンナン粒子を取り出した精粉あるいはこれらの混合物等
が使用できる。As a konjak source used for the regenerator material of the present invention, konjak potatoes are crushed raw or simmered, or konjac potatoes are cut,
A coarse powder obtained by drying and grinding to mill, a fine powder obtained by further wind-selecting the coarse powder to take out mannan particles, or a mixture thereof can be used.
【0007】[0007]
【作用】本発明の蓄冷材は水溶性高分子によってコンニ
ャク精粉またはコンニャクイモの摩砕物をゲル化したも
のであるので、取扱は容易で、またその蓄冷効果も優れ
ている。更に本発明の蓄冷材はコンニャク精粉および/
またはコンニャクイモの摩砕物と動植物性の多糖類、た
んぱく質等の水溶性高分子と水とからなるから、使用後
に廃棄する場合微生物による分解が可能であり環境汚染
を引き起こすことがない。また上記水溶性高分子は酸性
におけるたんぱく質の安定性を付与し、また粘性、結着
性を増加させたり、乳化粒子系を安定させたり、該水溶
性高分子を付加した食品のゲル化を促進したりすること
ができる。更に該水溶性高分子と水との親和性により遊
離水の割合が減少し、凍結したときの氷晶の大きさが小
さくなり、凍結解凍した時の組織の荒れや離水変化を防
止することができ、凍結前のゲル状態を維持するので、
上記蓄冷材は凍結、解凍後も不要になれば、ゼリー、ド
リンク、あるいはコンニャク加工物として食用に供する
ことができる。The regenerator material of the present invention is a gel of konjak refined powder or konjak millet ground with a water-soluble polymer, so that it is easy to handle and has an excellent regenerator effect. Further, the regenerator material of the present invention is konjac refined flour and /
Alternatively, since it is composed of ground material of konjac potato, water-soluble polymer such as animal and plant polysaccharides and proteins, and water, it can be decomposed by microorganisms when used and discarded without causing environmental pollution. In addition, the above water-soluble polymer imparts protein stability under acidic conditions, increases viscosity and binding property, stabilizes emulsion particle system, and promotes gelation of foods to which the water-soluble polymer is added. You can Further, the affinity of the water-soluble polymer with water reduces the proportion of free water, reduces the size of ice crystals when frozen, and prevents the roughening of tissues and the change in water separation when frozen and thawed. It can be done and maintains the gel state before freezing,
If the cold storage material becomes unnecessary after freezing and thawing, it can be used as a jelly, a drink, or a konjak processed product for food.
【0008】[0008]
【実施例】 〔実施例1〕コンニャク精粉3重量%、水97重量%を
含む混合物を混練してコンニャク精粉を膨潤させた混合
物に、更に安定剤としてカラギーナン5重量%を添加
し、クエン酸を用いてpHを3.5に調節した。該混合
物をポリエチレン製の袋に充填し、該袋を真空パックす
る。その後該袋を湯煎して、該袋中の混合物をゲル化さ
せる。Example 1 A mixture containing 3% by weight of konjak refined flour and 97% by weight of water was kneaded to swell the konjak refined flour, and 5% by weight of carrageenan was added as a stabilizer to the mixture. The pH was adjusted to 3.5 with acid. The mixture is filled in a polyethylene bag and the bag is vacuum packed. Then, the bag is roasted to gel the mixture in the bag.
【0009】〔実施例2〕コンニャクイモ1kgを煮沸し
た後摩砕し、該摩砕されたコンニャク摩砕物に安定剤と
してファーセレラン60gを添加して混練し、ジャンプ
を用いてpHを3.0に調節した。該混練物をポリプロ
ピレン製の袋に充填し、該袋を真空パックする。その後
該袋を湯煎して、該袋中の混合物をゲル化させる。[Example 2] 1 kg of konjac potato was boiled and then ground, and 60 g of furceleran as a stabilizer was added to the ground konjak ground material and kneaded, and the pH was adjusted to 3.0 using a jump. I adjusted. The kneaded product is filled in a polypropylene bag, and the bag is vacuum-packed. Then, the bag is roasted to gel the mixture in the bag.
【0010】〔蓄冷効果〕実施例1および2で作成した
蓄冷材に熱伝対を取付け、冷凍庫にいれて凍結させ、そ
の後室温に放置して、該蓄冷材の温度変化を測定した。
図1にその結果を示す。図1から明らかなように実施例
1で作成した蓄冷材は放置後30分から3時間30分後
の3時間にわたって0℃を維持し、高い蓄冷効果を示し
た。また実施例2で作成した蓄冷材も放置後30分から
1時間30分までの1時間の間0℃付近を維持し、その
後昇温した。以上のことから本発明の蓄冷材の蓄冷効果
は充分に満足のいくものであることが明らかになった。[0010] Mounting the thermocouple to the cold accumulating material created in [cold accumulating Effect] Examples 1 and 2 were frozen are are in the freezer, then allowed to stand at room temperature to measure the temperature change of the cold accumulation material.
The result is shown in FIG. As is clear from FIG. 1, the cold accumulating material prepared in Example 1 maintained a high temperature of 0 ° C. for 3 hours from 30 minutes to 3 hours 30 minutes after being left standing, and showed a high cold accumulating effect. Further, the cold storage material prepared in Example 2 was also maintained at around 0 ° C. for 1 hour from 30 minutes to 1 hour 30 minutes after being left standing, and then heated. From the above, it became clear that the cold storage effect of the cold storage material of the present invention is sufficiently satisfactory.
【0011】 上記実施例1および2で製造された蓄冷
材は、例えば家庭用冷蔵庫あるいは冷凍庫で冷却し、氷
枕として使用したり、炎症を起している患部に当てたり
する他、クーラーボックスに野菜、魚、肉等とともに収
納すれば、該野菜、魚、肉等の鮮度を維持したままキャ
ンプ場等へ運搬することができるし、またクーラーボッ
クスに蓄冷材を収納して釣った魚の保管箱としても使用
することができる。そして該蓄冷材が不要となれば、蓄
冷材はゼリー、ドリンク、あるいはコンニャク加工物と
して食用に供することができる。上記の他に該蓄冷材は
種々な用途に使用することができる。Cold storage produced in Examples 1 and 2 above
The material is cooled in, for example, a home refrigerator or a freezer and used as an ice pillow or applied to an affected area that is inflamed, and if stored together with vegetables, fish, meat, etc. in the cooler box, the vegetables, fish , Can be transported to campgrounds, etc. while maintaining the freshness of meat, etc., and can also be used as a storage box for fish caught by storing cool storage material in a cooler box. And if the cold accumulation material is unnecessary, cold storage material can be subjected to edible as jelly, drink or konjac workpiece. In addition to the above, the regenerator material can be used for various purposes.
【0012】[0012]
【発明の効果】したがって本発明の方法においては使用
後に廃棄した場合にも微生物によって分解可能で環境を
汚染することがなく、更に使用後不要になった場合には
ゼリー、ドリンクあるいはコンニャク加工物として食用
に供することができる蓄冷材が提供できる。Therefore, in the method of the present invention, it can be decomposed by microorganisms even when it is discarded after use and does not pollute the environment, and when it becomes unnecessary after use, it is used as a jelly, drink or konjak processed product. A cold storage material that can be used for food can be provided.
【図面の簡単な説明】[Brief description of drawings]
【図1】本発明の蓄冷材の蓄冷効果を示すグラフFIG. 1 is a graph showing the cold storage effect of the cold storage material of the present invention.
【手続補正4】[Procedure amendment 4]
【補正対象書類名】図面[Document name to be corrected] Drawing
【補正対象項目名】図1[Name of item to be corrected] Figure 1
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【図1】 FIG.
Claims (1)
イモの摩砕物を多糖類からなる安定剤でゲル化させたコ
ンニャク加工物を袋詰めしたことを特徴とする蓄冷材1. A regenerator material comprising a konjak processed product obtained by gelling ground konjak flour and / or konjak yam with a stabilizer consisting of a polysaccharide, and bagging the processed product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6171936A JPH0812966A (en) | 1994-06-29 | 1994-06-29 | Cool storage material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6171936A JPH0812966A (en) | 1994-06-29 | 1994-06-29 | Cool storage material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0812966A true JPH0812966A (en) | 1996-01-16 |
Family
ID=15932578
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6171936A Withdrawn JPH0812966A (en) | 1994-06-29 | 1994-06-29 | Cool storage material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0812966A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6101830A (en) * | 1997-12-03 | 2000-08-15 | Behr Gmbh & Co., | Cold storage device, in particular for an automobile |
| CN109439275A (en) * | 2018-09-03 | 2019-03-08 | 捷成实业(深圳)有限公司 | A kind of environmental protection fruit juice gel and preparation method thereof |
-
1994
- 1994-06-29 JP JP6171936A patent/JPH0812966A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6101830A (en) * | 1997-12-03 | 2000-08-15 | Behr Gmbh & Co., | Cold storage device, in particular for an automobile |
| CN109439275A (en) * | 2018-09-03 | 2019-03-08 | 捷成实业(深圳)有限公司 | A kind of environmental protection fruit juice gel and preparation method thereof |
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| Date | Code | Title | Description |
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| A300 | Withdrawal of application because of no request for examination |
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