JPH0820687A - Olefinic thermoplastic elastomer composition for air bag covering material - Google Patents
Olefinic thermoplastic elastomer composition for air bag covering materialInfo
- Publication number
- JPH0820687A JPH0820687A JP17605294A JP17605294A JPH0820687A JP H0820687 A JPH0820687 A JP H0820687A JP 17605294 A JP17605294 A JP 17605294A JP 17605294 A JP17605294 A JP 17605294A JP H0820687 A JPH0820687 A JP H0820687A
- Authority
- JP
- Japan
- Prior art keywords
- air bag
- thermoplastic elastomer
- composition
- weight
- polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 54
- 239000000463 material Substances 0.000 title claims description 35
- 229920002397 thermoplastic olefin Polymers 0.000 title claims description 17
- -1 polypropylene Polymers 0.000 claims abstract description 41
- 229920001971 elastomer Polymers 0.000 claims abstract description 30
- 239000005060 rubber Substances 0.000 claims abstract description 25
- 239000004698 Polyethylene Substances 0.000 claims abstract description 23
- 229920000573 polyethylene Polymers 0.000 claims abstract description 23
- 239000002480 mineral oil Substances 0.000 claims abstract description 22
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 22
- 239000004743 Polypropylene Substances 0.000 claims abstract description 18
- 229920001155 polypropylene Polymers 0.000 claims abstract description 18
- 229920001577 copolymer Polymers 0.000 claims abstract description 15
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 7
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 7
- 229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 6
- 239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 16
- 239000004902 Softening Agent Substances 0.000 claims description 14
- 150000001336 alkenes Chemical class 0.000 claims description 12
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 11
- 239000005977 Ethylene Substances 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 3
- 238000004898 kneading Methods 0.000 abstract description 11
- 238000002156 mixing Methods 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 8
- 239000012634 fragment Substances 0.000 abstract description 5
- 239000003921 oil Substances 0.000 abstract description 5
- 239000003208 petroleum Substances 0.000 abstract description 3
- 239000012530 fluid Substances 0.000 abstract 1
- 239000011369 resultant mixture Substances 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 16
- 230000000704 physical effect Effects 0.000 description 16
- 238000000465 moulding Methods 0.000 description 11
- 238000013016 damping Methods 0.000 description 10
- 229920001038 ethylene copolymer Polymers 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000012792 core layer Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000000314 lubricant Substances 0.000 description 6
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000012779 reinforcing material Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 239000002344 surface layer Substances 0.000 description 5
- 238000013329 compounding Methods 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000011342 resin composition Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000446313 Lamella Species 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 1
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 description 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- HYBLFDUGSBOMPI-BQYQJAHWSA-N (4e)-octa-1,4-diene Chemical compound CCC\C=C\CC=C HYBLFDUGSBOMPI-BQYQJAHWSA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- DSAYAFZWRDYBQY-UHFFFAOYSA-N 2,5-dimethylhexa-1,5-diene Chemical compound CC(=C)CCC(C)=C DSAYAFZWRDYBQY-UHFFFAOYSA-N 0.000 description 1
- NWPQAENAYWENSD-UHFFFAOYSA-N 5-butylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=CCCC)CC1C=C2 NWPQAENAYWENSD-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 206010016322 Feeling abnormal Diseases 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-UHFFFAOYSA-N norbornene Chemical compound C1C2CCC1C=C2 JFNLZVQOOSMTJK-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 229920006285 olefinic elastomer Polymers 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 239000008036 rubber plasticizer Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Air Bags (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、車両に安全装置として
搭載されるエアーバッグカバー材用オレフィン系熱可塑
性エラストマー組成物に関する。さらに詳しくいえば、
車両の衝突の際に瞬時に膨脹して運転手あるいは助手席
搭乗者を保護するエアーバッグを収納するためにステア
リングホイールやインストルパネル部分に装着され、作
動時には瞬間的に破壊されるが搭乗者を傷付ける破片を
生じず、車内装着に適した表面特性、制振性、破断強
度、曲げ弾性率および低温物性に優れたエアーバッグカ
バー材用オレフィン系熱可塑性エラストマー組成物に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an olefinic thermoplastic elastomer composition for an air bag cover material mounted on a vehicle as a safety device. More specifically,
It is attached to the steering wheel and the instrument panel part to store the airbag that protects the driver or passenger in the passenger seat by inflating it in the event of a vehicle collision. The present invention relates to an olefin-based thermoplastic elastomer composition for an air bag cover material, which is free from damage pieces and is excellent in surface properties, vibration damping property, breaking strength, flexural modulus and low temperature physical properties suitable for mounting in a vehicle.
【0002】[0002]
【従来の技術およびその課題】車両の衝突の際に運転手
あるいは助手席搭乗者を保護するエアーバッグシステム
は、衝突を感知する装置とエアーバッグ装置からなる。
後者のエアーバッグ装置はエアーバッグ、エアーバッグ
を膨脹させるガスを発生させる装置、およびそれらを収
納するカバーからなり、カバーは運転手前方のステアリ
ングホイールや助手席前方のインストルパネル部分に取
付けられる。2. Description of the Related Art An air bag system for protecting a driver or a passenger in a passenger seat in the event of a vehicle collision comprises a collision sensing device and an air bag device.
The latter air bag device is composed of an air bag, a device for generating gas for inflating the air bag, and a cover for housing them, and the cover is attached to a steering wheel in front of the driver or an instrument panel portion in front of the passenger seat.
【0003】衝突事故で感知装置が作動すると、ガス発
生器から瞬間的にガスが発生し、エアーバッグ内を充満
したガスの圧力で、収納カバーに予め設けた薄肉部分等
が破壊されて、搭乗者の全面にエアーバッグが膨脹放出
して、搭乗者を座席側に拘束しステアリングホイール等
の操縦装置、フロントガラス、計器盤等への衝突による
負傷事故を防止あるいは軽減することができる。When a sensing device is activated in a collision accident, gas is generated instantaneously from the gas generator, and the thin wall portion or the like provided in advance on the storage cover is destroyed by the pressure of the gas filling the inside of the air bag, and the passenger boarding. The airbag can be inflated and released over the entire surface of the person, restraining the occupant to the seat side, and preventing or reducing an injury accident due to a collision with a steering wheel or other control device, windshield, instrument panel, or the like.
【0004】エアーバッグカバー材に要求される特性と
しては、衝突時のエアーバッグ内のガス圧で瞬間的に確
実に破砕されること、破砕の際に搭乗者を傷付ける破片
を生じないこと、車内に装着するにふさわしい外観特性
を有すること、車体から伝達される振動を軽減する制振
性を有すること、寒冷地での使用に耐え得る低温物性
(強度等)を備えていること等が挙げられる。The characteristics required for an air bag cover material are that it is instantaneously and reliably crushed by the gas pressure in the air bag at the time of a collision, that no fragments will injure the occupant during the crushing, It has the appearance characteristics suitable for being mounted on a vehicle, has damping properties that reduce the vibration transmitted from the vehicle body, and has low-temperature properties (strength etc.) that can withstand use in cold regions. .
【0005】エアーバッグ収納カバーについては、従来
その構造あるいは材質が種々提案されているが、破砕時
の破片の飛散を防止する目的では、通常補強材が使用さ
れている。例えば、発泡ポリウレタン等の材料の破断想
定部分以外にネット等の補強材を埋め込んでカバー全体
を形成するものがあるが(特開昭50-127336 号、特開昭
55-110643 号等)、破断想定部分のみを除くカバー全体
に精度よく補強材を埋め込むための製造工程が複雑であ
り、生産効率が低く、コストが高くなるという問題があ
る。Various structures and materials have been proposed for the air bag storage cover, but a reinforcing material is usually used for the purpose of preventing scattering of fragments during crushing. For example, there is one in which a reinforcing material such as a net is embedded in a portion other than a portion of a material such as polyurethane foam which is supposed to be broken to form the entire cover (Japanese Patent Laid-Open Nos. 50-127336 and 50-327336).
No. 55-110643), the manufacturing process for accurately embedding the reinforcing material in the entire cover except for the fractured part is complicated, resulting in low production efficiency and high cost.
【0006】そこで、エアーバッグ装置に必要な強度と
形状を保持し得るコア層(内層)と、柔らかくソフト感
を与え得る表層とからなる二層タイプの収納カバーが提
案されている。例えば、オレフィン系ゴムを含有するコ
ア層と熱可塑性樹脂の表層とからなるもの(特開平2-22
0946号)、オレフィン系樹脂のコア層とスチレン系ゴム
を主要成分とする表層とからなるもの(特開平3-189252
号)、オレフィン系エラストマーとその表層材料よりも
引っ張り強度の大きいエラストマーまたは樹脂のコア層
からなるもの(特開平4-15145 号)、ポリウレタン系熱
可塑性エラストマーのコア層とスチレン系またはオレフ
ィン系熱可塑性エラストマーの表層からなるもの(特開
平5-286399号)等がある。Therefore, a two-layer type storage cover has been proposed which comprises a core layer (inner layer) capable of maintaining the strength and shape required for an air bag device, and a surface layer capable of giving a soft and soft feeling. For example, one comprising a core layer containing an olefinic rubber and a surface layer of a thermoplastic resin (Japanese Patent Application Laid-Open No. 2-22
No. 0946), which comprises a core layer of an olefin resin and a surface layer containing styrene rubber as a main component (JP-A-3-189252).
No. 4), an olefin elastomer and a core layer of an elastomer or resin having a tensile strength higher than that of the surface material thereof (JP-A-4-15145), a core layer of a thermoplastic polyurethane elastomer and a styrene or olefin thermoplastic For example, there is one having an elastomer surface layer (JP-A-5-286399).
【0007】いずれも作動時の破断を確実に行なうため
に破断部分を薄肉化したり、外層内部あるいは内層に溝
あるいはスリットを設けたものであり、一体成形により
製造されるので、補強材を埋め込んだものに比べて生産
効率が向上し、破砕性、外観、触感も良好であり、強度
の調整も容易に行なえるという利点がある。しかしなが
ら、2種以上の素材を用いてコア層および表層の二層成
形を行なう必要があるため、生産性には依然問題を有し
ており、また両層の物性が異なることから成形時あるい
は長期間の使用により変形やひび割れが発生するという
問題もある。In either case, the broken portion is thinned or a groove or slit is provided in the outer layer or in the inner layer in order to surely perform the breaking during operation. Since it is manufactured by integral molding, a reinforcing material is embedded. It has the advantages of higher production efficiency, better crushability, better appearance and feel, and easier strength adjustment. However, since it is necessary to perform two-layer molding of the core layer and the surface layer by using two or more kinds of materials, there is still a problem in productivity, and since the physical properties of both layers are different, there is a problem during or during molding. There is also a problem that deformation and cracks may occur due to use for a period of time.
【0008】そこで、近年、補強材を使用しない単層タ
イプのカバーも提案されている。例えば、ポリエステル
系、ポリオレフィン系、ポリウレタン系、ポリアミド系
等の各種熱可塑性エラストマーからなり、表面部におけ
るエアーバッグの作動時に破断すべき部分に沿って薄肉
部を形成すると共に、その表面部の薄肉部に近い部分が
薄く外周部が厚くなるように厚さを変化させてなるもの
(特開平4-151348号)、カバーの構成材料がJIS A
硬度(JIS K6301 )が70以上、曲げ弾性率(JIS K720
3 )が5000kg/cm2 以下のオレフィン系及び/又はスチ
レン系熱可塑性エラストマーからなるもの(特開平4-31
4648号)、さらに、脆弱な構造(スリット、溝、薄肉部
など)の破断予定部分を有する、水素添加スチレン−共
役ジエン重合体(SEBS)とゴム用可塑剤(パラフィ
ン系オイル)とオレフィン系樹脂(ポリプロピレン)と
添加剤(酸化防止剤など)からなるJIS A硬度(JI
S K6301 )が60〜85の熱可塑性エラストマーの射出
成形体(特開平5-38996 号)等がある。Therefore, in recent years, a single-layer type cover that does not use a reinforcing material has also been proposed. For example, it is made of various thermoplastic elastomers such as polyester-based, polyolefin-based, polyurethane-based, polyamide-based, etc., and forms a thin portion along the portion of the surface portion that should be broken when the airbag is operated, and the thin portion of the surface portion The thickness of the cover is changed so that the portion close to the wall is thin and the outer peripheral portion is thick (JP-A-4-151348).
Hardness (JIS K6301) 70 or more, flexural modulus (JIS K720
3) consisting of olefin-based and / or styrene-based thermoplastic elastomer having a weight of 5000 kg / cm 2 or less (JP-A-4-31
4648), and hydrogenated styrene-conjugated diene polymer (SEBS), rubber plasticizer (paraffinic oil) and olefinic resin having a fragile structure (slit, groove, thin portion, etc.) to be broken. JIS A hardness (JI) consisting of (polypropylene) and additives (such as antioxidants)
There is an injection-molded article (Japanese Patent Laid-Open No. 5-38996) of a thermoplastic elastomer having S K6301) of 60 to 85.
【0009】これらの組成物のうち、スチレン系の熱可
塑性エラストマー(スチレン−ブタジエンブロック共重
合体水素添加物,SEBS)を使用したものでは低温で
の衝撃強度が不充分である。また、SEBSはミクロ相
分離構造を形成しやすく、スチレン成分がロッド状のラ
メラ構造をとる傾向がある。このため、射出成形時にス
チレンラメラの配向が縦方向と横方向にアンバランスと
なり、機械的物性に差が生じやすく、均一破壊が起こり
にくいと考えられる。さらにこのSEBSを使用した組
成物では制振性の指標となる力学損失正接(tanδ)
の分散ピークが室温付近に存在せず、制振性が不充分で
ある。また、前記特開平4-314648号には、密度0.9 の非
架橋型エチレンプロピレンゴム−ポリプロピレン−ポリ
エチレンベースオレフィン系熱可塑性樹脂組成物を使用
したカバーが開示されているが、成形性および低温特性
が不充分である。Among these compositions, those using a styrene thermoplastic elastomer (styrene-butadiene block copolymer hydrogenated product, SEBS) have insufficient impact strength at low temperatures. Further, SEBS easily forms a microphase-separated structure, and the styrene component tends to have a rod-shaped lamella structure. Therefore, it is considered that the orientation of the styrene lamella becomes unbalanced in the longitudinal direction and the lateral direction during the injection molding, the mechanical properties are likely to be different, and uniform fracture is unlikely to occur. Further, in the composition using this SEBS, the mechanical loss tangent (tan δ), which is an index of vibration damping property,
The dispersion peak of does not exist near room temperature, and the vibration damping property is insufficient. Further, JP-A-4-314648 discloses a cover using a non-crosslinking type ethylene propylene rubber-polypropylene-polyethylene-based olefinic thermoplastic resin composition having a density of 0.9. Not enough.
【0010】従って、本発明の目的は、基本的に成形の
容易なポリオレフィン系組成物からなる材料を使用し
て、作動時には確実にカバーが破壊され、かつ破片が飛
散しないエアーバッグカバー材用オレフィン系熱可塑性
エラストマー組成物を提供することにある。また、本発
明の他の目的は、外観性、風合い、制振性、触感(柔軟
性)などの表面特性に優れ、寒冷地から熱帯地までの広
い範囲の温度条件下で使用可能な耐候性を有し、特に破
断強度、曲げ弾性率および低温物性に優れたエアーバッ
グカバー材用オレフィン系熱可塑性エラストマー組成物
を提供することにある。さらに、本発明の他の目的は、
成形性に優れ、エアーバッグカバー材を効率よく生産で
き、使用後にリサイクルが可能なオレフィン系熱可塑性
エラストマー組成物を提供することにある。Therefore, an object of the present invention is to use an olefin for an air bag cover material, which basically uses a material of a polyolefin composition which is easy to mold, so that the cover is surely destroyed during operation and the fragments are not scattered. To provide a thermoplastic elastomer composition. Further, another object of the present invention is excellent in surface properties such as appearance, texture, vibration damping and touch (flexibility), and weather resistance that can be used in a wide range of temperature conditions from cold regions to tropical regions. And to provide an olefin-based thermoplastic elastomer composition for an air bag cover material, which has excellent breaking strength, flexural modulus and low-temperature physical properties. Furthermore, another object of the present invention is to
An object of the present invention is to provide an olefin-based thermoplastic elastomer composition having excellent moldability, capable of efficiently producing an air bag cover material, and recyclable after use.
【0011】[0011]
【課題を解決するための手段】本発明者らは、ポリオレ
フィンおよびオレフィン系エラストマーからなるエアー
バッグカバー材用オレフィン系熱可塑性エラストマー組
成物について、鋭意研究を重ねた結果、ポリプロピレ
ン、ポリエチレンおよびエチレン系共重合体ゴムからな
る組成物は、機械的物性、特に破断強度、曲げ弾性率お
よび低温物性が優れたものであり、かつ成形時における
配向が小さく均一な破壊開裂が可能であり、また制振性
の指標となる力学損失正接(tanδ)の分散ピークが
室温付近に存在し制振性が良好であることを見出し、さ
らに、ポリプロピレンとして高流動性のもの、エチレン
系共重合体ゴムとして高分子量のもの、およびポリエチ
レンを用い、鉱油系軟化剤を添加配合した熱可塑性エラ
ストマー組成物、特にエチレン系共重合体ゴムに予め鉱
油系軟化剤を配合混練した組成物をポリプロピレンおよ
びポリエチレンと混練した組成物を使用することによ
り、前記課題が解決されることを確認し本発明を完成す
るに至った。Means for Solving the Problems The inventors of the present invention have conducted extensive studies on an olefin-based thermoplastic elastomer composition for an air bag cover material, which comprises a polyolefin and an olefin-based elastomer. The composition composed of a polymer rubber has excellent mechanical properties, particularly breaking strength, flexural modulus and low temperature physical properties, and has a small orientation during molding, which enables uniform fracture cleavage, and vibration damping properties. It was found that the dispersion peak of the mechanical loss tangent (tan δ), which is an index of, exists near room temperature and the vibration damping property is good. Furthermore, polypropylene with high fluidity and ethylene copolymer rubber with high molecular weight are used. And a thermoplastic elastomer composition in which a mineral oil-based softening agent is added and blended, By using a composition obtained by kneading an ethylene-based copolymer rubber with a mineral oil-based softening agent in advance and kneading it with polypropylene and polyethylene, it was confirmed that the aforementioned problems could be solved and the present invention was completed. It was
【0012】[0012]
【発明の構成】すなわち、本発明は以下のエアーバッグ
カバー材用オレフィン系熱可塑性エラストマー組成物を
提供する。 1) (a)メルトフローレート(230℃,2.16kg荷
重)20〜200g/10分のポリプロピレン20〜6
0重量%と、(b)ポリエチレン5〜30重量%と、
(c)ムーニー粘度(ML1+4 ,100℃)50以上の
エチレン系共重合体ゴム75〜10重量%と、前記成分
(a)と(b)と(c)の合計100重量部に対して
(d)鉱油系軟化剤10〜120重量部を含有してなる
エアーバッグカバー材用オレフィン系熱可塑性エラスト
マー組成物。 2) (b)ポリエチレンが低密度ポリエチレンである
前記1記載のエアーバッグカバー材用オレフィン系熱可
塑性エラストマー組成物。 3) (b)ポリエチレンが線状低密度ポリエチレンで
ある前記1記載のエアーバッグカバー材用オレフィン系
熱可塑性エラストマー組成物。That is, the present invention provides the following olefinic thermoplastic elastomer composition for an air bag cover material. 1) (a) Melt flow rate (230 ° C., 2.16 kg load) 20 to 200 g / 10 min polypropylene 20 to 6
0% by weight, (b) polyethylene 5 to 30% by weight,
(C) 75 to 10% by weight of an ethylene-based copolymer rubber having a Mooney viscosity (ML 1 + 4 , 100 ° C.) of 50 or more, and 100 parts by weight of the components (a), (b) and (c) in total. (D) An olefinic thermoplastic elastomer composition for an air bag cover material, which comprises 10 to 120 parts by weight of a mineral oil softening agent. 2) The olefin-based thermoplastic elastomer composition for an air bag cover material as described in 1 above, wherein (b) polyethylene is low-density polyethylene. 3) The olefin-based thermoplastic elastomer composition for an air bag cover material as described in 1 above, wherein the polyethylene (b) is a linear low-density polyethylene.
【0013】4) (c)成分のエチレン系共重合体ゴ
ムと(d)成分の鉱油系軟化剤が、予め両成分を混練し
た油展組成物として配合されている前記1〜3に記載の
エアーバッグカバー材用オレフィン系熱可塑性エラスト
マー組成物。 5) JIS A硬度(JIS K6301 )が80以上、曲げ
弾性率(JIS K7203 )が500〜2500kg/cm2 であ
る前記1〜4に記載のエアーバッグカバー材用オレフィ
ン系熱可塑性エラストマー組成物。4) The ethylene copolymer rubber as the component (c) and the mineral oil softener as the component (d) are blended as an oil-extended composition in which both components are kneaded in advance. An olefin-based thermoplastic elastomer composition for an air bag cover material. 5) The olefinic thermoplastic elastomer composition for an air bag cover material as described in 1 to 4 above, which has a JIS A hardness (JIS K6301) of 80 or more and a flexural modulus (JIS K7203) of 500 to 2500 kg / cm 2 .
【0014】[0014]
【組成物の成分】以下、本発明のエアーバッグカバー材
用オレフィン系熱可塑性エラストマー組成物について説
明する。本発明のエアーバッグカバー材用オレフィン系
熱可塑性エラストマー組成物は(a)ポリプロピレン
と、(b)ポリエチレンと、(c)エチレン系共重合体
ゴムと、(d)鉱油系軟化剤とを含有する。[Composition Components] The olefinic thermoplastic elastomer composition for air bag cover materials of the present invention will be described below. The olefinic thermoplastic elastomer composition for an air bag cover material of the present invention contains (a) polypropylene, (b) polyethylene, (c) ethylene copolymer rubber, and (d) mineral oil softener. .
【0015】(a)成分のポリプロピレンは、アイソタ
チックポリプロピレン、またはポリプロピレンとエチレ
ン、ブテン−1、ヘキセン−1等のα−オレフィンとの
ランダムあるいはブロック共重合体であってポリプロピ
レンが結晶部分を構成するものである。メルトフローレ
ート(MFR)(230℃,2.16kg荷重)は20g/1
0分以上のものであり、20〜200g/10分のもの
が好ましい。MFRが20g/10分未満のものを用い
た場合、成形性が悪化する。The polypropylene as the component (a) is an isotactic polypropylene or a random or block copolymer of polypropylene and an α-olefin such as ethylene, butene-1, hexene-1, and the polypropylene constitutes a crystal part. To do. Melt flow rate (MFR) (230 ℃, 2.16kg load) is 20g / 1
It is 0 minutes or more, and preferably 20 to 200 g / 10 minutes. If the MFR of less than 20 g / 10 minutes is used, the moldability is deteriorated.
【0016】(b)成分のポリエチレンは、エチレンの
重合体で、メルトフローレート(230℃,2.16kg荷
重)0.05g/10分以上、密度0.91〜0.97g/cm3 の
ものであり、高密度ポリエチレン、低密度ポリエチレ
ン、線状低密度ポリエチレンなどのいずれも用いること
ができる。ポリエチレンを加えることにより、破断強
度、曲げ弾性率が改善される。これらポリエチレン類の
中では、特に低密度ポリエチレンおよび線状低密度ポリ
エチレンが好ましい。The polyethylene as the component (b) is a polymer of ethylene and has a melt flow rate (230 ° C., 2.16 kg load) of 0.05 g / 10 minutes or more and a density of 0.91 to 0.97 g / cm 3 and has a high density. Any of polyethylene, low density polyethylene, linear low density polyethylene and the like can be used. By adding polyethylene, breaking strength and flexural modulus are improved. Among these polyethylenes, low density polyethylene and linear low density polyethylene are particularly preferable.
【0017】本発明で使用される(c)成分のエチレン
系共重合体ゴムとは、エチレンを主成分とする無定型ラ
ンダムな弾性共重合体であり、例えばエチレン−プロピ
レン共重合体ゴム(EPR)、エチレン−1−ブテン共
重合体ゴム(EBR)、エチレン−プロピレン−非共役
ジエン共重合体ゴム(EPDM)のようなゴムが挙げら
れる。The ethylene-based copolymer rubber as the component (c) used in the present invention is an amorphous random elastic copolymer containing ethylene as a main component. For example, ethylene-propylene copolymer rubber (EPR). ), Ethylene-1-butene copolymer rubber (EBR), and ethylene-propylene-non-conjugated diene copolymer rubber (EPDM).
【0018】ここで、EPDMの非共役ジエンモノマー
は炭素数5〜20の非共役ジエンであり、例えば1,4
−ペンタジエン、1,4−ヘキサジエン、1,5−ヘキ
サジエン、2,5−ジメチル−1,5−ヘキサジエンお
よび1,4−オクタジエンや、例えば1,4−シクロヘ
キサジエン、シクロオクタジエン、ジシクロペンタジエ
ンなどの環状ジエン、例えば5−エチリデン−2−ノル
ボルネン、5−ブチリデン−2−ノルボルネン、2−メ
タリル−5−ノルボルネンおよび2−イソプロペニル−
5−ノルボルネンなどのアルケニルノルボルネン等が挙
げられる。上記ゴムの中ではEPR、EBRおよびEP
DMが好ましく、特に耐熱性、引張特性および反発弾性
が優れた組成物を与える点から非共役ジエンとしてエチ
リデンノルボルネンを用いたEPDMが好ましい。Here, the non-conjugated diene monomer of EPDM is a non-conjugated diene having 5 to 20 carbon atoms, for example, 1,4
-Pentadiene, 1,4-hexadiene, 1,5-hexadiene, 2,5-dimethyl-1,5-hexadiene and 1,4-octadiene, and, for example, 1,4-cyclohexadiene, cyclooctadiene, dicyclopentadiene, etc. A cyclic diene such as 5-ethylidene-2-norbornene, 5-butylidene-2-norbornene, 2-methallyl-5-norbornene and 2-isopropenyl-
Examples thereof include alkenyl norbornene such as 5-norbornene. Among the above rubbers, EPR, EBR and EP
DM is preferred, and EPDM using ethylidene norbornene as the non-conjugated diene is particularly preferred from the viewpoint of providing a composition having excellent heat resistance, tensile properties and impact resilience.
【0019】EPDMを構成するコモノマーの割合は、
エチレン含有率が50〜80重量%、好ましくは55〜
70重量%、プロピレン含有率が20〜50重量%、好
ましくは25〜40重量%、ジエン化合物含有率が1〜
20重量%、好ましくは2〜10重量%である。ヨウ素
価は3〜70が好ましい。また、ムーニー粘度(ML
1+4 ,100℃)は50以上であり、100以上が好ま
しい。ムーニー粘度が50未満の低分子量のEPDMで
はオイル(鉱油系軟化剤)の抱き込み性が悪くなるでの
好ましくない。The proportion of comonomer composing EPDM is
Ethylene content is 50-80% by weight, preferably 55-
70% by weight, propylene content is 20 to 50% by weight, preferably 25 to 40% by weight, diene compound content is 1 to
It is 20% by weight, preferably 2 to 10% by weight. The iodine value is preferably 3 to 70. Also, the Mooney viscosity (ML
1 + 4 , 100 ° C.) is 50 or more, preferably 100 or more. A low molecular weight EPDM having a Mooney viscosity of less than 50 is not preferable because the embracing property of oil (mineral oil-based softening agent) is deteriorated.
【0020】(d)成分の鉱油系軟化剤は、ゴムをロー
ル加工する際、ゴムの分子間作用力を弱め、加工を容易
にすると共に、カーボンブラック、ホワイトカーボン等
の分散を助け、また熱可塑性エラストマーの流動性およ
び柔軟性を改善する。具体例としては、パラフィン系、
ナフテン系、芳香族系等の石油系軟化剤、重合した高沸
点強芳香族系オイル、流動パラフィン、ホワイトオイル
などが挙げられる。これらの中でも、石油系軟化剤が好
ましい。(d)成分を配合することにより、成形性が向
上するのみでなく、エアーバッグ収納用カバーの風合
い、触感、柔軟性、さらには低温物性も向上する。The mineral oil-based softening agent as the component (d) weakens the intermolecular action force of the rubber during roll processing of the rubber, facilitates the processing, assists dispersion of carbon black, white carbon, etc. Improves flowability and flexibility of plastic elastomers. As a specific example, paraffinic,
Examples include naphthene-based and aromatic petroleum-based softening agents, polymerized high-boiling strong aromatic oils, liquid paraffin, and white oil. Among these, petroleum-based softeners are preferable. By blending the component (d), not only the moldability is improved, but also the texture, feel, flexibility and low-temperature physical properties of the air bag storage cover are improved.
【0021】これらの成分に加工成形時の剥離性を向上
させるために、脂肪酸系滑剤(e)を配合するのが好ま
しい。脂肪酸系滑剤の具体的例としては、ステアリン酸
アミド、エルカ酸アミド、オレイン酸アミド、メチレン
ビスステアロアミド、エチレンビスステアロアミドおよ
びこれらの混合物、または含有物があり、成形加工温度
等の使用条件により選択することができる。これらの中
では特にエルカ酸アミドが好ましい。It is preferable to add a fatty acid type lubricant (e) to these components in order to improve the releasability during processing and molding. Specific examples of the fatty acid-based lubricant include stearic acid amide, erucic acid amide, oleic acid amide, methylene bis stearamide, ethylene bis stearamide, and mixtures or inclusions thereof. It can be selected depending on the conditions. Among these, erucic acid amide is particularly preferable.
【0022】本発明では上記した成分以外にも、所望に
より他の成分を配合することができる。例えばカーボン
ブラックを添加することにより着色と同時に良好な耐候
性を得ることができる。また、炭酸カルシウム、タル
ク、カオリン、マイカ、ガラス繊維、合成繊維などのフ
ィラーを加えることによって成形時の寸法安定性、離型
性等を向上させることができる。さらに、紫外線吸収
剤、加工助剤、熱安定剤、光安定剤、難燃剤、帯電防止
剤、造核剤等成形用樹脂組成物の分野で使用されている
添加剤を通常の割合で適宜配合することができる。In the present invention, in addition to the above components, other components can be blended if desired. For example, by adding carbon black, good weatherability can be obtained at the same time as coloring. Further, by adding a filler such as calcium carbonate, talc, kaolin, mica, glass fiber or synthetic fiber, it is possible to improve dimensional stability during molding, releasability and the like. Furthermore, ultraviolet absorbers, processing aids, heat stabilizers, light stabilizers, flame retardants, antistatic agents, nucleating agents, and the like, which are used in the field of molding resin compositions, are appropriately added in the usual proportions. can do.
【0023】[0023]
【各成分の配合割合】各成分の配合割合は、まず(a)
ポリプロピレンと(b)ポリエチレンと(c)エチレン
系共重合体ゴムとの割合は(a)成分が20〜60重量
%、好ましくは30〜50重量%で、成分(b)が5〜
30重量%、好ましくは5〜25重量%で、成分(c)
が75〜10重量%、好ましくは65〜25重量%であ
る。(d)鉱油系軟化剤の配合量は、前記成分(a)と
(b)と(c)との合計100重量部に対して、10〜
120重量部である。[Blending ratio of each component] The mixing ratio of each component is (a)
The proportion of polypropylene, (b) polyethylene, and (c) ethylene-based copolymer rubber is such that the component (a) is 20 to 60% by weight, preferably 30 to 50% by weight, and the component (b) is 5 to 5.
30% by weight, preferably 5 to 25% by weight of component (c)
Is 75 to 10% by weight, preferably 65 to 25% by weight. The amount of the mineral oil-based softening agent (d) is 10 to 100 parts by weight of the total of the components (a), (b) and (c).
It is 120 parts by weight.
【0024】成分(a)が20重量%未満では、得られ
る熱可塑性エラストマーの流動性が低くなるため成形性
が低下し、60重量%を超えると機械的強度が高くなり
すぎ、カバーの破壊想定部分の厚みを薄くする必要があ
り成形加工が困難となり、また光沢が発生するなど外観
がプラスチックライクとなり、触感も悪化する。成分
(b)が5重量%未満では物性の改善効果が現れず、3
0重量%を越えると曲げ弾性率等の機械的物性が上昇す
ることとなり、エアーバッグカバーとした際、エアーバ
ッグ膨脹の際のカバーの開裂破壊が困難となる。成分
(c)が10重量%未満では機械的強度が高くなりす
ぎ、かつ低温での衝撃強度等の物性が低下することとな
り、75重量%を越えると流動性が低くなり成形性が低
下する。When the content of the component (a) is less than 20% by weight, the thermoplastic elastomer obtained has a low fluidity, so that the moldability is deteriorated, and when it exceeds 60% by weight, the mechanical strength becomes too high and the cover is expected to break. Since it is necessary to reduce the thickness of the part, the molding process becomes difficult, and the appearance becomes plastic-like due to the occurrence of luster, and the touch feel deteriorates. When the content of the component (b) is less than 5% by weight, the effect of improving the physical properties does not appear and 3
If it exceeds 0% by weight, mechanical properties such as flexural modulus will increase, and it will be difficult to break the cover when the air bag is inflated when the air bag is expanded. If the content of the component (c) is less than 10% by weight, the mechanical strength will be too high and the physical properties such as impact strength at low temperature will be deteriorated, and if it exceeds 75% by weight, the fluidity will be low and the moldability will be deteriorated.
【0025】成分(d)(鉱油系軟化剤)の配合量が1
0重量部未満だと配合による効果が現われず、120重
量部を超えると成形物が変形したり、成形後に滲出(ブ
リードアウト)が発生したり、耐候性が悪化するので好
ましくない。The amount of component (d) (mineral oil-based softening agent) is 1
If it is less than 0 parts by weight, the effect of the compounding will not be exhibited, and if it exceeds 120 parts by weight, the molded product is deformed, bleeding out occurs after molding, and the weather resistance is deteriorated, which is not preferable.
【0026】また、成分(e)(脂肪酸系滑剤)は、前
記成分(a)と(b)と(c)との合計100重量部に
対して、0.2 〜2.0 重量部であり、配合量が0.2 重量部
未満だと配合による効果が現れず、2.0 重量部を超える
とブリードアウトし、離型性も悪化する。The component (e) (fatty acid-based lubricant) is 0.2 to 2.0 parts by weight with respect to 100 parts by weight of the components (a), (b) and (c) in total, and the compounding amount is If it is less than 0.2 parts by weight, the effect of the compounding will not be exhibited, and if it exceeds 2.0 parts by weight, bleed-out will occur and the releasability will be deteriorated.
【0027】[0027]
【組成物の製造方法】本発明のエアーバッグカバー材用
オレフィン系熱可塑性エラストマー組成物は、各成分を
上記の割合で、また、その他の添加剤を適宜使用して配
合混練することにより製造することができるが、配合混
練の操作手順を工夫することによって、製造プロセスが
簡略化されると共に、一層好ましい物性を有する組成物
を得ることができる。すなわち、混練は通常は一括して
配合することにより行なうことができるが、本発明にお
いては(c)エチレン系共重合体ゴムと(d)鉱油系軟
化剤を予め混練して油展組成物を調製し、この油展組成
物を(a)ポリプロピレンおよび(b)ポリエチレンに
配合し混練することが好ましい。[Production Method of Composition] The olefinic thermoplastic elastomer composition for air bag cover material of the present invention is produced by blending and kneading the respective components in the above proportions and other additives as appropriate. However, by devising the operation procedure of compounding and kneading, the production process can be simplified and a composition having more preferable physical properties can be obtained. That is, the kneading can be usually carried out by blending all at once, but in the present invention, (c) the ethylene copolymer rubber and (d) the mineral oil-based softening agent are previously kneaded to form an oil-extended composition. It is preferable to prepare, blend this oil-extended composition with (a) polypropylene and (b) polyethylene, and knead.
【0028】エチレン系共重合体ゴムと鉱油系軟化剤を
別個の成分として配合する場合には、鉱油系軟化剤の貯
蔵用タンク、ポンプ、予熱装置等の設備が必要となる
が、油展物を使用する場合には組成物の混練時間が短縮
できることや(別個の成分として配合した場合の約2/
3の時間で混練できる。)、エチレン系共重合体ゴムお
よび鉱油系軟化剤の分散性を高めることができ、物性が
向上するだけでなく、生産性の向上、コストの節減が可
能となる。具体的には、例えば、エチレン系共重合体ゴ
ムと鉱油系軟化剤をニーダーにて混練後、または予めE
PDMと鉱油系軟化剤を所定の割合で含有させた油展E
PDMを調製後、ポリプロピレン等の成分を二軸押出機
およびホットカッターを用いる方法、あるいはニーダー
またはバンバリーミキサーで混練後、フィーダールーダ
ー、単軸押出機およびホットカッターを用いる方法によ
り製造することができる。When the ethylene copolymer rubber and the mineral oil-based softening agent are blended as separate components, equipment such as a tank for storing the mineral oil-based softening agent, a pump, and a preheating device are required. When using, it is possible to shorten the kneading time of the composition and (about 2 / when compared as a separate component)
Can be kneaded in 3 hours. ), The dispersibility of the ethylene-based copolymer rubber and the mineral oil-based softening agent can be enhanced, and not only the physical properties are improved, but also the productivity and the cost can be reduced. Specifically, for example, after kneading the ethylene copolymer rubber and the mineral oil softener with a kneader, or E in advance.
Oil-extended E containing PDM and mineral oil-based softener in a prescribed ratio
After the PDM is prepared, components such as polypropylene can be produced by a method using a twin-screw extruder and a hot cutter, or by kneading with a kneader or a Banbury mixer and then using a feeder ruder, a single-screw extruder and a hot cutter.
【0029】エアーバッグカバー材用として利用される
本発明のオレフィン系熱可塑性エラストマー組成物は、
JIS A硬度(JIS K6301 )として80以上、曲げ弾
性率(JIS K7203 )として500〜2500kg/cm2 の
ものが特に好ましい。硬度が低いと変形を起こしやすく
保形性に劣り、また曲げ弾性率が高くなるとエアーバッ
グ膨脹の際のカバー開裂破壊が困難となる。The olefinic thermoplastic elastomer composition of the present invention used as an air bag cover material is
Those having a JIS A hardness (JIS K6301) of 80 or more and a flexural modulus (JIS K7203) of 500 to 2500 kg / cm 2 are particularly preferable. If the hardness is low, deformation is likely to occur and the shape retention is poor, and if the flexural modulus is high, it is difficult to break the cover when the airbag is inflated.
【0030】本発明のエアーバッグカバー材用オレフィ
ン系熱可塑性エラストマー組成物をエアーバッグ収納用
カバーに成形する方法としては、通常行なわれている方
法でよく、例えばエアーバッグの作動時に破断部分とな
る薄肉部を内面が例えばH字状の凹部となるような金型
を使用して、射出成形などの一般的な成形法により成形
する。The method for molding the olefinic thermoplastic elastomer composition for an air bag cover material of the present invention into a cover for accommodating an air bag may be a commonly used method, for example, a breakage portion when the air bag is operated. The thin portion is molded by a general molding method such as injection molding using a mold whose inner surface becomes a recess having an H shape, for example.
【0031】[0031]
【実施例】以下、実施例および比較例により本発明をさ
らに詳細に説明するが、本発明は下記の記載により限定
されるものではない。なお、各実施例および比較例にお
いて、樹脂原料および添加剤としては、以下のものを使
用した。The present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to the following description. In addition, in each of Examples and Comparative Examples, the following materials were used as the resin raw material and the additive.
【0032】(a)ポリプロピレン(PP):MFR
(230℃,2.16荷重)80g/10分。 (b)ポリエチレン(PE): (1)高密度ポリエチレン(HDPE):MFR(230
℃,2.16荷重)30g/10分,密度0.955 g/c
m3 、 (2)低密度ポリエチレン(LDPE):MFR(230
℃,2.16荷重)65g/10分,密度0.915 g/c
m3 、 (3)線状低密度ポリエチレン(LLDPE):MFR
(230℃,2.16荷重)50g/10分,密度0.926 g
/cm3 。 (c)エチレン−プロピレン−非共役ジエン共重合体
(EPDM):プロピレン含量28重量%,ヨウ素価1
5,ムーニー粘度(ML1+4 、100℃)320。 (d)鉱油軟化剤(オイル):パラフィン系鉱物油(P
W−380,出光(株)製)。 (e)脂肪酸系滑剤(滑剤):脂肪酸アミド系滑剤(ス
ラクトールWB−16,Schill and Seilacher社製)。 (f)スチレン−ブタジエンブロック共重合体水素添加
物(SEBS):スチレン含量30重量%,MFR(2
30℃,2.16荷重)10g/10分。(A) Polypropylene (PP): MFR
(230 ℃, 2.16 load) 80g / 10min. (B) Polyethylene (PE): (1) High density polyethylene (HDPE): MFR (230
℃, 2.16 load) 30g / 10min, density 0.955g / c
m 3 , (2) Low density polyethylene (LDPE): MFR (230
℃, 2.16 load) 65g / 10min, density 0.915g / c
m 3 , (3) Linear low density polyethylene (LLDPE): MFR
(230 ℃, 2.16 load) 50g / 10min, density 0.926g
/ Cm 3 . (C) Ethylene-propylene-non-conjugated diene copolymer (EPDM): propylene content 28% by weight, iodine value 1
5, Mooney viscosity (ML 1 + 4 , 100 ° C.) 320. (D) Mineral oil softener (oil): paraffinic mineral oil (P
W-380, manufactured by Idemitsu Co., Ltd. (E) Fatty acid-based lubricant (lubricant): Fatty acid amide-based lubricant (Sractol WB-16, manufactured by Schill and Seilacher). (F) Styrene-butadiene block copolymer hydrogenated product (SEBS): styrene content 30% by weight, MFR (2
30 ° C, 2.16 load) 10g / 10 minutes.
【0033】実施例1 表1に示した割合で(c)EPDMと(d)オイルを予
めニーダーにて溶融温度200℃で20分間混練してオ
イルを含有した油展EPDMとし、これに他の成分を加
え、樹脂温度220℃で二軸押出機にて溶融混練しホッ
トカッターで切断してオレフィン系熱可塑性エラストマ
ー組成物を得た。この組成物を成形して物性測定用のサ
ンプルを作成し、エアーバッグカバー材の指標となる物
性(MFR、JIS A硬度、破断強度、引裂強度、ア
イゾット衝撃強度、曲げ弾性率、制振性、成形性)を測
定した。各成分の配合割合と共に測定結果を表1に示
す。 Example 1 (c) EPDM and (d) oil in the proportions shown in Table 1 were kneaded in advance with a kneader at a melting temperature of 200 ° C. for 20 minutes to obtain an oil-extended EPDM, and other components were added. The components were added, and the mixture was melt-kneaded at a resin temperature of 220 ° C. with a twin-screw extruder and cut with a hot cutter to obtain an olefinic thermoplastic elastomer composition. This composition is molded to prepare a sample for measuring physical properties, and physical properties (MFR, JIS A hardness, breaking strength, tear strength, Izod impact strength, flexural modulus, vibration damping property, which serve as an index of an air bag cover material, Moldability) was measured. Table 1 shows the measurement results together with the blending ratio of each component.
【0034】実施例2〜4,比較例1〜3 各成分を表1に示した割合で使用し、実施例1と同様の
方法により、エアーバッグカバー材用オレフィン系熱可
塑性エラストマー組成物を得た。この組成物から物性測
定用のサンプル作成し、各物性を測定した。各成分の配
合割合と共に測定結果を表1に示す。 Examples 2 to 4 and Comparative Examples 1 to 3 Using the components in the proportions shown in Table 1, the same procedure as in Example 1 was carried out to obtain an olefinic thermoplastic elastomer composition for an air bag cover material. It was A sample for measuring physical properties was prepared from this composition, and each physical property was measured. Table 1 shows the measurement results together with the blending ratio of each component.
【0035】[0035]
【表1】 [Table 1]
【0036】表1に示した各物性の測定および評価方法
は以下のとおりである。 (1) MFR(g/10分):230℃,2.16kg荷重で測
定。 (2) JIS A硬度:JIS K6301 により測定。 (3) 破断強度(kg/cm2 ):JIS K6301 により測
定。 (4) 引裂強度(kg/cm):JIS K6301 により測定。 (5) アイゾット衝撃強度(kg・cm/cm2 ):JIS
K7110 (ノッチ付)により測定(−50℃)し、破壊の
有無を観察した。 NB:破壊せず、 ×:破壊。 (6) 曲げ弾性率(kg/cm2 ):JIS K7203 により測
定。The measurement and evaluation methods of each physical property shown in Table 1 are as follows. (1) MFR (g / 10 minutes): Measured at 230 ° C and 2.16 kg load. (2) JIS A hardness: Measured according to JIS K6301. (3) Breaking strength (kg / cm 2 ): Measured according to JIS K6301. (4) Tear strength (kg / cm): Measured according to JIS K6301. (5) Izod impact strength (kg · cm / cm 2 ): JIS
It was measured (−50 ° C.) with K7110 (with notch) and observed for breakage. NB: not destroyed, x: destroyed. (6) Flexural modulus (kg / cm 2 ): Measured according to JIS K7203.
【0037】(7) 成形性:220℃における高速剪断時
に測定(キャピラリーレオメーター(東洋精機製作所
製)により剪断速度1000/秒にて測定)した粘度に
より、成形性を以下の基準で評価した。 ◎:900poise 以下、 ○:900poise を超え1200poise 以下、 △:1200poise を超え1500poise 以下、 ×:1500poise を超えるもの。(7) Moldability: The moldability was evaluated according to the following criteria by the viscosity measured at a high-speed shearing at 220 ° C. (measured by a capillary rheometer (manufactured by Toyo Seiki Seisaku-sho, Ltd. at a shearing rate of 1000 / sec)). ⊚: 900 poise or less, ◯: 900 poise to 1200 poise or less, Δ: 1200 poise to 1500 poise or less, ×: 1500 poise or more.
【0038】(8) 制振性:固体粘弾性測定装置により、
−150℃〜200℃の範囲で5℃毎に1ヘルツ(H
z)の定周波を組成物に与え、各温度における貯蔵弾性
率および損失弾性率を測定し、その値より算出した力学
損失正接(tanδ)と温度により得た分散カーブによ
り以下の基準で評価した。 ○:tanδの分散カーブが−5〜30℃の温度範囲に
あるもの、 ×:tanδの分散カーブが−5〜30℃の温度範囲外
にあるもの。(8) Damping property: With a solid viscoelasticity measuring device,
1 Hertz (H) every 5 ° C in the range of -150 ° C to 200 ° C
The constant frequency of z) was applied to the composition, the storage elastic modulus and the loss elastic modulus at each temperature were measured, and the dispersion loss obtained by the mechanical loss tangent (tan δ) and the temperature was calculated according to the following criteria. . ◯: A dispersion curve of tan δ is in the temperature range of −5 to 30 ° C., ×: Dispersion curve of tan δ is outside the temperature range of −5 to 30 ° C.
【0039】表1より明らかなように、ポリエチレンを
加えたもの(実施例1〜4)は、破断強度が改善され、
低温物性(アイゾット衝撃強度:−50℃)、曲げ弾性
率も良好な値を示しており、特にポリエチレンをLDP
E(実施例3)、LLDPE(実施例4)とすることに
より低引裂強度で、かつ破断強度がいっそう改善され、
ポリエチレン未添加のもの(比較例1)、本発明の範囲
を越えたもの(比較例3)およびゴム成分としてSEB
Sを用いたもの(比較例2)に比べて、バランスのとれ
た良好な物性を示していることがわかる。As is clear from Table 1, the polyethylenes added (Examples 1 to 4) have improved breaking strength.
Low temperature physical properties (Izod impact strength: -50 ° C) and flexural modulus also show good values, especially polyethylene is LDP.
By using E (Example 3) and LLDPE (Example 4), the tear strength is low and the breaking strength is further improved.
Polyethylene not added (Comparative Example 1), one exceeding the range of the present invention (Comparative Example 3) and SEB as a rubber component
It can be seen that, as compared with the one using S (Comparative Example 2), it shows well-balanced and good physical properties.
【0040】[0040]
【発明の効果】本発明のエアーバッグカバー材用オレフ
ィン系熱可塑性エラストマー組成物は、メルトフローレ
ート(230℃,2.16kg荷重)が20〜200g/10
分の高流動性ポリプロピレンと、ポリエチレンと、ムー
ニー粘度(ML1+4 ,100℃)が50以上の高分子量
エチレン系共重合体と、鉱油系軟化剤とを配合、混練し
た組成物である。本発明のエアーバッグカバー材用組成
物はオレフィン系系熱可塑性樹脂組成物のみを使用する
ものであり、これにより作成したエアーバッグカバーは
作動時には確実に破壊され、ネットなどの補助材を使用
しなくても破片が飛び散らず、広い温度範囲において確
実に作動し、柔軟性も保ち、表面性、成形性に優れ、−
50℃という低温においても脆化はみられず温度適応性
にも優れている。また、従来のスチレン系熱可塑性エラ
ストマー(SEBS等)を用いたものに比べて使用頻度
の高い温度域(10〜25℃)での制振性に優れるほ
か、オレフィン系樹脂組成物を使用しているため効率良
く生産でき、また使用後のリサイクルも可能である。The olefinic thermoplastic elastomer composition for air bag cover material of the present invention has a melt flow rate (230 ° C., 2.16 kg load) of 20 to 200 g / 10.
A composition obtained by mixing and kneading a high-fluidity polypropylene, polyethylene, a high-molecular-weight ethylene copolymer having a Mooney viscosity (ML 1 + 4 , 100 ° C.) of 50 or more, and a mineral oil-based softening agent. The composition for an air bag cover material of the present invention uses only an olefinic thermoplastic resin composition, and the air bag cover created by this is reliably destroyed during operation, and an auxiliary material such as a net is used. Even if it is not used, fragments will not scatter, operate reliably in a wide temperature range, maintain flexibility, excellent surface property and moldability,
No brittleness is observed even at a low temperature of 50 ° C, and the temperature adaptability is excellent. Further, in addition to being superior in vibration damping in a temperature range (10 to 25 ° C.) in which the frequency of use is high, the olefin resin composition is used as compared with a conventional styrene thermoplastic elastomer (SEBS etc.). Therefore, it can be efficiently produced and can be recycled after use.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C08L 91/00 LSJ ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI technical display area C08L 91/00 LSJ
Claims (5)
2.16kg荷重)20〜200g/10分のポリプロピレン
20〜60重量%と、(b)ポリエチレン5〜30重量
%と、(c)ムーニー粘度(ML1+4 ,100℃)50
以上のエチレン系共重合体ゴム75〜10重量%と、前
記成分(a)と(b)と(c)の合計100重量部に対
して(d)鉱油系軟化剤10〜120重量部を含有して
なるエアーバッグカバー材用オレフィン系熱可塑性エラ
ストマー組成物。1. A melt flow rate (230 ° C.,
2.16 kg load) 20 to 200 g / 10 min polypropylene 20 to 60% by weight, (b) polyethylene 5 to 30% by weight, (c) Mooney viscosity (ML 1 + 4 , 100 ° C.) 50
75 to 10% by weight of the above ethylene-based copolymer rubber and 10 to 120 parts by weight of (d) a mineral oil-based softening agent based on 100 parts by weight of the components (a), (b) and (c) in total. An olefinic thermoplastic elastomer composition for an air bag cover material.
ンである請求項1記載のエアーバッグカバー材用オレフ
ィン系熱可塑性エラストマー組成物。2. The olefinic thermoplastic elastomer composition for an air bag cover material according to claim 1, wherein the polyethylene (b) is low density polyethylene.
チレンである請求項1記載のエアーバッグカバー材用オ
レフィン系熱可塑性エラストマー組成物。3. The olefinic thermoplastic elastomer composition for an air bag cover material according to claim 1, wherein the polyethylene (b) is a linear low density polyethylene.
(d)成分の鉱油系軟化剤が、予め両成分を混練した油
展組成物として配合されている請求項1乃至3のいずれ
かの項に記載のエアーバッグカバー材用オレフィン系熱
可塑性エラストマー組成物。4. The ethylene-based copolymer rubber as the component (c) and the mineral oil-based softener as the component (d) are blended as an oil-extended composition in which both components are kneaded in advance. An olefinic thermoplastic elastomer composition for an air bag cover material according to the above item.
上、曲げ弾性率(JIS K7203 )が500〜2500kg/
cm2 である請求項1乃至4のいずれかの項に記載のエア
ーバッグカバー材用オレフィン系熱可塑性エラストマー
組成物。5. A JIS A hardness (JIS K6301) of 80 or more and a flexural modulus (JIS K7203) of 500 to 2500 kg /
The olefin-based thermoplastic elastomer composition for an air bag cover material according to any one of claims 1 to 4, which has a cm 2 size.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17605294A JPH0820687A (en) | 1994-07-05 | 1994-07-05 | Olefinic thermoplastic elastomer composition for air bag covering material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17605294A JPH0820687A (en) | 1994-07-05 | 1994-07-05 | Olefinic thermoplastic elastomer composition for air bag covering material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0820687A true JPH0820687A (en) | 1996-01-23 |
Family
ID=16006881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17605294A Pending JPH0820687A (en) | 1994-07-05 | 1994-07-05 | Olefinic thermoplastic elastomer composition for air bag covering material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0820687A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100699741B1 (en) * | 2000-02-10 | 2007-03-27 | 스미또모 가가꾸 가부시끼가이샤 | Thermoplastic elastomer composition for calendar molding and sheet produced therefrom |
-
1994
- 1994-07-05 JP JP17605294A patent/JPH0820687A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100699741B1 (en) * | 2000-02-10 | 2007-03-27 | 스미또모 가가꾸 가부시끼가이샤 | Thermoplastic elastomer composition for calendar molding and sheet produced therefrom |
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