JPH08214936A - Hair coloring device - Google Patents
Hair coloring deviceInfo
- Publication number
- JPH08214936A JPH08214936A JP4474595A JP4474595A JPH08214936A JP H08214936 A JPH08214936 A JP H08214936A JP 4474595 A JP4474595 A JP 4474595A JP 4474595 A JP4474595 A JP 4474595A JP H08214936 A JPH08214936 A JP H08214936A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- comb
- hairdye
- comb teeth
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000037308 hair color Effects 0.000 title abstract description 7
- 239000000443 aerosol Substances 0.000 claims abstract description 23
- 238000004043 dyeing Methods 0.000 claims description 27
- 239000000975 dye Substances 0.000 claims description 11
- 239000000118 hair dye Substances 0.000 abstract description 43
- 244000126211 Hericium coralloides Species 0.000 abstract description 8
- 238000002347 injection Methods 0.000 abstract 4
- 239000007924 injection Substances 0.000 abstract 4
- -1 aluminum may corrode Chemical class 0.000 description 27
- 210000004761 scalp Anatomy 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 230000002378 acidificating effect Effects 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- 239000011550 stock solution Substances 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 8
- 239000003380 propellant Substances 0.000 description 8
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
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- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 238000012856 packing Methods 0.000 description 7
- 239000000049 pigment Substances 0.000 description 7
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- 239000002253 acid Substances 0.000 description 6
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- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
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- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 4
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- 235000012730 carminic acid Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
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- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
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- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000007854 depigmenting agent Substances 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- VPWFPZBFBFHIIL-UHFFFAOYSA-L disodium 4-[(4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 VPWFPZBFBFHIIL-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229920002549 elastin Polymers 0.000 description 1
- 235000012732 erythrosine Nutrition 0.000 description 1
- TVFJAZCVMOXQRK-UHFFFAOYSA-N ethenyl 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)OC=C TVFJAZCVMOXQRK-UHFFFAOYSA-N 0.000 description 1
- FYUWIEKAVLOHSE-UHFFFAOYSA-N ethenyl acetate;1-ethenylpyrrolidin-2-one Chemical compound CC(=O)OC=C.C=CN1CCCC1=O FYUWIEKAVLOHSE-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019277 ethyl gallate Nutrition 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229960002413 ferric citrate Drugs 0.000 description 1
- 229940032958 ferric phosphate Drugs 0.000 description 1
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 description 1
- 235000019268 ferrous carbonate Nutrition 0.000 description 1
- 229960004652 ferrous carbonate Drugs 0.000 description 1
- 229940062993 ferrous oxalate Drugs 0.000 description 1
- 229940116007 ferrous phosphate Drugs 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 229940071676 hydroxypropylcellulose Drugs 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- OWZIYWAUNZMLRT-UHFFFAOYSA-L iron(2+);oxalate Chemical compound [Fe+2].[O-]C(=O)C([O-])=O OWZIYWAUNZMLRT-UHFFFAOYSA-L 0.000 description 1
- ATEAWHILRRXHPW-UHFFFAOYSA-J iron(2+);phosphonato phosphate Chemical compound [Fe+2].[Fe+2].[O-]P([O-])(=O)OP([O-])([O-])=O ATEAWHILRRXHPW-UHFFFAOYSA-J 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 description 1
- 229910000015 iron(II) carbonate Inorganic materials 0.000 description 1
- 229910000155 iron(II) phosphate Inorganic materials 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 1
- 229910000399 iron(III) phosphate Inorganic materials 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- SDEKDNPYZOERBP-UHFFFAOYSA-H iron(ii) phosphate Chemical compound [Fe+2].[Fe+2].[Fe+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O SDEKDNPYZOERBP-UHFFFAOYSA-H 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 229940046892 lead acetate Drugs 0.000 description 1
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- IBKQQKPQRYUGBJ-UHFFFAOYSA-N methyl gallate Natural products CC(=O)C1=CC(O)=C(O)C(O)=C1 IBKQQKPQRYUGBJ-UHFFFAOYSA-N 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- AXKVOSSFZLZIDC-UHFFFAOYSA-N n,n-diaminoaniline Chemical class NN(N)C1=CC=CC=C1 AXKVOSSFZLZIDC-UHFFFAOYSA-N 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- 229960003893 phenacetin Drugs 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Chemical compound O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- ZZYXNRREDYWPLN-UHFFFAOYSA-N pyridine-2,3-diamine Chemical class NC1=CC=CN=C1N ZZYXNRREDYWPLN-UHFFFAOYSA-N 0.000 description 1
- 229940095042 pyridoxine dipalmitate Drugs 0.000 description 1
- ZUFQODAHGAHPFQ-UHFFFAOYSA-N pyridoxine hydrochloride Chemical compound Cl.CC1=NC=C(CO)C(CO)=C1O ZUFQODAHGAHPFQ-UHFFFAOYSA-N 0.000 description 1
- 229960004172 pyridoxine hydrochloride Drugs 0.000 description 1
- 235000019171 pyridoxine hydrochloride Nutrition 0.000 description 1
- 239000011764 pyridoxine hydrochloride Substances 0.000 description 1
- 229940051201 quinoline yellow Drugs 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- LGZQSRCLLIPAEE-UHFFFAOYSA-M sodium 1-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C(S([O-])(=O)=O)C2=C1 LGZQSRCLLIPAEE-UHFFFAOYSA-M 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 235000012756 tartrazine Nutrition 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 229960000943 tartrazine Drugs 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Landscapes
- Cleaning And Drying Hair (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、染毛用具に関するもの
で、詳しくは、染毛剤を毛髪に均一に塗布し、かつ頭皮
を染着せずに染毛することができ、また、使用時に垂れ
落ちて地肌や衣服を汚染することもなく、手指も汚すこ
となく簡便に使用できる毛髪着色用具に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair dyeing tool, and more specifically, it can apply a hair dye uniformly to hair and dye the hair without dyeing the scalp. The present invention relates to a hair coloring tool that can be easily used without dripping to contaminate the skin or clothes and stain the fingers.
【0002】[0002]
【従来の技術】従来、実開昭61−190230号など
に開示されているように、ブラシを有する塗布部を装着
したエアゾール容器に毛髪化粧料を充填したものがあっ
た。これらの毛髪化粧料は、手軽に塗布できるために、
ヘアカラーやヘアケアに広く利用されてきた。2. Description of the Related Art Conventionally, as disclosed in Japanese Utility Model Application Laid-Open No. 61-190230, there has been one in which an aerosol container equipped with an application part having a brush is filled with hair cosmetics. Since these hair cosmetics can be easily applied,
It has been widely used in hair coloring and hair care.
【0003】[0003]
【発明が解決しようとする課題】しかし、従来のヘアカ
ラー用の塗布具では、頭髪に均一に塗布し、かつ頭皮を
染着せずに染毛するには、ある程度の熟練を要するとい
う欠点があった。また、使用時に染毛料が垂れ落ちて地
肌や衣服を汚染するという欠点があった。However, the conventional hair color applicator has a drawback that it requires a certain amount of skill to apply it evenly to the hair and to dye the hair without dyeing the scalp. It was Further, there is a drawback that the hair dye drips during use and contaminates the skin and clothes.
【0004】[0004]
【課題を解決するための手段】本発明者らは、染毛剤を
収容するエアゾール容器に、櫛部を取り付けた染毛用具
において、噴出ノズルと連通するL字型のパイプを設け
たことにより、簡単な構造で、頭髪に均一に塗布し、か
つ頭皮を染着せずに染毛することができ、また、使用時
に垂れ落ちて地肌や衣服を汚染することもなく、手指も
汚すことなく簡便に使用できる染毛用具を完成した。Means for Solving the Problems In the hair dyeing tool in which a comb portion is attached to an aerosol container containing a hair dye, the present inventors have provided an L-shaped pipe communicating with a jet nozzle. With a simple structure, it can be applied evenly to the hair, and it can be dyed without dyeing the scalp, and it does not drips during use and contaminates the skin or clothes, and it does not stain the hands or fingers easily. A usable hair dyeing tool has been completed.
【0005】本発明の染毛用具を用いれば、エアゾール
容器に充填された染毛剤は、噴射剤の圧力により噴出ノ
ズル、L字型パイプを通り、排出通路に排出される。噴
出ノズルから櫛部へ染毛剤を供給するために、L字型パ
イプを用いることにより、噴出ノズルの上部にプッシュ
ボタンを設けることができ、力を入れやすい構造にする
ことができた。なお、L字型パイプはプッシュボタンの
上下動作と連動して上下動作する。その材質はステンレ
ス製などの金属製あるいは合成樹脂製などのある程度の
硬度を有するものであればよい。また、L字型パイプか
ら排出通路に排出された染毛剤が逆流しないようにパッ
キンを設けた。なお、このパッキン6はL字型パイプ2
が上下動作しやすいように中空構造とした。With the hair dyeing tool of the present invention, the hair dye filled in the aerosol container is discharged to the discharge passage through the jet nozzle and the L-shaped pipe by the pressure of the propellant. By using the L-shaped pipe to supply the hair dye from the ejection nozzle to the comb portion, the push button can be provided on the upper portion of the ejection nozzle, and the structure can be easily applied. The L-shaped pipe moves up and down in conjunction with the up and down operation of the push button. The material may be metal such as stainless steel or synthetic resin having a certain degree of hardness. In addition, packing is provided so that the hair dye discharged from the L-shaped pipe to the discharge passage does not flow back. The packing 6 is an L-shaped pipe 2
It has a hollow structure to facilitate vertical movement.
【0006】排出通路は櫛歯の先端から間隔をおいた部
位に設られた注出孔に連通している。従って、排出され
た染毛剤は櫛歯の中間〜根元付近に均一に供給される。
このような状態で、櫛歯を頭髪に接触させると、櫛歯に
よって整髪しながら均一に染毛することことができる。
また、染毛剤は櫛歯の中間部〜根元付近にあるので頭皮
を染着する恐れがない。特に、酸性染料を用いる染毛剤
のように地肌に染着しやすい染毛料の場合は有用であ
る。The discharge passage communicates with a pouring hole provided at a position spaced from the tips of the comb teeth. Therefore, the discharged hair dye is uniformly supplied from the middle of the comb teeth to the vicinity of the root.
When the comb teeth are brought into contact with the hair in such a state, the hair can be uniformly dyed while the hair is adjusted by the comb teeth.
In addition, since the hair dye is located between the middle part and the root of the comb teeth, there is no risk of dyeing the scalp. In particular, it is useful in the case of a hair dye that is easily dyed on the background such as a hair dye using an acid dye.
【0007】櫛部は多数の、例えば5本〜40本の櫛歯
からなり、櫛歯は長さ1〜5cm、厚み1〜6mmから
なり、巾は根元付近が2〜8mm、先端付近が0.5〜
4mmで先端の方が巾は狭くなっている。そして、排出
通路と連通する注出孔が櫛部の先端から間隔をおいた部
位に設けられている。注出孔は、先端から櫛歯の長さの
45%〜95%、好ましくは50%〜90%の部位、例
えば、櫛歯の長さが20mmの場合、先端から9〜19
mm、好ましくは10〜18mmの部位に注出孔が設け
られる。The comb portion is composed of a large number, for example, 5 to 40 comb teeth, the comb teeth are 1 to 5 cm in length and 1 to 6 mm in thickness, and the width is 2 to 8 mm near the base and 0. 5-
At 4 mm, the width is narrower at the tip. A spout hole communicating with the discharge passage is provided at a portion spaced from the tip of the comb portion. The pouring hole is 45% to 95%, preferably 50% to 90% of the length of the comb tooth from the tip, for example, 9 to 19% from the tip when the comb tooth length is 20 mm.
A pouring hole is provided at a site of mm, preferably 10 to 18 mm.
【0008】エアゾール容器本体は、その内部には染毛
剤および噴射剤からなる原液が充填されている。エアゾ
ール容器本体の材質は、原液の液性、特に、酸性染毛料
および脱色剤の場合はpHが酸性であることから、アル
ミニウムなどの金属は腐食する恐れがあるため、エポキ
シ樹脂やフェノール樹脂の合成樹脂でコーティングされ
たアルミニウム、あるいはポリエチレンテレフタレート
などの合成樹脂が好ましい。The aerosol container main body is filled with a stock solution of a hair dye and a propellant. The material of the aerosol container body is the liquidity of the undiluted solution, especially in the case of acidic hair dyes and depigmenting agents, the pH is acidic, so metals such as aluminum may corrode, so the synthesis of epoxy resin and phenol resin A resin-coated aluminum or a synthetic resin such as polyethylene terephthalate is preferable.
【0009】本発明の染毛剤としては、酸性染料を用い
る酸性染毛料あるいはヘアマニキュア、酸化染料を用い
る酸化染毛剤、金属塩を用いる金属染毛剤、あるいは植
物性染料を用いる植物染毛剤、過酸化水素を用いる毛髪
脱色剤などの公知の染毛剤が挙げられる。As the hair dye of the present invention, an acidic hair dye or hair nail polish using an acid dye, an oxidative hair dye using an oxidative dye, a metal hair dye using a metal salt, or a plant hair dye using a vegetable dye Examples of known hair dyes such as hair bleaching agents and hair bleaching agents using hydrogen peroxide.
【0010】本発明に用いられる酸性染料および/また
は顔料は次に挙げられる。「医薬品等に使用することが
できるタール色素を定める省令」(昭和41年告示、厚
生省)により定められたもの、例えば、赤色2号、赤色
3号、赤色102号、赤色104号の(1)、赤色10
5号の(1)、赤色106号、赤色201号、赤色22
7号、赤色230号の(1)、赤色230号の(2)、
赤色231号、赤色232号、赤色401号、赤色50
2号、赤色503号、赤色504号、赤色506号、黄
色4号、黄色5号、黄色202号の(1)、黄色202
号の(2)、黄色203号、黄色402号、黄色403
号の(1)、黄色406号、黄色407号、だいだい色
205号、だいだい色207号、だいだい色402号、
緑色3号、緑色204号、緑色205号、緑色401
号、緑色402号、紫色401号、青色1号、青色2
号、青色202号、青色203号、青色205号、かっ
色201号、黒色401号などが挙げられる。その配合
量は0.01〜10重量%、好ましくは0.1〜5重量
%である。The acid dyes and / or pigments used in the present invention are listed below. Those stipulated by the "Ministerial Ordinance that defines tar dyes that can be used in pharmaceutical products" (Notification in 1966, Ministry of Health and Welfare), for example, Red No. 2, Red No. 3, Red No. 102, Red No. 104 (1) , Red 10
No. 5 (1), Red 106, Red 201, Red 22
No. 7, red 230 (1), red 230 (2),
Red 231, Red 232, Red 401, Red 50
No. 2, Red No. 503, Red No. 504, Red No. 506, Yellow No. 4, Yellow No. 5, Yellow No. 202 (1), Yellow No. 202
No. (2), Yellow 203, Yellow 402, Yellow 403
No. (1), Yellow 406, Yellow 407, Day 205, Day 207, Day 402,
Green No. 3, Green No. 204, Green No. 205, Green 401
No. 402, Green No. 402, Purple No. 401, Blue No. 1, Blue No. 2
No. Blue No. 202, Blue No. 203, Blue No. 205, Brown No. 201, Black No. 401 and the like. The blending amount is 0.01 to 10% by weight, preferably 0.1 to 5% by weight.
【0011】無機顔料としては、酸化亜鉛、酸化チタ
ン、ベンガラ、酸化クロム、酸化コバルト、黒酸化鉄、
黄酸化鉄、水酸化クロム、水酸化アルミニウム、紺青、
硫酸バリウム、含水珪酸塩、無水珪酸、珪酸アルミニウ
ム、タルク、カオリン、カルミン、雲母、炭酸マグネシ
ウム、ベントナイト、群青、マンガンバイオレット、カ
ーボンブラック、アルミニウム、銅、金、雲母チタン、
有機顔料としては、赤色202,203,204,20
5,206,207,208,219,220,22
1,228,404,405号、だいだい色203,2
04,401号、黄色205,401号、青色404
号、その他、染料樹脂固溶体、昼光蛍光顔料、天然顔料
である鉱物顔料(クレー等)や天然染料レーキ(マダー
レーキ、コチニールレーキ等)などが用いられる。これ
らの内、ベンガラ、紺青、群青、黄酸化鉄、カルミン、
雲母チタン、カーボンブラツク、アゾ顔料、フタロシア
ニン顔料が好ましい。その配合量は、0.01〜15
%、好ましくは0.1〜10%である。0.01%未満
では十分な効果が得られず、また15%を越えた場合に
は安定に分散させることが困難となる。As the inorganic pigment, zinc oxide, titanium oxide, red iron oxide, chromium oxide, cobalt oxide, black iron oxide,
Yellow iron oxide, chromium hydroxide, aluminum hydroxide, navy blue,
Barium sulfate, hydrous silicate, anhydrous silicic acid, aluminum silicate, talc, kaolin, carmine, mica, magnesium carbonate, bentonite, ultramarine, manganese violet, carbon black, aluminum, copper, gold, titanium mica,
As the organic pigment, red 202, 203, 204, 20
5,206,207,208,219,220,22
No. 1,228,404,405, Daidai color 203,2
04,401, yellow 205,401, blue 404
In addition, dye resin solid solutions, daylight fluorescent pigments, natural pigments such as mineral pigments (such as clay) and natural dye lakes (Madder lake, cochineal lake, etc.) are used. Of these, red iron oxide, dark blue, ultramarine, yellow iron oxide, carmine,
Mica titanium, carbon black, azo pigments and phthalocyanine pigments are preferred. The blending amount is 0.01 to 15
%, Preferably 0.1 to 10%. If it is less than 0.01%, a sufficient effect cannot be obtained, and if it exceeds 15%, stable dispersion becomes difficult.
【0012】その他、下記のものを適宜、配合すること
ができる。染色助剤として、芳香族アルコールであるベ
ンジルアルコール、フェネチルアルコール、ベンジルオ
キシエタノール等、アルキルピロリドンであるN−メチ
ルピロリドン、N−エチルピロリドン等、低級アルキレ
ンカーボネートであるエチレンカーボネート、プロピレ
ンカーボネート等、低級アルコールであるエチルアルコ
ール、イソプロピルアルコール等が挙げられる。その配
合量1〜40重量%、好ましくは3〜30重量%であ
る。In addition to the above, the following can be appropriately blended. As a dyeing aid, benzyl alcohol which is an aromatic alcohol, phenethyl alcohol, benzyloxyethanol and the like, N-methylpyrrolidone which is an alkylpyrrolidone, N-ethylpyrrolidone and the like, ethylene carbonate which is a lower alkylene carbonate, propylene carbonate and a lower alcohol. Examples thereof include ethyl alcohol and isopropyl alcohol. The blending amount is 1 to 40% by weight, preferably 3 to 30% by weight.
【0013】樹脂として、カチオン性、両性、アニオン
性及び非イオン性樹脂が挙げられる。例えば、ポリビニ
ルピロリドン系高分子化合物であるポリビニルピロリド
ン、ビニルピロリドンと酢酸ビニルの共重合物、ポリビ
ニルピロリドン/メタアクリル酸/メタアクリル酸エス
テルの共重合物、ビニルピロリドン/酢酸ビニル/アル
キルアミノアクリレートの共重合物など、市販品として
は、BASF社のLuviscol K,VA,VA
P,GAF社のPVP X,PVP/VAなどが挙げら
れる。また、酸性ビニルエーテル系高分子化合物である
メチルビニルエーテルと無水マレイン酸の共重合物の低
級アルキルハーフエステルなど、市販品としては、GA
F社のガントレッツES−225,ES−335,ES
−425などが挙げられる。酸性ポリ酢酸ビニル系高分
子化合物である酢酸ビニルとクロトン酸の共重合物、酢
酸ビニルとクロトン酸とネオデカン酸ビニルの三元共重
合体、酢酸ビニルとクロトン酸とプロピオン酸ビニルの
三元共重合体、酢酸ビニルとN−ビニル−5−メチル−
2−オキサゾリンの共重合体など、市販品としては、B
ASF社のルビセットCA,CAP,National
Starch社のレジン28−1310,28−29
30,Dow Chemical社のDewlexなど
が挙げられる。酸性アクリル系高分子化合物であるアク
リル酸および/またはメタクリル酸と、アクリル酸アル
キルエステルおよび/またはメタクリル酸アルキルエス
テルとの共重合体、アクリル酸とアクリル酸アルキルエ
ステルとN−アルキルアクリルアミドの共重合体など、
市販品としては、互応化学のプラスサイズL−53P,
53D,7400,7410,7420,7480,5
3PB,8011、BASF社のウルトラホールド8な
どが挙げられる。両性アクリル系高分子化合物であるジ
アルキルアミノエチルメタクリレート、ジアルキルアミ
ノエチルアクリレート、ジアセトンアクリルアミド等と
アクリル酸、メタクリル酸、アクリル酸アルキルエステ
ル、メタクリル酸アルキルエステル等を共重合し、ハロ
ゲン化酢酸で両性化した化合物、アクリル酸ヒドロキシ
プロピルとメタアクリル酸ブチルアミノエチル及びアク
リル酸オクチルアミドの三元共重合体など、市販品とし
ては、三菱油化のユカフォーマーAM75−201,2
02,204,R205,R205S,206,W,W
H,National Starch社のAmphom
erなどが挙げられる。これらの内、酸性アクリル系高
分子化合物、N−メタクリロイルエチル−N,N−ジメ
チルアンモニウム・α−N−メチルカルボキシベタイン
・メタクリル酸ブチル共重合体が高い染毛効果が得られ
るので好ましい。その配合量は0.1〜15重量%、好
ましくは1〜10重量%である。Resins include cationic, amphoteric, anionic and nonionic resins. For example, polyvinylpyrrolidone polymer compound polyvinylpyrrolidone, copolymer of vinylpyrrolidone and vinyl acetate, copolymer of polyvinylpyrrolidone / methacrylic acid / methacrylic acid ester, copolymer of vinylpyrrolidone / vinyl acetate / alkylaminoacrylate Commercially available products such as polymers are Luviscol K, VA and VA manufactured by BASF.
P, PVP X, PVP / VA, etc. of GAF. In addition, commercially available products such as lower alkyl half esters of copolymers of methyl vinyl ether, which is an acidic vinyl ether polymer, and maleic anhydride are commercially available.
Company G's Gantrez ES-225, ES-335, ES
-425 and the like. Copolymers of vinyl acetate and crotonic acid, which are acidic polyvinyl acetate polymers, terpolymers of vinyl acetate, crotonic acid and vinyl neodecanoate, terpolymers of vinyl acetate, crotonic acid and vinyl propionate Combined, vinyl acetate and N-vinyl-5-methyl-
Commercially available products such as a copolymer of 2-oxazoline may be B
ASF Rubiset CA, CAP, National
Starch resins 28-1310, 28-29
30, Dewlex manufactured by Dow Chemical Company, and the like. Copolymers of acrylic acid and / or methacrylic acid, which are acidic acrylic polymer compounds, and acrylic acid alkyl esters and / or methacrylic acid alkyl esters, and copolymers of acrylic acid, acrylic acid alkyl esters, and N-alkylacrylamide Such,
Commercially available products include Plus Size L-53P from Reciprocal Chemistry,
53D, 7400, 7410, 7420, 7480, 5
3PB, 8011, Ultrahold 8 manufactured by BASF, and the like. Copolymerization of acrylic acid, methacrylic acid, acrylic acid alkyl ester, methacrylic acid alkyl ester, etc. with amphoteric acrylic polymer compounds such as dialkylaminoethyl methacrylate, dialkylaminoethyl acrylate and diacetone acrylamide, and amphoteric conversion with halogenated acetic acid. Examples of commercially available products, such as terpolymers of hydroxypropyl acrylate, butylaminoethyl methacrylate and octylamide acrylate, are commercially available from Mitsubishi Yuka Yukaformer AM75-201,2.
02, 204, R205, R205S, 206, W, W
Amphom of H, National Starch
er and the like. Among these, acidic acrylic polymer compounds and N-methacryloylethyl-N, N-dimethylammonium / α-N-methylcarboxybetaine / butyl methacrylate copolymers are preferable because a high hair dyeing effect can be obtained. The blending amount is 0.1 to 15% by weight, preferably 1 to 10% by weight.
【0014】その他、公知の毛髪化粧料の成分を配合す
ることができる。例えば、ポリペプタイドとしてコラー
ゲン、ケラチン、エラスチン、フィブロイン、コンキオ
リン、大豆蛋白、カゼイン、ゼラチン等の蛋白質を酸、
アルカリ、酵素等をにより加水分解した加水分解物、及
びこれらを4級化したカチオン変性蛋白質、発泡剤であ
る非イオン界面活性剤としてポリオキシエチレンアルキ
ルエーテル、ポリオキシエチレンアルキルフェニルエー
テル、ポリオキシエチレンソルビタン脂肪酸エステル、
ポリオキシエチレングリセリルモノ脂肪酸エステル、ポ
リオキシエチレンソルビトール脂肪酸エステル、硬化ヒ
マシ油誘導体、ポリオキシエチレン脂肪酸エステル、高
級脂肪酸グリセリンエステル、ソルビタン脂肪酸エステ
ルなど、粘度調整剤としてメチルセルロース、ヒドロキ
シエチルセルロース、ヒドロキシプロピルメチルセルロ
ース、ヒドロキシプロピルセルロース、エチルセルロー
ス、ヒドロキシエチルセルロースエチルエーテル、カル
ボキシメチルセルロースナトリウム、第4級窒素含有セ
ルロースエーテル、キサンタンガムなど、保湿剤として
グリセリン、1,3−ブチレングリコール、プロピレン
グリコール、ポリエチレングリコール、ピロリドンカル
ボン酸ナトリウム、乳酸ナトリウム、ソルビトール、ヒ
アルロン酸など、油脂類としてヒマシ油、カカオ脂、ミ
ンク油、アボガド油、オリーブ油など、ロウ類としてミ
ツロウ、鯨ロウ、ラノリン、カルナウバロウ、キャンデ
リラロウなど、高級アルコールとしてセチルアルコー
ル、オレイルアルコール、ラウリルアルコール、ステア
リルアルコールなど、脂肪酸エステルとしてミリスチン
酸イソプロピル、ラウリン酸ヘキシル、乳酸セチル、モ
ノステアリン酸プロピレングリコール、オレイン酸オレ
イル、2−エチルヘキサン酸ヘキサデシル、ミリスチン
酸オクチルドデシルなど、シリコーン誘導体としてジメ
チルポリシロキサン、メチルフェニルポリシロキサン、
ポリエーテル変性シリコーン、エポキシ変性シリコー
ン、アミノ変性シリコーン、アルキル変性シリコーンな
ど、その他、香料、防腐・殺菌剤、酸化防止剤、紫外線
吸収剤、動・植物抽出成分、pH調整剤、金属イオン封
鎖剤などを適宜配合できる。Other known hair cosmetic ingredients may be added. For example, as a polypeptide, collagen, keratin, elastin, fibroin, conchiolin, soybean protein, casein, proteins such as gelatin, acid,
Hydrolyzate obtained by hydrolyzing alkali, enzyme, etc., cation-denatured protein obtained by quaternizing these, polyoxyethylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene as nonionic surfactant which is a foaming agent Sorbitan fatty acid ester,
Polyoxyethylene glyceryl monofatty acid ester, polyoxyethylene sorbitol fatty acid ester, hydrogenated castor oil derivative, polyoxyethylene fatty acid ester, higher fatty acid glycerin ester, sorbitan fatty acid ester, etc. as viscosity modifiers methyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose, hydroxy Propyl cellulose, ethyl cellulose, hydroxyethyl cellulose ethyl ether, sodium carboxymethyl cellulose, quaternary nitrogen-containing cellulose ether, xanthan gum and the like, as a moisturizing agent, glycerin, 1,3-butylene glycol, propylene glycol, polyethylene glycol, sodium pyrrolidonecarboxylate, sodium lactate. , Sorbitol, hyaluronic acid, etc., Fats such as castor oil, cocoa butter, mink oil, avocado oil, and olive oil, waxes such as beeswax, whale wax, lanolin, carnauba wax, and candelilla wax, and higher alcohols such as cetyl alcohol, oleyl alcohol, lauryl alcohol, and stearyl alcohol. , Isopropyl myristate, hexyl laurate, cetyl lactate, propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, octyldodecyl myristate, dimethyl polysiloxane as a silicone derivative, methylphenyl polysiloxane,
Polyether-modified silicone, epoxy-modified silicone, amino-modified silicone, alkyl-modified silicone, etc., as well as fragrances, antiseptic / bactericidal agents, antioxidants, ultraviolet absorbers, animal / plant extract components, pH adjusters, sequestering agents, etc. Can be appropriately mixed.
【0015】酸化染毛剤としては、酸化染料中間体とし
て、通常、フェニレンジアミン類、アミノフェノール
類、トルイレンジアミン類、アミノニトロフェノール
類、ジフェニルアミン類、ジアミノフェニルアミン類、
N−フェニルフェニレンジアミン類、ジアミノピリジン
類等およびそれらの塩類の1種または2種以上が挙げら
れる。その配合量は例えば、第1剤の全重量に対して
0.01〜10重量%程度である。また、カップラーと
してレゾルシン、ピロガロール、カテコール、メタアミ
ノフェノール、メタフェニレンジアミン等を配合するこ
とができる。また、「医薬部外品原料規格」(1991
年6月発行,薬事日報社)に収載されたものを用いるこ
とができる。これは過酸化水素などの酸化剤と組み合わ
せ、使用することにより、染毛することができる。ま
た、酸化剤を使用しない自動酸化染毛剤には、酸化染料
中間体としては、パラフェニレンジアミン、パラトルイ
レンジアミン、N,N−ビス(2−ヒドロキシエチル)
−パラフェニレンジアミン、N−フェニル−パラフェニ
レンジアミン、4,4’−ジアミノジフェニルアミン、
2−クロロパラフェニレンジアミン、N,N−ジメチル
パラフェニレンジアミン、2,6−ジクロロパラフェニ
レンジアミン、パラアミノフェニルスルファミン酸およ
びそれらの塩類の1種または2種以上が挙げられる。塩
類としては塩酸塩、硫酸塩、酢酸塩等が挙げられる。こ
れらの中でも、パラフェニレンジアミン、パラトルイレ
ンジアミン、N,N−ビス(2−ヒドロキシエチル)−
パラフェニレンジアミンまたはその塩が高い染毛効果が
得られるので好ましい。その配合量は0.01〜10重
量%である。また、没食子酸、タンニン酸またはその誘
導体としては、没食子酸エチル、没食子酸メチル、およ
び没食子酸プロピルなどの没食子酸アルキルエステル、
タンニン酸、五倍子、パラアミノフェノール、オルトア
ミノフェノール、2,4−ジアミノフェノール、トルエ
ン−3,4−ジアミン、レゾルシン、ピロガロール、カ
テコール、メタアミノフェノール、メタフェニレンジア
ミン、トルエン−2,4−ジアミン、ハイドロキノン、
α−ナフトール、2−ニトロパラフェニレンジアミン、
4−ニトロオルトフェニレンジアミン、2−アミノ−4
−ニトロフェノール、2−アミノ−5−ニトロフェノー
ル、2,6−ジアミノピリジン、1,5−ジヒドロキシ
ナフタレン、5−アミノオルトクレゾール、ピクラミン
酸、ピクリン酸、ジフェニルアミン、パラメチルアミノ
フェノール、1,2,4−ベンゼントリオール、フロロ
グルシン、2,4−ジアミノフェノキシエタノール、5
−(2−ヒドロキシエチルアミノ)−2−メチルフェノ
ール、1−アミノ−4−メチルアミノアントラキノン、
1,4−ジアミノアントラキノン等およびそれらの塩を
配合することができる。As the oxidative hair dye, as an oxidative dye intermediate, usually, phenylenediamines, aminophenols, toluylenediamines, aminonitrophenols, diphenylamines, diaminophenylamines,
One or more N-phenylphenylenediamines, diaminopyridines and the like and salts thereof can be mentioned. The blending amount is, for example, about 0.01 to 10% by weight based on the total weight of the first agent. Further, resorcin, pyrogallol, catechol, metaaminophenol, metaphenylenediamine and the like can be blended as a coupler. In addition, “Standard for Quasi-drug Raw Materials” (1991
It is possible to use those listed in Yakuji Nippo Co., Ltd., issued June 2006. Hair can be dyed by using it in combination with an oxidizing agent such as hydrogen peroxide. In addition, for autoxidative hair dyes that do not use an oxidizing agent, para-phenylenediamine, para-toluylenediamine, and N, N-bis (2-hydroxyethyl) are used as oxidation dye intermediates.
-Paraphenylenediamine, N-phenyl-paraphenylenediamine, 4,4'-diaminodiphenylamine,
One or more of 2-chloroparaphenylenediamine, N, N-dimethylparaphenylenediamine, 2,6-dichloroparaphenylenediamine, paraaminophenylsulfamic acid and salts thereof can be mentioned. Examples of the salts include hydrochloride, sulfate, acetate and the like. Among these, paraphenylenediamine, paratoluylenediamine, N, N-bis (2-hydroxyethyl)-
Paraphenylenediamine or a salt thereof is preferable because a high hair dyeing effect can be obtained. The blending amount is 0.01 to 10% by weight. Further, as gallic acid, tannic acid or a derivative thereof, gallic acid alkyl ester such as ethyl gallate, methyl gallate, and propyl gallate,
Tannic acid, quintuple, paraaminophenol, orthoaminophenol, 2,4-diaminophenol, toluene-3,4-diamine, resorcin, pyrogallol, catechol, metaaminophenol, metaphenylenediamine, toluene-2,4-diamine, hydroquinone ,
α-naphthol, 2-nitroparaphenylenediamine,
4-nitroorthophenylenediamine, 2-amino-4
-Nitrophenol, 2-amino-5-nitrophenol, 2,6-diaminopyridine, 1,5-dihydroxynaphthalene, 5-aminoorthocresol, piclamic acid, picric acid, diphenylamine, paramethylaminophenol, 1,2, 4-benzenetriol, phloroglucin, 2,4-diaminophenoxyethanol, 5
-(2-hydroxyethylamino) -2-methylphenol, 1-amino-4-methylaminoanthraquinone,
1,4-Diaminoanthraquinone and the like and salts thereof can be blended.
【0016】金属染毛剤としては、公知の金属塩とし
て、硫酸第一鉄、塩化第一鉄、酢酸第一鉄、リン酸第一
鉄、蓚酸第一鉄、硝酸第一鉄、クエン酸第一鉄、炭酸第
一鉄、ピロリン酸第一鉄、塩素酸第一鉄、硫酸第二鉄、
塩化第二鉄、酢酸第二鉄、リン酸第二鉄、硝酸第二鉄な
どの鉄塩、硫酸銅、塩化銅などの銅塩、塩化亜鉛、硝酸
亜鉛、硫酸亜鉛、酢酸亜鉛などの亜鉛塩、および塩化
鉛、硝酸鉛、硫酸鉛、酢酸鉛などの鉛塩などが挙げられ
る。これらの中でも、鉄塩が高い染毛効果が得られるの
で好ましい。その配合量は、0.01〜20重量%,好
ましくは0.1〜10重量%である。発色剤として没食
子酸、没食子酸プロピル等の没食子酸エステル類、タン
ニン酸およびそのエステル類、ピロガロール、カテコー
ル、レゾルシン、ヒドロキノン、ヘマテイン、ヘマトキ
シリン、サリチル酸、インドール誘導体(5,6−ジヒ
ドロキシインドール、4−ヒドロキシインドール、5,
6−ジヒドロキシインドール−2−カルボン酸)、塩酸
ピリドキシン、ジカプリル酸ピリドキシン、ジパルミチ
ン酸ピリドキシンなどのビタミンB6類、オキシンなど
が挙げられる。その配合量は、0.01〜10重量%で
ある。法定色素としては、キノリンエローWS、キノリ
ンエローSS、タートラジン、サンセットエローFC
F、フルオレセイン、ウラニン、ハンザエローなどが挙
げられる。その配合量は、0.01〜5重量%である。As the metal hair dye, known metal salts include ferrous sulfate, ferrous chloride, ferrous acetate, ferrous phosphate, ferrous oxalate, ferrous nitrate and ferric citrate. Ferrous iron, ferrous carbonate, ferrous pyrophosphate, ferrous chlorate, ferric sulfate,
Iron salts such as ferric chloride, ferric acetate, ferric phosphate and ferric nitrate, copper salts such as copper sulfate and copper chloride, zinc salts such as zinc chloride, zinc nitrate, zinc sulfate and zinc acetate. , And lead salts such as lead chloride, lead nitrate, lead sulfate, and lead acetate. Among these, iron salts are preferable because they can obtain a high hair dyeing effect. The blending amount is 0.01 to 20% by weight, preferably 0.1 to 10% by weight. As color formers, gallic acid, gallic acid esters such as propyl gallate, tannic acid and its esters, pyrogallol, catechol, resorcin, hydroquinone, hematein, hematoxylin, salicylic acid, indole derivatives (5,6-dihydroxyindole, 4-hydroxy). Indole, 5,
6-dihydroxyindole-2-carboxylic acid), pyridoxine hydrochloride, dicaprylic acid pyridoxine, dipalmitic acid pyridoxine and other vitamins B 6 and oxins. The blending amount is 0.01 to 10% by weight. As legal dyes, quinoline yellow WS, quinoline yellow SS, tartrazine, sunset yellow FC
F, fluorescein, uranine, Hansa Yellow and the like. The blending amount is 0.01 to 5% by weight.
【0017】植物染毛剤としてはヘンナ、ヘマテイン、
ヘマトキシリンなとが用いられる。これは前記金属塩と
も組み合わせて使用することもできる。As a plant hair dye, henna, hematine,
Hematoxylin starch is used. It can also be used in combination with the above metal salts.
【0018】脱色剤としては、過酸化水素を0.5〜1
2重量%、好ましくは1〜10重量%を含む。また、安
定剤として、例えば、フェナセチン、EDTA、8−ヒ
ドロキシキノリン、アセトアニリド、ピロリン酸ナトリ
ウム、バルビツール酸、尿酸、タンニン酸、パラベンな
どが挙げられる。また、pH調整剤として、例えば、リ
ン酸、クエン酸、硫酸、酢酸、乳酸、酒石酸などを用い
て、pH2〜6に調整するのが好ましい。その他、上記
のものを適宜、配合することができる。尚、この脱色剤
は、ブリーチ剤の他、酸化染毛剤の酸化剤およびパーマ
ネントウエーブ用第2剤として用いることもできる。As a decolorizing agent, hydrogen peroxide is 0.5 to 1
2% by weight, preferably 1-10% by weight. Examples of the stabilizer include phenacetin, EDTA, 8-hydroxyquinoline, acetanilide, sodium pyrophosphate, barbituric acid, uric acid, tannic acid, paraben and the like. Further, it is preferable to adjust the pH to 2 to 6 by using, for example, phosphoric acid, citric acid, sulfuric acid, acetic acid, lactic acid, tartaric acid, etc. as the pH adjusting agent. In addition, the above-mentioned materials can be appropriately mixed. In addition to the bleaching agent, this decolorizing agent can also be used as an oxidizing agent for an oxidative hair dye and a second agent for a permanent wave.
【0019】本発明に用いられる噴射剤としては、クロ
ルアルカン系噴射剤、液化石油ガス、ジメチルエーテ
ル、炭酸ガス、窒素ガスまたはこれらの混合物が挙げら
れる。この中でも特にジメチルエーテル、液化石油ガス
が地肌汚れが少なく安定性に優れるので好ましい。その
配合量は1〜30重量%、好ましくは2〜20重量%で
ある。Examples of the propellant used in the present invention include chloralkane-based propellant, liquefied petroleum gas, dimethyl ether, carbon dioxide gas, nitrogen gas or a mixture thereof. Of these, dimethyl ether and liquefied petroleum gas are particularly preferable because they are less likely to stain the background and have excellent stability. The blending amount is 1 to 30% by weight, preferably 2 to 20% by weight.
【0020】[0020]
【作用】エアゾール容器に充填された染毛剤の原液は、
噴射剤の圧力により噴出ノズルとL字型パイプを通って
排出通路に排出される。排出通路は櫛歯の先端から間隔
をおいた部位に設られた注出孔に連通している。従っ
て、排出された原液は櫛歯の中間〜根元付近に均一に供
給される。このような状態で、櫛歯を頭髪に接触させる
と、櫛歯によって整髪しながら均一に染毛あるいは脱色
することができる。原液は櫛歯の中間部に供給されるの
で頭皮を染着する恐れがない。特に、酸性染料を用いる
染毛剤のように地肌に染着しやすい染毛料の場合は有用
である。また、櫛部はカバー部とともに回転させること
によりエアゾール容器から取り外せるので、櫛部の掃除
や交換が容易である。[Function] The stock solution of the hair dye filled in the aerosol container is
It is discharged into the discharge passage through the jet nozzle and the L-shaped pipe by the pressure of the propellant. The discharge passage communicates with a pouring hole provided at a position spaced from the tips of the comb teeth. Therefore, the discharged stock solution is uniformly supplied from the middle of the comb teeth to the vicinity of the root. When the comb teeth are brought into contact with the hair in such a state, the hair can be uniformly dyed or bleached while the hair is adjusted by the comb teeth. Since the stock solution is supplied to the middle part of the comb teeth, there is no risk of dyeing the scalp. In particular, it is useful in the case of a hair dye that is easily dyed on the background such as a hair dye using an acid dye. Further, since the comb portion can be removed from the aerosol container by rotating the comb portion together with the cover portion, the comb portion can be easily cleaned and replaced.
【0021】[0021]
【実施例】以上説明した本発明の構成・作用を一層明ら
かにするために、以下本発明の好適な実施例について説
明する。Preferred embodiments of the present invention will be described below in order to further clarify the structure and operation of the present invention described above.
【0022】実施例1 図1に本発明の染毛用具の側面断面図を示す。既存のエ
アゾール容器8にネジ部4を取り付け、噴出ノズル11
にプッシュボタン3およびL字型パイプ2を取り付け
る。ネジ部4にカバー部7を螺合させ、カバー部7に櫛
部5を取り付ける。L字型パイプ2はパッキン6に上下
移動が可能なように挿入され、櫛部5の排出通路9に通
じるように設定される。櫛部5の櫛歯12には注出孔1
0が設けられている。Example 1 FIG. 1 is a side sectional view of a hair dyeing tool of the present invention. The screw part 4 is attached to the existing aerosol container 8 and the jet nozzle 11 is attached.
Attach the push button 3 and the L-shaped pipe 2 to. The cover portion 7 is screwed onto the screw portion 4, and the comb portion 5 is attached to the cover portion 7. The L-shaped pipe 2 is inserted into the packing 6 so as to be vertically movable, and is set so as to communicate with the discharge passage 9 of the comb portion 5. The pouring hole 1 is formed in the comb teeth 12 of the comb portion 5.
0 is provided.
【0023】エアゾール容器8に充填された染毛剤は、
噴射剤の圧力により噴出ノズル11、L字型パイプ2を
通り、排出通路9に排出される。噴出ノズル11から櫛
部5へ染毛剤を供給するために、L字型パイプ2を用い
ることにより、噴出ノズル11の上部にプッシュボタン
3を設けることができ、力を入れやすい構造にすること
ができた。なお、L字型パイプ2はプッシュボタン3の
上下動作と連動して上下動作する。その材質はステンレ
ス製などの金属製あるいは合成樹脂製などのある程度の
硬度を有するものであればよい。また、L字型パイプ2
から排出通路9に排出された染毛剤が逆流しないように
パッキン6を設けた。なお、このパッキン6はL字型パ
イプ2が上下動作しやすいように中空構造とした。The hair dye filled in the aerosol container 8 is
The pressure of the propellant passes through the jet nozzle 11 and the L-shaped pipe 2 and discharges into the discharge passage 9. By using the L-shaped pipe 2 in order to supply the hair dye from the ejection nozzle 11 to the comb portion 5, the push button 3 can be provided on the upper portion of the ejection nozzle 11 and the structure can be easily applied. did it. The L-shaped pipe 2 moves up and down in conjunction with the up and down operation of the push button 3. The material may be metal such as stainless steel or synthetic resin having a certain degree of hardness. In addition, L-shaped pipe 2
The packing 6 is provided to prevent the hair dye discharged from the discharge passage 9 from flowing back. The packing 6 has a hollow structure so that the L-shaped pipe 2 can easily move up and down.
【0024】排出通路9は櫛歯12の先端から間隔をお
いた部位に設られた注出孔10に連通している。従っ
て、排出された染毛剤は櫛歯12の中間〜根元付近に均
一に供給される。このような状態で、櫛歯12を頭髪に
接触させると、櫛歯12によって整髪しながら均一に染
毛することことができる。また、染毛剤は櫛歯12の中
間部〜根元付近にあるので頭皮を染着する恐れがない。
特に、酸性染料を用いる染毛剤のように地肌に染着しや
すい染毛料の場合は有用である。The discharge passage 9 communicates with a pouring hole 10 provided at a portion spaced from the tips of the comb teeth 12. Therefore, the discharged hair dye is uniformly supplied from the middle of the comb teeth 12 to the vicinity of the root. When the comb teeth 12 are brought into contact with the hair in such a state, the hair can be uniformly dyed while the hair is adjusted by the comb teeth 12. Further, since the hair dye is present in the middle of the comb teeth 12 to near the root, there is no risk of dyeing the scalp.
In particular, it is useful in the case of a hair dye that is easily dyed on the background such as a hair dye using an acid dye.
【0025】櫛部5は多数の、例えば5本〜40本の櫛
歯12からなり、櫛歯12は長さ1〜5cm、厚み1〜
6mmからなり、巾は根元付近が2〜8mm、先端付近
が0.5〜4mmで先端の方が巾は狭くなっている。そ
して、注出通路13を介して排出通路9と連通する注出
孔10が櫛歯12の先端から間隔をおいた部位に設けら
れている。注出孔10は、地肌汚れを少なくするため
に、櫛歯12の先端から櫛歯12の長さの45%〜95
%、好ましくは50%〜90%の部位、例えば、櫛歯1
2の長さが20mmの場合、先端から9〜19mm、好
ましくは10〜18mmの部位に注出孔10が設けられ
る。The comb portion 5 is composed of a large number, for example, 5 to 40 comb teeth 12, each of which has a length of 1 to 5 cm and a thickness of 1 to 1.
The width is 6 mm, the width is 2 to 8 mm near the base, and 0.5 to 4 mm near the tip, and the width is narrower at the tip. A pouring hole 10 that communicates with the discharge passage 9 through the pouring passage 13 is provided at a portion spaced from the tips of the comb teeth 12. The pouring hole 10 is 45% to 95% of the length of the comb tooth 12 from the tip of the comb tooth 12 in order to reduce the background stain.
%, Preferably 50% to 90%, for example, comb teeth 1
When the length of 2 is 20 mm, the pouring hole 10 is provided at a site 9 to 19 mm, preferably 10 to 18 mm from the tip.
【0026】ここで、L字型パイプ2は排出通路9のほ
ぼ中央部に位置するように設定される。このL字型パイ
プ2が長すぎる場合あるいは短かすぎる場合は、その先
端が排出通路9の上端部付近あるいは下端部付近に位置
するため、染毛剤が上端部付近に位置する櫛歯12ある
いは下端部付近に位置する櫛歯12にのみ供給されるた
め、櫛歯12全体に均一に供給されなくなる。従って、
L字型パイプ2の先端部が排出通路9のほぼ中央部に位
置するように設定すれば、染毛剤は排出通路9の全体に
充満し、均一に注出孔10に排出されるため、櫛歯12
全体に均一に供給される。L字型パイプ2の先端部は、
例えば排出通路9の上端と下端の距離の約1/2の位置
であればよいが、その範囲は1/4〜3/4、好ましく
は1/3〜2/3であり、この位置は排出通路の体積お
よび形、および注出孔32の直径の大きさにより変わる
が、染毛剤が櫛歯12全体に均一に供給されるように設
定される。また、図1のように排出通路9を上方に行く
に従い次第に大きくなるように形成するか、あるいは注
出通路13および/または注出孔10を櫛部5の上方に
位置するに従い次第に大きくなるように形成することに
より、櫛歯12全体に均一に供給されるように設定する
こともできる。Here, the L-shaped pipe 2 is set so as to be located substantially in the center of the discharge passage 9. If the L-shaped pipe 2 is too long or too short, the tip of the L-shaped pipe 2 is located near the upper end or the lower end of the discharge passage 9. Since it is supplied only to the comb teeth 12 located near the lower end portion, it is not uniformly supplied to the entire comb teeth 12. Therefore,
If the tip of the L-shaped pipe 2 is set to be located substantially in the center of the discharge passage 9, the hair dye will fill the entire discharge passage 9 and be uniformly discharged into the pouring hole 10. Comb teeth 12
It is supplied uniformly throughout. The tip of the L-shaped pipe 2 is
For example, the position may be about 1/2 of the distance between the upper end and the lower end of the discharge passage 9, but the range is 1/4 to 3/4, preferably 1/3 to 2/3, and this position is the discharge position. The hair dye is set so as to be uniformly supplied to the entire comb teeth 12, depending on the volume and shape of the passage and the size of the diameter of the pouring hole 32. In addition, as shown in FIG. 1, the discharge passage 9 is formed so as to be gradually larger as it goes upward, or the discharge passage 13 and / or the discharge hole 10 is gradually made larger as it is located above the comb portion 5. By forming it, it can be set so as to be uniformly supplied to the entire comb tooth 12.
【0027】また、エアゾール容器8の上端部付近を覆
うようにカバー部7が設けられており、カバー部7とネ
ジ部4は取り外し可能に螺合されている。また、櫛部5
は、使用し易いようにエアゾール容器8の長手方向中心
線に対して、櫛部5の櫛歯12側に0〜45度、好まし
くは5〜40度の角度で取り付けられている。Further, a cover portion 7 is provided so as to cover the vicinity of the upper end portion of the aerosol container 8, and the cover portion 7 and the screw portion 4 are detachably screwed together. Also, the comb part 5
Is attached to the comb tooth 12 side of the comb portion 5 at an angle of 0 to 45 degrees, preferably 5 to 40 degrees with respect to the center line in the longitudinal direction of the aerosol container 8 for easy use.
【0028】また、カバー部7はネジ部4と螺合してい
るので、櫛部5はカバー部7とともに回転させることに
よりエアゾール容器から取り外せるので、櫛部の掃除や
交換が容易である。また、櫛部5とカバー部7の取付を
螺合にすれば、櫛部5のみカバー部7から取り外すこと
も可能である。さらに櫛部5を180度回転すれば保管
時にスペースを取らず、また販売するためにパッケージ
に入れる場合もスペースを節約できるという利点があ
る。Further, since the cover portion 7 is screwed with the screw portion 4, the comb portion 5 can be removed from the aerosol container by rotating it together with the cover portion 7, so that the comb portion can be easily cleaned and replaced. If the comb portion 5 and the cover portion 7 are screwed together, only the comb portion 5 can be removed from the cover portion 7. Further, if the comb portion 5 is rotated by 180 degrees, there is an advantage that it does not take up a space during storage and that the space can be saved even when it is put in a package for sale.
【0029】なお、図2は櫛部5、カバー部7、ネジ部
4およびエアゾール容器の組立行程図であり、図3は櫛
部5、パッキン6、カバー部7、プッシュボタン3およ
びL字型パイプ2の組立行程図である。FIG. 2 is an assembly process diagram of the comb part 5, the cover part 7, the screw part 4 and the aerosol container, and FIG. 3 is the comb part 5, the packing 6, the cover part 7, the push button 3 and the L-shaped pipe 2. FIG.
【0030】このエアゾール容器8の内部には原液とし
て、酸性染料および/または顔料、および噴射剤からな
る下記原液A1が充填されている。The aerosol container 8 is filled with the following undiluted solution A1 comprising an acidic dye and / or pigment and a propellant as undiluted solution.
【0031】エアゾール容器8の材質は、毛髪着色料の
原液の液性、特に、pHが酸性であることから、アルミ
ニウムなどの金属は腐食する恐れがあるため、エポキシ
樹脂やフェノール樹脂の合成樹脂でコーティングされた
アルミニウム、あるいはポリエチレンテレフタレートな
どの合成樹脂が好ましい。本実施例は、エポキシ樹脂コ
ーティングアルミニウムである。The aerosol container 8 is made of a synthetic resin such as an epoxy resin or a phenolic resin, since the stock solution of the hair coloring agent, especially the pH, is acidic so that metals such as aluminum may corrode. Coated aluminum or synthetic resins such as polyethylene terephthalate are preferred. This example is an epoxy resin coated aluminum.
【0032】使用時には、エアゾール容器8を片手で握
り、人差指でプッシュボタン3を押し下げる。噴射され
た原液は、L字型パイプ2を経由して排出通路9に充満
し、注出通路13を通り注出孔10から噴出して櫛歯1
2の中間付近に到達する。この櫛歯12で毛髪を梳くこ
とにより、染毛する。At the time of use, the aerosol container 8 is grasped with one hand and the push button 3 is pushed down with the index finger. The sprayed stock solution fills the discharge passage 9 through the L-shaped pipe 2, passes through the spout passage 13 and is spouted from the spout hole 10 to form the comb teeth 1
Reach the middle of 2. Hair is dyed by combing the hair with the comb teeth 12.
【0033】 原液A1 重量% 黒色401号 0.5 赤色404号 0.3 黄色205号 0.2 N−メタクリロイルエチルN,N−ジメチルアンモニウム・ 8.5 α−N−メチルカルボキシベタイン・メタクリル酸ブチル 共重合体(30%) ヤシ油脂肪酸アミドプロピルベタイン(30%) 0.5 コラーゲン加水分解物 0.5 ジグリセリン 0.3 95%エタノール 20.0 香料 0.1 LPG(3.0kgf/cm2, 20゜C) 7.0 精製水 残部 この原液を、図1のエアゾール容器8に充填し、使用し
たところ、櫛歯12への過不足のない泡の送付ができ泡
のたれおちもなく、毛髪へ十分な被覆力で着色でき、地
肌を汚染することもなかった。Undiluted solution A1% by weight Black No. 401 0.5 Red No. 404 0.3 Yellow No. 205 0.2 N-methacryloylethyl N, N-dimethylammonium · 8.5 α-N-methylcarboxybetaine / butyl methacrylate Copolymer (30%) Coconut oil fatty acid amide propyl betaine (30%) 0.5 Collagen hydrolyzate 0.5 Diglycerin 0.3 95% Ethanol 20.0 Perfume 0.1 LPG (3.0 kgf / cm 2 , 20 ° C) 7.0 Purified water balance This undiluted solution was filled into the aerosol container 8 of FIG. 1 and used, and it was possible to send bubbles to the comb teeth 12 without excess or deficiency, The hair could be colored with sufficient covering power and did not contaminate the background.
【0034】同様に原液A1の代わりに下記の原液A2
〜A5を充填した。 原液A2 重量% 過酸化水素(35%) 8.0 エタノール 10.0 ポリオキシエチレン(7.5)ノニルフェニルエーテル 5.0 水溶性シリコーン 1.0 酒石酸 0.2 LPG 7.0 精製水で100%にする。上記のエアゾールフォーム状
の脱色剤を、毛髪に塗布すると、均一に脱色でき、しか
も頭皮への刺激は認められなかった。Similarly, instead of the stock solution A1, the following stock solution A2 was used.
~ A5 was loaded. Stock solution A2 wt% hydrogen peroxide (35%) 8.0 ethanol 10.0 polyoxyethylene (7.5) nonylphenyl ether 5.0 water-soluble silicone 1.0 tartaric acid 0.2 LPG 7.0 100 with purified water %. When the above aerosol foam decolorizing agent was applied to hair, it was possible to decolorize it uniformly and no irritation to the scalp was observed.
【0035】 原液A3 重量% セトステアリルアルコール 0.2 ポリオキシエチレンノニルフェニルエーテル 1.0 カチオン化セルロース 0.1 硫酸N,N−ビスヒドロキシエチルパラフェニレンジアミン 1.0 没食子酸 1.0 塩酸2,4−ジアミノフェノール 0.5 2,6−ジアミノピリジン 0.5 亜硫酸ナトリウム 0.5 トリエタノールアミン 1.0 噴射剤(DME/LPG) 5.0 精製水 残部 このヘアムースを毛髪に塗布し、30分放置すると、自
然な黒色に染毛され、しかも頭皮への染着は認められな
かった。Undiluted solution A3 wt% cetostearyl alcohol 0.2 polyoxyethylene nonylphenyl ether 1.0 cationized cellulose 0.1 N, N-bishydroxyethyl paraphenylenediamine sulfate 1.0 gallic acid 1.0 hydrochloric acid 2, 4-diaminophenol 0.5 2,6-diaminopyridine 0.5 sodium sulfite 0.5 triethanolamine 1.0 propellant (DME / LPG) 5.0 purified water balance The hair mousse was applied to the hair for 30 minutes. When left to stand, the hair was dyed in a natural black color and no dyeing on the scalp was observed.
【0036】 原液A4 重量% 塩化第一鉄 1.5 ジパルミチン酸ピリドキシン 1.5 ステアリン酸アスコルビル 0.7 モノステアリン酸ポリオキシエチレングリセリン 5.0 ポリビニルピロリドン 1.0 LPG 7.0 精製水 残部 上記組成のエアゾールフォーム状染毛剤を調製し、白髪
に塗布し30分放置した後、シャンプーを用いて洗髪し
た。この操作を3回繰り返したところ、染め上がりに優
れ、自然な黒褐色に染毛され、しかも頭皮への染着は認
められなかった。Undiluted solution A4 wt% ferrous chloride 1.5 pyridoxine dipalmitate 1.5 ascorbyl stearate 0.7 polyoxyethylene glycerin monostearate 5.0 polyvinylpyrrolidone 1.0 LPG 7.0 purified water balance above An aerosol foam hair dye having the composition was prepared, applied to white hair, left for 30 minutes, and then washed with shampoo. When this operation was repeated 3 times, the dyeing was excellent, the hair was dyed in a natural black brown color, and no dyeing on the scalp was observed.
【0037】 原液A5 重量% 硫酸第一鉄 1.0 ヘマテイン 0.3 ピロガロール 0.1 塩酸オキシン 1.0 ポリオキシエチレンノニルフェニルエーテル 2.0 ジステアリルジメチルアンモニウムクロライド 0.2 セタノール 1.0 ジメチルエーテル 4.0 精製水 残部 上記組成のエアゾールフォーム状染毛剤を調製し、白髪
に塗布し30分放置した後、シャンプーを用いて洗髪し
た。この操作を3回繰り返したところ、染め上がりに優
れ、自然な黒褐色に染毛され、しかも頭皮への染着は認
められなかった。Undiluted solution A5 wt% ferrous sulfate 1.0 hematein 0.3 pyrogallol 0.1 oxine hydrochloride 1.0 polyoxyethylene nonylphenyl ether 2.0 distearyldimethylammonium chloride 0.2 cetanol 1.0 dimethyl ether 4 0.0 Purified water Remainder An aerosol foam hair dye having the above composition was prepared, applied to white hair, left for 30 minutes, and then washed with shampoo. When this operation was repeated 3 times, the dyeing was excellent, the hair was dyed in a natural black brown color, and no dyeing on the scalp was observed.
【0038】[0038]
【発明の効果】以上詳述したように、本発明の染毛用具
によれば、頭髪に均一に塗布し、かつ頭皮を染着せずに
染毛することができ、あるいは脱色することができ、ま
た、使用時に垂れ落ちて地肌や衣服を汚染することもな
く、手指も汚すことなく簡便に使用できる塗布用具を提
供できる。As described in detail above, according to the hair dyeing tool of the present invention, it is possible to apply it evenly to the hair and dye the hair without dyeing the scalp, or decolorize it. In addition, it is possible to provide an application tool that can be easily used without dripping during use to contaminate the skin or clothes and to keep fingers and hands clean.
【0039】[0039]
【図1】実施例の染毛用具の断面図である。FIG. 1 is a cross-sectional view of a hair dyeing tool of an embodiment.
【図2】実施例の染毛用具の組立工程図である。FIG. 2 is an assembly process diagram of the hair dyeing tool of the embodiment.
【図3】実施例の染毛用具の組立工程図である。FIG. 3 is an assembly process diagram of the hair dyeing tool of the embodiment.
1 染毛用具 2 L字型パイプ 3 プッシュボタン 4 ネジ部 5 櫛部 6 パッキン 7 カバー部 8 エアゾール容器 9 排出通路 10 注出孔 11 噴出ノズル 12 櫛歯 13 注出通路 1 Hair dyeing tool 2 L-shaped pipe 3 Push button 4 Screw part 5 Comb part 6 Packing 7 Cover part 8 Aerosol container 9 Discharge passage 10 Spout hole 11 Spout nozzle 12 Comb tooth 13 Spout passage
Claims (1)
を取り付けた染毛用具において、噴出ノズルと連通する
L字型のパイプを設けたことを特徴とする染毛用具。1. A hair dyeing tool in which a comb portion is attached to an aerosol container containing a hair dyeing agent, wherein an L-shaped pipe communicating with the ejection nozzle is provided.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4474595A JPH08214936A (en) | 1995-02-08 | 1995-02-08 | Hair coloring device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4474595A JPH08214936A (en) | 1995-02-08 | 1995-02-08 | Hair coloring device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08214936A true JPH08214936A (en) | 1996-08-27 |
Family
ID=12699991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4474595A Pending JPH08214936A (en) | 1995-02-08 | 1995-02-08 | Hair coloring device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08214936A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002240873A (en) * | 2001-12-25 | 2002-08-28 | Hoyu Co Ltd | Aerosol container and two-agent discharge container |
| KR20020096504A (en) * | 2001-06-20 | 2002-12-31 | 최용식 | Nozzle pressing apparatus of hair setting machine |
| WO2012057050A1 (en) | 2010-10-26 | 2012-05-03 | 富士フイルム株式会社 | Hair dye |
| AU2010202628B2 (en) * | 2007-12-17 | 2012-08-09 | Michel Mercier Ltd | Agents, compositions and devices for temporary coloring local hair areas |
| US9427060B2 (en) | 2010-06-25 | 2016-08-30 | Kampalook Ltd. | Device, kit and method for coloring hair |
-
1995
- 1995-02-08 JP JP4474595A patent/JPH08214936A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020096504A (en) * | 2001-06-20 | 2002-12-31 | 최용식 | Nozzle pressing apparatus of hair setting machine |
| JP2002240873A (en) * | 2001-12-25 | 2002-08-28 | Hoyu Co Ltd | Aerosol container and two-agent discharge container |
| AU2010202628B2 (en) * | 2007-12-17 | 2012-08-09 | Michel Mercier Ltd | Agents, compositions and devices for temporary coloring local hair areas |
| US8939158B2 (en) | 2007-12-17 | 2015-01-27 | S.O.S. Color Ltd. | Agents, compositions and devices for temporary coloring local hair areas |
| US9427060B2 (en) | 2010-06-25 | 2016-08-30 | Kampalook Ltd. | Device, kit and method for coloring hair |
| WO2012057050A1 (en) | 2010-10-26 | 2012-05-03 | 富士フイルム株式会社 | Hair dye |
| US8579992B2 (en) | 2010-10-26 | 2013-11-12 | Fujifilm Corporation | Hair dye |
| KR20130141535A (en) | 2010-10-26 | 2013-12-26 | 후지필름 가부시키가이샤 | Hair dye |
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