JPH08233394A - Heating method and apparatus thereof - Google Patents

Heating method and apparatus thereof

Info

Publication number
JPH08233394A
JPH08233394A JP7060097A JP6009795A JPH08233394A JP H08233394 A JPH08233394 A JP H08233394A JP 7060097 A JP7060097 A JP 7060097A JP 6009795 A JP6009795 A JP 6009795A JP H08233394 A JPH08233394 A JP H08233394A
Authority
JP
Japan
Prior art keywords
container
hydrogen
hydrogen storage
heat
heated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7060097A
Other languages
Japanese (ja)
Inventor
Masayuki Kawai
政征 河合
Harunobu Takeda
晴信 竹田
Yuichi Wakizaka
裕一 脇坂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Steel Works Ltd
Original Assignee
Japan Steel Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Steel Works Ltd filed Critical Japan Steel Works Ltd
Priority to JP7060097A priority Critical patent/JPH08233394A/en
Publication of JPH08233394A publication Critical patent/JPH08233394A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E70/00Other energy conversion or management systems reducing GHG emissions
    • Y02E70/30Systems combining energy storage with energy generation of non-fossil origin

Landscapes

  • Cleaning Of Streets, Tracks, Or Beaches (AREA)
  • Road Paving Structures (AREA)
  • Sorption Type Refrigeration Machines (AREA)

Abstract

(57)【要約】 【目的】 水素吸蔵合金による発生熱を利用して、被昇
温部である路面、屋根等の雪、氷等を加熱して溶かし、
また、凍結を防止する。これにより、特別の熱源又は発
熱用のヒータを使用せず未利用の比較的低温の熱源を使
用して、構造簡素かつ小形にして省エネルギーとなるヒ
ーティング方法及びその装置を提供する。 【構成】 水素吸蔵合金A1,A2をそれぞれ収容する
第1,第2MH容器1,2を配置し、第1MH容器1を
熱源35によつて加熱すると共に、第1MH容器1から
第2MH容器2に向けて水素を強制的に送り込むことに
より、第2MH容器2の水素吸蔵合金A2に発熱反応を
生じさせ、該第2MH容器2での発生熱によつて被昇温
部10aを昇温させる。
(57) [Abstract] [Purpose] Using the heat generated by the hydrogen storage alloy to heat and melt snow, ice, etc. on the road surface, roof, etc.
It also prevents freezing. As a result, a heating method and an apparatus thereof are provided which uses a relatively low temperature heat source that is not used without using a special heat source or a heater for heat generation, has a simple structure and is small in size, and saves energy. [Structure] First and second MH containers 1 and 2 respectively accommodating hydrogen storage alloys A1 and A2 are arranged, and the first MH container 1 is heated by a heat source 35, and at the same time from the first MH container 1 to the second MH container 2. By forcibly feeding hydrogen toward the hydrogen storage alloy A2 of the second MH container 2, an exothermic reaction is caused, and the temperature of the heated portion 10a is raised by the heat generated in the second MH container 2.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、路面、屋根等の融雪及
び凍結防止を図るヒーティング装置に関するものであ
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heating device for preventing snow melting and freezing on road surfaces, roofs and the like.

【0002】[0002]

【従来の技術及びその課題】従来のこの種のヒーティン
グ装置として、例えば道路表層部にヒータを埋設するも
のが知られている。これは、ヒータに電気を通して道路
表層部を昇温させ、路面の融雪及び凍結防止を図る。し
かしながら、発熱に電気を使用するため、ランニングコ
ストが嵩むという技術的課題があつた。また、路面の近
くに設置した熱源によつて湯を発生させ、この湯を道路
表層部に埋設したパイプに通すものも知られている。こ
れは、ガス、灯油等の燃料を使用して湯を発生させ、パ
イプに通した湯によつて道路表層部を昇温させ、路面の
融雪及び凍結防止を図る。このため、路面の近くに燃焼
装置等の熱源を設置する必要があり、構造が複雑かつ大
形化すると共に、パイプ内で凍結を生じて使用不可能な
状態を生ずる恐れがあるという技術的課題があつた。
2. Description of the Related Art As a conventional heating device of this type, there is known a device in which a heater is embedded in a road surface portion, for example. This allows electricity to be passed through the heater to raise the temperature of the road surface and prevent snow melting and freezing on the road surface. However, since electricity is used for heat generation, there is a technical problem that running cost increases. It is also known that hot water is generated by a heat source installed near the road surface and the hot water is passed through a pipe buried in the road surface layer. This is to generate hot water by using fuel such as gas and kerosene, and to raise the temperature of the road surface layer by the hot water that has passed through the pipe to prevent snow melting and freezing on the road surface. Therefore, it is necessary to install a heat source such as a combustion device near the road surface, and the structure becomes complicated and large-sized, and there is a possibility that freezing may occur in the pipe and an unusable state may occur. I got it.

【0003】[0003]

【課題を解決するための手段】本発明は、このような従
来の技術的課題に鑑みてなされたもので、その構成は次
の通りである。請求項1の発明の構成は、水素吸蔵合金
A1,A2をそれぞれ収容する第1,第2MH容器1,
2を配置し、第1MH容器1を熱源35によつて加熱す
ると共に、第1MH容器1から第2MH容器2に向けて
水素を強制的に送り込むことにより、第2MH容器2の
水素吸蔵合金A2に発熱反応を生じさせ、該第2MH容
器2での発生熱によつて被昇温部10aを昇温させるこ
とを特徴とするヒーティング方法である。請求項2の発
明の構成は、水素吸蔵合金A1,A2をそれぞれ収容す
る第1,第2MH容器1,2と、第1MH容器1から第
2MH容器2に向けて水素を強制的に送り込むコンプレ
ッサ4と、開閉バルブ14を付属し、第2MH容器2か
ら第1MH容器1に向けて水素を還流させる流路15と
を有し、第1MH容器1を熱源35によつて加熱可能に
配置させ、第2MH容器2の水素吸蔵合金A2の発熱反
応による発生熱によつて被昇温部10aを昇温させるこ
とを特徴とするヒーティング装置である。請求項3の発
明の構成は、各MH容器1,2の水素吸蔵合金A1,A
2を加熱又は冷却するための熱媒体通路1a,2aを備
えさせると共に、両熱媒体通路1a,2aの間で熱媒体
を循環させるポンプ3を備えることを特徴とする請求項
2のヒーティング装置である。請求項4の発明の構成
は、水素吸蔵合金A1,A2をそれぞれ収容する第1,
第2MH容器1,2と、第1MH容器1から第2MH容
器2に向けて水素を強制的に送り込むコンプレッサ4
と、開閉バルブ14を付属し、第2MH容器2から第1
MH容器1に向けて水素を還流させる流路15と、各M
H容器1,2の水素吸蔵合金A1,A2にそれぞれ付属
する加熱用熱媒体通路20a,20bとを有し、加熱用
熱媒体通路20a,20bの熱媒体を熱源35によつて
加熱可能に配置させ、各水素吸蔵合金A1,A2の発熱
反応による発生熱によつて被昇温部10aを昇温させる
ことを特徴とするヒーティング装置である。請求項5の
発明の構成は、加熱用熱媒体通路20a,20bを、熱
源35によつて加熱可能に配置するタンク28に接続さ
せると共に、各水素吸蔵合金A1,A2の発生熱を取り
出す熱放出用熱媒体通路21a,21bをそれぞれ設
け、各熱放出用熱媒体通路21a,21bを被昇温部1
0aに近接させて配置するタンク27に接続させること
を特徴とする請求項4のヒーティング装置である。
The present invention has been made in view of such conventional technical problems, and has the following structure. According to the configuration of the invention of claim 1, the first and second MH containers 1 and 2 respectively containing the hydrogen storage alloys A1 and A2.
2 is arranged, the first MH container 1 is heated by the heat source 35, and hydrogen is forcibly fed from the first MH container 1 toward the second MH container 2, whereby the hydrogen storage alloy A2 of the second MH container 2 is supplied. The heating method is characterized by causing an exothermic reaction and raising the temperature of the temperature-raised part 10a by the heat generated in the second MH container 2. According to a second aspect of the invention, the first and second MH containers 1 and 2 respectively containing the hydrogen storage alloys A1 and A2, and the compressor 4 forcibly feeding hydrogen from the first MH container 1 toward the second MH container 2 are provided. And a flow path 15 which is attached with an opening / closing valve 14 and causes hydrogen to flow back from the second MH container 2 toward the first MH container 1, and the first MH container 1 is arranged so as to be heated by a heat source 35. The heating device is characterized in that the heated portion 10a is heated by the heat generated by the exothermic reaction of the hydrogen storage alloy A2 of the 2MH container 2. According to the third aspect of the invention, the hydrogen storage alloys A1, A of the MH containers 1, 2
3. The heating device according to claim 2, further comprising a heat medium passage 1a, 2a for heating or cooling 2, and a pump 3 for circulating the heat medium between the both heat medium passages 1a, 2a. Is. According to a fourth aspect of the present invention, there are provided first and second hydrogen storage alloys A1 and A2, respectively.
Second MH containers 1 and 2, and a compressor 4 forcibly sending hydrogen from the first MH container 1 to the second MH container 2.
And an opening / closing valve 14 are attached to the first MH container 2 to the first
A flow path 15 for refluxing hydrogen toward the MH container 1 and each M
It has heating heat medium passages 20a and 20b attached to the hydrogen storage alloys A1 and A2 of the H containers 1 and 2, respectively, and the heat medium in the heating heat medium passages 20a and 20b is arranged to be heated by the heat source 35. The heating device is characterized in that the heated portion 10a is heated by the heat generated by the exothermic reaction of the hydrogen storage alloys A1 and A2. According to the configuration of the invention of claim 5, the heating heat medium passages 20a, 20b are connected to the tank 28 arranged so as to be heatable by the heat source 35, and the heat generated by the hydrogen storage alloys A1, A2 is taken out. Heat medium passages 21a and 21b are provided respectively, and the heat-dissipating heat medium passages 21a and 21b are connected to the heated portion 1
The heating device according to claim 4, wherein the heating device is connected to a tank 27 arranged close to 0a.

【0004】[0004]

【作用】請求項1の発明によれば、第1MH容器1の水
素吸蔵合金A1に水素が吸蔵された状態で、第1MH容
器1の水素吸蔵合金A1は、熱源35によつて比較的低
温に加熱され、所定圧未満では水素化物を形成し難い状
態にある。熱源35としては、下水、地熱等の未利用熱
源を使用できる。この状態から、第1MH容器1から第
2MH容器2に向けて水素を強制的に送り込む。これに
より、水素吸蔵合金A1から水素が放出され、水素吸蔵
量が次第に減少し、放出された水素は第2MH容器2に
比較的高圧で送り込まれる。
According to the first aspect of the invention, the hydrogen storage alloy A1 of the first MH container 1 is kept at a relatively low temperature by the heat source 35 in a state where hydrogen is stored in the hydrogen storage alloy A1 of the first MH container 1. When heated and less than a predetermined pressure, it is difficult to form a hydride. As the heat source 35, an unused heat source such as sewage or geothermal heat can be used. From this state, hydrogen is forcibly sent from the first MH container 1 to the second MH container 2. As a result, hydrogen is released from the hydrogen storage alloy A1, the hydrogen storage amount gradually decreases, and the released hydrogen is sent to the second MH container 2 at a relatively high pressure.

【0005】これにより、第2MH容器2の水素吸蔵合
金A2に水素吸蔵に伴う発熱反応を生じるので、第2M
H容器2での発生熱によつて被昇温部10aを昇温させ
ることができる。被昇温部10aを路面、屋根等とする
ことにより、これらの融雪及び凍結防止を図ることがで
きる。
As a result, an exothermic reaction due to hydrogen storage occurs in the hydrogen storage alloy A2 of the second MH container 2, so that the second M
The temperature of the heated portion 10a can be raised by the heat generated in the H container 2. By making the heated portion 10a a road surface, a roof, or the like, it is possible to prevent snow melting and freezing of these.

【0006】請求項2の発明によれば、第1MH容器1
の水素吸蔵合金A1に水素が吸蔵され、開閉バルブ14
が閉じた状態で、第1MH容器1の水素吸蔵合金A1
は、未利用の熱源35によつて比較的低温に加熱され、
所定圧未満では水素化物を形成し難い状態にある。熱源
35としては、下水、地熱等の未利用熱源を使用でき
る。この状態から、コンプレッサ4を駆動して第1MH
容器1内を減圧する。これにより、水素吸蔵合金A1か
ら水素が放出され、放出された水素は第2MH容器2に
比較的高圧で送り込まれる。
According to the invention of claim 2, the first MH container 1
Hydrogen is stored in the hydrogen storage alloy A1 of
With the hydrogen closed, the hydrogen storage alloy A1 of the first MH container 1
Is heated to a relatively low temperature by an unused heat source 35,
If the pressure is less than the predetermined pressure, it is difficult to form a hydride. As the heat source 35, an unused heat source such as sewage or geothermal heat can be used. From this state, the compressor 4 is driven to drive the first MH.
The pressure inside the container 1 is reduced. As a result, hydrogen is released from the hydrogen storage alloy A1, and the released hydrogen is sent to the second MH container 2 at a relatively high pressure.

【0007】これにより、第2MH容器2では、水素の
流入によつて内圧が上昇しながら水素吸蔵合金A2に水
素が効果的に吸蔵され、発熱反応に伴う発生熱によつて
所定温度に上昇し、水素を吸蔵し続ける。この水素吸蔵
合金A2の昇温によつて被昇温部10aを加熱すること
ができるので、被昇温部10a上の雪、氷等を溶かすこ
とができると共に再凍結を防止することができる。
As a result, in the second MH container 2, hydrogen is effectively stored in the hydrogen storage alloy A2 while the internal pressure is increased by the inflow of hydrogen, and the temperature is raised to a predetermined temperature by the heat generated by the exothermic reaction. , Keep absorbing hydrogen. Since the heated portion 10a can be heated by raising the temperature of the hydrogen storage alloy A2, snow, ice, etc. on the heated portion 10a can be melted and refreezing can be prevented.

【0008】第2MH容器2内の水素吸蔵合金A2に水
素が吸蔵されたなら、コンプレッサ4の駆動を停止する
と共に、開閉バルブ14を開き、第2MH容器2内の水
素を流路15を通して第1MH容器1内に導入させる。
これにより、第2MH容器2内が減圧され、水素吸蔵合
金A2から水素の放出が促される。同時に、両MH容器
1,2内の圧力差に基づいて、第1MH容器1内が昇圧
するので、水素吸蔵合金A1に水素が吸蔵される。第2
MH容器2の水素吸蔵合金A2から水素が放出され、ま
た、第1MH容器1の水素吸蔵合金A1に水素が吸蔵さ
れ、当初の吸蔵量にそれぞれ復帰したなら、開閉バルブ
14を閉じる。
When hydrogen is stored in the hydrogen storage alloy A2 in the second MH container 2, the driving of the compressor 4 is stopped, the opening / closing valve 14 is opened, and the hydrogen in the second MH container 2 is passed through the flow path 15 to the first MH. It is introduced into the container 1.
As a result, the pressure inside the second MH container 2 is reduced, and the release of hydrogen from the hydrogen storage alloy A2 is promoted. At the same time, the pressure inside the first MH container 1 is increased based on the pressure difference between the two MH containers 1 and 2, so that hydrogen is stored in the hydrogen storage alloy A1. Second
When hydrogen is released from the hydrogen storage alloy A2 of the MH container 2 and hydrogen is stored in the hydrogen storage alloy A1 of the first MH container 1, and the initial storage amount is restored, the on-off valve 14 is closed.

【0009】このように、コンプレッサ4を使用して第
1MH容器1内の水素を第2MH容器2内に強制的に送
り込んで圧力差を生じさせるので、両水素吸蔵合金A
1,A2の温度差が小さい場合であつても、水素の吸蔵
・放出を繰り返して行わせることができる。
As described above, since the hydrogen in the first MH container 1 is forcibly sent into the second MH container 2 by using the compressor 4 to generate a pressure difference, both hydrogen storage alloys A
Even when the temperature difference between 1 and A2 is small, hydrogen absorption and desorption can be repeated.

【0010】請求項3の発明によれば、開閉バルブ14
を開き、第2MH容器2内の水素を流路15を通して第
1MH容器1内に導入させる際、ポンプ3を駆動し、熱
媒体を両熱媒体通路1a,2aを通じて循環させる。こ
れにより、第2MH容器2の水素吸蔵合金A2が吸熱反
応に伴う過度の温度低下を生ずることなく、水素の放出
が維持されると同時に、第1MH容器1の水素吸蔵合金
A1が発熱反応に伴う過度の温度上昇を生ずることな
く、水素の吸蔵作用が維持される。
According to the invention of claim 3, the on-off valve 14
When the hydrogen in the second MH container 2 is introduced into the first MH container 1 through the flow path 15, the pump 3 is driven to circulate the heat medium through both heat medium passages 1a and 2a. As a result, the hydrogen storage alloy A2 of the second MH container 2 does not cause an excessive temperature drop due to the endothermic reaction, and the release of hydrogen is maintained. The hydrogen occlusion action is maintained without causing an excessive temperature rise.

【0011】請求項4の発明によれば、第1MH容器1
の水素吸蔵合金A1に水素が吸蔵され、開閉バルブ14
が閉じた状態で、第1MH容器1の水素吸蔵合金A1
は、熱源35で加熱される加熱用熱媒体通路20a,2
0b内の熱媒体によつて比較的低温に加熱され、所定圧
未満では水素化物を形成し難い状態にある。熱源35と
しては、下水、地熱等の未利用熱源を使用できる。
According to the invention of claim 4, the first MH container 1
Hydrogen is stored in the hydrogen storage alloy A1 of
With the hydrogen closed, the hydrogen storage alloy A1 of the first MH container 1
Is the heating medium passages 20a, 2 for heating by the heat source 35.
It is heated to a relatively low temperature by the heat medium in 0b, and it is difficult to form a hydride at a pressure lower than a predetermined pressure. As the heat source 35, an unused heat source such as sewage or geothermal heat can be used.

【0012】この状態からコンプレッサ4を駆動すれ
ば、第1MH容器1内の圧力低下に伴つて水素吸蔵合金
A1から水素が放出され、放出された水素は、第2MH
容器2に比較的高圧で送り込まれ、水素吸蔵合金A2に
吸蔵される。第1MH容器1内では、減圧傾向を呈して
水素放出が促され、吸熱反応を生じるが、加熱用熱媒体
通路20aの熱媒体が熱源35によつて加熱されること
により、過度の温度低下が防止される。一方、第2MH
容器2では、圧力上昇を生じながら水素吸蔵合金A2に
水素が効果的に吸蔵され、発熱反応を生ずる。この水素
吸蔵合金A2の発熱反応による発生熱によつて被昇温部
10aを昇温させることができる。これにより、被昇温
部10a付近の雪、氷等を溶かすことができると共に、
再凍結を防止することができる。
If the compressor 4 is driven from this state, hydrogen is released from the hydrogen storage alloy A1 as the pressure in the first MH container 1 drops, and the released hydrogen is released into the second MH.
It is sent to the container 2 at a relatively high pressure and stored in the hydrogen storage alloy A2. In the first MH container 1, a depressurization tendency is exhibited, hydrogen release is promoted, and an endothermic reaction occurs. However, since the heat medium in the heating medium passage 20a is heated by the heat source 35, an excessive temperature decrease occurs. To be prevented. On the other hand, the second MH
In the container 2, hydrogen is effectively stored in the hydrogen storage alloy A2 while increasing the pressure, and an exothermic reaction occurs. Due to the heat generated by the exothermic reaction of the hydrogen storage alloy A2, the temperature rising part 10a can be heated. This makes it possible to melt snow, ice, etc. near the heated portion 10a,
Refreezing can be prevented.

【0013】第2MH容器2内の水素吸蔵合金A2に水
素が吸蔵されたなら、コンプレッサ4の駆動を停止する
と共に、開閉バルブ14を開き、第2MH容器2内の水
素を第1MH容器1に導入する。これにより、第2MH
容器2では水素の放出がなされ、また、第1MH容器1
では水素の吸蔵がなされる。その際、第2MH容器2で
は、加熱用熱媒体通路20bによつて所定温度に加熱さ
れて水素の放出が促され、第1MH容器1では、水素の
吸蔵による反応熱を生ずる。
When hydrogen is stored in the hydrogen storage alloy A2 in the second MH container 2, the drive of the compressor 4 is stopped and the opening / closing valve 14 is opened to introduce the hydrogen in the second MH container 2 into the first MH container 1. To do. As a result, the second MH
Hydrogen is released in the container 2, and the first MH container 1
Then hydrogen is absorbed. At that time, the second MH container 2 is heated to a predetermined temperature by the heating heat medium passage 20b to promote release of hydrogen, and the first MH container 1 generates reaction heat due to storage of hydrogen.

【0014】しかして、第1MH容器1の水素吸蔵合金
A1の発熱により、被昇温部10aを昇温させることが
できる。これにより、被昇温部10a付近の雪、氷等を
溶かすことができると共に再凍結を防止することができ
る。このように、コンプレッサ4を使用して第1MH容
器1内の水素を第2MH容器2内に強制的に送り込んで
圧力差を生じさせるので、両水素吸蔵合金A1,A2の
温度差が小さい場合であつても、水素の吸蔵・放出を繰
り返して行わせることができる。
Therefore, the temperature of the heated portion 10a can be raised by the heat generated by the hydrogen storage alloy A1 of the first MH container 1. As a result, snow, ice, etc. near the heated portion 10a can be melted and refreezing can be prevented. As described above, since the pressure in the first MH container 1 is forcedly sent into the second MH container 2 by using the compressor 4 to generate the pressure difference, it is possible to reduce the temperature difference between the hydrogen storage alloys A1 and A2. Even at that time, hydrogen can be stored and released repeatedly.

【0015】請求項5の発明によれば、加熱用熱媒体通
路20a,20bを熱源35によつて加熱可能に配置す
るタンク28に接続させるので、加熱用熱媒体通路20
a,20bによる第1,第2MH容器1の水素吸蔵合金
A1,A2の加熱は、タンク28内の熱媒体が各加熱用
熱媒体通路20a,20bに導入されてなされる。ま
た、各水素吸蔵合金A1,A2の発生熱が、各熱放出用
熱媒体通路21a,21bからタンク27に導入される
熱媒体によつて移動し、タンク27付近の被昇温部10
aを加熱する。
According to the fifth aspect of the present invention, since the heating heat medium passages 20a and 20b are connected to the tank 28 which can be heated by the heat source 35, the heating heat medium passage 20 is provided.
The heating of the hydrogen storage alloys A1 and A2 of the first and second MH containers 1 by a and 20b is performed by introducing the heating medium in the tank 28 into the heating heating medium passages 20a and 20b. The heat generated by the hydrogen storage alloys A1 and A2 is moved by the heat medium introduced into the tank 27 from the heat release heat medium passages 21a and 21b, and the heated portion 10 near the tank 27 is heated.
Heat a.

【0016】[0016]

【実施例】以下、本発明の実施例について図面を参照し
て説明する。図1,図2は本発明に係るヒーティング装
置の第1実施例を示す。図1中において符号1,2はそ
れぞれ水素吸蔵合金A1,A2を収容する第1,第2M
H容器を示す。第2MH容器2は、道路10の表層部に
埋設され、第1MH容器1は、地中の適所に埋設されて
いる。水素吸蔵合金A1,A2は、各MH容器1,2内
に通気性を有するフィルター1b,2bによつて区画し
て配置され、各MH容器1,2内に水素空間1c,2c
を形成している。水素は、この水素空間1c,2cから
出入りする。また、各水素吸蔵合金A1,A2内には、
水素吸蔵合金A1,A2を加熱又は冷却するための熱媒
体通路1a,2aが付属されている。ここで、水素吸蔵
合金A1,A2は、例えばTiZrCrFeMnNiCu系合金であ
る。なお、図上では各MH容器1,2内の上部に水素空
間1c,2cを形成し、下部に水素吸蔵合金A1,A2
を収容してあるが、下部に水素空間1c,2cを形成
し、上部に水素吸蔵合金A1,A2を収容することもで
きる。
Embodiments of the present invention will be described below with reference to the drawings. 1 and 2 show a first embodiment of a heating device according to the present invention. In FIG. 1, reference numerals 1 and 2 denote first and second M housing hydrogen storage alloys A1 and A2, respectively.
H container is shown. The second MH container 2 is buried in the surface layer of the road 10, and the first MH container 1 is buried in a proper place in the ground. The hydrogen storage alloys A1 and A2 are arranged in the MH containers 1 and 2 so as to be partitioned by the air-permeable filters 1b and 2b, and the hydrogen spaces 1c and 2c are provided in the MH containers 1 and 2.
Is formed. Hydrogen enters and leaves the hydrogen spaces 1c and 2c. In addition, in each hydrogen storage alloy A1, A2,
Heat medium passages 1a and 2a for heating or cooling the hydrogen storage alloys A1 and A2 are attached. Here, the hydrogen storage alloys A1 and A2 are, for example, TiZrCrFeMnNiCu based alloys. In the figure, hydrogen spaces 1c and 2c are formed in the upper part of each MH container 1 and 2, and hydrogen storage alloys A1 and A2 are formed in the lower part.
However, it is also possible to form the hydrogen spaces 1c and 2c in the lower part and accommodate the hydrogen storage alloys A1 and A2 in the upper part.

【0017】しかして、第2MH容器2は、路面10a
に近接して配置され、第1MH容器1の水素吸蔵合金A
1は、未利用の熱源35、例えば下水、地中の地熱等に
よつて比較的低温(例えば約10℃)に加熱可能な箇所
に配置してある。なお、路面10aは、融雪等のために
加熱を必要とする被昇温部であればよく、屋根等でもよ
い。
Thus, the second MH container 2 has the road surface 10a.
The hydrogen storage alloy A of the first MH container 1 arranged close to
No. 1 is arranged at a location where it can be heated to a relatively low temperature (for example, about 10 ° C.) by an unused heat source 35, for example, sewage, underground geothermal heat, or the like. The road surface 10a may be a temperature-raised part that needs to be heated for snow melting or the like, and may be a roof or the like.

【0018】そして、両水素空間1c,2cの他端部同
士は、コンプレッサ4を介在する配管13によつて連通
させ、一端部同士は、開閉バルブ14を介在する流路1
5によつて連通させてある。コンプレッサ4は、第1M
H容器1から第2MH容器2に向けて水素を強制的に送
り込む機能を有し、また、流路15は、第2MH容器2
から第1MH容器1に向けて水素を還流させる機能を有
する。また、両熱媒体通路1a,2aの一端部同士は、
循環用のポンプ3を介在する配管11によつて連通さ
せ、他端部同士は、配管12によつて連通させて閉回路
を構成させ、これらの両熱媒体通路1a,2a及び配管
11,12内には、熱媒体を充填させてある。なお、本
発明で使用する熱媒体は、全て塩化カルシウム水溶液、
フロリナート等の凍結し難いもので構成してある。
The other ends of the two hydrogen spaces 1c and 2c are communicated with each other by a pipe 13 having a compressor 4 interposed therebetween, and one ends thereof have a flow path 1 having an opening / closing valve 14 interposed therebetween.
It is made to communicate by 5. The compressor 4 is the first M
It has a function of forcibly feeding hydrogen from the H container 1 toward the second MH container 2, and the flow path 15 is provided in the second MH container 2
Has a function of refluxing hydrogen toward the first MH container 1. In addition, the ends of both heat medium passages 1a and 2a are
The circulation pump 3 is connected through a pipe 11, and the other ends are communicated through a pipe 12 to form a closed circuit. The heat medium passages 1a and 2a and the pipes 11 and 12 are connected to each other. The inside is filled with a heat medium. The heat medium used in the present invention is an aqueous calcium chloride solution,
It is made of something that is hard to freeze, such as Fluorinert.

【0019】次に、上記実施例の作用について説明す
る。第1MH容器1の水素吸蔵合金A1に十分な水素が
吸蔵され、開閉バルブ14が閉じた状態で、第1MH容
器1の水素吸蔵合金A1は、未利用の熱源35によつて
比較的低温(例えば約10℃)に常時加熱されている。
水素吸蔵合金A1は、所定圧未満では水素化物を形成し
難い状態にあるので、水素が放出され易い傾向にある。
この状態から、コンプレッサ4を駆動して第1MH容器
1内を減圧する。これにより、水素吸蔵合金A1から水
素が放出され、図2(水素圧力−組成等温線図)に点H
〜点Iに示すように水素吸蔵量が次第に減少し、放出さ
れた水素は配管13を通つて第2MH容器2に比較的高
圧で送り込まれる。
Next, the operation of the above embodiment will be described. When sufficient hydrogen is stored in the hydrogen storage alloy A1 of the first MH container 1 and the opening / closing valve 14 is closed, the hydrogen storage alloy A1 of the first MH container 1 is kept at a relatively low temperature by the unused heat source 35 (for example, It is constantly heated to about 10 ° C.
Since the hydrogen storage alloy A1 is in a state in which it is difficult to form a hydride at a pressure lower than the predetermined pressure, hydrogen tends to be easily released.
From this state, the compressor 4 is driven to reduce the pressure inside the first MH container 1. As a result, hydrogen is released from the hydrogen storage alloy A1, and a point H is shown in FIG. 2 (hydrogen pressure-composition isotherm diagram).
As shown at point I, the hydrogen storage amount gradually decreases, and the released hydrogen is sent to the second MH container 2 at a relatively high pressure through the pipe 13.

【0020】すなわち、第1MH容器1内は次第に減圧
されて水素を放出し続ける。一方、雪又は氷で冷却され
ている第2MH容器2では、図2に点Jで示すように水
素吸蔵量が少なかつたものが、図2に点J〜点Kに示す
ように水素の流入によつて内圧が上昇しながら水素吸蔵
合金A2に水素が効果的に吸蔵され、発熱反応に伴う発
生熱によつて所定温度(例えば約30℃)に上昇し、水
素を吸蔵し続ける。この水素吸蔵合金A2の昇温によつ
て路面10aが加熱を受けるので、路面10a上の雪、
氷等が溶けると共に再凍結が防止される。
That is, the inside of the first MH container 1 is gradually depressurized and continues to release hydrogen. On the other hand, in the second MH container 2 cooled by snow or ice, the one having a small hydrogen storage amount as shown by the point J in FIG. 2 does not enter the hydrogen as shown by the points J to K in FIG. As a result, hydrogen is effectively stored in the hydrogen storage alloy A2 while the internal pressure increases, and the heat generated by the exothermic reaction raises the temperature to a predetermined temperature (for example, about 30 ° C.) and continues to store hydrogen. Since the road surface 10a is heated by the temperature rise of the hydrogen storage alloy A2, snow on the road surface 10a,
The ice is melted and refreezing is prevented.

【0021】第2MH容器2内の水素吸蔵合金A2に十
分に水素が吸蔵されたなら、コンプレッサ4の駆動を停
止すると共に、開閉バルブ14を開き、第2MH容器2
内の水素を流路15を通して第1MH容器1内に導入さ
せる。これにより、路面10a上の雪、氷等によつて冷
却を受けた状態で第2MH容器2内が減圧され、水素吸
蔵合金A2から水素の放出が促される。同時に、両MH
容器1,2の水素空間1c,2c内の圧力差に基づい
て、第1MH容器1内が昇圧するので、反応熱が熱源3
5に吸収されながら、水素吸蔵合金A1に水素が吸蔵さ
れる。
When hydrogen has been sufficiently stored in the hydrogen storage alloy A2 in the second MH container 2, the driving of the compressor 4 is stopped and the opening / closing valve 14 is opened to open the second MH container 2
The hydrogen therein is introduced into the first MH container 1 through the flow path 15. As a result, the inside of the second MH container 2 is depressurized while being cooled by snow, ice, or the like on the road surface 10a, and the release of hydrogen from the hydrogen storage alloy A2 is promoted. At the same time, both MH
Since the pressure inside the first MH container 1 is increased based on the pressure difference between the hydrogen spaces 1c and 2c of the containers 1 and 2, the heat of reaction is the heat source 3
While being absorbed by 5, hydrogen is absorbed by the hydrogen storage alloy A1.

【0022】また、開閉バルブ14を開操作すると共に
ポンプ3を駆動すれば、熱媒体が両熱媒体通路1a,2
a及び配管11,12を通じて循環する。これにより、
第2MH容器2の水素吸蔵合金A2が吸熱反応に伴う過
度の温度低下を生ずることなく、水素の放出が維持され
ると同時に、第1MH容器1の水素吸蔵合金A1が発熱
反応に伴う過度の温度上昇を生ずることなく、水素の吸
蔵作用が維持される。第2MH容器2での水素の放出
は、図2に点L〜点Mに示すように行われ、第1MH容
器1での水素の吸蔵は、図2に点N〜点Oに示すように
行われ、両MH容器1,2内がほぼ同圧(図2に示すP
0 )となつて終了する。
When the opening / closing valve 14 is opened and the pump 3 is driven, the heat medium is transferred to both heat medium passages 1a, 2
a and the pipes 11 and 12 are circulated. This allows
The hydrogen storage alloy A2 of the second MH container 2 does not undergo excessive temperature drop due to the endothermic reaction, and the release of hydrogen is maintained, and at the same time, the hydrogen storage alloy A1 of the first MH container 1 has an excessive temperature accompanying the exothermic reaction. The hydrogen occlusion action is maintained without increasing. The release of hydrogen in the second MH container 2 is performed as shown at points L to M in FIG. 2, and the storage of hydrogen in the first MH container 1 is performed as shown at points N to O in FIG. The pressure inside the MH containers 1 and 2 is almost the same (see P
0 ) to end.

【0023】第2MH容器2の水素吸蔵合金A2から十
分な水素が放出され、また、第1MH容器1の水素吸蔵
合金A1に十分な水素が吸蔵され、当初の吸蔵量にそれ
ぞれ復帰したなら、開閉バルブ14を閉じると共に、ポ
ンプ3の駆動を停止する。ポンプ3の駆動によつて両M
H容器1,2間で温度の均一化が促されることにより、
第2MH容器2の水素吸蔵合金A2から水素が放出され
ることに伴う吸熱反応に起因して、路面10aが過度に
冷却されることが防止されると共に、第1MH容器1の
水素吸蔵合金A1に水素が吸蔵されることに伴う発熱反
応に起因して、水素吸蔵合金A1への水素吸蔵が阻害さ
れることが良好に防止される。
When sufficient hydrogen is released from the hydrogen storage alloy A2 of the second MH container 2 and sufficient hydrogen is stored in the hydrogen storage alloy A1 of the first MH container 1 and the initial storage amount is restored, opening / closing The valve 14 is closed and the driving of the pump 3 is stopped. By driving the pump 3, both M
By promoting the equalization of temperature between the H containers 1 and 2,
The road surface 10a is prevented from being excessively cooled due to an endothermic reaction accompanying the release of hydrogen from the hydrogen storage alloy A2 of the second MH container 2, and the hydrogen storage alloy A1 of the first MH container 1 is prevented. It is possible to satisfactorily prevent the hydrogen storage alloy A1 from inhibiting the hydrogen storage due to the exothermic reaction accompanying the storage of hydrogen.

【0024】このように、コンプレッサ4を使用して第
1MH容器1内の水素を第2MH容器2内に強制的に送
り込んで圧力差を生じさせるので、両水素吸蔵合金A
1,A2の温度差が小さい場合であつても、水素の吸蔵
・放出を繰り返して行わせることができる。
As described above, since the hydrogen in the first MH container 1 is forcibly sent into the second MH container 2 by using the compressor 4 to generate a pressure difference, both hydrogen storage alloys A
Even when the temperature difference between 1 and A2 is small, hydrogen absorption and desorption can be repeated.

【0025】このような作動の繰り返しにより、路面1
0a上の雪、氷等を間欠的に加熱して溶かし、また、凍
結の防止作用が長時間得られることになる。なお、上記
構成のヒーティング装置を複数個配置し、両MH容器
1,2における水素の吸蔵及び放出を逆位相で実施する
ことにより、路面10aを連続的に加熱することも可能
である。
By repeating such operations, the road surface 1
The snow, ice, etc. on the surface 0a are intermittently heated and melted, and the antifreezing action can be obtained for a long time. It is also possible to continuously heat the road surface 10a by arranging a plurality of heating devices having the above-mentioned configuration and performing the hydrogen absorption and desorption in both MH containers 1 and 2 in opposite phases.

【0026】図3,図4は本発明に係るヒーティング装
置の第2実施例を示し、第1実施例と実質的に同一機能
の部分には同一符号を付してそれらの説明は省略する。
第1,第2MH容器1,2は、いずれも道路10の表層
部に埋設させて外気による温度影響を防止してある。ま
た、各水素吸蔵合金A1,A2の外部には、水素吸蔵合
金A1,A2をそれぞれ加熱するための加熱用熱媒体通
路20a,20b及び各水素吸蔵合金A1,A2の発熱
反応に伴う発生熱を外部に取り出すための熱放出用熱媒
体通路21a,21bをそれぞれ付属させてある。
FIGS. 3 and 4 show a second embodiment of the heating apparatus according to the present invention, parts having substantially the same functions as those of the first embodiment are designated by the same reference numerals, and their description will be omitted. .
Both the first and second MH containers 1 and 2 are buried in the surface layer of the road 10 to prevent the influence of temperature by the outside air. Further, outside the respective hydrogen storage alloys A1 and A2, heat generated by the exothermic reaction of the heating heat medium passages 20a and 20b for heating the hydrogen storage alloys A1 and A2 and the hydrogen storage alloys A1 and A2, respectively. The heat-dissipating heat medium passages 21a and 21b for taking out to the outside are attached respectively.

【0027】そして、第1,第2MH容器1,2の水素
吸蔵合金A1,A2に付属する加熱用熱媒体通路20
a,20bは、配管23a,23b,24a,24bを
介して例えば下水、地中の地熱等の未利用の熱源35に
よつて加熱可能な箇所に配置したタンク28に接続さ
れ、それぞれ熱媒体が循環可能である。この加熱用熱媒
体通路20a,20b、配管23a,23b,24a,
24b及びタンク28により、各水素吸蔵合金A1,A
2を比較的低温(例えば約10℃)に加熱する加熱装置
を構成している。加熱されたタンク28内の熱媒体は、
加熱用熱媒体通路20a,20bが冷却された状態で、
自然対流で加熱用熱媒体通路20a,20bを循環する
ように配置してあるが、配管23a,24a又は23
b,24bの適所に、熱媒体を循環させるポンプをそれ
ぞれ介在させることもできる。なお、路面10aは、融
雪等のために加熱を必要とする被昇温部であればよく、
屋根等でもよい。
The heating heat medium passage 20 attached to the hydrogen storage alloys A1 and A2 of the first and second MH containers 1 and 2.
a and 20b are connected via pipes 23a, 23b, 24a, and 24b to tanks 28 arranged at locations where they can be heated by an unused heat source 35 such as sewage or underground geothermal heat, and the heat medium is It can be circulated. The heating heat medium passages 20a, 20b, the pipes 23a, 23b, 24a,
The hydrogen storage alloys A1 and A are provided by 24b and the tank
A heating device for heating 2 to a relatively low temperature (for example, about 10 ° C.) is configured. The heating medium in the heated tank 28 is
With the heating heat medium passages 20a and 20b being cooled,
Although arranged so as to circulate through the heating medium paths 20a, 20b by natural convection, the pipes 23a, 24a or 23
Pumps for circulating the heat medium may be provided at appropriate positions of b and 24b. In addition, the road surface 10a may be a temperature-raised part that needs to be heated for snow melting or the like,
It may be a roof.

【0028】また、第1,第2MH容器1,2の水素吸
蔵合金A1,A2に付属する熱放出用熱媒体通路21
a,21bは、路面10aに近接させて配置したタンク
27に配管25a,25b,26a,26bを介して接
続され、それぞれ熱媒体が循環可能である。この熱放出
用熱媒体通路21a,21b、配管25a,25b,2
6a,26b及びタンク27により、所定温度(約30
℃)の熱利用装置を構成している。冷却されたタンク2
7内の熱媒体は、加熱用熱媒体通路21a,21bが加
熱された状態で、自然対流で加熱用熱媒体通路21a,
21bを循環するように配置してあるが、配管25a,
26a又は25b,26bの適所に、熱媒体を循環させ
るポンプをそれぞれ介在させることもできる。
Further, the heat-releasing heat medium passage 21 attached to the hydrogen storage alloys A1 and A2 of the first and second MH containers 1 and 2.
The a and 21b are connected to the tank 27 arranged close to the road surface 10a through the pipes 25a, 25b, 26a and 26b, and the heat medium can circulate respectively. The heat-releasing heat medium passages 21a, 21b and the pipes 25a, 25b, 2
6a, 26b and the tank 27, a predetermined temperature (about 30
℃) heat utilization device. Cooled tank 2
The heat medium in 7 is heated by the heat medium passages 21a, 21b for heating by the natural convection.
21b are arranged so as to circulate, but the pipes 25a,
It is also possible to interpose a pump for circulating the heat medium at an appropriate place of 26a or 25b, 26b.

【0029】勿論、両水素空間1c,2c同士は、コン
プレッサ4を介在する配管13によつて連通させ、第1
MH容器1から第2MH容器2に向けて水素を強制的に
送り込むことができると共に、開閉バルブ14を介在す
る配管15によつて連通させ、第2MH容器2から第1
MH容器1に向けて水素を還流させることができるよう
になつている。
Of course, both hydrogen spaces 1c and 2c are communicated with each other by a pipe 13 with a compressor 4 interposed therebetween, and
Hydrogen can be forcibly sent from the MH container 1 to the second MH container 2 and is communicated by a pipe 15 with an opening / closing valve 14 interposed between the second MH container 2 and the first MH container 2.
The hydrogen can be refluxed toward the MH container 1.

【0030】次に、第2実施例の作用について説明す
る。第1MH容器1の水素吸蔵合金A1に十分な水素が
吸蔵され、開閉バルブ14が閉じた状態で、第1MH容
器1の水素吸蔵合金A1は、未利用の熱源35で加熱さ
れた加熱用熱媒体通路20aによつて比較的低温に加熱
(約10℃)されている。水素吸蔵合金A1は、所定圧
未満では水素化物を形成し難い状態にあるので、水素が
放出され易い傾向にある。
Next, the operation of the second embodiment will be described. With sufficient hydrogen stored in the hydrogen storage alloy A1 of the first MH container 1 and the opening / closing valve 14 closed, the hydrogen storage alloy A1 of the first MH container 1 is heated by the unused heat source 35. It is heated to a relatively low temperature (about 10 ° C.) by the passage 20a. Since the hydrogen storage alloy A1 is in a state in which it is difficult to form a hydride at a pressure lower than the predetermined pressure, hydrogen tends to be easily released.

【0031】この状態からコンプレッサ4を駆動すれ
ば、第1MH容器1の水素吸蔵合金A1から図4(水素
圧力−組成等温線図)に点P〜点Qに示すように水素が
放出され、放出された水素は、配管13を通つて第2M
H容器2に比較的高圧で送り込まれ、図4に点R〜点S
に示すように水素吸蔵合金A2に吸蔵される。第1MH
容器1内では、減圧傾向を呈して水素化物を更に形成し
難い状態になつて水素放出が促され、吸熱反応を生じる
が、タンク28内の熱媒体が加熱用熱媒体通路20aに
導入されて加熱される。一方、第2MH容器2では、圧
力上昇を生じながら水素吸蔵合金A2に水素が効果的に
吸蔵され、発熱反応を生ずる。この水素吸蔵合金A2の
発熱により、熱放出用熱媒体通路21b内の熱媒体が昇
温し、昇温した熱媒体(約30℃)が対流によつてタン
ク27に流入するので、路面10aが加熱を受けて昇温
する。これにより、路面10a上の雪、氷等が溶けると
共に再凍結が防止される。
When the compressor 4 is driven from this state, hydrogen is released from the hydrogen storage alloy A1 of the first MH container 1 as shown by points P to Q in FIG. 4 (hydrogen pressure-composition isotherm diagram), and released. The generated hydrogen is passed through the pipe 13 to the second M
It is sent into the H container 2 at a relatively high pressure, and points R to S in FIG.
As shown in, the hydrogen is absorbed in the hydrogen storage alloy A2. 1st MH
In the container 1, a depressurization tendency is exhibited and it becomes more difficult to form a hydride, and hydrogen release is promoted to cause an endothermic reaction. However, the heat medium in the tank 28 is introduced into the heating medium passage 20a for heating. Be heated. On the other hand, in the second MH container 2, hydrogen is effectively stored in the hydrogen storage alloy A2 while increasing the pressure, and an exothermic reaction occurs. Due to the heat generated by the hydrogen storage alloy A2, the temperature of the heat medium in the heat-releasing heat medium passage 21b rises, and the heated medium (about 30 ° C.) flows into the tank 27 by convection. It is heated to raise the temperature. This melts snow, ice, etc. on the road surface 10a and prevents re-freezing.

【0032】第2MH容器2内の水素吸蔵合金A2に十
分に水素が吸蔵されたなら、コンプレッサ4の駆動を停
止すると共に、開閉バルブ14を開き、第2MH容器2
内の水素を第1MH容器1に導入する。これにより、第
2MH容器2では、図4に示す点Tから点Uに向けて水
素の放出がなされ、また、第1MH容器1では、点Vか
ら点Wに向けて水素の吸蔵がなされ、両MH容器1,2
内がほぼ同圧(図4に示すP1 )となつて終了する。そ
の際、第2MH容器2では、加熱用熱媒体通路20bに
よつて所定温度(約10℃)に加熱されて水素の放出が
促され、第1MH容器1では、水素の吸蔵による反応熱
(約30℃)を生ずる。
When hydrogen has been sufficiently stored in the hydrogen storage alloy A2 in the second MH container 2, the driving of the compressor 4 is stopped and the opening / closing valve 14 is opened, so that the second MH container 2 is closed.
The hydrogen therein is introduced into the first MH container 1. As a result, in the second MH container 2, hydrogen is released from point T to point U shown in FIG. 4, and in the first MH container 1, hydrogen is occluded from point V to point W. MH container 1,2
The inside pressure is almost the same (P 1 shown in FIG. 4) and the process ends. At that time, in the second MH container 2, the heating heat medium passage 20b is heated to a predetermined temperature (about 10 ° C.) to accelerate the release of hydrogen, and in the first MH container 1, the reaction heat due to the absorption of hydrogen (about 30 ° C.).

【0033】しかして、第1MH容器1の水素吸蔵合金
A1の発熱により、熱放出用熱媒体通路21aが昇温
し、昇温した熱媒体が対流によつてタンク27に流入す
るので、路面10aが加熱を受けて昇温する。これによ
り、路面10a上の雪、氷等が溶けると共に凍結が連続
的に防止される。
However, due to the heat generation of the hydrogen storage alloy A1 of the first MH container 1, the temperature of the heat-releasing heat medium passage 21a rises, and the heated heat medium flows into the tank 27 by convection. Receives heat and rises in temperature. As a result, snow, ice, etc. on the road surface 10a are melted and freezing is continuously prevented.

【0034】このように、コンプレッサ4を使用して一
方のMH容器1,2内の水素を他方のMH容器2,1内
に強制的に送り込んで圧力差を生じさせるので、両水素
吸蔵合金A1,A2の温度差が小さい場合であつても、
水素の吸蔵・放出を繰り返して行わせることができる。
このような作動の繰り返しにより、路面10a上の雪、
氷等を連続的に加熱して溶かし、また、凍結の防止を長
時間行わせることができる。
As described above, since the hydrogen in the one MH container 1 or 2 is forcibly sent into the other MH container 2 or 1 by using the compressor 4 to generate a pressure difference, both hydrogen storage alloys A1 , Even if the temperature difference between A2 is small,
It is possible to repeatedly store and release hydrogen.
By repeating such operations, snow on the road surface 10a,
It is possible to continuously heat and melt ice or the like and prevent freezing for a long time.

【0035】[0035]

【発明の効果】以上の説明によつて理解されるように、
本発明に係るヒーティング方法及びその装置によれば、
一対のMH容器間で一方から他方に向けて水素を強制的
に送り込むことにより、MH容器の水素吸蔵合金に発熱
反応を生じさせ、水素吸蔵合金による発生熱を利用して
被昇温部である路面、屋根等の雪、氷等を加熱して溶か
し、また、凍結を防止する。しかして、特別の熱源又は
発熱用のヒータを使用せず未利用の比較的低温の熱源を
使用できるので、構造簡素かつ小形にして省エネルギー
となる。
As can be understood from the above description,
According to the heating method and the device thereof according to the present invention,
By forcibly feeding hydrogen from one to the other between the pair of MH containers, an exothermic reaction is caused in the hydrogen storage alloy in the MH container, and the heat generated by the hydrogen storage alloy is used to generate the temperature-raised part. Heats and melts snow and ice on roads and roofs and prevents freezing. Since an unused heat source at a relatively low temperature can be used without using a special heat source or a heater for heat generation, the structure is simple and small, and energy is saved.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明の第1実施例に係るヒーティング装置
を一部断面で示す概念図。
FIG. 1 is a conceptual diagram showing a partial cross-section of a heating device according to a first embodiment of the present invention.

【図2】 同じく水素吸蔵合金の水素圧力−組成等温線
図。
FIG. 2 is a hydrogen pressure-composition isotherm diagram of a hydrogen storage alloy.

【図3】 本発明の第2実施例に係るヒーティング装置
を一部断面で示す概念図。
FIG. 3 is a conceptual view showing a partial cross section of a heating device according to a second embodiment of the present invention.

【図4】 同じく水素吸蔵合金の水素圧力−組成等温線
図。
FIG. 4 is a hydrogen pressure-composition isotherm diagram of a hydrogen storage alloy.

【符号の説明】[Explanation of symbols]

1:第1MH容器、2:第2MH容器、1a,2a:熱
媒体通路、1b,2b:フィルター、1c,2c:水素
空間、3:ポンプ、4:コンプレッサ、10:道路、1
0a:路面(被昇温部)、11,12:配管、13,1
5:流路、14:開閉バルブ、20a,20b:加熱用
熱媒体通路、21a,21b:熱放出用熱媒体通路、2
7,28:タンク、35:熱源、A1,A2:水素吸蔵
合金。
1: 1st MH container, 2: 2nd MH container, 1a, 2a: Heat medium passage, 1b, 2b: Filter, 1c, 2c: Hydrogen space, 3: Pump, 4: Compressor, 10: Road, 1
0a: Road surface (part to be heated), 11, 12: Piping, 13, 1
5: flow path, 14: open / close valve, 20a, 20b: heat medium passage for heating, 21a, 21b: heat medium passage for heat release, 2
7, 28: Tank, 35: Heat source, A1, A2: Hydrogen storage alloy.

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 水素吸蔵合金(A1,A2)をそれぞれ
収容する第1,第2MH容器(1,2)を配置し、第1
MH容器(1)を熱源(35)によつて加熱すると共
に、第1MH容器(1)から第2MH容器(2)に向け
て水素を強制的に送り込むことにより、第2MH容器
(2)の水素吸蔵合金(A2)に発熱反応を生じさせ、
該第2MH容器(2)での発生熱によつて被昇温部(1
0a)を昇温させることを特徴とするヒーティング方
法。
1. A first and a second MH container (1, 2) respectively accommodating hydrogen storage alloys (A1, A2) are arranged,
By heating the MH container (1) by the heat source (35) and forcibly sending hydrogen from the first MH container (1) to the second MH container (2), the hydrogen in the second MH container (2) is Causing an exothermic reaction in the storage alloy (A2),
Due to the heat generated in the second MH container (2), the part to be heated (1
0a) is heated.
【請求項2】 水素吸蔵合金(A1,A2)をそれぞれ
収容する第1,第2MH容器(1,2)と、第1MH容
器(1)から第2MH容器(2)に向けて水素を強制的
に送り込むコンプレッサ(4)と、開閉バルブ(14)
を付属し、第2MH容器(2)から第1MH容器(1)
に向けて水素を還流させる流路(15)とを有し、第1
MH容器(1)を熱源(35)によつて加熱可能に配置
させ、第2MH容器(2)の水素吸蔵合金(A2)の発
熱反応による発生熱によつて被昇温部(10a)を昇温
させることを特徴とするヒーティング装置。
2. Forced hydrogen from the first and second MH containers (1, 2) respectively containing the hydrogen storage alloys (A1, A2) and from the first MH container (1) to the second MH container (2). Compressor (4) to send to and open / close valve (14)
Attached, the second MH container (2) to the first MH container (1)
A flow path (15) for refluxing hydrogen toward the first
The MH container (1) is arranged so that it can be heated by the heat source (35), and the heated portion (10a) is raised by the heat generated by the exothermic reaction of the hydrogen storage alloy (A2) in the second MH container (2). A heating device characterized by heating.
【請求項3】 各MH容器(1,2)の水素吸蔵合金
(A1,A2)を加熱又は冷却するための熱媒体通路
(1a,2a)を備えさせると共に、両熱媒体通路(1
a,2a)の間で熱媒体を循環させるポンプ(3)を備
えることを特徴とする請求項2のヒーティング装置。
3. A heat medium passage (1a, 2a) for heating or cooling the hydrogen storage alloy (A1, A2) of each MH container (1, 2) is provided, and both heat medium passages (1) are provided.
3. The heating device according to claim 2, characterized in that it comprises a pump (3) for circulating a heat carrier between a, 2a).
【請求項4】 水素吸蔵合金(A1,A2)をそれぞれ
収容する第1,第2MH容器(1,2)と、第1MH容
器(1)から第2MH容器(2)に向けて水素を強制的
に送り込むコンプレッサ(4)と、開閉バルブ(14)
を付属し、第2MH容器(2)から第1MH容器(1)
に向けて水素を還流させる流路(15)と、各MH容器
(1,2)の水素吸蔵合金(A1,A2)にそれぞれ付
属する加熱用熱媒体通路(20a,20b)とを有し、
加熱用熱媒体通路(20a,20b)の熱媒体を熱源
(35)によつて加熱可能に配置させ、各水素吸蔵合金
(A1,A2)の発熱反応による発生熱によつて被昇温
部(10a)を昇温させることを特徴とするヒーティン
グ装置。
4. Forced hydrogen from the first and second MH containers (1, 2) respectively containing the hydrogen storage alloys (A1, A2) and from the first MH container (1) to the second MH container (2). Compressor (4) to send to and open / close valve (14)
Attached, the second MH container (2) to the first MH container (1)
And a heating heat medium passage (20a, 20b) attached to the hydrogen storage alloys (A1, A2) of the MH containers (1, 2), respectively.
The heat medium in the heating heat medium passages (20a, 20b) is arranged so that it can be heated by the heat source (35), and the portion to be heated (heated portion) is generated by the heat generated by the exothermic reaction of each hydrogen storage alloy (A1, A2). A heating device for heating 10a).
【請求項5】 加熱用熱媒体通路(20a,20b)
を、熱源(35)によつて加熱可能に配置するタンク
(28)に接続させると共に、各水素吸蔵合金(A1,
A2)の発生熱を取り出す熱放出用熱媒体通路(21
a,21b)をそれぞれ設け、各熱放出用熱媒体通路
(21a,21b)を被昇温部(10a)に近接させて
配置するタンク(27)に接続させることを特徴とする
請求項4のヒーティング装置。
5. A heating medium passage (20a, 20b) for heating
Is connected to a tank (28) arranged to be heated by a heat source (35), and each hydrogen storage alloy (A1,
A2) heat-releasing heat medium passage for extracting heat generated (21)
a) and 21b) are respectively provided, and each heat-releasing heat medium passage (21a, 21b) is connected to a tank (27) arranged close to the temperature-raised part (10a). Heating device.
JP7060097A 1995-02-24 1995-02-24 Heating method and apparatus thereof Pending JPH08233394A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7060097A JPH08233394A (en) 1995-02-24 1995-02-24 Heating method and apparatus thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7060097A JPH08233394A (en) 1995-02-24 1995-02-24 Heating method and apparatus thereof

Publications (1)

Publication Number Publication Date
JPH08233394A true JPH08233394A (en) 1996-09-13

Family

ID=13132259

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7060097A Pending JPH08233394A (en) 1995-02-24 1995-02-24 Heating method and apparatus thereof

Country Status (1)

Country Link
JP (1) JPH08233394A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6733741B2 (en) * 2000-09-05 2004-05-11 Toyota Jidosha Kabushiki Kaisha Method and apparatus for activating a hydrogen-absorbing alloy
JP2007521619A (en) * 2003-10-08 2007-08-02 ゼネラル・モーターズ・コーポレーション Metal hydride heating element

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6733741B2 (en) * 2000-09-05 2004-05-11 Toyota Jidosha Kabushiki Kaisha Method and apparatus for activating a hydrogen-absorbing alloy
JP2007521619A (en) * 2003-10-08 2007-08-02 ゼネラル・モーターズ・コーポレーション Metal hydride heating element

Similar Documents

Publication Publication Date Title
US7793651B2 (en) Heat storage apparatus
JP2019052845A (en) Heat exchange device control method, heat exchange device, water-cooled heat pump air conditioner, and water-cooled heat pump device
WO1993003314A1 (en) Solid/gas reaction cooling plant having a reactor equipped with cooling means
JP2005016766A (en) Heat accumulating device
JPH08233394A (en) Heating method and apparatus thereof
JPH076708B2 (en) Chemical heat storage system
JP3720160B2 (en) Low temperature liquefied gas vaporization method and equipment
JPS5926878B2 (en) latent heat storage
JP4035566B2 (en) Forced circulation air temperature type liquefied gas vaporizer
JP2856246B2 (en) Heat recovery / supply device
JP5083881B2 (en) Thermal storage device and thermal management method thereof
JP2006284031A (en) Heat storage device
JPH1073337A (en) Cooling and heating method and device
CN116018492A (en) Thermal energy storage and retrieval system and method thereof
JP3013481B2 (en) Cooling and heating equipment
JP4162948B2 (en) Warm-up jacket and fuel cell system
JP3464337B2 (en) Cold heat generator using hydrogen storage alloy and method of operating the same
KR20070089987A (en) Fuel cell desalination unit integrated with refrigerant accumulator
JPH02110263A (en) Heat-utilizing system utilizing hydrogen storage alloy and operation thereof
JP3365371B2 (en) Ice storage device
FR2730299A1 (en) DIPHASIC HEAT EXCHANGER WITH CONTROLLED TEMPERATURE
JP3418047B2 (en) Operating method of cold heat generator
JPH11148751A (en) Ice machine
JP2001173898A (en) Hydrogen supply device
JPH11294803A (en) Cooling and heating method and apparatus using heat pump