JPH08501505A - 印刷版 - Google Patents
印刷版Info
- Publication number
- JPH08501505A JPH08501505A JP6507029A JP50702993A JPH08501505A JP H08501505 A JPH08501505 A JP H08501505A JP 6507029 A JP6507029 A JP 6507029A JP 50702993 A JP50702993 A JP 50702993A JP H08501505 A JPH08501505 A JP H08501505A
- Authority
- JP
- Japan
- Prior art keywords
- support
- surface layer
- layer
- particle size
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007639 printing Methods 0.000 title claims abstract description 64
- 239000000463 material Substances 0.000 claims abstract description 106
- 238000000034 method Methods 0.000 claims abstract description 96
- 239000002245 particle Substances 0.000 claims abstract description 88
- 239000002344 surface layer Substances 0.000 claims abstract description 75
- 239000010410 layer Substances 0.000 claims abstract description 51
- 239000000758 substrate Substances 0.000 claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 claims abstract description 19
- 238000000151 deposition Methods 0.000 claims abstract description 14
- 238000000469 dry deposition Methods 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims description 28
- 238000000576 coating method Methods 0.000 claims description 28
- 229910052782 aluminium Inorganic materials 0.000 claims description 26
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 26
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 21
- 239000007921 spray Substances 0.000 claims description 20
- 239000007769 metal material Substances 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 238000005516 engineering process Methods 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 4
- 238000007750 plasma spraying Methods 0.000 claims description 4
- 238000003780 insertion Methods 0.000 claims description 3
- 230000037431 insertion Effects 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 abstract description 5
- 230000008569 process Effects 0.000 description 24
- 238000011282 treatment Methods 0.000 description 24
- 229940024548 aluminum oxide Drugs 0.000 description 20
- 239000002585 base Substances 0.000 description 19
- 239000000843 powder Substances 0.000 description 16
- 229910045601 alloy Inorganic materials 0.000 description 11
- 239000000956 alloy Substances 0.000 description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- 238000003384 imaging method Methods 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229910000838 Al alloy Inorganic materials 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 5
- 238000005530 etching Methods 0.000 description 5
- 238000005755 formation reaction Methods 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 238000005137 deposition process Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000003746 surface roughness Effects 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- -1 steel Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000011538 cleaning material Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 2
- 239000012954 diazonium Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-O diazynium Chemical compound [NH+]#N IJGRMHOSHXDMSA-UHFFFAOYSA-O 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000010891 electric arc Methods 0.000 description 2
- 238000002848 electrochemical method Methods 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 101100083746 Caenorhabditis elegans pmk-3 gene Proteins 0.000 description 1
- 241001481710 Cerambycidae Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000001828 Gelatine Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000007743 anodising Methods 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004439 roughness measurement Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/03—Chemical or electrical pretreatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/006—Printing plates or foils; Materials therefor made entirely of inorganic materials other than natural stone or metals, e.g. ceramics, carbide materials, ferroelectric materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
- B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
- B41N1/083—Printing plates or foils; Materials therefor metallic for lithographic printing made of aluminium or aluminium alloys or having such surface layers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Printing Plates And Materials Therefor (AREA)
- Manufacture Or Reproduction Of Printing Formes (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9219214.5 | 1992-09-10 | ||
| GB929219214A GB9219214D0 (en) | 1992-09-10 | 1992-09-10 | Lithographic substrate preparation |
| GB9308182A GB2277383A (en) | 1993-04-21 | 1993-04-21 | A light sensitive printing plate |
| GB9308182.6 | 1993-04-21 | ||
| PCT/GB1993/001910 WO1994005507A1 (en) | 1992-09-10 | 1993-09-09 | Printing plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08501505A true JPH08501505A (ja) | 1996-02-20 |
Family
ID=26301596
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6507029A Pending JPH08501505A (ja) | 1992-09-10 | 1993-09-09 | 印刷版 |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0659119B1 (es) |
| JP (1) | JPH08501505A (es) |
| AU (1) | AU4977693A (es) |
| BR (1) | BR9307032A (es) |
| DE (1) | DE69308861T2 (es) |
| DK (1) | DK0659119T3 (es) |
| ES (1) | ES2102209T3 (es) |
| WO (1) | WO1994005507A1 (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5881645A (en) * | 1992-09-10 | 1999-03-16 | Lenney; John Richard | Method of thermally spraying a lithographic substrate with a particulate material |
| WO1995007496A1 (en) * | 1993-09-09 | 1995-03-16 | Horsell Graphic Industries Ltd. | A light sensitive printing plate |
| EP0771367A1 (en) * | 1994-08-18 | 1997-05-07 | Horsell Graphic Industries Limited | Improvements in and relating to the manufacture of printing plates |
| US6779449B1 (en) | 1994-09-15 | 2004-08-24 | Man Roland Druckmaschinen Ag | Carrying sleeve for printing and transfer forms and a process for production of such a carrying sleeve |
| DE4432814A1 (de) * | 1994-09-15 | 1996-03-28 | Roland Man Druckmasch | Trägerhülse für Druck- und Übertragungsformen |
| DE19610015C2 (de) * | 1996-03-14 | 1999-12-02 | Hoechst Ag | Thermisches Auftragsverfahren für dünne keramische Schichten und Vorrichtung zum Auftragen |
| JPH11505292A (ja) * | 1995-03-17 | 1999-05-18 | ヘキスト・アクチェンゲゼルシャフト | セラミックの薄層を溶着させる熱溶着法および関連装置 |
| US5711991A (en) * | 1995-11-20 | 1998-01-27 | Aluminum Company Of America | Process for making lithographic sheet material having a thermoplastic adhesive layer |
| EP0862518B2 (en) * | 1995-11-24 | 2006-05-17 | Kodak Polychrome Graphics Company Ltd. | Hydrophilized support for planographic printing plates and its preparation |
| US5795647A (en) * | 1996-09-11 | 1998-08-18 | Aluminum Company Of America | Printing plate having improved wear resistance |
| GB9624224D0 (en) | 1996-11-21 | 1997-01-08 | Horsell Graphic Ind Ltd | Planographic printing |
| GB9702568D0 (en) * | 1997-02-07 | 1997-03-26 | Horsell Graphic Ind Ltd | Planographic printing |
| GB9710552D0 (en) | 1997-05-23 | 1997-07-16 | Horsell Graphic Ind Ltd | Planographic printing |
| US6357351B1 (en) | 1997-05-23 | 2002-03-19 | Kodak Polychrome Graphics Llc | Substrate for planographic printing |
| DE19839454A1 (de) | 1998-08-29 | 2000-03-02 | Agfa Gevaert Ag | Aufzeichnungsmaterial aus einem Träger und einer auf einer Oberfläche des Trägers aufgebrachten Keramikschicht |
| US6293197B1 (en) | 1999-08-17 | 2001-09-25 | Kodak Polychrome Graphics | Hydrophilized substrate for planographic printing |
| DE102004051262A1 (de) * | 2004-10-21 | 2006-04-27 | Man Roland Druckmaschinen Ag | Offsetdruckmaschine |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH126412A (de) * | 1927-05-26 | 1928-06-16 | Polygraphische Ges | Verfahren zum Körnen von Flachdruckplatten. |
| US2032770A (en) * | 1934-01-26 | 1936-03-03 | Multigraph Co | Planographic printing plate |
| US2032779A (en) * | 1934-01-26 | 1936-03-03 | Multigraph Co | Flexible composite planographic plate |
| CH208963A (de) * | 1938-01-11 | 1940-03-15 | Walther Georg | Verfahren zur Herstellung von Druckplatten für den Hoch-, Tief- und Flachdruck. |
| US3871881A (en) * | 1973-02-12 | 1975-03-18 | Minnesota Mining & Mfg | Coated aluminum substrates having a binder of aluminum hydroxyoxide |
| DE3046757C2 (de) * | 1980-12-12 | 1985-09-12 | W.C. Heraeus Gmbh, 6450 Hanau | Tiefdruckzylinder |
| DE3237775A1 (de) * | 1981-10-12 | 1983-04-28 | Daishin Kagaku Kogyo K.K., Niiza, Saitama | Material fuer eine plandruckplatte und verfahren zu dessen herstellung |
| US4596189A (en) * | 1984-03-01 | 1986-06-24 | Surface Science Corp. | Lithographic printing plate |
| US4526839A (en) * | 1984-03-01 | 1985-07-02 | Surface Science Corp. | Process for thermally spraying porous metal coatings on substrates |
-
1993
- 1993-09-09 WO PCT/GB1993/001910 patent/WO1994005507A1/en not_active Ceased
- 1993-09-09 BR BR9307032A patent/BR9307032A/pt not_active IP Right Cessation
- 1993-09-09 DE DE69308861T patent/DE69308861T2/de not_active Expired - Fee Related
- 1993-09-09 JP JP6507029A patent/JPH08501505A/ja active Pending
- 1993-09-09 DK DK94908815.7T patent/DK0659119T3/da active
- 1993-09-09 AU AU49776/93A patent/AU4977693A/en not_active Abandoned
- 1993-09-09 ES ES94908815T patent/ES2102209T3/es not_active Expired - Lifetime
- 1993-09-09 EP EP94908815A patent/EP0659119B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69308861T2 (de) | 1997-10-02 |
| BR9307032A (pt) | 1999-06-29 |
| EP0659119A1 (en) | 1995-06-28 |
| DK0659119T3 (da) | 1997-07-28 |
| EP0659119B1 (en) | 1997-03-12 |
| DE69308861D1 (de) | 1997-04-17 |
| ES2102209T3 (es) | 1997-07-16 |
| AU4977693A (en) | 1994-03-29 |
| WO1994005507A1 (en) | 1994-03-17 |
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