JPH08506328A - 美容用洗浄剤中への高濃度電解質の使用 - Google Patents
美容用洗浄剤中への高濃度電解質の使用Info
- Publication number
- JPH08506328A JPH08506328A JP6517509A JP51750994A JPH08506328A JP H08506328 A JPH08506328 A JP H08506328A JP 6517509 A JP6517509 A JP 6517509A JP 51750994 A JP51750994 A JP 51750994A JP H08506328 A JPH08506328 A JP H08506328A
- Authority
- JP
- Japan
- Prior art keywords
- water
- cleaning
- cleaning composition
- weight
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003792 electrolyte Substances 0.000 title claims abstract description 34
- 239000002537 cosmetic Substances 0.000 title claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 87
- 238000004140 cleaning Methods 0.000 claims abstract description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000012141 concentrate Substances 0.000 claims abstract description 17
- 239000000126 substance Substances 0.000 claims abstract description 11
- 208000001840 Dandruff Diseases 0.000 claims abstract description 5
- 239000013543 active substance Substances 0.000 claims abstract description 5
- 201000004624 Dermatitis Diseases 0.000 claims abstract description 4
- 230000002265 prevention Effects 0.000 claims abstract description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 42
- 239000011780 sodium chloride Substances 0.000 claims description 21
- 238000009472 formulation Methods 0.000 claims description 11
- -1 phosphoric oxide Chemical compound 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 239000002280 amphoteric surfactant Substances 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 150000001449 anionic compounds Chemical class 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 3
- 230000003796 beauty Effects 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 150000002891 organic anions Chemical class 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- 150000003751 zinc Chemical class 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000003568 Sodium, potassium and calcium salts of fatty acids Substances 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 2
- 229940043230 sarcosine Drugs 0.000 claims description 2
- 235000013875 sodium salts of fatty acid Nutrition 0.000 claims description 2
- 229940117986 sulfobetaine Drugs 0.000 claims description 2
- 230000035515 penetration Effects 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 description 15
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000008103 glucose Substances 0.000 description 4
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 3
- 210000004400 mucous membrane Anatomy 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- PWYQYDKNFZJVQN-QKPAOTATSA-N (2r,3r,4s,5r)-1,2,3,4,5-pentahydroxyhexadecan-6-one Chemical compound CCCCCCCCCCC(=O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO PWYQYDKNFZJVQN-QKPAOTATSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 238000010612 desalination reaction Methods 0.000 description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000003851 biochemical process Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- GFYXELHUDBJJEV-UHFFFAOYSA-N dioxo-lambda5-phosphane Chemical class O=P=O GFYXELHUDBJJEV-UHFFFAOYSA-N 0.000 description 1
- 229940079886 disodium lauryl sulfosuccinate Drugs 0.000 description 1
- KHIQYZGEUSTKSB-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O.CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O KHIQYZGEUSTKSB-UHFFFAOYSA-L 0.000 description 1
- OPGYRRGJRBEUFK-UHFFFAOYSA-L disodium;diacetate Chemical compound [Na+].[Na+].CC([O-])=O.CC([O-])=O OPGYRRGJRBEUFK-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 229910001412 inorganic anion Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical class [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19934304066 DE4304066C2 (de) | 1993-02-11 | 1993-02-11 | Verwendung von hohen Elektrolytkonzentrationen in kosmetischen Reinigungsmitteln |
| DE4304066.7 | 1993-02-11 | ||
| PCT/DE1994/000068 WO1994017782A2 (de) | 1993-02-11 | 1994-01-27 | Verwendung von hohen elektrolytkonzentrationen in kosmetischen reinigungsmitteln |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08506328A true JPH08506328A (ja) | 1996-07-09 |
Family
ID=6480205
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6517509A Pending JPH08506328A (ja) | 1993-02-11 | 1994-01-27 | 美容用洗浄剤中への高濃度電解質の使用 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0683663A1 (de) |
| JP (1) | JPH08506328A (de) |
| DE (1) | DE4304066C2 (de) |
| WO (1) | WO1994017782A2 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19631220C2 (de) * | 1996-08-02 | 2000-03-23 | Beiersdorf Ag | Schaumförmige oder schäumbare Zubereitungen mit einem Gehalt an grenzflächenaktiven Substanzen und Elektrolyten |
| US6020375A (en) * | 1997-06-13 | 2000-02-01 | Senju Pharmaceutical Co., Ltd. | Bactericidal composition |
| DE19838034A1 (de) * | 1998-08-21 | 2000-02-24 | Beiersdorf Ag | Verwendung von waschaktiven Substanzen, gewählt aus der Gruppe der N-Acylaminosäuren und der Salze von N-Acylaminosäuren zur Steigerung der Verträglichkeit kosmetischer oder dermatologischer Reinigungszubereitungen |
| DE19960767A1 (de) | 1999-12-16 | 2001-06-21 | Beiersdorf Ag | Verfahren zur Herstellung besonders hautverträglicher kosmetischer oder dermatologischer Reinigungszubereitungen |
| DE19960766A1 (de) * | 1999-12-16 | 2001-06-21 | Beiersdorf Ag | Verfahren zur Herstellung besonders hautverträglicher kosmetischer oder dermatologischer Reinigungszubereitungen |
| DE10123771B4 (de) | 2001-05-16 | 2019-01-10 | Beiersdorf Ag | Verwendung von Elektrolyten zur Stärkung der Barrierefunktion der Haut |
| US20060292105A1 (en) * | 2005-06-28 | 2006-12-28 | Lever O W Jr | Topical preservative compositions |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2024051C3 (de) * | 1970-05-16 | 1986-05-07 | Henkel KGaA, 4000 Düsseldorf | Verwendung der Veresterungsprodukte von Glycerin-Äthylenoxid-Addukten mit Fettsäuren als Rückfettungsmittel in kosmetischen Zubereitungen |
| US3996350A (en) * | 1975-01-02 | 1976-12-07 | Geraldine Fay Weisz | Methods and compositions for alleviating fungus infections of the skin |
| US4296104A (en) * | 1979-08-30 | 1981-10-20 | Herschler R J | Therapeutic dimethyl sulfoxide composition and methods of use |
| DE3017814A1 (de) * | 1980-05-09 | 1981-11-19 | Henkel Kgaa | Neuartige tenside, deren herstellung und verwendung in kosmetischen reinigungsmitteln sowie diese enthaltende hautfreundliche, kosmetische reinigungsmittel |
| US4780249A (en) * | 1984-12-20 | 1988-10-25 | Warner-Lambert Company | Irritation inhibiting detergent formulations |
| DE3528843A1 (de) * | 1985-08-10 | 1987-02-12 | Henkel Kgaa | Selbstdekontaminierende reinigungsmittel |
| FR2590273A1 (fr) * | 1985-09-20 | 1987-05-22 | Brevier Christiane | Produit nouveau resultant de l'association d'un micro-organisme marin, avec de l'eau de mer applique en produits esthetiques en dermatologie, en cosmetologie, en pharmacie |
| US4931274A (en) * | 1986-02-27 | 1990-06-05 | Physiological Research Associates | Composition for the effective treatment of scalp diseases that delivers magnesium adsorbed in alumina silicate clays to affected sites |
| DE3622438A1 (de) * | 1986-07-04 | 1988-01-07 | Henkel Kgaa | Kosmetischer waschrohstoff |
| DE3817415A1 (de) * | 1988-05-21 | 1989-11-30 | Henkel Kgaa | Verdickte waessrige tensidloesungen |
| DE3902374A1 (de) * | 1989-01-27 | 1990-08-02 | Solvay Werke Gmbh | Wasch- reinigungs- und/oder koerperreinigungsmittel |
| JPH0699708B2 (ja) * | 1989-03-20 | 1994-12-07 | 花王株式会社 | 中性液体洗浄剤組成物 |
| DE3910652C2 (de) * | 1989-04-01 | 1997-12-18 | Benckiser Gmbh Joh A | Tensidmischung für den Einsatz in schäumenden Körperreinigungsmitteln |
| DE3928773A1 (de) * | 1989-08-31 | 1991-03-07 | Benckiser Gmbh Joh A | Duschgel |
| DE3930725A1 (de) * | 1989-09-14 | 1991-03-21 | Benckiser Gmbh Joh A | Extra-milde duschgel- und haarshampoo-formulierung mit niedriger tensidkonzentration |
| JP2681527B2 (ja) * | 1990-02-15 | 1997-11-26 | ジャパンファインケミカル株式会社 | 細胞活性促進外用剤 |
| DK0442519T4 (da) * | 1990-02-16 | 1998-08-31 | Benckiser Nv | Selvkonserverende flydende tensidsystemer |
| DE4009616A1 (de) * | 1990-03-26 | 1991-10-02 | Henkel Kgaa | Fluessige koerperreinigungsmittel |
| DE4129124A1 (de) * | 1991-09-02 | 1993-03-04 | Henkel Kgaa | Milde reinigungsmittel |
| GB9204175D0 (en) * | 1992-02-27 | 1992-04-08 | Unilever Plc | Cleansing composition |
| EP0647262A4 (de) * | 1992-06-16 | 1998-04-29 | Henkel Corp | Tensidkonzentratzusammensetzungen mit eingestellter viskosität. |
-
1993
- 1993-02-11 DE DE19934304066 patent/DE4304066C2/de not_active Expired - Fee Related
-
1994
- 1994-01-27 WO PCT/DE1994/000068 patent/WO1994017782A2/de not_active Ceased
- 1994-01-27 EP EP94904971A patent/EP0683663A1/de not_active Withdrawn
- 1994-01-27 JP JP6517509A patent/JPH08506328A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE4304066A1 (de) | 1994-08-18 |
| DE4304066C2 (de) | 1995-01-26 |
| EP0683663A1 (de) | 1995-11-29 |
| WO1994017782A2 (de) | 1994-08-18 |
| WO1994017782A3 (de) | 1994-09-29 |
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