JPH0860331A - Anticorrosion treatment method for hydraulic equipment components - Google Patents
Anticorrosion treatment method for hydraulic equipment componentsInfo
- Publication number
- JPH0860331A JPH0860331A JP6192346A JP19234694A JPH0860331A JP H0860331 A JPH0860331 A JP H0860331A JP 6192346 A JP6192346 A JP 6192346A JP 19234694 A JP19234694 A JP 19234694A JP H0860331 A JPH0860331 A JP H0860331A
- Authority
- JP
- Japan
- Prior art keywords
- coat layer
- bond coat
- layer
- hydraulic equipment
- sprayed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Coating By Spraying Or Casting (AREA)
Abstract
(57)【要約】
【目的】 水力機器部材の溶射境界部に露出したボンド
コ―ト層を被膜によって覆い、優れた耐摩耗性および耐
食性を付与すること。
【構成】 ガイドベ―ン1の処理対象部に低温溶射層3
を構成するボンドコ―ト層3aをNi−Alにより、ミ
ドルコ―ト層3bを13Cr鋼により、トップコ―ト層3
cをステンレス鋼によりそれぞれ形成する。さらに、溶
射境界部に露出したボンドコ―ト層3aを高速ガス炎溶
射、例えばダイヤモンドジェット溶射法を用いてCrC
サ―メット材を溶射し、高速ガス炎溶射被覆層4を形成
する。
(57) [Abstract] [Purpose] To provide excellent wear resistance and corrosion resistance by covering the bond coat layer exposed at the thermal spray boundary of hydraulic equipment components with a film. [Structure] The low temperature sprayed layer 3 is formed on the processing target portion of the guide vane 1.
The bond coat layer 3a and the middle coat layer 3b are made of Ni-Al and 13Cr steel, respectively.
c are each made of stainless steel. Further, the bond coat layer 3a exposed at the thermal spray boundary is subjected to high-speed gas flame spraying, for example, diamond jet spraying to form CrC.
The cermet material is sprayed to form a high-speed gas flame sprayed coating layer 4.
Description
【0001】[0001]
【産業上の利用分野】本発明は水力機器部材の防食処理
方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for anticorrosion treatment of hydraulic equipment members.
【0002】[0002]
【従来の技術】従来、水力機器に使用される部材は使用
される水によって広範囲にわたり腐食を受けることがあ
る。この防食対策として熱による変形の少ない低温ガス
溶射によって耐食性に優れたステンレス鋼をトップコ―
トとして厚い被膜を形成している。しかしながら、溶射
境界部には施工上溶射被膜と母材の密着力を向上させる
ためにボンドコ―トと呼ばれる溶射を同時に行ってい
る。このボンドコ―ト層は溶射境界に露出する部分があ
り、ボンドコ―ト材は腐食に弱く、ボンドコ―ト層が選
択的に腐食され、剥離が生じる。この対策として耐水用
塗料の塗装もしくはエポキシ樹脂材の塗布と併用した防
食処理方法が施されている。2. Description of the Related Art Conventionally, members used in hydraulic power equipment may be extensively corroded by the water used. As a countermeasure against this corrosion, stainless steel, which has excellent corrosion resistance by low temperature gas spraying with little deformation due to heat, is used as the top coat.
A thick film is formed as a sheet. However, in order to improve the adhesion between the thermal spray coating and the base material, the thermal spray boundary is subjected to thermal spraying called a bond coat at the same time. This bond coat layer has a portion exposed to the thermal spray boundary, and the bond coat material is vulnerable to corrosion, and the bond coat layer is selectively corroded and peeling occurs. As a countermeasure against this, an anticorrosion treatment method is used in combination with the coating of water resistant paint or the coating of epoxy resin material.
【0003】一方、高速ガス炎溶射では溶射の機構上13
80m/秒の音速で基材に溶射粒子が衝突するため低温ガ
ス溶射に比べ、非常に緻密且つ高密着力の溶射被膜が得
られることが知られているが、緻密な溶射被膜であるた
め、膜厚は最高 0.3mm程度が限界であり厚膜の溶射施工
は不可能である。On the other hand, in high-speed gas flame spraying, 13
It is known that the sprayed particles collide with the base material at a sound velocity of 80 m / sec, so that a sprayed film with extremely high density and high adhesion can be obtained as compared with low temperature gas spraying. The maximum thickness is about 0.3 mm, and thermal spraying of thick film is impossible.
【0004】[0004]
【発明が解決しようとする課題】従来の防食方法は耐食
性に優れているが、土砂による摩耗やキャビテ―ション
によって塗装されたエポキシ樹脂材が早期に摩耗したり
あるいは剥離してしまう。このように塗膜が早期に剥離
するため溶射境界部のボンドコ―ト層が露出してしま
い、長期にわたって効果を持続させることができない。Although the conventional anticorrosion method is excellent in corrosion resistance, the coated epoxy resin material is prematurely worn or peeled off due to abrasion due to earth and sand or cavitation. Since the coating film peels off early in this way, the bond coat layer at the thermal spray boundary is exposed, and the effect cannot be maintained for a long time.
【0005】本発明の目的は溶射境界部に露出したボン
ドコ―ト層を被膜によって覆い、優れた耐摩耗性および
耐食性を付与することのできる水力機器防食部材の処理
方法を提供することにある。An object of the present invention is to provide a method for treating a corrosion protection member for hydraulic equipment, which is capable of covering the bond coat layer exposed at the thermal spray boundary with a coating and imparting excellent wear resistance and corrosion resistance.
【0006】[0006]
【課題を解決するための手段】上記目的を達成するため
に、本発明における防食処理方法は、部材の表層に低温
ガス溶射を施し、その溶射層の母材境界部表面を薄膜の
高速ガス炎溶射被膜によって覆うことを特徴とするもの
である。In order to achieve the above object, a method of anticorrosion treatment according to the present invention is that a surface of a member is subjected to low temperature gas spraying, and a surface of a base material boundary portion of the sprayed layer is a thin film high-speed gas flame. It is characterized by being covered with a thermal spray coating.
【0007】[0007]
【作用】ボンドコ―ト材の腐食による剥離を防止するた
めには2通りの方法がある。一つは腐食の原因である水
との接触を断つこと、他の方法は十分な耐食性を付与さ
せることである。本発明は前者の水との接触を断つこと
に主眼を置いたもので、ボンドコ―ト層の露出した溶射
境界部を緻密な溶射被膜によって覆う。すなわち、ボン
ドコ―ト層なしでも高密着力の得られる高速ガス炎溶射
を用いて被覆する。こうして水との接触を完全に断って
腐食を防ぐ。一方、高速ガス炎溶射材を低温ガス溶射で
は施工できない耐摩耗性に優れた材料、例えばセラミッ
クスと金属の混合粉末によるサ―メット材を使用するこ
とで被覆層の耐摩耗性を著しく向上させることができ
る。また、これらの施工は現地における施工も容易であ
り、補修を短期間に完了させることができる。Operation: There are two methods for preventing the peeling of the bond coat material due to corrosion. One is to cut off the contact with water, which is the cause of corrosion, and the other is to provide sufficient corrosion resistance. The present invention focuses on the former case of breaking the contact with water, and the exposed thermal spray boundary portion of the bond coat layer is covered with a dense thermal spray coating. That is, coating is performed using high-speed gas flame spraying, which provides high adhesion even without a bond coat layer. This completely prevents contact with water and prevents corrosion. On the other hand, it is possible to remarkably improve the wear resistance of the coating layer by using a high wear resistance material that cannot be applied by high temperature gas flame spraying with low temperature gas spraying, such as a cermet material made of a mixed powder of ceramics and metal. You can Further, these constructions are easy to carry out locally, and repairs can be completed in a short period of time.
【0008】[0008]
【実施例】以下、本発明の一実施例を図1ないし図2を
参照して説明する。図2は水力機器部材であるガイドベ
―ン1を示している。ガイドベ―ン1は水に接する箇所
が局部的に腐食を受けることから、防食処理が施され
る。この処理部2に、図1に示すような、低温溶射層3
を構成するボンドコ―ト層3aをNi−Alにより、ミ
ドルコ―ト層3bを13Cr鋼により、トップコ―ト層3
cをステンレス鋼によりそれぞれ形成する。この低温ガ
ス溶射層3はすべての層で膜厚5mmに形成している。溶
射境界部に露出したボンドコ―ト層3aを高速ガス炎溶
射、例えばダイヤモンドジェット溶射法を用いて溶射境
界部から溶射層側に各20mm溶射し、高速ガス炎溶射被覆
層4を形成する。この材料は耐摩耗性に優れたCrCサ
―メット材を用いる。さらに、この高速ガス炎溶射被覆
層4の上に樹脂を塗布して完成させる。 (実験例1)従来法および本発明法により製作した試験
片のブラストエロ―ジョン試験を行った結果、従来法お
よび本発明法共に塗膜は3秒後に摩耗してしまったが 1
80秒後では従来法の試験片は基材および低温ガス溶射層
の摩耗が顕著に認められるのに対し、本発明法の試験片
では高速ガス炎溶射による緻密な被膜により摩耗が認め
られず、優れた耐摩耗性を有することが確認された。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIGS. FIG. 2 shows a guide vane 1 which is a hydraulic equipment member. The guide vane 1 is subjected to anticorrosion treatment because the part in contact with water is locally corroded. The low temperature sprayed layer 3 as shown in FIG.
The bond coat layer 3a and the middle coat layer 3b are made of Ni-Al and 13Cr steel, respectively.
c are each made of stainless steel. The low temperature gas sprayed layer 3 is formed to have a film thickness of 5 mm in all layers. The bond coat layer 3a exposed at the thermal spray boundary portion is sprayed by high-speed gas flame spraying, for example, 20 mm from the thermal spray boundary portion to the thermal spray layer side by using, for example, a diamond jet spraying method, to form the high-speed gas flame spray coating layer 4. As this material, a CrC cermet material having excellent wear resistance is used. Further, a resin is applied on the high-speed gas flame spray coating layer 4 to complete the coating. (Experimental Example 1) As a result of the blast erosion test of the test pieces manufactured by the conventional method and the method of the present invention, the coating film was worn after 3 seconds in both the conventional method and the method of the present invention.
After 80 seconds, the test piece of the conventional method is remarkably worn on the base material and the low temperature gas sprayed layer, whereas the test piece of the method of the present invention is not worn due to the dense coating by high-speed gas flame spraying, It was confirmed to have excellent wear resistance.
【0009】また、ブラストエロ―ジョン試験により塗
膜の摩耗した従来法および本発明法の試験片の塩水噴霧
試験を行った結果、従来法では72hr以内で溶射境界であ
るボンドコ―ト層近傍に発錆が認められたのに対し、本
発明法によって製作した試験片は144hr 以上においても
発錆は認められず、2倍以上の耐腐食性を有することが
確認された。このように本発明によれば、従来法に比較
し、水力機器部材の寿命を著しく向上することができ
る。Further, as a result of performing a salt spray test of the test pieces of the conventional method and the method of the present invention in which the coating film is abraded by the blast erosion test, it was found that the conventional method was within 72 hours in the vicinity of the bond coat layer which was the thermal spray boundary. While rusting was observed, the test piece manufactured by the method of the present invention did not show rusting even after 144 hours, and it was confirmed that the test piece had a corrosion resistance more than double. As described above, according to the present invention, compared with the conventional method, the life of the hydraulic equipment member can be remarkably improved.
【0010】[0010]
【発明の効果】以上述べたように本発明においては溶射
層の母材境界部表面を薄膜の高速ガス炎溶射被膜によっ
て覆うので、腐食しやすいボンドコ―ト層が水に触れ
ず、低温ガス溶射層の剥離を防止することができる。し
たがって、本発明によれば、水力機器部材に優れた耐摩
耗耐食性を与えることができ、水力機器の寿命を大幅に
延ばすことが可能である。As described above, in the present invention, since the surface of the base material boundary portion of the sprayed layer is covered with the thin film of high-speed gas flame spray coating, the corrosive bond coat layer does not come into contact with water, and low temperature gas spraying is performed. It is possible to prevent peeling of layers. Therefore, according to the present invention, it is possible to impart excellent wear resistance and corrosion resistance to the hydraulic equipment member, and it is possible to significantly extend the life of the hydraulic equipment.
【図1】本発明による防食処理方法を適用したガイドベ
―ンの断面図。FIG. 1 is a sectional view of a guide vane to which the anticorrosion treatment method according to the present invention is applied.
【図2】本発明によるガイドベ―ンの斜視図。FIG. 2 is a perspective view of a guide vane according to the present invention.
【符号の説明】 1…ガイドベ―ン 2…処理部 3
…低温ガス溶射層 3a…ボンドコ―ト層 3b…ミドルコ―ト層 3
c…トップコ―ト層 4…高速ガス炎溶射被覆層 5…塗膜[Explanation of Codes] 1 ... Guide vane 2 ... Processing unit 3
... Low temperature gas sprayed layer 3a ... Bond coat layer 3b ... Middle coat layer 3
c ... Top coat layer 4 ... High-speed gas flame sprayed coating layer 5 ... Coating film
Claims (1)
その部材の表層に低温ガス溶射を施し、その溶射層の母
材境界表面を薄膜の高速ガス炎溶射被膜によって覆うこ
とを特徴とする水力機器部材の防食処理方法。1. To prevent pitting corrosion of hydraulic equipment members,
A method for anticorrosion treatment of a hydraulic equipment member, characterized in that the surface layer of the member is subjected to low temperature gas spraying, and the base material boundary surface of the sprayed layer is covered with a thin high-speed gas flame spray coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6192346A JPH0860331A (en) | 1994-08-16 | 1994-08-16 | Anticorrosion treatment method for hydraulic equipment components |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6192346A JPH0860331A (en) | 1994-08-16 | 1994-08-16 | Anticorrosion treatment method for hydraulic equipment components |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0860331A true JPH0860331A (en) | 1996-03-05 |
Family
ID=16289754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6192346A Pending JPH0860331A (en) | 1994-08-16 | 1994-08-16 | Anticorrosion treatment method for hydraulic equipment components |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0860331A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007182776A (en) * | 2006-01-05 | 2007-07-19 | Hitachi Ltd | Turbine blade repair method and turbine blade |
-
1994
- 1994-08-16 JP JP6192346A patent/JPH0860331A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007182776A (en) * | 2006-01-05 | 2007-07-19 | Hitachi Ltd | Turbine blade repair method and turbine blade |
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