JPH088429B2 - Radio wave absorption method - Google Patents
Radio wave absorption methodInfo
- Publication number
- JPH088429B2 JPH088429B2 JP3153984A JP15398491A JPH088429B2 JP H088429 B2 JPH088429 B2 JP H088429B2 JP 3153984 A JP3153984 A JP 3153984A JP 15398491 A JP15398491 A JP 15398491A JP H088429 B2 JPH088429 B2 JP H088429B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon fiber
- radio wave
- carbon fibers
- carbon
- orientation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000010521 absorption reaction Methods 0.000 title claims description 12
- 238000000034 method Methods 0.000 title claims description 10
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 130
- 239000004917 carbon fiber Substances 0.000 claims description 130
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 84
- 239000000835 fiber Substances 0.000 claims description 30
- 239000006096 absorbing agent Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 26
- 230000005684 electric field Effects 0.000 claims description 20
- 239000004570 mortar (masonry) Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 239000011159 matrix material Substances 0.000 claims description 6
- 238000012360 testing method Methods 0.000 description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000013598 vector Substances 0.000 description 10
- 238000005259 measurement Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000010586 diagram Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000011398 Portland cement Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 235000010981 methylcellulose Nutrition 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011300 coal pitch Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
Landscapes
- Conductive Materials (AREA)
- Building Environments (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、炭素繊維を含有して形
成した炭素繊維含有組成物である電波吸収体を用いて、
効率良くTV電波や無線電波などを吸収する方法に関す
る。FIELD OF THE INVENTION The present invention uses a radio wave absorber which is a carbon fiber-containing composition formed by containing carbon fibers.
The present invention relates to a method of efficiently absorbing TV radio waves and radio waves.
【0002】[0002]
【従来の技術】高層ビル、送電線の鉄塔、橋梁、新幹
線、高速道路、ゴルフ練習場などの各種の建造物とか航
空機などが、良質なTV電波や無線電波などを遮蔽、反
射して広い地域でゴースト障害を発生させていることが
知られている。2. Description of the Related Art Various structures such as high-rise buildings, transmission line towers, bridges, Shinkansen, highways, golf driving ranges, aircraft, etc. shield and reflect high-quality TV and radio waves, and spread over large areas. Are known to cause ghost disorders.
【0003】従来、このようなゴースト障害を防止する
ために、例えば、特開昭58−108603号公報や特
開昭58−108602号公報に開示されているよう
に、普通コンクリートやモルタルや軽量コンクリートと
いったコンクリートに炭素繊維(カーボンファイバ)を
含有して形成した電波吸収体を用いることが知られてい
る。Conventionally, in order to prevent such ghost damage, for example, as disclosed in Japanese Patent Laid-Open Nos. 58-108603 and 58-108602, ordinary concrete, mortar and lightweight concrete are disclosed. It is known to use a radio wave absorber formed by containing carbon fiber in such concrete.
【0004】[0004]
【発明が解決しようとする課題】しかしながら、従来の
電波吸収体では、電波の吸収効率を向上させるには、炭
素繊維の含有率を多くするとか、電波吸収体を厚くする
といったことが必要であった。However, in the conventional electromagnetic wave absorber, in order to improve the electromagnetic wave absorption efficiency, it is necessary to increase the carbon fiber content or to thicken the electromagnetic wave absorber. It was
【0005】誘電体の複素誘電率εは次式で表される。 ε=ε’−jε” 上式において、実数部ε’は通常の誘電率を、虚数部
ε”は損失率をそれぞれ示している。The complex permittivity ε of the dielectric is expressed by the following equation. [epsilon] = [epsilon] '-j [epsilon] "In the above equation, the real number part [epsilon]' indicates the normal permittivity, and the imaginary part [epsilon]" indicates the loss rate.
【0006】そして、この実数部ε’を横軸にとるとと
もに、虚数部ε”を縦軸にとり、試料の厚さdと、その
試料に入射する電波の波長λ0との関係値D(=d/λ
0)における無反射条件の特性曲線を求めたときに、図
3のグラフに示す結果を得られることが知られている。
図3中の数値はDの値である。The real part ε'is plotted on the abscissa and the imaginary part ε "is plotted on the ordinate, and the relational value D (= D) between the thickness d of the sample and the wavelength λ 0 of the radio wave incident on the sample. d / λ
It is known that the result shown in the graph of FIG. 3 can be obtained when the characteristic curve under the non-reflection condition in ( 0 ) is obtained.
Numerical values in FIG. 3 are values of D.
【0007】例えば、2chのテレビ電波(割当周波
数:96〜102MHz、映像搬送周波数97.25M
Hz、音声搬送周波数101.75MHz)を厚みが1
0cmの壁面で無反射で吸収する場合を考察すれば、長
波長となる映像搬送用の電波の波長λ0は、 λ0=(3×1010)÷(97.25×106) ≒308.48cm となり、関係値Dは、 D=10÷308.48 ≒0.032 となり、この関係値Dを満たすときの実数部ε’および
虚数部ε”それぞれの値は、 ε’≒61 ε”≒10 となる。[0007] For example, 2 ch television radio waves (assigned frequency: 96 to 102 MHz, video carrier frequency 97.25 M
Hz, audio carrier frequency 101.75 MHz) with a thickness of 1
Considering the case of non-reflective absorption on a 0 cm wall surface, the wavelength λ 0 of the radio wave for video transmission, which is a long wavelength, is λ 0 = (3 × 10 10 ) ÷ (97.25 × 10 6 ) ≈308 .48 cm, the relation value D becomes D = 10 / 308.48 ≈0.032, and the values of the real part ε ′ and the imaginary part ε ″ when this relation value D is satisfied are ε′≈61 ε ″. ≈10.
【0008】また、試料の厚みを5cmにした場合で見
てみれば、 D≒0.016 となり、実数部ε’をより大きな値にする必要があるこ
とがわかる。Further, when the thickness of the sample is set to 5 cm, D≈0.016, which means that the real part ε'needs to be larger.
【0009】ところが、従来の炭素繊維を含有した電波
吸収体では、このように大きな値の実数部ε’を得るこ
とが難しく、そのため電波の十分な吸収能力がないとい
う欠点があった。However, the conventional radio wave absorber containing carbon fibers has a drawback that it is difficult to obtain such a large real part ε ', and therefore the radio wave absorber does not have a sufficient radio wave absorption capability.
【0010】そこで、特開昭58−188193号公報
に開示されるように、フェライト、高分子樹脂及びファ
イバーから吸収体を構成するとともに、各吸収体それぞ
れにおいて、ファイバーを一定方向に配列し、そして、
各層のファイバー配向方向が相互に異なるように吸収体
を積層させ、電波の方向に対して、一方の吸収体が有効
に働かなくても、他方の吸収体が有効に働き、電波吸収
体の貼り付け方向のいかんにかかわらず、全体として、
均一な電波吸収特性が得られるようにした電波吸収体が
あったが、吸収体を積層させるがために、厚みが大きく
なってしまう欠点があった。 Therefore, Japanese Patent Laid-Open No. 58-188193
As disclosed in
The absorber is composed of aver and each absorber is
In which the fibers are aligned in a certain direction, and
Absorber so that the fiber orientation direction of each layer is different from each other
Is laminated, and one absorber is effective in the direction of the radio wave
Even if it does not work, the other absorber works effectively
Regardless of the attachment direction of the body, as a whole,
A radio wave absorber designed to have uniform radio wave absorption characteristics
However, since the absorber is laminated, the thickness is large.
There was a drawback that became.
【0011】本発明の電波吸収方法は、このような事情
に鑑みてなされたものであって、その厚みが薄く、しか
も、炭素繊維の含有率が少ない炭素繊維含有組成物を用
いても電波を十分吸収できるようにすることを目的とす
る。The radio wave absorption method of the present invention has been made in view of such circumstances, and the radio wave is absorbed even when a carbon fiber-containing composition having a small thickness and a low carbon fiber content is used. The purpose is to be able to absorb enough.
【0012】[0012]
【課題を解決するための手段】本発明の電波吸収方法
は、上述のような目的を達成するために、吸収しようと
する電波を炭素繊維含有組成物の任意の方向に照射した
ときの前記炭素繊維含有組成物の複素誘電率の実数部を
ε’、虚数部をε”とし、それらの最大値および最小値
を、ε max ’,ε min ’、ε max ”,ε min ”
とし、炭素繊維の配向度Aをε max ’−ε min ’、
配向度Bをε max ”−ε min ”で定義する場合に、
炭素繊維の配向度Aが25以上、および/または、配向
度Bが5以上となるように炭素繊維を特定方向に配向し
て含有した炭素繊維含有組成物を用い、含有炭素繊維の
配向方向を吸収しようとする電波の電界方向と一致させ
るように前記炭素繊維含有組成物を配置し、前記炭素繊
維含有組成物により電波を吸収することを特徴としてい
る。In order to achieve the above-mentioned object, the electromagnetic wave absorption method of the present invention attempts to absorb the electromagnetic waves.
Irradiating radio waves in any direction of the carbon fiber-containing composition
When the real part of the complex dielectric constant of the carbon fiber-containing composition is
Let ε ', the imaginary part be ε ″, and their maximum and minimum values
Where ε max ′, ε min ′, ε max ″, ε min ″
And the degree of orientation A of the carbon fiber is ε max '− ε min ',
When the orientation degree B is defined by ε max ″ −ε min ″,
Orientation A of carbon fiber is 25 or more and / or orientation
Orient the carbon fiber in a specific direction so that the degree B is 5 or more.
Using the carbon fiber-containing composition contained as
Align the orientation direction with the electric field direction of the radio wave to be absorbed.
The carbon fiber-containing composition is arranged so that the carbon fiber
It is characterized by absorbing radio waves by a fiber-containing composition .
【0013】含有炭素繊維の配向方向を吸収しようとす
る電波の電界方向と一致させるとは、炭素繊維の配向方
向を完全に電界方向に一致させて配置することは当然と
して、吸収しようとする電波を炭素繊維含有組成物の任
意の方向に照射したときの前記炭素繊維含有組成物の複
素誘電率の実数部をε’、虚数部をε”とし、それらの
最大値および最小値を、εmax’,εmin’、ε
max”,εmin”としたときに、 ε’≧εmin’+(εmax’−εmin’)×0.5 および/または、 ε”≧εmin”+(εmax”−εmin”)×0.5 になる範囲で配置することを含む。 配向度をA=εmax’−εmin’、B=εmax”
−εmin”で定義した。 Attempts to absorb the orientation direction of the contained carbon fibers
That radio waves Rutowa to match the electric field direction, be arranged to match the full electric field direction orientation direction <br/> direction of the carbon fibers is of course a, the radio wave to be absorbed in the carbon fiber-containing composition Let ε ′ be the real part and ε ″ be the real part and the imaginary part of the complex permittivity of the carbon fiber-containing composition when irradiated in an arbitrary direction, and the maximum and minimum values thereof are ε max ′, ε min ′, ε
max ″, ε min ″, ε ′ ≧ ε min ′ + (ε max ′ −ε min ′) × 0.5 and / or ε ″ ≧ ε min ″ + (ε max ″ −ε min ″ ) × 0.5. Degree of orientation is A = ε max '−ε min ', B = ε max ″
−ε min ”.
【0014】詳述すれば、図4の配向度の説明に供する
側面図に示すように、炭素繊維含有組成物の試験体を任
意の平面で切断し、その切断面において、中心Oを通っ
て直交する2本の軸をX−X’、Y−Y’とするとき、
X−X’を基準線として中心Oを通るカット線P−P’
との交角をθとし、その交角θを0°〜180°の範囲
で変化させた場合に最大となる複素誘電率の実数部ε’
および虚数部ε”それぞれをεmax’,εmax”、
最小となる複素誘電率の実数部ε’および虚数部ε”そ
れぞれをεmin’,εmin”として、(εmax’
−εmin’)を配向度A、(εmax”−
εmin”)を配向度Bとする(ε’およびε”それぞ
れの測定は、カット線P−P’に平行に電界をかけて測
定する)。More specifically, as shown in the side view for explaining the degree of orientation of FIG. 4, a test body of the carbon fiber-containing composition is cut along an arbitrary plane, and the cut surface passes through the center O. When two axes orthogonal to each other are XX ′ and YY ′,
Cut line P-P 'passing through the center O with XX' as a reference line
And the angle of intersection is θ, and the real part ε ′ of the complex permittivity that becomes maximum when the angle of intersection θ is changed in the range of 0 ° to 180 °.
And imaginary part ε ″ are respectively defined as ε max ', ε max ″,
The real part of the smallest complex dielectric constant epsilon 'and imaginary part epsilon "respectively ε min', ε min" as, (ε max '
−ε min ') is the orientation degree A, (ε max ″ −
ε min ″) is the orientation degree B (measurement of ε ′ and ε ″ is performed by applying an electric field parallel to the cut line PP ′).
【0015】炭素繊維が全くランダムに配向していると
きは、εmax’=εmin’、εmax”=
εmin”となるのでA=0、B=0となる。A、Bが
大きいほど配向している炭素繊維含有組成物である。A
<25、B<5では配向度が小さく、炭素繊維の含有率
を高くして炭素繊維を多く混入するか、吸収体の厚さを
大きくしなければならない。When the carbon fibers are oriented at random, ε max '= ε min ', ε max ″ =
Since ε min ″, A = 0 and B = 0. The larger A and B are, the more oriented the carbon fiber-containing composition is.
When <25 and B <5, the degree of orientation is small, and it is necessary to increase the carbon fiber content and mix a large amount of carbon fibers, or to increase the thickness of the absorber.
【0016】炭素繊維としては、レーヨン系、ポリアク
リロニトリル(PAN)系、フェノール樹脂系、石炭ピ
ッチ系、石油ピッチ系など、各種の炭素繊維が使用で
き、そして、通常、繊維直径が2〜30μm程度、平均
繊維長さが0.1〜10mm程度、好ましくは、マトリ
ックスがモルタルまたはコンクリートのときは0.2〜
0.8mm、樹脂のときは0.2〜5mm程度のものを
使用するのが好ましい。As the carbon fiber, various carbon fibers such as rayon type, polyacrylonitrile (PAN) type, phenol resin type, coal pitch type and petroleum pitch type can be used, and the fiber diameter is usually about 2 to 30 μm. The average fiber length is about 0.1-10 mm, preferably 0.2-when the matrix is mortar or concrete.
It is preferable to use 0.8 mm, and in the case of resin, about 0.2 to 5 mm.
【0017】ここに言う炭素繊維の長さは、炭素繊維含
有組成物を製造するときに入れる炭素繊維の長さでは無
く、炭素繊維含有組成物中に存在する状態での値であ
る。炭素繊維の長さは長い程好ましいが、炭素繊維含有
組成物を製造する場合、特にモルタルまたはコンクリー
ト製の炭素繊維含有組成物は、その製造時のミキシング
により炭素繊維が切断されるため、および、作業性の面
から長さが10mmを越えるものを得ることは難しい。
また、0.1mm未満では、炭素繊維の含有率を高くし
ても、複素誘電率εの実数部ε’および虚数部ε”とも
絶対値そのものが大きくならない(ε’≒10、ε”≒
1〜2程度にしかならない)。The length of the carbon fiber as referred to herein is not the length of the carbon fiber to be added when producing the carbon fiber-containing composition, but the value in the state of being present in the carbon fiber-containing composition. The longer the length of the carbon fiber is, the more preferable it is, but when producing the carbon fiber-containing composition, in particular, the mortar- or concrete-made carbon fiber-containing composition, because the carbon fiber is cut by the mixing during the production, and, From the viewpoint of workability, it is difficult to obtain a product having a length exceeding 10 mm.
On the other hand, if the carbon fiber content is less than 0.1 mm, the absolute values of both the real part ε ′ and the imaginary part ε ″ of the complex permittivity ε do not increase (ε′≈10, ε ″ ≈ even if the carbon fiber content is increased.
It is only about 1-2).
【0018】電波吸収体を構成する母材としては、セメ
ントと細骨材と混和材と水とから成るモルタルとか、そ
のモルタルに粗骨材を混合したコンクリート等の水硬組
成物、石膏、エポキシ樹脂等の樹脂、セラミックス、ゴ
ムなどが適用できる。The base material constituting the electromagnetic wave absorber is mortar composed of cement, fine aggregate, admixture and water, or a hydraulic composition such as concrete in which coarse aggregate is mixed with mortar, gypsum, epoxy. Resins such as resins, ceramics, and rubber can be applied.
【0019】炭素繊維の含有率は、水硬組成物(例え
ば、モルタル)中の水硬成分(例えば、セメント)に対
して0.5〜10重量%であるのが好ましい。0.5重
量%未満では、電波に対するマッチング条件が難しく、
一方、10重量%を越えると、炭素繊維のマトリックス
中での均一分散が難しくなるからである。The carbon fiber content is preferably 0.5 to 10% by weight based on the hydraulic component (eg cement) in the hydraulic composition (eg mortar). If it is less than 0.5% by weight, matching conditions for radio waves are difficult,
On the other hand, if it exceeds 10% by weight, it becomes difficult to uniformly disperse the carbon fibers in the matrix.
【0020】また、樹脂に含有する場合において、その
樹脂に対する炭素繊維の含有率は5〜25重量%である
のが好ましい。5重量%未満では、電波に対するマッチ
ング条件が難しく、一方、25重量%を越えると、炭素
繊維のマトリックス中での均一分散が難しくなるからで
ある。When the carbon fiber is contained in the resin, the carbon fiber content of the resin is preferably 5 to 25% by weight. If it is less than 5% by weight, the matching condition for radio waves is difficult, while if it exceeds 25% by weight, it is difficult to uniformly disperse the carbon fibers in the matrix.
【0021】[0021]
【作用】本発明の電波吸収方法の構成によれば、吸収し
ようとする電波が水平偏波または垂直偏波のいずれにも
適用できる。例えば、水平偏波の電波であれば、それに
よって発生する電界の方向が水平方向であるため、揃え
た炭素繊維の向きが電波の進行方向に対して交差する水
平方向になるように、建物外壁を電波吸収体そのもので
構成するとか、電波吸収体を各種の建造物などに取り付
ける。こうすることによって、電波の電界方向に対し、
誘電率が大きくなり、図3のDの値の小さいところでマ
ッチングがとれ、結果として、従来にない薄い電波吸収
体で電波を吸収することができる。According to the configuration of the radio wave absorption method of the present invention, the radio wave to be absorbed can be applied to either horizontal polarization or vertical polarization. For example, in the case of horizontally polarized radio waves, the direction of the electric field generated by it is horizontal, so that the aligned carbon fibers should be oriented in the horizontal direction that intersects the traveling direction of the radio waves. Is composed of the electromagnetic wave absorber itself, or the electromagnetic wave absorber is attached to various structures. By doing this, with respect to the electric field direction of the radio wave,
The permittivity increases, and matching is achieved where the value of D in FIG. 3 is small, and as a result, it is possible to absorb radio waves with a thin radio wave absorber that has never existed before.
【0022】[0022]
【実施例】以下、本発明の実施例を詳細に説明する。EXAMPLES Examples of the present invention will be described in detail below.
【0023】<第1実施例> 普通ポルトランドセメントと、細骨材としての硅砂6号
と、混和材としてのメチルセルロースと、水と、繊維径
が13μmで平均繊維長さが3mm、6mm、8mmの
炭素繊維(S−231、S−232、S−233:いず
れも株式会社ドナック製)とを表1に示す割合で配合
し、モルタルを母材とした電波吸収体の試験体を作成し
た。<First Example> Ordinary Portland cement, silica sand No. 6 as fine aggregate, methyl cellulose as an admixture, water, and a fiber diameter of 13 μm and an average fiber length of 3 mm, 6 mm and 8 mm. Carbon fibers (S-231, S-232, S-233: all manufactured by Donac Co., Ltd.) were mixed in the proportions shown in Table 1 to prepare a radio wave absorber test body using mortar as a base material.
【表1】 [Table 1]
【0024】作成手順としては、先ず、普通ポルトラン
ドセメントとメチルセルロースと炭素繊維とを、容量5
リットルのオムニミキサーによって60秒間予備混練
し、その後に水を加えて120秒間混練し、しかる後
に、硅砂6号を加えて60秒間混練し、炭素繊維入りの
モルタルを調整した。As a procedure for producing, first, ordinary Portland cement, methyl cellulose and carbon fiber were mixed in a volume of 5
Preliminary kneading was performed for 60 seconds with a liter omni mixer, water was then added and kneading for 120 seconds, after which silica sand No. 6 was added and kneading for 60 seconds to prepare a carbon fiber-containing mortar.
【0025】こうして得られたモルタルを、40×40
×160の大きさの型枠内に、炭素繊維の長手方向が型
枠の長手方向を向くように手で揃えながら打設し、20
℃で80%の恒温恒湿雰囲気下で1日間養生してから脱
型し、しかる後に、その硬化体を、20℃の恒温水槽中
で養生し、恒温水槽から取り出した後に、更に、20℃
で60%の恒温恒湿雰囲気下で1日間養生した。The mortar thus obtained was mixed with 40 × 40
In the mold of size × 160, the carbon fibers are placed by hand while aligning them so that the longitudinal direction of the carbon fibers faces the longitudinal direction of the mold.
After curing at 80 ° C in a constant temperature and humidity atmosphere of 80% for 1 day and then removing from the mold, the cured product is then cured in a constant temperature water tank at 20 ° C, and then removed from the constant temperature water tank, and then at 20 ° C.
It was cured for 1 day under a constant temperature and humidity atmosphere of 60%.
【0026】こうして得た硬化体1を、図1の斜視図に
示すように、横断切断線X1,X2,X3,X4,X
5、および、縦断切断線Y1,Y2で切断し、その内の
型枠の中央部側に位置する大きさが約40×40×10
のものを取り出して、図2の(a)の斜視図に示すよう
に、炭素繊維の長手方向の向きが厚み方向を向くように
揃った縦タイプの測定用の試験体A1,A2と、図2の
(b)の斜視図に示すように、炭素繊維の長手方向の向
きが厚み方向に直交する方向を向くように揃った横タイ
プの測定用の試験体B1,B2とを得た。As shown in the perspective view of FIG. 1, the cured product 1 thus obtained is cut along the transverse cutting lines X1, X2, X3, X4, X.
5 and the vertical cutting lines Y1 and Y2, the size of which is located on the central side of the mold is about 40 × 40 × 10
As shown in the perspective view of FIG. 2 (a), the vertical type test specimens A1 and A2 for measurement in which the longitudinal direction of the carbon fibers are aligned so as to face the thickness direction, and FIG. As shown in the perspective view of 2 (b), horizontal type test specimens B1 and B2 for measurement were obtained in which the longitudinal direction of the carbon fibers was aligned in the direction orthogonal to the thickness direction.
【0027】これらの各測定用の試験体A1,A2,B
1,B2それぞれに対して、厚みが10mmになるよう
にA60の紙ヤスリで粗ケズリした後、A200の紙ヤ
スリで対向面が平行になるように仕上げる。Specimens A1, A2, B for each of these measurements
After roughly scraping each of 1 and B2 with a paper file of A60 so as to have a thickness of 10 mm, finishing is performed with a paper file of A200 so that the facing surfaces are parallel to each other.
【0028】静電容量Cpと導電値Gとの測定に先立
ち、測定の前日に、乾燥機によって100℃で7時間強
制乾燥し、その強制乾燥後にデシケーターにより真空冷
却し、室温まで完全に冷却した後、吸湿しない様にロッ
ト毎に乾燥剤(シリカゲル)を入れたチャック付のポリ
エチレン製袋内に収納した。Prior to the measurement of the capacitance Cp and the electric conductivity value G, on the day before the measurement, the product was forcedly dried at 100 ° C. for 7 hours by a dryer, and after the forced drying, it was vacuum-cooled by a desiccator and completely cooled to room temperature. Then, each lot was placed in a polyethylene bag with a zipper containing a desiccant (silica gel) so as not to absorb moisture.
【0029】そして、各試験体A1,A2,B1,B2
それぞれを、図5の測定装置の概略構成図に示すよう
に、インピーダンスアナライザ(4191A:横河ヒュ
ーレットパッカード社製)2の電極用銅板3,3間に挟
み、厚み方向に電界をかけて静電容量Cpと導電値Gと
を測定し、その測定された静電容量Cpと導電値Gとに
基づいて、複素誘電率(比誘電率)の実数部の値ε’お
よび虚数部の値ε”それぞれを求めた。Then, each test body A1, A2, B1, B2
As shown in the schematic configuration diagram of the measuring device of FIG. 5, each of them is sandwiched between the copper plates 3 and 3 for electrodes of an impedance analyzer (4191A: Yokogawa Hewlett-Packard Co.) 2 and an electrostatic field is applied in the thickness direction. The capacitance Cp and the conductivity value G are measured, and based on the measured capacitance Cp and the conductivity value G, the value ε ′ of the real part and the value ε ″ of the imaginary part of the complex permittivity (relative permittivity). I asked each one.
【0030】すなわち、静電容量Cpと実数部の値ε’
との間には、次の関係式 Cp=ε0・ε’・S/d ε’=Cp・d/(ε0・S) が成り立つ。ここで、ε0は真空中での誘電率で8.8
54×10−12であり、そして、Sは試験体の面積、
dは試験体の厚みであり、静電容量Cpを求めることに
よって、実数部の値ε’を求めることができるのであ
る。That is, the capacitance Cp and the value ε'of the real part
The following relational expression Cp = ε 0 · ε ′ · S / d ε ′ = Cp · d / (ε 0 · S) holds between and. Here, ε 0 is a dielectric constant in a vacuum of 8.8.
54 × 10 −12 , and S is the area of the specimen,
d is the thickness of the test body, and the value ε'of the real part can be obtained by obtaining the capacitance Cp.
【0031】また、導電値Gと虚数部の値ε”との間に
は、次の関係式 G=σ・S/d σ=G・d/S ε”=σ/(ε0・ω) =σ/(ε0・2πf) =G・d/(S・ε0・2πf) が成り立つ。ここで、σは導電率、ε0は真空中での誘
電率で8.854×10−12であり、そして、Sは試
験体の面積、dは試験体の厚みであり、また、fは吸収
しようとする既知の電波の周波数であり、導電値Gを求
めることによって、虚数部の値ε”を求めることができ
る。Between the conductivity value G and the value ε ″ of the imaginary part, the following relational expression G = σ · S / d σ = G · d / S ε ″ = σ / (ε 0 · ω) = Σ / (ε 0 · 2πf) = G · d / (S · ε 0 · 2πf) holds. Here, σ is the conductivity, ε 0 is the dielectric constant in a vacuum of 8.854 × 10 −12 , S is the area of the test body, d is the thickness of the test body, and f is It is the frequency of the known radio wave to be absorbed, and the value ε ″ of the imaginary part can be obtained by obtaining the conductivity value G.
【0032】このようにして、平均繊維長さが3mmで
チョップ状の炭素繊維を、前述の表に示したように、モ
ルタルに対する含有率が1重量%、2重量%、3重量
%、4重量%、5重量%になるように含有したものと、
炭素繊維を含有するものと同様にして作成した炭素繊維
を含有しないものとによる縦タイプの試験体A1,A2
と横タイプの試験体B1,B2それぞれに付き、電波の
周波数を100MHzに固定して複素誘電率(比誘電
率)の実数部の値ε’および虚数部の値ε”それぞれを
求めたところ、表2および図6のグラフそれぞれに示す
結果を得た。ミキシング中に切断されるため、試料中で
の炭素繊維の平均繊維長さは約0.2〜0.8mmにな
っている。炭素繊維の含有率(重量%)が高い程、炭素
繊維が切断されて短くなる。すなわち、炭素繊維の含有
率が高い程粘度が大きくなって剪断を受けやすくなるた
めと考えられる。Thus, the chopped carbon fibers having an average fiber length of 3 mm have a content of 1% by weight, 2% by weight, 3% by weight, 4% by weight with respect to the mortar as shown in the above table. %, 5% by weight, and
Longitudinal type test bodies A1 and A2 prepared by the same manner as those containing carbon fibers and those not containing carbon fibers
When the frequency of the radio wave is fixed to 100 MHz and the value ε ′ of the real part and the value ε ″ of the imaginary part of the complex permittivity (relative permittivity) are obtained for each of the horizontal type test bodies B1 and B2, The results shown in each of Table 2 and the graph of Fig. 6 were obtained.Because the fibers were cut during mixing, the average fiber length of the carbon fibers in the sample was about 0.2 to 0.8 mm. The higher the content (% by weight) of carbon fiber is, the shorter the carbon fiber is cut, which is considered to be because the higher the content of carbon fiber is, the higher the viscosity is and the more easily it is sheared.
【表2】 [Table 2]
【0033】また、平均繊維長さが6mmでチョップ状
の炭素繊維についても同様にして複素誘電率(比誘電
率)の実数部の値ε’および虚数部の値ε”それぞれを
求めたところ、表3および図7のグラフそれぞれに示す
結果を得た。試料中の炭素繊維の平均繊維長さは約0.
6〜1.0mmである。Also, for a chopped carbon fiber having an average fiber length of 6 mm, the real part ε ′ and the imaginary part ε ″ of the complex permittivity (relative permittivity) were obtained in the same manner. The results shown in Table 3 and the graph of Fig. 7 were obtained, and the average fiber length of the carbon fibers in the sample was about 0.
It is 6 to 1.0 mm.
【表3】 [Table 3]
【0034】平均繊維長さが6mmでチョップ状の炭素
繊維を含有してモルタルを調整したときの残存繊維の平
均繊維長さ(mm)と炭素繊維の含有率(重量%)との
関係を測定したところ、図8のグラフに示す結果を得
た。The relationship between the average fiber length (mm) of residual fibers and the carbon fiber content (% by weight) when the mortar was prepared by containing chopped carbon fibers having an average fiber length of 6 mm was measured. Then, the results shown in the graph of FIG. 8 were obtained.
【0035】ここでの炭素繊維の含有率はセメントに対
する重量比で示しており、骨材等を含めた場合には、そ
の含有率が約半分になる。The carbon fiber content here is indicated by the weight ratio with respect to the cement, and when the aggregate and the like are included, the content rate becomes about half.
【0036】上記結果において、炭素繊維の含有率が高
くなる程残存繊維の平均繊維長さが短くなっているの
は、炭素繊維の含有率が高くなる程粘度が大きくなって
剪断力がかかり、炭素繊維が切断されるためである。In the above results, the higher the carbon fiber content, the shorter the average fiber length of the residual fibers. The higher the carbon fiber content, the higher the viscosity and shear force. This is because the carbon fibers are cut.
【0037】更に、平均繊維長さが3mmの炭素繊維
(試料中では約0.9mm)を、モルタルに対する含有
率2重量%にして含有し、それらを一軸スクリュータイ
プの真空押出成形機によって押出成形し、炭素繊維の長
手方向が厚み方向に向かって並ぶように揃った縦タイプ
の試験体と、炭素繊維の長手方向が厚み方向に直交する
方向に向かって並ぶように揃った横タイプの試験体とを
作成し、それぞれに付いて電波の周波数と複素誘電率
(比誘電率)の実数部の値ε’および虚数部の値ε”そ
れぞれとの関係を求めたところ、図9および図10それ
ぞれのグラフに示す結果を得た。Further, carbon fibers having an average fiber length of 3 mm (about 0.9 mm in the sample) were contained at a content of 2% by weight with respect to the mortar, and they were extruded by a single screw type vacuum extruder. However, a vertical type test body in which the longitudinal direction of the carbon fibers is aligned in the thickness direction and a horizontal type test body in which the longitudinal direction of the carbon fibers are aligned in a direction orthogonal to the thickness direction 9 and FIG. 10 are obtained by calculating the relations between the radio frequency and the real part value ε ′ of the complex permittivity (relative permittivity) and the imaginary part value ε ″ of The results shown in the graph are obtained.
【0038】上述の結果から次のことが明らかである。 炭素繊維の長手方向が厚み方向に向かって並ぶよう
に揃った縦タイプの試験体A1,A2の方が、炭素繊維
の長手方向が厚み方向に直交する方向に向かって並ぶよ
うに揃った横タイプの試験体B1,B2に比べ、複素誘
電率(比誘電率)の実数部の値ε’を大きくできる。From the above results, the following is clear. The vertical type test bodies A1 and A2 in which the longitudinal directions of the carbon fibers are aligned in the thickness direction are horizontal types in which the longitudinal directions of the carbon fibers are aligned in the direction orthogonal to the thickness direction. The value ε'of the real part of the complex permittivity (relative permittivity) can be made larger than those of the test bodies B1 and B2.
【0039】 図6および図7からわかるように、炭
素繊維の長さが3mmのものでは、含有率が4重量%で
複素誘電率(比誘電率)の実数部の値ε’が大きくなる
が、炭素繊維の長さが6mmのものでは、含有率が2重
量%でも複素誘電率(比誘電率)の実数部の値ε’が大
きくなり、長い炭素繊維を含有するときには、その含有
率が少なくても、電波を良好に吸収できる。As can be seen from FIGS. 6 and 7, when the carbon fiber length is 3 mm, the content ε ′ of the real part of the complex permittivity (relative permittivity) becomes large when the content is 4% by weight. When the carbon fiber length is 6 mm, the value ε'in the real part of the complex permittivity (relative permittivity) becomes large even when the content rate is 2% by weight, and when the long carbon fiber content is included, the content rate is At least, it can absorb radio waves well.
【0040】 真空押出成形機を利用することによ
り、手で揃える場合よりも、自ずと炭素繊維の向きを特
定方向(押出方向)に良好に揃えることができ、作業性
を向上できる。By using a vacuum extrusion molding machine, the orientation of the carbon fibers can be naturally aligned in a specific direction (extrusion direction) better than when aligned by hand, and workability can be improved.
【0041】以上の構成により、例えば、水平偏波を対
象とする場合であれば、図11の斜視図に示すように、
電波Wの入射方向に位置する側の建物外壁Tを、前述の
ようにして得られるモルタル、あるいは、それに粗骨材
を加えたコンクリートによって、炭素繊維の向き(CF
で示す)が壁面方向に沿った水平方向に向くように揃う
状態で構築し、ゴースト障害を防止できる。With the above configuration, for example, in the case of horizontal polarization, as shown in the perspective view of FIG.
The outer wall T of the building on the side located in the incident direction of the radio wave W is made of the mortar obtained as described above or the concrete in which coarse aggregate is added to the carbon fiber
(Shown by) are aligned so that they are oriented in the horizontal direction along the wall surface direction, and ghost obstacles can be prevented.
【0042】詳述すれば、図12の作用説明図に示すよ
うに、電波Wの入射に伴って発生する電界Eにより炭素
繊維に電圧を誘起して電波Wを吸収する。このとき、電
波Wの入射方向が建物外壁Tに対して所定角度θ傾斜し
ていれば、その電界成分はEcosθとなるが、その分
の電波Wだけでも吸収することでゴースト障害防止効果
が有る。More specifically, as shown in the operation explanatory view of FIG. 12, a voltage is induced in the carbon fiber by the electric field E generated by the incidence of the radio wave W to absorb the radio wave W. At this time, if the incident direction of the radio wave W is inclined at a predetermined angle θ with respect to the outer wall T of the building, the electric field component becomes Ecos θ, but by absorbing only the radio wave W by that amount, there is a ghost obstacle prevention effect. .
【0043】垂直偏波を対象とする場合であれば、炭素
繊維の向きが壁面方向に沿った鉛直方向に向くように揃
う状態で建物外壁Tを構築すれば良い。In the case of targeting vertically polarized waves, the building outer wall T may be constructed in a state where the carbon fibers are oriented in the vertical direction along the wall surface direction.
【0044】<第2実施例> 繊維径が13μmで平均繊維長さが0.70mmの炭素
繊維(S−244:株式会社ドナック製)を乾燥し、そ
の乾燥した炭素繊維を、図13の概略構成図に示すよう
に、混合槽4内に溜められた主剤としての液状のエポキ
シ樹脂(エピコート827:油化シェル株式会社製)に
混合して撹拌する。<Second Embodiment> A carbon fiber having a fiber diameter of 13 μm and an average fiber length of 0.70 mm (S-244: manufactured by Donac Co., Ltd.) was dried, and the dried carbon fiber was roughly as shown in FIG. As shown in the configuration diagram, a liquid epoxy resin (Epicoat 827: manufactured by Yuka Shell Co., Ltd.) as a main component, which is stored in the mixing tank 4, is mixed and stirred.
【0045】次いで、真空引きにより脱泡してから、炭
素繊維を混合したエポキシ樹脂液を冷却し、そこに、副
剤としての硬化剤(ハードナーH4510:ACR株式
会社製)を、主剤の50重量%分混合して撹拌し、直径
が40mmで高さが300mmの円筒状型枠5を用いて
真空ポンプ6により吸引し、吸引完了後に円筒状型枠5
の下部開口をゴム栓7で塞ぎ、しかる後に取り出して水
槽内に24時間入れ、常温まで冷却してから脱型する。Next, after degassing by evacuation, the epoxy resin liquid mixed with carbon fibers is cooled, and a curing agent (HARDNER H4510: manufactured by ACR Co., Ltd.) as an auxiliary agent is added to 50 weight% of the main agent. %, Mixed and stirred, and suctioned by a vacuum pump 6 using a cylindrical mold 5 having a diameter of 40 mm and a height of 300 mm, and after completion of the suction, the cylindrical mold 5
The lower opening of the is closed with a rubber stopper 7, then taken out, put in a water tank for 24 hours, cooled to room temperature, and then released from the mold.
【0046】その後、乾燥機により、80℃で加熱乾燥
し、厚みが10mm、直径が40mmで、炭素繊維の長
手方向が特定方向を向いて揃うように切断し、炭素繊維
の長手方向が厚み方向を向くように揃った縦タイプの試
験体A3と、炭素繊維の長手方向が厚み方向に直交する
方向を向くように揃った横タイプの試験体B3とを得
た。ミキシングをしていないために、試料中の炭素繊維
の長さが混入前の値とほぼ同じであることを、試料を溶
剤で溶かして測定することにより確認した。After that, it is heated and dried at 80 ° C. by a drier, cut so that the longitudinal direction of the carbon fibers is 10 mm in thickness and 40 mm in diameter, and the longitudinal direction of the carbon fibers is aligned in a specific direction. A vertical type test body A3 aligned so as to face each other and a horizontal type test body B3 aligned so that the longitudinal direction of the carbon fibers were oriented in a direction orthogonal to the thickness direction were obtained. It was confirmed by dissolving the sample in a solvent and measuring that the length of the carbon fiber in the sample was almost the same as the value before mixing because the sample was not mixed.
【0047】そして、主剤と副剤と炭素繊維の合計重量
に対する炭素繊維の含有率を5重量%、10重量%およ
び15重量%それぞれにして、両試験体A3,B3それ
ぞれを、前述第1実施例と同様に、インピーダンスアナ
ライザ(4191A:横河ヒューレットパッカード社
製)2を用い(図5参照)、電極用銅板3,3間に挟
み、静電容量Cpと導電値Gとを測定し、その測定され
た静電容量Cpと導電値Gとに基づいて、複素誘電率
(比誘電率)の実数部の値ε’を求めたところ、図14
のグラフに示す結果を得た。Then, the carbon fiber contents were set to 5% by weight, 10% by weight and 15% by weight with respect to the total weight of the main agent, the auxiliary agent and the carbon fiber, respectively, and both the test bodies A3 and B3 were subjected to the above-mentioned first embodiment. Similar to the example, an impedance analyzer (4191A: manufactured by Yokogawa Hewlett-Packard Co.) 2 was used (see FIG. 5) and sandwiched between the electrode copper plates 3 and 3 to measure the capacitance Cp and the conductivity value G, and The value ε ′ of the real part of the complex permittivity (relative permittivity) was calculated based on the measured capacitance Cp and the conductivity value G, and FIG.
The results shown in the graph are obtained.
【0048】この結果、縦タイプの試験体A3におい
て、横タイプの試験体B3に比べ、実数部の値ε’を極
めて大きな値にできるとともに、その値が炭素繊維の含
有率に比例して増大できることが明らかであった。As a result, in the vertical type test body A3, the value ε'of the real part can be made extremely large as compared with the horizontal type test body B3, and the value increases in proportion to the carbon fiber content. It was clear that it could be done.
【0049】<第3実施例> 繊維径が13μmで平均繊維長さが0.60mmの炭素
繊維を乾燥し、その乾燥した炭素繊維を、前述第2実施
例と同様にして、エポキシ樹脂(エピコート827:油
化シェル株式会社製)をマトリックスとする炭素繊維含
有組成物を得、炭素繊維の長手方向が特定方向を向いて
揃うように切断し、図15に示すように、炭素繊維の長
手方向が厚み方向を向くように揃ったタイプの試験体C
1と、炭素繊維の長手方向が厚み方向に対して30°傾
斜した方向を向くように揃ったタイプの試験体C2と、
炭素繊維の長手方向が厚み方向に対して60°傾斜した
方向を向くように揃ったタイプの試験体C3と、炭素繊
維の長手方向が厚み方向に直交する方向を向くように揃
ったタイプの試験体C4とを得た。ミキシングをしてい
ないために、試料中の炭素繊維の長さが混入前の値とほ
ぼ同じであることを、試料を溶剤で溶かして測定するこ
とにより確認した。<Third Embodiment> A carbon fiber having a fiber diameter of 13 μm and an average fiber length of 0.60 mm was dried, and the dried carbon fiber was treated with an epoxy resin (Epicoat) in the same manner as in the second embodiment. 827: manufactured by Yuka Shell Co., Ltd.) is used as a matrix to obtain a carbon fiber-containing composition, which is cut so that the longitudinal directions of the carbon fibers are aligned in a specific direction, and as shown in FIG. Specimens C of the type in which the
1 and a test body C2 of a type in which the longitudinal direction of the carbon fibers is aligned in a direction inclined by 30 ° with respect to the thickness direction,
A test body C3 of a type in which the longitudinal direction of the carbon fibers is oriented in a direction inclined by 60 ° with respect to the thickness direction, and a test of a type in which the longitudinal direction of the carbon fibers is oriented in a direction orthogonal to the thickness direction. Got body C4. It was confirmed by dissolving the sample in a solvent and measuring that the length of the carbon fiber in the sample was almost the same as the value before mixing because the sample was not mixed.
【0050】そして、主剤と副剤と炭素繊維の合計重量
に対する炭素繊維の含有率を10重量%にし、各試験体
C1,C2,C3,C4それぞれを用い、測定周波数9
2.75MHzとして、炭素繊維の長手方向に対する電
界方向(図15では、Eにベクトル表示記号を付して表
示している)の角度を、0°、±30°、±60°、±
90°となるようにして、前述第1実施例と同様に、イ
ンピーダンスアナライザ(4191A:横河ヒューレッ
トパッカード社製)2を用い(図5参照)、電極用銅板
3,3間に挟み、静電容量Cpと導電値Gとを測定し、
その測定された静電容量Cpと導電値Gとに基づいて、
複素誘電率の実数部の値ε’および虚数部の値ε”それ
ぞれを求めたところ、表4および図15のグラフに示す
結果を得た。Then, the carbon fiber content was set to 10% by weight based on the total weight of the main agent, the auxiliary agent, and the carbon fiber, and each of the test bodies C1, C2, C3 and C4 was used, and the measurement frequency was set to 9
At 2.75 MHz, the angle of the electric field direction (in FIG. 15, E is attached with a vector display symbol) with respect to the longitudinal direction of the carbon fiber is 0 °, ± 30 °, ± 60 °, ±
As in the first embodiment, an impedance analyzer (4191A: Yokogawa Hewlett-Packard Co., Ltd.) 2 was used so as to be 90 ° (see FIG. 5), and was sandwiched between the electrode copper plates 3 and 3, and electrostatic The capacitance Cp and the conductivity value G are measured,
Based on the measured capacitance Cp and the conductivity value G,
When the value ε ′ of the real part and the value ε ″ of the imaginary part of the complex permittivity were obtained, the results shown in Table 4 and the graph of FIG. 15 were obtained.
【表4】 [Table 4]
【0051】この結果から、炭素繊維の長手方向を吸収
しようとする電波の電界方向に向けて配置する程、複素
誘電率の実数部の値ε’および虚数部の値ε”のいずれ
をも高くできることが明らかであった。From these results, it can be seen that both the real part ε ′ and the imaginary part ε ″ of the complex permittivity become higher as the carbon fibers are arranged in the electric field direction of the radio wave to be absorbed. It was clear that it could be done.
【0052】上述のようにして得られる、樹脂を母材と
した電波吸収体は、例えば、送電線の鉄塔、橋梁、新幹
線、高速道路、ゴルフ練習場などの各種の建造物とか航
空機の外面に、吸収しようとする電波によって発生する
電界の方向と同じ方向に炭素繊維の向きが揃う状態で貼
り付けて使用すれば良い。The electromagnetic wave absorber made of resin as a base material obtained as described above is applied to various structures such as power line towers, bridges, bullet trains, highways, golf driving ranges, and outer surfaces of aircraft. The carbon fibers may be attached and used in the same direction as the direction of the electric field generated by the electric wave to be absorbed.
【0053】上述第1および第2実施例のいずれにおい
ても、複素誘電率(比誘電率)の測定において、周波数
を100MHzに固定していながら、高い複素誘電率
(比誘電率)の実数部の値ε’を得ることができる。In both the first and second embodiments described above, in the measurement of the complex permittivity (relative permittivity), the real part of the high complex permittivity (relative permittivity) was measured while the frequency was fixed at 100 MHz. The value ε'can be obtained.
【0054】そして、電波吸収体は、通常、特定の周波
数の電波を吸収するように設計する。この場合、設計に
用いた吸収させたい周波数の電波だけでなく、その周波
数に近い周波数の電波をも吸収できる。複素誘電率(比
誘電率)の実数部の値ε’と虚数部の値ε”とのマッチ
ングが良い場合は、より広範囲の周波数の電波を吸収す
ることができる。The radio wave absorber is usually designed to absorb radio waves of a specific frequency. In this case, it is possible to absorb not only the radio wave having the frequency to be absorbed used in the design but also the radio wave having a frequency close to that frequency. When the value ε ′ of the real part and the value ε ″ of the imaginary part of the complex permittivity (relative permittivity) are well matched, radio waves in a wider range of frequencies can be absorbed.
【0055】例えば、2cHの電波を吸収するように設
計した場合について考えて見れば、周波数と反射係数と
の間に、図16に示すような関係があり、2cHの周波
数に近い1cHおよび3cHの電波に対しても、反射係
数が−14dB程度になり、それらの電波をも良好に吸
収できることが明らかである。また、4cHから12c
Hの電波の周波数は、200MHzの近辺に集中してお
り、200MHzの電波を吸収するように設計すること
により、4cHから12cHの電波を良好に吸収できる
ことになる。Considering, for example, a case of designing to absorb a radio wave of 2 cH, there is a relationship between the frequency and the reflection coefficient as shown in FIG. 16, and there are 1 cH and 3 cH close to the frequency of 2 cH. Even with respect to radio waves, the reflection coefficient is about -14 dB, and it is clear that these radio waves can be absorbed well. Also, 4cH to 12c
The frequency of the H radio wave is concentrated in the vicinity of 200 MHz, and by designing to absorb the 200 MHz radio wave, the 4 cH to 12 cH radio wave can be favorably absorbed.
【0056】上述第1および第2実施例のいずれにおい
ても、吸収しようとする電波の周波数に応じ、それらに
必要な複素誘電率(比誘電率)の実数部の値ε’を、使
用した炭素繊維の平均繊維長さとの関係において、炭素
繊維の含有率を極力小さくして得るように設計する方が
好ましい。 <第4実施例> 普通ポルトランドセメント2000gと、細骨材として
の硅砂6号1000gと、混和材を15gと、水100
0gと、繊維径が18μmで繊維長さが0.5mmの炭
素繊維(ドナカーボS−344:株式会社ドナック製)
160gとを混合し、炭素繊維入りのモルタルを得、こ
のモルタルを、押出機を用いて成形板を作成し、前述第
1実施例と同様にして養生して硬化体を得た。そして、
上記硬化体を厚さ20cmになるように切断して供試体
を作成し、その供試体を炭素繊維の方向(配向)が、電
波(平面波)の電界ベクトルに平行で、かつ、磁界ベク
トルおよびポインチングベクトルのいずれにも垂直とな
るように配置したものを第4実施例とした。一方、供試
体を炭素繊維の方向(配向)が、電波(平面波)の磁界
ベクトルに平行で、かつ、電界ベクトルおよびポインチ
ングベクトルのいずれにも垂直となるように配置したも
のを第1比較例とし、そして、供試体を炭素繊維の方向
(配向)が、電波(平面波)のポインチングベクトルに
平行で、かつ、電界ベクトルおよび磁界ベクトルのいず
れにも垂直となるように配置したものを第2比較例と
し、第4実施例、第1および第2比較例それぞれの電波
吸収能の物理量として電波減衰量を測定した。なお、電
波減衰量=10・log(反射電波エネルギー/入射電
波エネルギー)として求めた。この測定の結果、第4実
施例の場合、図17の周波数と電波減衰量との関係を示
すグラフに示されるように、432MHzで−18dB
の電波の減衰があった。これに対して、第1比較例の場
合、図18の周波数と電波減衰量との関係を示すグラフ
に示されるように、650MHzの付近で最大−5dB
程度の電波の減衰しか無く、また、第2比較例の場合、
図19の周波数と電波減衰量との関係を示すグラフに示
されるように、45MHzから1GHzの範囲内での電
波の減衰がほとんど無く、テレビ帯域の周波数に対して
は、炭素繊維の長手方向を電波の電界方向に向けて配置
することにより、電波を良好に吸収できることが明らか
であった。In both the first and second embodiments described above, the value ε'of the real part of the complex permittivity (relative permittivity) required for the radio waves to be absorbed is used as the carbon used. In terms of the relationship with the average fiber length of the fibers, it is preferable to design so that the carbon fiber content is obtained as small as possible. <Fourth Example> 2000 g of ordinary Portland cement, 1000 g of silica sand No. 6 as fine aggregate, 15 g of admixture, and 100 of water.
0 g, carbon fiber having a fiber diameter of 18 μm and a fiber length of 0.5 mm (DONACARBO S-344: manufactured by DONAC CORPORATION)
160 g was mixed to obtain a mortar containing carbon fibers. A molding plate was prepared from this mortar using an extruder, and was cured in the same manner as in the first embodiment to obtain a cured product. And
The cured body is cut to a thickness of 20 cm to prepare a sample, and the direction (orientation) of the carbon fiber in the sample is parallel to the electric field vector of the radio wave (plane wave), and the magnetic field vector and the poin The fourth embodiment is arranged so as to be perpendicular to any of the teaching vectors. On the other hand, the first comparative example was arranged such that the direction (orientation) of the carbon fiber was parallel to the magnetic field vector of the radio wave (plane wave) and perpendicular to both the electric field vector and the pointing vector. Then, the test piece is arranged so that the direction (orientation) of the carbon fiber is parallel to the pointing vector of the radio wave (plane wave) and is perpendicular to both the electric field vector and the magnetic field vector. As a comparative example, a radio wave attenuation amount was measured as a physical quantity of the radio wave absorbing ability of each of the fourth embodiment, the first and second comparative examples. The radio wave attenuation amount was calculated as 10 · log (reflected radio wave energy / incident radio wave energy). As a result of this measurement, in the case of the fourth embodiment, as shown in the graph of FIG. 17 showing the relationship between the frequency and the amount of radio wave attenuation, -18 dB at 432 MHz.
There was attenuation of radio waves. On the other hand, in the case of the first comparative example, as shown in the graph showing the relationship between the frequency and the radio wave attenuation amount in FIG. 18, a maximum of −5 dB near 650 MHz.
In the case of the second comparative example, there is only a certain degree of radio wave attenuation,
As shown in the graph of FIG. 19 showing the relationship between the frequency and the amount of radio wave attenuation, there is almost no attenuation of radio waves in the range of 45 MHz to 1 GHz, and the longitudinal direction of the carbon fiber is in the longitudinal direction for frequencies in the television band. It was clear that the radio waves can be favorably absorbed by arranging them in the electric field direction of the radio waves.
【0057】[0057]
【発明の効果】以上の説明から明らかなように、本発明
の電波吸収方法によれば、吸収しようとする電波が水平
偏波または垂直偏波のいかんにかかわらず、電波吸収体
の取り付け姿勢を電波によって発生する電界の方向に対
応させ、揃えた炭素繊維の向きが電界の方向に一致する
ようにするから、炭素繊維の含有率が少なくても、ま
た、炭素繊維の量そのものが少なくても、電波を炭素繊
維に効率良く吸収して減衰することができる。しかも、
配向方向が異なるように吸収体を積層するといったこと
をせずに、炭素繊維をひとつの方向に配向した単層の吸
収体を用いるだけであるから、炭素繊維の含有率が低
く、厚みが薄くて軽量の電波吸収体を用いながら吸収効
率の高い状態で電波を吸収できた。このため、高層ビル
の外壁や、新幹線や高速道路の防音壁自体を電波吸収体
で構築するとか、あるいは、高層ビル、送電線、鉄塔、
橋梁、新幹線、高速道路、ゴルフ練習場などの各種の建
造物や航空機の外面に電波吸収体を貼るなどによって、
ゴースト障害を、取り扱い性良好に、かつ、安価にして
防止できるようになった。As is apparent from the above description, according to the radio wave absorption method of the present invention, regardless of whether the radio wave to be absorbed is horizontally polarized wave or vertically polarized wave, the mounting posture of the electromagnetic wave absorber can be changed. Since the direction of the aligned carbon fibers is made to correspond to the direction of the electric field by making it correspond to the direction of the electric field generated by the radio wave, even if the carbon fiber content is low or the amount of carbon fiber itself is low. The radio waves can be efficiently absorbed by the carbon fiber and attenuated. Moreover,
For example, stacking absorbers with different orientations
Without a single layer, the carbon fiber is oriented in one direction
Since only the collector is used, it was possible to absorb radio waves with high absorption efficiency while using a radio wave absorber having a low carbon fiber content, a thin thickness, and a light weight. For this reason, the outer walls of high-rise buildings and the soundproof walls of bullet trains and highways are constructed with electromagnetic wave absorbers, or high-rise buildings, power lines, steel towers,
By attaching a radio wave absorber to various structures such as bridges, bullet trains, highways, driving ranges, and the outer surface of aircraft,
It has become possible to prevent ghost failures with good handleability and at low cost.
【図1】本発明の電波吸収方法に用いる電波吸収体の試
験体を得るための硬化体の斜視図である。FIG. 1 is a perspective view of a cured body for obtaining a test body of a radio wave absorber used in the radio wave absorption method of the present invention.
【図2】試験体の斜視図を示し、図2の(a)は、縦タ
イプの試験体の斜視図、図2の(b)は、横タイプの試
験体の斜視図である。FIG. 2 shows a perspective view of a test body, FIG. 2 (a) is a perspective view of a vertical type test body, and FIG. 2 (b) is a perspective view of a horizontal type test body.
【図3】無反射条件の特性曲線を示すグラフである。FIG. 3 is a graph showing a characteristic curve under a non-reflection condition.
【図4】配向度の説明に供する側面図である。FIG. 4 is a side view for explaining the degree of orientation.
【図5】測定装置の概略構成図である。FIG. 5 is a schematic configuration diagram of a measuring device.
【図6】炭素繊維の含有率と比誘電率との関係を示すグ
ラフである。FIG. 6 is a graph showing the relationship between the carbon fiber content and the relative dielectric constant.
【図7】炭素繊維の含有率と比誘電率との関係を示すグ
ラフである。FIG. 7 is a graph showing the relationship between carbon fiber content and relative dielectric constant.
【図8】平均繊維長さが6mmでチョップ状の炭素繊維
を含有して調整したときの残存繊維の平均繊維長さと炭
素繊維の含有率との関係を示すグラフである。FIG. 8 is a graph showing the relationship between the average fiber length of residual fibers and the carbon fiber content when the chopped carbon fiber having an average fiber length of 6 mm is prepared and adjusted.
【図9】周波数と比誘電率の実数部との関係を示すグラ
フである。FIG. 9 is a graph showing a relationship between frequency and a real part of relative permittivity.
【図10】周波数と比誘電率の虚数部との関係を示すグ
ラフである。FIG. 10 is a graph showing the relationship between frequency and the imaginary part of the relative permittivity.
【図11】建物への使用状態を示す概略斜視図である。FIG. 11 is a schematic perspective view showing a state of use in a building.
【図12】電界発生状態の説明図である。FIG. 12 is an explanatory diagram of an electric field generation state.
【図13】樹脂を母材とした電波吸収体の作成装置の概
略構成図である。FIG. 13 is a schematic configuration diagram of an apparatus for producing a radio wave absorber using resin as a base material.
【図14】炭素繊維の含有率と比誘電率との関係を示す
グラフである。FIG. 14 is a graph showing the relationship between the carbon fiber content and the relative dielectric constant.
【図15】炭素繊維の方向と電界方向の角度に対する比
誘電率との関係を示すグラフである。FIG. 15 is a graph showing the relationship between the direction of carbon fibers and the relative dielectric constant with respect to the angle of the electric field direction.
【図16】周波数と反射係数との関係を示すグラフであ
る。FIG. 16 is a graph showing the relationship between frequency and reflection coefficient.
【図17】第4実施例の周波数と電波減衰量との関係を
示すグラフである。FIG. 17 is a graph showing the relationship between frequency and radio wave attenuation amount in the fourth embodiment.
【図18】第1比較例の周波数と電波減衰量との関係を
示すグラフである。FIG. 18 is a graph showing the relationship between the frequency and the amount of radio wave attenuation in the first comparative example.
【図19】第2比較例の周波数と電波減衰量との関係を
示すグラフである。FIG. 19 is a graph showing the relationship between the frequency and the amount of radio wave attenuation in the second comparative example.
CF…炭素繊維 W…電波 CF ... Carbon fiber W ... Radio wave
フロントページの続き (72)発明者 吉田 吉明 京都府京都市下京区中堂寺南町17 京都リ サーチパーク KRIインターナショナル 内 (56)参考文献 特開 昭58−188193(JP,A) 特開 昭58−184799(JP,A) 特開 昭58−108603(JP,A)Front Page Continuation (72) Inventor Yoshiaki Yoshida 17 Nakadoji Minami-cho, Shimogyo-ku, Kyoto Prefecture Kyoto Research Search Park KRI International (56) References JP-A-58-188193 (JP, A) JP-A-58-184799 (JP, A) JP 58-108603 (JP, A)
Claims (3)
成物の任意の方向に照射したときの前記炭素繊維含有組
成物の複素誘電率の実数部をε’、虚数部をε”とし、
それらの最大値および最小値を、ε max ’,
ε min ’、ε max ”,ε min ”とし、炭素繊維の
配向度Aをε max ’−ε min ’、配向度Bをε
max ”−ε min ”で定義する場合に、炭素繊維の配
向度Aが25以上、および/または、配向度Bが5以上
となるように炭素繊維を特定方向に配向して含有した炭
素繊維含有組成物を用い、含有炭素繊維の配向方向を吸
収しようとする電波の電界方向と一致させるように前記
炭素繊維含有組成物を配置し、前記炭素繊維含有組成物
により電波を吸収することを特徴とする電波吸収方法。1. A set containing carbon fibers for absorbing radio waves to be absorbed.
The composition containing carbon fibers when the composition is irradiated in any direction
Let ε ′ be the real part and ε ″ of the imaginary part of the complex permittivity of the product,
The maximum and minimum values of them are given by ε max ',
ε min ', ε max ″, ε min ″,
Orientation degree A is ε max '− ε min ' and orientation degree B is ε
When it is defined by max “−ε min ”, the carbon fiber distribution
The orientation A is 25 or more, and / or the orientation B is 5 or more.
Containing carbon fibers oriented in a specific direction so that
Using a composition containing elemental fibers, the orientation direction of the included carbon fibers is absorbed.
The above mentioned so that it matches the electric field direction of the radio wave to be collected.
Disposing a carbon fiber-containing composition, the carbon fiber-containing composition
Wave absorber wherein the absorbing radio waves by.
ルタルまたはコンクリート製の外壁であって、炭素繊維
の含有率が0.5〜10重量%である請求項1に記載の
電波吸収方法。2. The radio wave absorbing method according to claim 1, wherein the matrix of the carbon fiber-containing composition is an outer wall made of mortar or concrete, and the carbon fiber content is 0.5 to 10% by weight.
脂であり、炭素繊維の含有率が5〜25重量%である請
求項1に記載の電波吸収方法。3. The radio wave absorption method according to claim 1, wherein the matrix of the carbon fiber-containing composition is a resin, and the carbon fiber content is 5 to 25% by weight.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3153984A JPH088429B2 (en) | 1990-05-28 | 1991-05-28 | Radio wave absorption method |
| PCT/JP1991/001544 WO1992022193A1 (en) | 1991-05-28 | 1991-11-12 | Method for absorbing electromagnetic wave |
| EP91919176A EP0546182B1 (en) | 1991-05-28 | 1991-11-12 | Method for absorbing electromagnetic wave |
| US07/965,265 US5394149A (en) | 1991-05-28 | 1991-11-12 | Method of absorbing electromagnetic waves |
| DE69126784T DE69126784T2 (en) | 1991-05-28 | 1991-11-12 | METHOD FOR DAMPING ELECTROMAGNETIC WAVES |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2-137487 | 1990-05-28 | ||
| JP13748790 | 1990-05-28 | ||
| JP3153984A JPH088429B2 (en) | 1990-05-28 | 1991-05-28 | Radio wave absorption method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04297097A JPH04297097A (en) | 1992-10-21 |
| JPH088429B2 true JPH088429B2 (en) | 1996-01-29 |
Family
ID=26470787
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3153984A Expired - Lifetime JPH088429B2 (en) | 1990-05-28 | 1991-05-28 | Radio wave absorption method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH088429B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007108478A1 (en) * | 2006-03-20 | 2007-09-27 | Osaka Prefectural Government | Electromagnetic wave absorbing device and method for controlling electromagnetic wave absorption |
| JP6546717B2 (en) * | 2012-09-20 | 2019-07-17 | Jsr株式会社 | Electromagnetic wave absorbing composition and electromagnetic wave absorber |
| JP2015029220A (en) * | 2013-07-30 | 2015-02-12 | シヤチハタ株式会社 | Far field wave absorption method of polarization using wave absorbing material, far field wave absorption structure and method for adjusting wave absorption property of polarization |
| JP2015070113A (en) * | 2013-09-30 | 2015-04-13 | 京セラ株式会社 | Magnetic sheet and electronic device using the same |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58108603A (en) * | 1981-12-14 | 1983-06-28 | 清水 康敬 | Radio wave absorber and method of producing same |
| JPS58184799A (en) * | 1982-04-22 | 1983-10-28 | 日本電気株式会社 | Radio wave absorber composition |
| JPS58188193A (en) * | 1982-04-28 | 1983-11-02 | 住友電気工業株式会社 | radio wave absorber |
-
1991
- 1991-05-28 JP JP3153984A patent/JPH088429B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04297097A (en) | 1992-10-21 |
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| EXPY | Cancellation because of completion of term |