JPH09124342A - Crystalline chrysanthemum-patterned stone and its production - Google Patents
Crystalline chrysanthemum-patterned stone and its productionInfo
- Publication number
- JPH09124342A JPH09124342A JP30984395A JP30984395A JPH09124342A JP H09124342 A JPH09124342 A JP H09124342A JP 30984395 A JP30984395 A JP 30984395A JP 30984395 A JP30984395 A JP 30984395A JP H09124342 A JPH09124342 A JP H09124342A
- Authority
- JP
- Japan
- Prior art keywords
- chrysanthemum
- crystalline
- stone
- glaze
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 46
- 239000004575 stone Substances 0.000 title claims abstract description 44
- 241000723353 Chrysanthemum Species 0.000 claims abstract description 65
- 235000007516 Chrysanthemum Nutrition 0.000 claims abstract description 65
- 239000013078 crystal Substances 0.000 claims abstract description 33
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000004927 clay Substances 0.000 claims abstract description 7
- 239000010433 feldspar Substances 0.000 claims abstract description 7
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 6
- 238000000151 deposition Methods 0.000 claims abstract description 5
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 239000011505 plaster Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 13
- 238000002156 mixing Methods 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 238000001816 cooling Methods 0.000 abstract description 3
- 235000019353 potassium silicate Nutrition 0.000 abstract description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract description 2
- 235000015895 biscuits Nutrition 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 239000002801 charged material Substances 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 229910052602 gypsum Inorganic materials 0.000 abstract 1
- 239000010440 gypsum Substances 0.000 abstract 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011044 quartzite Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000003086 colorant Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000004570 mortar (masonry) Substances 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000014692 zinc oxide Nutrition 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000010437 gem Substances 0.000 description 2
- 229910001751 gemstone Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、釉と酸化物とによ
り、結晶釉として菊模様の結晶を析出し、固化して原石
状に形成して、宝石状態を醸し出すものを製造して、各
種身飾品、その他の装身具等の装飾物に供する結晶菊石
及び結晶菊石の製造方法に関するものである。ここで、
結晶釉とは、釉は一般に非晶質であるが、釉内に結晶を
包含させ、結晶が大きな場合は模様状を呈するものをい
う。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a glazed crystal and a chrysanthemum-patterned crystal that is precipitated as a crystal glaze and solidifies to form a rough ore to produce a gem-like state. The present invention relates to a crystal chrysanthemum stone used for ornaments such as ornaments and other accessories, and a method for producing the crystal chrysanthemum stone. here,
The crystal glaze is a material in which the glaze is generally amorphous, but the crystal is included in the glaze, and when the crystal is large, it has a pattern.
【０００２】[0002]
【従来の技術】従来の釉は、陶磁器製品の表面に施し、
これを焼成して、該陶磁器製品の表面に溶着した薄く比
較的均質な珪酸塩混合物である。化学的又は物理的性質
においてはガラス状を呈して硬く、強酸と強アルカリ以
外は不溶性であり、ガラスと同様に所定の化学組成を有
せず固溶体とも見られる。ガラスと同じく通常は肉眼的
には構造を視認しえない。なお、結晶釉や乳濁釉にあっ
ては顕微鏡又は肉眼で、その結晶が容易に視認されると
されている。2. Description of the Related Art Conventional glaze is applied to the surface of ceramic products,
This is a thin, relatively homogeneous silicate mixture that is fired and deposited on the surface of the ceramic product. In terms of chemical or physical properties, it is glassy and hard, insoluble except for strong acids and strong alkalis, and does not have a predetermined chemical composition like glass, and is also seen as a solid solution. As with glass, the structure is usually invisible to the naked eye. It should be noted that crystal glazes and emulsion glazes are said to be easily visible with a microscope or the naked eye.
【０００３】[0003]
【発明が解決しようとする課題】しかし、従来の釉は、
上述したとおり、陶磁器製品の表面に施釉し、焼成し
て、該陶磁器製品の表面をガラス状とし、硬く、強酸と
強アルカリ以外には不溶性か、又は僅かに溶解するのも
のであるから、一般に光沢を有し、表面は反射率が高
く、ガラスと同様に施釉されたそのものの結晶等の構造
は視認できない。さらに、結晶釉や乳濁釉等は顕微鏡又
は肉眼で結晶を容易に視認できるとはされているが、こ
れを装飾的に利用し実用化しうるものは、いまだ案出さ
れていない。However, the conventional glaze is
As described above, the surface of a ceramic product is glazed and fired to form a glass-like surface of the ceramic product, which is hard and insoluble except for strong acid and strong alkali, or slightly soluble, and thus generally It has a luster, the surface has a high reflectance, and the structure of its own crystal such as glazed glass is not visible. Further, although it is said that crystal glazes, emulsion glazes, etc. can easily visually recognize crystals with a microscope or the naked eye, no one has yet been devised that can be put to practical use by decoratively using the crystals.
【０００４】そこで、本発明は、釉原料と各種金属酸化
物とを混合した結晶菊石乾式調合物を、製造用容器内で
所定の熱処理をなし、釉内に装飾模様の菊模様を析出
し、固化し、原石状として結晶菊石の原石となして、宝
石状態を醸し出すものとして、各種装飾物品等として提
供することを目的とするものである。なお、ここでいう
結晶菊石とは、任意の釉原料と任意の金属酸化物とによ
り、結晶釉として菊模様を析出し表出して原石状にした
ものを意味する。Therefore, according to the present invention, a crystalline chrysanthemum stone dry formulation prepared by mixing a glaze material and various metal oxides is subjected to a predetermined heat treatment in a production container to deposit a decorative chrysanthemum pattern in the glaze. The object of the present invention is to provide a variety of decorative articles and the like, which are solidified and become a rough stone of crystalline chrysanthemum to give a gem state. In addition, the crystalline chrysanthemum stone here means that a chrysanthemum pattern is deposited and exposed as a crystalline glaze by using an arbitrary glaze material and an arbitrary metal oxide to form a rough stone.
【０００５】[0005]
【課題を解決するための手段】本発明は、上記問題点を
解決するために創作されたものであって、第一には、結
晶菊石であって、釉原料と金属酸化物とにより、釉に菊
模様の結晶を析出して固化させてなることを特徴とする
ものである。この第一の構成の結晶菊石においては、任
意の釉原料と任意の金属酸化物とを混合して、これを熱
的処理を施すことにより固化し、結晶内に菊模様を析出
してなる原石状のものを形成して、各種の装飾物品等に
供しうるものとする。The present invention was created in order to solve the above-mentioned problems, and, firstly, a crystalline chrysanthemum stone, which comprises a glaze material and a metal oxide, It is characterized in that chrysanthemum-shaped crystals are deposited on the glaze and solidified. In the crystal chrysanthemum stone of the first constitution, an arbitrary glaze material and an arbitrary metal oxide are mixed, and this is thermally treated to be solidified, and a chrysanthemum pattern is deposited in the crystal. A rough stone-like material can be formed and used for various decorative articles.
【０００６】また、第二には、第一の構成の結晶菊石に
おいて、金属酸化物が、亜鉛又はコバルト又はマンガン
又はチタン又はタングステン又は鉄でなることを特徴と
するものである。この第二の構成の結晶菊石において
は、菊模様の結晶は析出され、金属による各種の色彩の
ものとなり、より多くの身飾品、その他の装身具等の装
飾物品や、その他の分野にも供しうるものとする。Secondly, the crystalline chrysanthemum stone of the first structure is characterized in that the metal oxide is zinc, cobalt, manganese, titanium, tungsten, or iron. In the crystal chrysanthemum stone of the second structure, chrysanthemum-patterned crystals are deposited and become various colors of metal, and are also used for more ornaments, other ornamental articles such as jewelry, and other fields. Let's get it.
【０００７】また、第三には、結晶菊石の製造方法にお
いて、主成分たる長石と金属酸化物とでなる原料を、製
造用容器内へ収納し、高温加熱後、冷却して、釉に菊模
様の結晶を析出して結晶菊石を形成することを特徴とす
るものである。この第三の構成の結晶菊石の製造方法に
おいては、容易、的確に結晶釉内に菊模様を析出した原
石状の結晶菊石を製造しうるものとする。Thirdly, in the method for producing crystalline chrysanthemum, the raw material consisting of feldspar and metal oxide as main components is placed in a production container, heated at high temperature, cooled, and then made into a glaze. It is characterized in that chrysanthemum-patterned crystals are deposited to form crystalline chrysanthemum stones. In the method for producing a crystalline chrysanthemum stone of the third configuration, it is possible to easily and accurately produce a rough crystalline chrysanthemum stone in which a chrysanthemum pattern is deposited in the crystal glaze.
【０００８】また、第四には、第三の構成の結晶菊石の
製造方法において、金属酸化物が、亜鉛又はコバルト又
はマンガン又はチタン又はタングステン又は鉄でなるこ
とを特徴とするものである。この第四の結晶菊石の製造
方法においては、各種金属酸化物を主成分たる長石に混
合せしめて製造するので、各金属特有の色彩のものとし
て表出されて、より多くの装飾物品や、その他の分野に
も供しうるものとする。Fourthly, in the method for producing crystalline chrysanthemum stone of the third constitution, the metal oxide is zinc, cobalt, manganese, titanium, tungsten or iron. In the fourth method for producing crystalline chrysanthemum, since it is produced by mixing various metal oxides with feldspar as the main component, it is expressed as a color peculiar to each metal, and more decorative articles and It can also be used in other fields.
【０００９】さらに、第五には、第三又は第四の構成の
結晶菊石の製造方法において、製造用容器が、陶石と木
節粘土の泥漿を石膏型に入れて素焼してなることを特徴
とするものである。この第五の結晶菊石の製造方法にお
いては、前記結晶菊石の熱的条件がより適切なものとな
って、歩留まりのよい製造を可能とし、次工程の作業を
容易とする。Fifthly, in the method for producing crystalline chrysanthemum stone of the third or fourth constitution, the production container is made by putting clay of ceramic stone and kibushi clay in a plaster mold and bisquering. It is characterized by. In the fifth method for producing crystalline chrysanthemum stone, the thermal condition of the crystalline chrysanthemum stone is more appropriate, which enables production with high yield and facilitates the work of the next step.
【００１０】[0010]
【発明の実施の形態】以下引き続き、本発明の結晶菊石
及び結晶菊石の製造方法の要旨をさらに明確にするた
め、図面を利用して実施の形態としての一具体例を説明
する。図１ないし図５を利用して一具体例としての結晶
菊石の製造方法を説明する。まず、図１に示されるよう
に、結晶菊石を製造するための箱型の製造用容器１を製
造する。重量比で陶石７０％と木節粘土３０％とを調合
した上、これに重量比で水４０％と水硝子０．４％とを
加えて、ポットミルを使用して３０時間細磨する。そし
てその後、この泥漿化したものを箱型をした石膏型に流
し込む。次いで、自然乾燥後、７００℃で素焼きして箱
型の製造用容器１を製造する。BEST MODE FOR CARRYING OUT THE INVENTION In order to further clarify the gist of the crystalline chrysanthemum and the method for producing the crystalline chrysanthemum of the present invention, one specific example as an embodiment will be described below with reference to the drawings. A method of manufacturing crystalline chrysanthemum stone will be described with reference to FIGS. 1 to 5. First, as shown in FIG. 1, a box-shaped manufacturing container 1 for manufacturing crystalline chrysanthemum is manufactured. 70% by weight of pottery stone and 30% of kibushi clay are mixed, and then 40% by weight of water and 0.4% by weight of water glass are added thereto and finely ground for 30 hours using a pot mill. After that, the sludge is poured into a box-shaped plaster mold. Then, after being naturally dried, it is unglazed at 700 ° C. to manufacture the box-shaped manufacturing container 1.
【００１１】次に、結晶菊石乾式調合物４を製造する。
図２に示すように、乳鉢２の鉢開口部２１より、機台上
に設けたモータ３１と接続された乳棒３を自転させつ
つ、さらに、該乳鉢２内を回動させて、上記乳鉢２に入
れた粉末状の各種原料を、乾式細磨、すなわち、磨きつ
つかきまぜ混合させる。ここで、各種原料とは、主原料
として粉末状の長石と亜鉛華とをいい、その他にフリッ
トと珪石とがある。通常、重量比で、長石５０％、亜鉛
華２０％、フリット２０％、珪石１０％で構成される。
なお、金属酸化物は、亜鉛華に代えてコバルトをはじ
め、マンガン、チタン、タングステン、鉄等を使用して
もよく、いずれの金属酸化物によっても、菊模様の結晶
を析出し表出しえて、かつ、各種金属が発色する固有の
色彩と、製造条件とにより、各種の発色、とりわけ釉地
の部分が鮮明な色彩で発色し、かつ、菊模様部分は、該
釉地色との混合色で発色し、変化のある色彩で表出され
ることになる。そして、上記各種原料を１０時間混合す
ると、結晶菊石乾式調合物４ができあがる。なお、フリ
ットは、温度調整用として、また、珪石は熱膨脹調整用
として機能するので、作業操作等で場合によっては必ず
しも使用する必要がない。Next, a crystalline chrysanthemum dry formulation 4 is produced.
As shown in FIG. 2, while rotating the pestle 3 connected to the motor 31 provided on the machine base through the bowl opening 21 of the mortar 2, the mortar 2 is further rotated to rotate the mortar 2 The various powdery raw materials put in the above are dry finely ground, that is, mixed by stirring while polishing. Here, various raw materials refer to powdered feldspar and zinc white as main raw materials, and in addition, there are frit and silica stone. Usually, it is composed of feldspar 50%, zinc white 20%, frit 20%, and silica 10% by weight.
The metal oxide may be cobalt, instead of zinc white, and may be manganese, titanium, tungsten, iron, or the like, and by any metal oxide, a crystal having a chrysanthemum pattern can be deposited and exposed. And, depending on the unique color that various metals develop, and manufacturing conditions, various colors, especially the glaze part develops a clear color, and the chrysanthemum pattern part is a mixed color with the glaze color. It will be colored and will be expressed in varying colors. Then, the above-mentioned various raw materials are mixed for 10 hours, and the crystalline chrysanthemum dry formulation 4 is completed. Since the frit functions as a temperature control and the silica stone functions as a thermal expansion control, it is not always necessary to use the frit in a work operation or the like.
【００１２】次に、図３及び図４に示すように、上記箱
型の製造用容器１に該結晶菊石乾式調合物４を流し込ん
で、箱型の製造用容器１の容器開口部１１付近に至るま
で満たすようにする。そして、その箱型の製造用容器１
を、図示しない電気炉に入れて１１００〜１３００℃の
温度で４０分間熱処理する。その後、箱型の製造用容器
１を次のようにして冷却させていく。まず、人工的に１
時間を要して１０５０℃まで温度を徐々に下げ、さら
に、４時間かけて温度を徐々に１０００℃まで下げる。
その後、５０時間を要して自然冷却を行うと、結晶菊石
乾式調合物４は、前記箱型の製造用容器１内で図３に示
す固化線Ｌ以下で固まって、菊模様５１が釉地５２に析
出した結晶菊石原石５を配設したものとなり、これを窯
出する。次に、箱型の製造用容器１のみを図示しないグ
ラインダーを使用してカットすると、菊模様５１が釉地
５２に析出した結晶菊石原石５となる。これを図示しな
いグラインダー、水ペーパー等で形状を整えつつ、酸化
クローム（液状）等を加えると、図５に示されるような
結晶菊石６を製造できる。なお、前記高熱の１１００〜
１３００℃の範囲内で菊模様５１が釉地５２内で適切に
析出し、また、発色も適宜になしうる。因に前記具体例
においては、略１２００℃で加熱して釉地５２は濃紺色
で、菊模様は青味がかった白色で、釉内へ結晶釉として
鮮明に表出された。Next, as shown in FIG. 3 and FIG. 4, the crystalline chrysanthemum dry formulation 4 is poured into the box-shaped manufacturing container 1 and the vicinity of the container opening 11 of the box-shaped manufacturing container 1. To be satisfied. Then, the box-shaped manufacturing container 1
Is placed in an electric furnace (not shown) and heat-treated at a temperature of 1100 to 1300 ° C. for 40 minutes. Then, the box-shaped manufacturing container 1 is cooled as follows. First, artificially 1
The temperature is gradually lowered to 1050 ° C over a period of time, and further gradually lowered to 1000 ° C over 4 hours.
After that, when it is naturally cooled for 50 hours, the crystalline chrysanthemum dry formulation 4 is solidified in the box-shaped production container 1 below the solidification line L shown in FIG. 3, and the chrysanthemum pattern 51 is glazed. The crystal Kikuishi ore 5 deposited on the ground 52 is arranged, and this is removed from the kiln. Next, when only the box-shaped manufacturing container 1 is cut using a grinder (not shown), the chrysanthemum pattern 51 becomes the crystalline chrysanthemum stone 5 deposited on the glaze 52. By adding chrome oxide (liquid) or the like while adjusting the shape with a grinder, water paper or the like (not shown), crystalline chrysanthemum stone 6 as shown in FIG. 5 can be manufactured. The high heat of 1100 to 100
The chrysanthemum pattern 51 is appropriately deposited in the glaze 52 within the range of 1300 ° C., and color development can be appropriately performed. In the above specific example, the glaze 52 was dark blue by heating at about 1200 ° C., the chrysanthemum pattern was bluish white, and was clearly expressed in the glaze as a crystalline glaze.
【００１３】上記製造過程によりなる結晶菊石６は、図
５に示すとおり、平板状であって、内部にランダムに菊
模様の結晶が多数析出して形成されている。従って、該
結晶菊石６を、ダイヤモンドカッターで切断し、グライ
ンダー１００番、２００番で形を造り、水ペーパー２４
０番、４００番、６００番、１２００番、セロックスで
磨くことにより光沢が出て、指輪をはじめ、帯止め、ブ
ローチ、カフスボタン等の装飾物の部材として、またそ
の他の分野に使用することが可能となる。As shown in FIG. 5, the crystal chrysanthemum stone 6 produced by the above-mentioned manufacturing process has a flat plate shape and is formed by randomly depositing a large number of chrysanthemum crystal grains therein. Therefore, the crystal chrysanthemum stones 6 are cut with a diamond cutter, shaped with a grinder No. 100 and No. 200, and water paper 24
No. 400, No. 400, No. 600, No. 1200, glossy by polishing with Celox, it can be used as a member of ornaments such as rings, bandages, brooches, cufflinks, and other fields. It will be possible.
【００１４】なお、本発明に係る結晶菊石及び結晶菊石
の製造方法は、前記本発明の目的にかなうものであれ
ば、使用材料、製造容器の形状、大きさ、材質及び製造
過程の具体的内容等、さらに、具体的な使用方法等は、
前記した課題、解決手段及び後記する発明の効果が達成
される範囲内においてそれぞれ任意に定められてよく、
これらの変更はいずれも本発明の要旨を何ら変更するも
のでないことは申すまでもない。The crystalline chrysanthemum stone and the method for producing the crystalline chrysanthemum stone according to the present invention can be used as long as they meet the purpose of the present invention. Content, etc., and specific usage etc.
The above-mentioned problems, the solving means, and the effects of the invention described below may be arbitrarily determined within a range in which they are achieved,
It goes without saying that any of these changes does not change the gist of the present invention.
【００１５】[0015]
【発明の効果】以上詳細に説明したように、本発明は、
主成分たる長石と各種金属酸化物とでなる原料を、製造
用容器内へ収納し、高温加熱後、冷却して、釉に菊模様
の結晶を析出して結晶菊石を形成する結晶菊石の製造方
法によれば、容易、的確に結晶釉内に菊模様を析出した
原石状の結晶菊石を製造しうるものとする。また、任意
の釉原料と任意の金属酸化物とを混合して、これを熱的
処理を施すことにより固化し、釉を菊模様として析出し
て原石状のものを形成してなる結晶菊石とすることによ
り、任意形状に切断する等によって、各種金属固有の色
彩と製造条件により、各種に発色した色彩を帯びた各種
の装飾物品等に供しうるものとする。以上説明したよう
に、本発明は、従来にない独特の効果を奏し、まことに
実用的で優れた発明である。As described in detail above, the present invention provides
A crystalline chrysanthemum stone that forms a crystalline chrysanthemum stone by storing a raw material consisting of feldspar, which is the main component, and various metal oxides in a manufacturing container, heating it at high temperature, and then cooling it to deposit chrysanthemum-patterned crystals on the glaze. According to the manufacturing method of 1., a rough crystal chrysanthemum stone in which a chrysanthemum pattern is deposited in the crystal glaze can be easily and accurately manufactured. A crystalline chrysanthemum stone formed by mixing an arbitrary glaze material and an arbitrary metal oxide, solidifying the mixture by thermal treatment, and depositing the glaze in a chrysanthemum pattern to form a rough ore. By this, it can be used for various decorative articles and the like that are colored in various colors depending on the color unique to various metals and manufacturing conditions by cutting into arbitrary shapes. As described above, the present invention has unique effects that have never been seen before, and is a practical and excellent invention.
【図１】結晶菊石の製造に使用する箱型の製造用容器の
斜視図である。FIG. 1 is a perspective view of a box-shaped manufacturing container used for manufacturing crystalline chrysanthemum.
【図２】結晶菊石の製造過程を一部破断して示す正面図
である。FIG. 2 is a front view showing a partially broken view of a production process of crystalline chrysanthemum stone.
【図３】結晶菊石の製造過程を一部破断して示す正面図
である。FIG. 3 is a front view showing a partially broken process of manufacturing a crystalline chrysanthemum stone.
【図４】結晶菊石の製造過程を示す平面図である。FIG. 4 is a plan view showing a manufacturing process of crystalline chrysanthemums.
【図５】結晶菊石の結晶構造を示す写真である。FIG. 5 is a photograph showing the crystal structure of crystalline chrysanthemum.
１ 製造用容器 １１ 容器開口部 ２ 乳鉢 ２１ 鉢開口部 ３ 乳棒 ４ 結晶菊石乾式調合物 ５ 結晶菊石原石 ５１ 菊模様 ６ 結晶菊石 1 Manufacturing Container 11 Container Opening 2 Mortar 21 Bowl Opening 3 Pestle 4 Crystalline Chrysanthemum Dry Formula 5 Crystalline Kikuishi Gemstone 51 Chrysanthemum Pattern 6 Crystal Chrysanthemum
Claims (5)
様の結晶を析出して固化させてなることを特徴とする結
晶菊石。1. A crystalline chrysanthemum stone, which is obtained by depositing and solidifying chrysanthemum-patterned crystals on a glaze by using a glaze raw material and a metal oxide.
ンガン又はチタン又はタングステン又は鉄でなることを
特徴とする請求項１記載の結晶菊石。2. The crystalline chrysanthemum stone according to claim 1, wherein the metal oxide is zinc, cobalt, manganese, titanium, tungsten, or iron.
料を、製造用容器内へ収納し、高温加熱後、冷却して、
釉に菊模様の結晶を析出して結晶菊石を形成することを
特徴とする結晶菊石の製造方法。3. A raw material composed of feldspar, which is a main component, and a metal oxide is placed in a manufacturing container, heated at high temperature, and then cooled,
A method for producing a crystalline chrysanthemum, comprising depositing chrysanthemum-shaped crystals on a glaze to form a crystalline chrysanthemum.
ンガン又はチタン又はタングステン又は鉄でなることを
特徴とする請求項３記載の結晶菊石の製造方法。4. The method for producing crystalline chrysanthemum stone according to claim 3, wherein the metal oxide is zinc, cobalt, manganese, titanium, tungsten, or iron.
石膏型に入れて素焼してなることを特徴とする請求項３
又は４記載の結晶菊石の製造方法。5. The production container is made by putting clay of clay and kibushi clay in a plaster mold and bisquering.
Alternatively, the method for producing crystalline chrysanthemum stone according to item 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30984395A JP3187308B2 (en) | 1995-11-01 | 1995-11-01 | Crystal chrysanthemum and method for producing crystal chrysanthemum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30984395A JP3187308B2 (en) | 1995-11-01 | 1995-11-01 | Crystal chrysanthemum and method for producing crystal chrysanthemum |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH09124342A true JPH09124342A (en) | 1997-05-13 |
| JP3187308B2 JP3187308B2 (en) | 2001-07-11 |
Family
ID=17997955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30984395A Expired - Fee Related JP3187308B2 (en) | 1995-11-01 | 1995-11-01 | Crystal chrysanthemum and method for producing crystal chrysanthemum |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3187308B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113354284A (en) * | 2021-06-10 | 2021-09-07 | 佛山欧神诺陶瓷有限公司 | Ceramic glaze material with seven-color halo effect, ceramic rock plate and preparation method and application thereof |
| CN114262210A (en) * | 2021-12-17 | 2022-04-01 | 佛山欧神诺陶瓷有限公司 | Foamed ceramic with high sunlight reflection performance and heat insulation and preservation and preparation method thereof |
| CN115947541A (en) * | 2023-01-03 | 2023-04-11 | 蒙娜丽莎集团股份有限公司 | Cerium-tin-zinc series crystal glaze rich in color particles, ceramic tile and preparation method thereof |
-
1995
- 1995-11-01 JP JP30984395A patent/JP3187308B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113354284A (en) * | 2021-06-10 | 2021-09-07 | 佛山欧神诺陶瓷有限公司 | Ceramic glaze material with seven-color halo effect, ceramic rock plate and preparation method and application thereof |
| CN114262210A (en) * | 2021-12-17 | 2022-04-01 | 佛山欧神诺陶瓷有限公司 | Foamed ceramic with high sunlight reflection performance and heat insulation and preservation and preparation method thereof |
| CN115947541A (en) * | 2023-01-03 | 2023-04-11 | 蒙娜丽莎集团股份有限公司 | Cerium-tin-zinc series crystal glaze rich in color particles, ceramic tile and preparation method thereof |
| CN115947541B (en) * | 2023-01-03 | 2023-12-08 | 蒙娜丽莎集团股份有限公司 | Cerium-tin-zinc system crystal glaze rich in colored particles, ceramic tile and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3187308B2 (en) | 2001-07-11 |
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