JPH09143793A - Aluminum alloy surface treatment method - Google Patents

Aluminum alloy surface treatment method

Info

Publication number
JPH09143793A
JPH09143793A JP32246795A JP32246795A JPH09143793A JP H09143793 A JPH09143793 A JP H09143793A JP 32246795 A JP32246795 A JP 32246795A JP 32246795 A JP32246795 A JP 32246795A JP H09143793 A JPH09143793 A JP H09143793A
Authority
JP
Japan
Prior art keywords
alumite
aluminum alloy
clear coating
film
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP32246795A
Other languages
Japanese (ja)
Inventor
Shinichi Hosaka
眞一 穂坂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Avionics Co Ltd
Original Assignee
Nippon Avionics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Avionics Co Ltd filed Critical Nippon Avionics Co Ltd
Priority to JP32246795A priority Critical patent/JPH09143793A/en
Publication of JPH09143793A publication Critical patent/JPH09143793A/en
Pending legal-status Critical Current

Links

Landscapes

  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

(57)【要約】 【課題】 アルミニウム合金に装飾性、耐食性を付与す
るためにアルマイト処理しその後にクリヤー塗装を行う
場合に、アルマイト皮膜上のクリヤー塗膜の透明性、光
沢性を十分に確保することができる表面処理方法を提供
する。 【解決手段】 a.被処理物の表面を前処理した後、
b.硫酸約20重量%の溶液中に浸漬し、100〜20
0A/m2の電流密度で陽極処理することによってアル
マイト皮膜を形成し、c.このアルマイト皮膜を温水中
で超音波洗浄し、d.さらにメチルアルコールに浸漬し
てから乾燥し、e.クリヤー塗装を行う。すなわち、電
解浴(アルマイト処理浴)として硫酸浴を用い電流密度
を大にして皮膜の多孔質の孔径を大きくし、温浴の超音
波洗浄による硫酸イオンの除去を容易にした。さらにメ
タノール洗浄することにより透明性のよいクリヤー塗膜
を得るようにした。
(57) [Abstract] [Problem] When alumite treatment is applied to an aluminum alloy to impart decorativeness and corrosion resistance, and then clear coating is performed, sufficient transparency and gloss of the clear coating film on the alumite film are secured. Provided is a surface treatment method capable of SOLUTION: a. After pretreatment of the surface of the object to be treated,
b. Immerse in a solution of about 20% by weight of sulfuric acid,
Forming an alumite coating by anodizing at a current density of 0 A / m 2 , c. This alumite film is ultrasonically cleaned in warm water, d. Further dipped in methyl alcohol and dried, e. Clear coating is performed. That is, a sulfuric acid bath was used as an electrolytic bath (alumite treatment bath) to increase the current density to increase the pore size of the porous film and facilitate the removal of sulfate ions by ultrasonic cleaning of a warm bath. Further, it was washed with methanol to obtain a clear coating film having good transparency.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明が属する技術分野】本発明は、アルミニウムある
いはアルミニウム合金の表面をアルマイト処理した後
に、クリヤー塗装を施す表面処理方法に関するものであ
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a surface treatment method of applying a clear coating after alumite-treating the surface of aluminum or an aluminum alloy.

【0002】[0002]

【従来の技術】アルミニウムやアルミニウム合金(以下
単にアルミニウム合金という)の表面に装飾性や耐食性
を付与するための方法として、アルミニウム合金を硫酸
浴中に浸漬しアルマイト処理(陽極酸化処理)すること
が公知である。
2. Description of the Related Art As a method for imparting decorativeness and corrosion resistance to the surface of aluminum or an aluminum alloy (hereinafter simply referred to as an aluminum alloy), the aluminum alloy is immersed in a sulfuric acid bath and anodized (anodized). It is known.

【0003】ここに使用する硫酸浴の一般的な組成は、
硫酸15〜20重量%溶液であり、アルミニウム合金を
この浴に浸漬して陽極に接続し電解処理を行うことでア
ルミニウム合金の光沢あるアルマイト皮膜が得られるも
のである。またこのアルマイト処理を行った後に、この
アルマイト皮膜の耐久性を得るためにクリヤー塗装を行
うことも公知である。すなわちアルマイト皮膜の上に透
明なアクリル樹脂クリヤー塗料を塗布するものである。
The general composition of the sulfuric acid bath used here is:
It is a solution containing 15 to 20% by weight of sulfuric acid, which is obtained by immersing an aluminum alloy in this bath, connecting it to an anode and performing electrolytic treatment to obtain a glossy alumite coating of the aluminum alloy. It is also known to perform clear coating in order to obtain the durability of the alumite coating after performing the alumite treatment. That is, a transparent acrylic resin clear paint is applied on the alumite film.

【0004】[0004]

【従来技術の問題点】しかしながらこの従来の技術で
は、クリヤー塗装した塗膜の外観に曇りが生じ易く、時
には部分的にツブ状の白濁が生じるという問題があっ
た。その原因は次にように考えられている。すなわちの
陽極酸化処理(アルマイト処理)で得られたアルマイト
皮膜は多孔質であるため、電解液である硫酸がこの多孔
質の小孔内にできる空隙に残留し、クリヤー塗装した後
にその残留硫酸が小孔内から出てクリヤー塗膜に曇りや
白濁を生じさせる、というものである。
However, this conventional technique has a problem that the clear coated film is liable to be fogged and sometimes partially has a turbid white turbidity. The cause is considered as follows. That is, since the anodized film obtained by the anodizing treatment (alumite treatment) is porous, sulfuric acid as an electrolytic solution remains in the voids formed in the small pores of the porous material, and the residual sulfuric acid is left behind after clear coating. It goes out from the small holes and causes clouding or cloudiness in the clear coating film.

【0005】従ってこのクリヤー塗膜に曇りや白濁が生
じた場合は、再度表面処理を行う必要があった。この再
処理の一例としては、そのクリヤー塗膜を除去しアルマ
イト皮膜表面を露出させてからラッカーやシンナに浸漬
処理し、その後に90〜100℃の湯水洗浄を行った後
に再度クリヤー塗装を行う方法がある。しかしこの湯水
による洗浄にしても、多孔質の小孔内へ深く侵入した硫
酸を完全に除去するのは非常困難であり、クリヤー塗装
の曇りや白濁を確実に防止するのは困難であった。
Therefore, when the clear coating film becomes cloudy or cloudy, it is necessary to perform the surface treatment again. As an example of this re-treatment, a method of removing the clear coating film to expose the surface of the alumite coating, immersing it in lacquer or thinner, and then performing hot-water washing at 90 to 100 ° C. and then performing clear coating again There is. However, even with this washing with hot water, it is extremely difficult to completely remove the sulfuric acid that has penetrated deeply into the porous small holes, and it is difficult to reliably prevent fogging and clouding of the clear coating.

【0006】[0006]

【発明の目的】本発明はこのような事情に鑑みなされた
ものであり、アルミニウム合金に装飾性、耐食性を付与
するためにアルマイト処理しその後にクリヤー塗装を行
う場合に、アルマイト皮膜上のクリヤー塗膜の透明性、
光沢性を十分に確保することができる表面処理方法を提
供することを目的とする。
SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and in the case where an aluminum alloy is anodized for the purpose of imparting decorative properties and corrosion resistance, and then clear coating is performed, a clear coating on an alumite film is performed. Membrane transparency,
It is an object of the present invention to provide a surface treatment method capable of ensuring sufficient glossiness.

【0007】[0007]

【発明の構成】本発明によればこの目的は、アルミニウ
ムまたはアルミニウム合金からなる被処理物の表面にア
ルマイト皮膜を形成した後、このアルマイト皮膜にクリ
ヤー塗装を行うアルミニウム合金の表面処理方法におい
て、 a.前記被処理物の表面を前処理した後、 b.硫酸約20重量%の溶液中に浸漬し、100〜20
0A/m2の電流密度で陽極処理することによってアル
マイト皮膜を形成し、 c.このアルマイト皮膜を温水中で超音波洗浄し、 d.さらにメチルアルコールに浸漬してから乾燥し、 e.クリヤー塗装を行う、 ことを特徴とするアルミニウム合金の表面処理方法によ
り達成される。
According to the present invention, an object of the present invention is to provide a surface treatment method for an aluminum alloy, comprising forming an alumite coating on the surface of an object to be treated made of aluminum or an aluminum alloy and then performing clear coating on the alumite coating. . After pre-treating the surface of the object to be treated, b. Immerse in a solution of about 20% by weight of sulfuric acid,
Forming an alumite coating by anodizing at a current density of 0 A / m 2 , c. Ultrasonically clean the alumite film in warm water, d. Further dipping in methyl alcohol and drying, e. This is achieved by a method for surface treatment of an aluminum alloy, which is characterized by performing clear coating.

【0008】すなわち本発明は、電解浴(アルマイト処
理浴)として硫酸浴を用い電流密度を大にして皮膜の多
孔質の孔径を大きくし、温浴の超音波洗浄による硫酸イ
オンの除去を容易にした。そしてさらにメタノール洗浄
することにより透明性のよいクリヤー塗膜塗膜を得るよ
うにしたものである。
That is, according to the present invention, a sulfuric acid bath is used as an electrolytic bath (alumite treatment bath) to increase the current density to increase the pore size of the porous film and facilitate the removal of sulfate ions by ultrasonic cleaning of a warm bath. . Then, by further washing with methanol, a clear coating film having good transparency can be obtained.

【0009】[0009]

【発明の実施の態様】以下に本発明の処理方法を具体的
に説明する。図1は本発明の一実施態様の処理工程を示
す図である。
BEST MODE FOR CARRYING OUT THE INVENTION The processing method of the present invention will be specifically described below. FIG. 1 is a diagram showing the processing steps of one embodiment of the present invention.

【0010】まずアルミニウム合金の被処理物を準備し
(図1のステップ100)、これに脱脂やエッチング処
理など所定の前処理を施して表面に付着している汚れや
油脂類を除去する(ステップ102)。そして本発明に
係わる陽極酸化処理浴中で、アルミニウム合金を陽極に
接続しアルマイト処理を行う(ステップ104)。この
溶液は、約20重量%の硫酸浴であり、この浴を用いて
孔径の大きい多孔質のアルマイト皮膜を形成するため、
電流密度を大きくて直流100〜200A/m2で処理
することがこの発明の1つの特徴である。
First, an object to be treated of an aluminum alloy is prepared (step 100 in FIG. 1) and subjected to a predetermined pretreatment such as degreasing or etching to remove dirt and oils and fats adhering to the surface (step). 102). Then, in the anodizing bath according to the present invention, the aluminum alloy is connected to the anode and anodized (step 104). This solution is a sulfuric acid bath of about 20% by weight, which is used to form a porous alumite film having a large pore size.
It is one of the features of the present invention that the current density is increased and the direct current is processed at 100 to 200 A / m 2 .

【0011】すなわち多孔質の孔内に入った硫酸液ある
いは硫酸イオンを次工程の洗浄で除去し易くするため、
孔径を大きくする。孔内の硫酸を除去するための洗浄工
程としては、40℃〜50℃の温水での超音波洗浄が適
する(ステップ106)。この洗浄工程ではさらにメタ
ノールに浸漬する。このメタノール浸漬により小孔内に
残留する硫酸をさらに確実に除去することができる(ス
テップ108)。その後のクリヤー塗装を行えば(ステ
ップ110)、透明で光沢感のある塗膜が得られる。
That is, in order to make it easier to remove the sulfuric acid solution or the sulfuric acid ions that have entered the porous pores by the washing in the next step,
Increase the pore size. As a cleaning process for removing the sulfuric acid in the holes, ultrasonic cleaning with hot water at 40 ° C to 50 ° C is suitable (step 106). In this washing step, the substrate is further immersed in methanol. The sulfuric acid remaining in the small holes can be more surely removed by this methanol immersion (step 108). If clear coating is performed thereafter (step 110), a transparent and glossy coating film can be obtained.

【0012】[0012]

【実施例1】アルミニウム合金2024材を被処理材物
とし、これを前処理としてメチレンクロライドに浸漬
し、3分間有機溶剤脱脂処理した。その後に、非エッチ
ングアルカリ脱脂剤浴中に10分間浸漬してさらに脱脂
処理を行った。
Example 1 An aluminum alloy 2024 material was used as a material to be treated, and as a pretreatment, it was immersed in methylene chloride and subjected to an organic solvent degreasing treatment for 3 minutes. Then, it was immersed in a non-etching alkaline degreasing agent bath for 10 minutes for further degreasing treatment.

【0013】このように前処理した被処理物を、20重
量%の硫酸浴に浸し、電流密度を30〜230A/m2
に変化させつつ電解時間を15〜80分に変化させてア
ルマイト処理を行った。その後直ちに40℃の温水で5
分間超音波洗浄し、さらにメチルアルコール液に浸漬し
て洗浄してから乾燥した。その上に熱硬化性のアクリル
樹脂クリヤーを塗布した。ここに用いるクリヤー塗料と
しては、例えば日本ペイント株式会社製造の商品名「ス
ーパーラック」が適する。この時のアルマイト処理条件
と塗膜の仕上がり外観を表1に示した。
The object thus pretreated is immersed in a 20 wt% sulfuric acid bath and the current density is 30 to 230 A / m 2.
The alumite treatment was performed while changing the electrolysis time to 15 to 80 minutes while changing the temperature to 1. Immediately afterwards, 5 with warm water at 40 ° C
It was ultrasonically cleaned for a minute, further immersed in a methyl alcohol solution for cleaning, and then dried. A thermosetting acrylic resin clear was applied thereon. As the clear paint used here, for example, the product name “Super Rack” manufactured by Nippon Paint Co., Ltd. is suitable. Table 1 shows the alumite treatment conditions and the finished appearance of the coating film at this time.

【0014】[0014]

【表1】 [Table 1]

【0015】その結果、電流密度100〜200Am2
で、良好な透明性と光沢性のあるクリヤー塗膜が得られ
ることが解った。これは電流密度が高いとアルマイト皮
膜の孔径が大きくなり、孔内に入った硫酸液を洗浄によ
り除去し易くなり、そのため塗膜の透明性が向上するも
のと考えられる。
As a result, the current density is 100 to 200 Am 2
It was found that a clear coating film having good transparency and gloss can be obtained. It is considered that when the current density is high, the pore diameter of the alumite coating becomes large, and the sulfuric acid solution that has entered the pores is easily removed by washing, and therefore the transparency of the coating film is improved.

【0016】[0016]

【実施例2】実施例1と同様に脱脂のための前処理を行
った後に、一定の電流密度100A/m2で、電解時間
を15〜80分に変化させてアルマイト処理した。その
後直ちに超音波洗浄水の温度が常温、40℃、50℃の
場合にそれぞれ超音波洗浄時間を1、3、5、10、1
5分に変化させて洗浄した。その後、5秒間メタノール
に浸漬し、乾燥した後クリヤー塗装を行った。この時の
処理条件と塗膜仕上がり外観を表2に示した。
Example 2 After pretreatment for degreasing was carried out in the same manner as in Example 1, the electrolysis time was changed to 15 to 80 minutes at a constant current density of 100 A / m 2 , and alumite treatment was performed. Immediately thereafter, when the temperature of the ultrasonic cleaning water is room temperature, 40 ° C. and 50 ° C., the ultrasonic cleaning time is 1, 3, 5, 10, 1 respectively.
It was changed to 5 minutes and washed. Then, it was immersed in methanol for 5 seconds, dried and then subjected to clear coating. Table 2 shows the processing conditions and the appearance of the finished coating film at this time.

【0017】[0017]

【表2】 [Table 2]

【0018】この結果、透明性塗光沢性のある良好なク
リヤー仕上げを得るには、電解時間が長くなるほど超音
波洗浄時間を長くする必要があることが解った。またこ
の超音波洗浄時間は、超音波洗浄水が常温の時アルマイ
ト皮膜1μ当たり0.5分以上行うと好ましい結果が得
られることも解った。
As a result, it was found that in order to obtain a good clear finish having a transparent coating gloss, it is necessary to lengthen the ultrasonic cleaning time as the electrolysis time becomes longer. Further, it was also found that this ultrasonic cleaning time gives preferable results when the ultrasonic cleaning water is at room temperature for 0.5 minutes or more per 1 μm of the alumite coating.

【0019】また、洗浄水の温度を上げることにより、
透明性のあるクリヤー仕上がり外観を得るために必要な
洗浄時間を短くできることも解った。このことから、ア
ルマイト処理でできた小孔に入った液あるいは硫酸イオ
ンを孔外に排出させるためには、超音波洗浄水の温度を
高くすることが有効であることが解る。例えば40℃の
場合はアルマイト皮膜1μ当たり0.3分以上、50℃
の場合はアルマイト皮膜1μ当たり0.1分以上超音波
洗浄を行うことで好ましい結果が得られる。なお60℃
以上になると温湯中に気泡が発生し、超音波の伝波が妨
害されるので、温水は60℃未満、好ましくは50℃以
下にすべきである。
By increasing the temperature of the washing water,
It was also found that the cleaning time required to obtain a transparent clear finish can be shortened. From this, it can be understood that it is effective to raise the temperature of the ultrasonic cleaning water in order to discharge the liquid or sulfate ion that has entered the small holes formed by the alumite treatment to the outside of the holes. For example, at 40 ° C, 0.3 min or more per 1μ of alumite coating, 50 ° C
In this case, a preferable result can be obtained by performing ultrasonic cleaning for 0.1 minute or more per 1 μ of the alumite film. 60 ℃
In the above case, bubbles are generated in the hot water and the propagation of ultrasonic waves is disturbed, so the temperature of the hot water should be lower than 60 ° C, preferably 50 ° C or lower.

【0020】[0020]

【実施例4】実施例1の前処理により脱脂を行った後、
電流密度100〜200A/m2、電解時間20〜35
分にてアルマイト処理した。その後直ちに40℃温水に
て5分間の超音波洗浄した後、5秒間のメタノール浸漬
を行ったものとメタノール浸漬をしないものについてク
リヤー塗装の仕上がり外観を比較した。この結果を表4
に示す。
Example 4 After degreasing by the pretreatment of Example 1,
Current density 100-200 A / m 2 , electrolysis time 20-35
Anodized in minutes. Immediately thereafter, ultrasonic cleaning was carried out for 5 minutes in warm water at 40 ° C., and then the finish appearance of clear coating was compared between those subjected to methanol immersion for 5 seconds and those not subjected to methanol immersion. Table 4 shows the results.
Shown in

【0021】[0021]

【表4】 [Table 4]

【0022】その結果メタノール浸漬することで、超音
波洗浄水の水洗ジミが発生しなくなり外観上好ましい仕
上がり状態が得られた。
As a result, the immersion in methanol did not cause water-washing stains in the ultrasonic cleaning water, resulting in a favorable finished appearance.

【0023】[0023]

【発明の効果】請求項1の発明は以上のように、アルミ
ニウムまたはアルミニウム合金からなる被処理物を硫酸
20重量%の溶液内で、電流密度100〜200A/m
2でアルマイト処理するから、アルマイト処理で表面に
できる多孔質のアルマイト皮膜の小孔を大きくすること
ができる。
As described above, according to the first aspect of the present invention, an object to be treated made of aluminum or aluminum alloy is treated in a solution containing 20% by weight of sulfuric acid at a current density of 100 to 200 A / m.
Since the alumite treatment is performed in 2 , it is possible to enlarge the small pores of the porous alumite coating formed on the surface by the alumite treatment.

【0024】このためこの小孔内に残留する硫酸を、そ
の後の温水による超音波洗浄とメチルアルコール浸漬に
より確実に除去することができる。従ってこのアルマイ
ト皮膜にクリヤー塗装を施せば、このクリヤー塗膜に曇
りやツブ状の白濁が発生せず、長期間に亘って透明で光
沢性のある美しい外観を保持させることが可能である。
また前処理は脱脂処理およびエッチング処理の少なくと
も一方を含む(請求項2)。ここに超音波洗浄は60℃
以下特に40〜50℃の温水で行うのが望ましい。
Therefore, the sulfuric acid remaining in the small holes can be reliably removed by subsequent ultrasonic cleaning with warm water and immersion in methyl alcohol. Therefore, by applying a clear coating to the alumite coating, it is possible to maintain a transparent, glossy and beautiful appearance for a long period of time without causing clouding or turbid white turbidity in the clear coating.
The pretreatment includes at least one of degreasing treatment and etching treatment (claim 2). Ultrasonic cleaning here 60 ℃
In particular, it is desirable to carry out with warm water of 40 to 50 ° C.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一実施態様の処理工程を示す図FIG. 1 is a diagram showing processing steps of an embodiment of the present invention.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 アルミニウムまたはアルミニウム合金か
らなる被処理物の表面にアルマイト皮膜を形成した後、
このアルマイト皮膜にクリヤー塗装を行うアルミニウム
合金の表面処理方法において、 a.前記被処理物の表面を前処理した後、 b.硫酸約20重量%の溶液中に浸漬し、100〜20
0A/m2の電流密度で陽極処理することによってアル
マイト皮膜を形成し、 c.このアルマイト皮膜を温水中で超音波洗浄し、 d.さらにメチルアルコールに浸漬してから乾燥し、 e.クリヤー塗装を行う、 ことを特徴とするアルミニウム合金の表面処理方法。
1. After forming an alumite coating on the surface of an object to be treated made of aluminum or an aluminum alloy,
In the surface treatment method for an aluminum alloy, the clear coating is applied to the alumite coating, comprising: a. After pre-treating the surface of the object to be treated, b. Immerse in a solution of about 20% by weight of sulfuric acid,
Forming an alumite coating by anodizing at a current density of 0 A / m 2 , c. Ultrasonically clean the alumite film in warm water, d. Further dipping in methyl alcohol and drying, e. A method for surface treatment of an aluminum alloy, which comprises performing clear coating.
【請求項2】 請求項1の工程aにおいて、前処理は脱
脂処理およびエッチング処理の少なくとも一方を含むア
ルミニウム合金の表面処理方法。
2. The surface treatment method for an aluminum alloy according to claim 1, wherein the pretreatment includes at least one of degreasing treatment and etching treatment.
JP32246795A 1995-11-17 1995-11-17 Aluminum alloy surface treatment method Pending JPH09143793A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP32246795A JPH09143793A (en) 1995-11-17 1995-11-17 Aluminum alloy surface treatment method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP32246795A JPH09143793A (en) 1995-11-17 1995-11-17 Aluminum alloy surface treatment method

Publications (1)

Publication Number Publication Date
JPH09143793A true JPH09143793A (en) 1997-06-03

Family

ID=18143978

Family Applications (1)

Application Number Title Priority Date Filing Date
JP32246795A Pending JPH09143793A (en) 1995-11-17 1995-11-17 Aluminum alloy surface treatment method

Country Status (1)

Country Link
JP (1) JPH09143793A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6416072B1 (en) * 1998-08-10 2002-07-09 Honda Giken Kogyo Kabushiki Kaisha Vehicle body frame for motorcycle and it fabrication method
KR100575299B1 (en) * 2003-07-01 2006-04-28 광성전자(주) method for making outer decoration product with anodized and tilted glossy faces and the product made by the same
JP2013082994A (en) * 2011-09-29 2013-05-09 Denka Himaku Inc Method for manufacturing colored aluminum product or colored aluminum alloy product, pigment composition for coloration, and colored aluminum product or colored aluminum alloy product
JP2013173628A (en) * 2012-02-23 2013-09-05 Sumitomo Electric Ind Ltd Method for producing glass preform for optical fiber and method for cleaning metal mesh
JP2013237888A (en) * 2012-05-14 2013-11-28 Denka Himaku Inc Printed product, method for producing the same, and medium to be printed

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6416072B1 (en) * 1998-08-10 2002-07-09 Honda Giken Kogyo Kabushiki Kaisha Vehicle body frame for motorcycle and it fabrication method
US6796030B2 (en) 1998-08-10 2004-09-28 Honda Giken Kogyo Kabushiki Kaisha Method of fabricating a vehicle body frame for a motorcycle
KR100575299B1 (en) * 2003-07-01 2006-04-28 광성전자(주) method for making outer decoration product with anodized and tilted glossy faces and the product made by the same
JP2013082994A (en) * 2011-09-29 2013-05-09 Denka Himaku Inc Method for manufacturing colored aluminum product or colored aluminum alloy product, pigment composition for coloration, and colored aluminum product or colored aluminum alloy product
JP2013173628A (en) * 2012-02-23 2013-09-05 Sumitomo Electric Ind Ltd Method for producing glass preform for optical fiber and method for cleaning metal mesh
JP2013237888A (en) * 2012-05-14 2013-11-28 Denka Himaku Inc Printed product, method for producing the same, and medium to be printed

Similar Documents

Publication Publication Date Title
JP4721708B2 (en) Color finishing method
CN104786426B (en) Method for injection molding metal insert and injection molded product of metal insert
JP4135459B2 (en) Method for pretreatment of electroless plating material and method for manufacturing plating coated member
KR102143590B1 (en) Method for anodizing surface treatment for film formation having high resistance to thermal shock
WO2014187049A1 (en) Micro-nano processing method for aluminum or aluminum alloy surface, and aluminum or aluminum alloy structure
FR2838754A1 (en) Method of anodizing aluminum alloy part, e.g. aviation component, involves dipping part into bath comprising sulfuric acid, applying voltage to dipped part, and maintaining part in bath until coating of desired thickness has been obtained
JPH09143793A (en) Aluminum alloy surface treatment method
JP6078851B2 (en) Method for electrolytic polishing of aluminum material
JP2002275668A (en) Surface treatment method for magnesium alloy molded products
JPS5911678B2 (en) Manufacturing method of porous copper thin film
JP2005113236A (en) Plating material, plating coated member and manufacturing method thereof
JPH1197298A (en) Manufacturing method of electrode foil for aluminum electrolytic capacitor
JPS6148595B2 (en)
CN109801789B (en) Method for preparing medium-pressure corrosion foil by using two-section direct current power generation hole
JP2004295062A (en) Method and apparatus for cleaning a substrate for an electrophotographic photosensitive member
US5269904A (en) Single tank de-oxidation and anodization process
RU2709913C1 (en) Method of applying galvanic coatings on complex-profile parts
JP3246298B2 (en) Method for producing pure titanium or titanium alloy material with beautiful surface
JPH04289039A (en) Mirror surface finishing of aluminum alloy material
JPH08318232A (en) Washing method
JP4372491B2 (en) Method for producing plating-coated member
JPH02153087A (en) Production of electroformed mold
JPH05214578A (en) Production of noble metal electrocasting
KR20040088439A (en) Guitar and producing method of the same
JP2002173791A (en) Pretreatment method for electroforming

Legal Events

Date Code Title Description
A977 Report on retrieval

Effective date: 20040726

Free format text: JAPANESE INTERMEDIATE CODE: A971007

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20040910

A521 Written amendment

Effective date: 20041104

Free format text: JAPANESE INTERMEDIATE CODE: A523

A02 Decision of refusal

Effective date: 20050118

Free format text: JAPANESE INTERMEDIATE CODE: A02

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050311

A911 Transfer of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20050318

A912 Removal of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A912

Effective date: 20050408