JPH0914877A - Heat exchange element - Google Patents
Heat exchange elementInfo
- Publication number
- JPH0914877A JPH0914877A JP7163338A JP16333895A JPH0914877A JP H0914877 A JPH0914877 A JP H0914877A JP 7163338 A JP7163338 A JP 7163338A JP 16333895 A JP16333895 A JP 16333895A JP H0914877 A JPH0914877 A JP H0914877A
- Authority
- JP
- Japan
- Prior art keywords
- heat exchange
- heat storage
- heat
- exchange element
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は相転移に伴う潜熱を利用
した蓄熱体からなる熱交換素子に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heat exchange element composed of a heat storage body utilizing latent heat associated with a phase transition.
【0002】[0002]
【従来の技術】相転移に伴う潜熱を利用した潜熱蓄熱材
として、パラフィン等の有機系蓄熱材を樹脂に担持した
蓄熱体が知られている。上記蓄熱体は適当なハウジング
に収納し、熱媒と直接接触することにより蓄熱及び放熱
を行うことができる。しかし、例えば、床材や壁材等に
組み込んで利用する場合、設置される個所が限定され、
蓄熱体と熱媒の接触面積が小さく熱交換性能を高くする
ことが困難である。そこで、上記蓄熱体と熱媒の接触面
積を上げるため、蓄熱体を球状や円筒状の粒子の状態で
用いることが検討されている。2. Description of the Related Art As a latent heat storage material utilizing latent heat accompanying a phase transition, a heat storage material in which an organic heat storage material such as paraffin is supported on a resin is known. The heat storage body is housed in an appropriate housing and can directly store heat and release heat by directly contacting the heat medium. However, for example, when it is used by incorporating it into a floor material, a wall material, etc., the installation location is limited,
Since the contact area between the heat storage medium and the heat medium is small, it is difficult to improve the heat exchange performance. Therefore, in order to increase the contact area between the heat storage medium and the heat medium, it has been studied to use the heat storage medium in the form of spherical or cylindrical particles.
【0003】[0003]
【発明が解決しようとする課題】しかし、粒子状の蓄熱
体を用いた場合、輸送中や、長時間多量の熱媒流を受け
た際に、粒子状の蓄熱体に偏りを生じる。蓄熱体に偏り
を生じた場合、熱交換性能を低下させたり、最悪の場合
熱媒の流路を閉塞する恐れがある。However, when a particulate heat storage material is used, the particulate heat storage material is biased during transportation or when a large amount of heat transfer medium is received for a long time. If the heat storage body is biased, the heat exchange performance may be deteriorated, or in the worst case, the flow path of the heat medium may be blocked.
【0004】本発明は上記事実に鑑みてなされたもの
で、その目的とするところは、良好な熱交換性能が保持
される熱交換素子を提供することにある。The present invention has been made in view of the above facts, and an object of the present invention is to provide a heat exchange element which maintains good heat exchange performance.
【0005】[0005]
【課題を解決するための手段】本発明の請求項1に係る
熱交換素子は、結晶化度40%未満の低結晶性ポリオレ
フィンからなる基質と、この基質に担持された、固相−
液相間を可逆的に相転移する有機系蓄熱材を構成材料と
する蓄熱体1、及び、この蓄熱体1に直接接触する熱媒
の流路2を備える熱交換素子であって、上記蓄熱体1が
互いに一部を固着した粒子1aの集合体であり、これら
粒子1a間の空隙を流路2とすることを特徴とする。The heat exchange element according to claim 1 of the present invention comprises a substrate made of a low crystalline polyolefin having a crystallinity of less than 40%, and a solid phase-supported on the substrate.
A heat exchange element comprising a heat storage body (1) having an organic heat storage material that reversibly undergoes a phase transition between liquid phases as a constituent material, and a heat medium flow path (2) that is in direct contact with the heat storage body (1). The body 1 is an aggregate of particles 1a that are partially fixed to each other, and the voids between these particles 1a are used as the flow paths 2.
【0006】本発明の請求項2に係る熱交換素子は、請
求項1記載の熱交換素子において、上記集合体は蓄熱体
の粒子1aを融着させたものであることを特徴とする。A heat exchange element according to a second aspect of the present invention is characterized in that, in the heat exchange element according to the first aspect, the aggregate is obtained by fusing particles 1a of a heat storage body.
【0007】本発明の請求項3に係る熱交換素子は、請
求項1又は請求項2記載の熱交換素子において、上記基
質が、さらに結晶化度40%以上の結晶性ポリオレフィ
ンを構成材料とすることを特徴とする。The heat exchange element according to claim 3 of the present invention is the heat exchange element according to claim 1 or 2, wherein the substrate further comprises a crystalline polyolefin having a crystallinity of 40% or more as a constituent material. It is characterized by
【0008】本発明の請求項4に係る熱交換素子は、請
求項1乃至請求項3いずれか記載の熱交換素子におい
て、上記有機系蓄熱材が結晶性ハイドロカーボン、結晶
性脂肪酸、及び結晶性脂肪酸エステルから選ばれる少な
くとも1種であることを特徴とする。The heat exchange element according to claim 4 of the present invention is the heat exchange element according to any one of claims 1 to 3, wherein the organic heat storage material is crystalline hydrocarbon, crystalline fatty acid, and crystalline. It is characterized by being at least one selected from fatty acid esters.
【0009】以下、本発明を詳しく説明する。図1は本
発明の一実施例に係る蓄熱素子を使用した熱交換器の透
視した斜視図であり、図2は図1に示す熱交換器の断面
図である。Hereinafter, the present invention will be described in detail. 1 is a perspective view of a heat exchanger using a heat storage element according to an embodiment of the present invention, and FIG. 2 is a cross-sectional view of the heat exchanger shown in FIG.
【0010】本発明の熱交換素子を構成する蓄熱体1
は、結晶化度40%未満の低結晶性ポリオレフィンから
なる基質と、この基質に担持された、固相−液相間を可
逆的に相転移する有機系蓄熱材を構成材料とする。Heat storage body 1 constituting the heat exchange element of the present invention
Is composed of a substrate made of a low crystalline polyolefin having a crystallinity of less than 40% and an organic heat storage material supported on the substrate which reversibly undergoes a phase transition between a solid phase and a liquid phase.
【0011】上記低結晶性ポリオレフィンはX線回折法
による結晶化度が40%未満であり、この低結晶性ポリ
オレフィンとしては、例えば、ポリプロピレン、アタク
チックポリプロピレン、エチレンとα−オレフィンとの
共重合体が挙げられる。このα−オレフィンとしては、
プロピレン、1−ブテン、1−ペンテン、1−ヘキセ
ン、4−メチル−1−ペンテン、1−オクテン等が挙げ
られる。The low crystalline polyolefin has a degree of crystallinity of less than 40% by X-ray diffractometry. Examples of the low crystalline polyolefin include polypropylene, atactic polypropylene, and a copolymer of ethylene and α-olefin. Is mentioned. As this α-olefin,
Propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-octene and the like can be mentioned.
【0012】上記蓄熱体1の基質に、蓄熱体1の強度を
向上させるために、樹脂として、上記低結晶性のポリオ
レフィンと共に、結晶化度40%以上の結晶性ポリオレ
フィンを用いると、蓄熱体1の形状保持力を高めること
ができる。特に、低結晶性のポリオレフィンの結晶化度
が30%以下の場合は、効果的である。上記結晶化度4
0%以上の結晶性ポリオレフィンとしては、高密度ポリ
エチレン、中密度ポリエチレン、低密度ポリエチレン、
直鎖低密度ポリエチレン、ポリプロピレン等が挙げられ
る。なお、高密度ポリエチレン、中密度ポリエチレン、
低密度ポリエチレンは、JIS−K−6760で規定さ
れているものである。When a crystalline polyolefin having a crystallinity of 40% or more is used as a resin for the substrate of the heat storage body 1 in order to improve the strength of the heat storage body 1, the heat storage body 1 is used. It is possible to increase the shape retention power of the. In particular, it is effective when the crystallinity of the low crystalline polyolefin is 30% or less. Crystallinity 4 above
As 0% or more of crystalline polyolefin, high density polyethylene, medium density polyethylene, low density polyethylene,
Linear low density polyethylene, polypropylene, etc. may be mentioned. In addition, high density polyethylene, medium density polyethylene,
The low-density polyethylene is defined by JIS-K-6760.
【0013】上記有機系蓄熱材は固相−液相間を可逆的
に相転移する性質を有する物質であって、上記結晶化度
40%未満の低結晶性のポリオレフィンと相溶性を有す
るものが望ましく、上記結晶化度40%以上の結晶性ポ
リオレフィンを用いる場合はこの結晶性ポリオレフィン
とも相溶性を有するものが望ましい。上記有機系蓄熱材
としては、特に限定はしないが、具体的には、パラフィ
ン、パラフィンワックス、イソパラフィン、ポリエチレ
ンワックス等のハイドロカーボン、脂肪酸、及び脂肪酸
エステル類(以下脂肪酸類と記す)等が挙げられる。上
記有機系蓄熱材は融点が5〜90℃のものが好ましく、
望ましくは融点が20〜80℃のものである。これらは
1種のみを用いてもよいし、2種以上を併用してもよ
い。上記有機系蓄熱材は、蓄熱の効率を保持する点よ
り、20cal/g以上の相転移熱量を有する結晶性物
質であることが望ましい。The above organic heat storage material is a substance having a property of reversibly undergoing a phase transition between a solid phase and a liquid phase, and is compatible with the low crystalline polyolefin having a crystallinity of less than 40%. Desirably, when a crystalline polyolefin having a crystallinity of 40% or more is used, one having compatibility with the crystalline polyolefin is desirable. The organic heat storage material is not particularly limited, but specific examples thereof include hydrocarbons such as paraffin, paraffin wax, isoparaffin, and polyethylene wax, fatty acids, and fatty acid esters (hereinafter referred to as fatty acids). . The organic heat storage material preferably has a melting point of 5 to 90 ° C.,
Desirably, the melting point is 20 to 80 ° C. These may use only 1 type and may use 2 or more types together. The organic heat storage material is preferably a crystalline substance having a heat quantity of phase transition of 20 cal / g or more from the viewpoint of maintaining heat storage efficiency.
【0014】上記蓄熱体1に用いられる構成材料の配合
比率は、蓄熱体1の用途により適宜決められるが、例え
ば、結晶化度40%未満の低結晶性のポリオレフィンは
10〜30重量%、有機系蓄熱材は70〜90重量%が
適当である。また、結晶化度40%以上の結晶性ポリオ
レフィンを用いる場合は、結晶化度40%以上の結晶性
ポリオレフィンは5〜20重量%、結晶化度40%未満
の低結晶性のポリオレフィンは10〜40重量%、有機
系蓄熱材は40〜85重量%が適当である。The blending ratio of the constituent materials used for the heat storage body 1 is appropriately determined depending on the use of the heat storage body 1. For example, 10 to 30% by weight of a low crystalline polyolefin having a crystallinity of less than 40%, an organic 70 to 90% by weight is suitable for the system heat storage material. When a crystalline polyolefin having a crystallinity of 40% or more is used, the crystalline polyolefin having a crystallinity of 40% or more is 5 to 20% by weight, and the low crystalline polyolefin having a crystallinity of less than 40% is 10 to 40%. %, And 40 to 85% by weight is suitable for the organic heat storage material.
【0015】本発明においては、上記蓄熱体1が互いに
一部を固着した粒子1aの集合体であり、これら粒子1
a間の空隙を熱媒の流路2とする。上記蓄熱体1の粒子
1aの作製は、例えば、低結晶性のポリオレフィン等の
樹脂の融点以上の温度で混練機等で混練し、この溶融混
合物を粒子状に成形することによって実現できる。上記
成形は、例えば、押出成形、射出成形等通常のプラスチ
ックの成形方法が採用できる。なお、上記粒子の形状
は、球状、円筒状、角状等限定されない。上記蓄熱体1
には、樹脂、及び、有機系蓄熱材の他に必要に応じて、
無機、及び有機のフィラー、ガラス繊維、ウィスカー、
金属繊維、難燃剤、酸化防止剤等を構成材料としてもよ
い。In the present invention, the heat storage body 1 is an assembly of particles 1a partially fixed to each other.
The space between a is the flow path 2 for the heat medium. The particles 1a of the heat storage body 1 can be produced, for example, by kneading with a kneader or the like at a temperature equal to or higher than the melting point of a resin such as a low crystalline polyolefin and molding the molten mixture into particles. For the molding, for example, a usual plastic molding method such as extrusion molding or injection molding can be adopted. The shape of the particles is not limited to spherical, cylindrical, angular, or the like. The heat storage body 1
In addition to the resin and the organic heat storage material,
Inorganic and organic fillers, glass fibers, whiskers,
Metal fibers, flame retardants, antioxidants and the like may be used as constituent materials.
【0016】これら蓄熱体1の粒子1aの固着方法は限
定されず、例えば、接着剤を用いて接着しても、蓄熱体
1の構成材料の融点以上の温度を加えて融着しても、常
温で加圧してもよい。また、必要に応じて加温と加圧の
両方を行ってもよいが、連続する空隙が失われないよう
注意を要する。なお、融着による作製は、蓄熱体1の構
成材料が熱可塑性樹脂であるので、容易に固着できる点
から好ましい。The method for fixing the particles 1a of the heat storage body 1 is not limited. For example, even if the particles are adhered using an adhesive, or if they are fused by applying a temperature higher than the melting point of the constituent material of the heat storage body 1, You may pressurize at normal temperature. Both heating and pressurization may be performed as necessary, but care must be taken so that continuous voids are not lost. In addition, since the constituent material of the heat storage body 1 is a thermoplastic resin, the production by fusion is preferable because it can be easily fixed.
【0017】その後、例えば、図1に示す如く、全体の
形状を略平板とした熱交換素子3は、前後の端面に熱媒
の入口5と出口6が設けられた、平板なハウジング4に
収納し、熱交換器に使用される。After that, for example, as shown in FIG. 1, the heat exchange element 3 whose overall shape is a substantially flat plate is housed in a flat housing 4 having a heat medium inlet 5 and a heat medium outlet 6 at its front and rear end faces. Used in heat exchangers.
【0018】上述の如く、蓄熱体1が粒子1aの集合体
で、この粒子1aの空隙を熱媒の流路2とするので、蓄
熱体1と熱媒が直接接触するため熱交換性能が良いと共
に、蓄熱体1からなる粒子1aが互いに一部を固着して
いるので、輸送中や長時間多量の熱媒流を受けても偏り
を発生することがなく、形状がいつまでも保持される。
その結果、長期間にわたり良好な熱交換性能が保持され
る。As described above, the heat storage body 1 is an aggregate of the particles 1a, and the voids of the particles 1a are used as the flow path 2 for the heat medium. At the same time, the particles 1a made of the heat storage body 1 are partially fixed to each other, so that even if a large amount of heat medium flow is received during transportation or for a long time, no deviation occurs and the shape is maintained forever.
As a result, good heat exchange performance is maintained for a long period of time.
【0019】[0019]
【作用】本発明の請求項1に係る熱交換素子は、蓄熱体
1が粒子1aの集合体で、この粒子1aの空隙を熱媒の
流路2とするので、蓄熱体1と熱媒が直接接触するため
熱交換性能が良いと共に、蓄熱体1からなる粒子1aが
互いに一部を固着しているので、輸送中や長時間多量の
熱媒流を受けても偏りを発生することがない。In the heat exchange element according to claim 1 of the present invention, the heat storage body 1 is an aggregate of particles 1a, and the voids of the particles 1a are used as the flow path 2 of the heat medium. Since they are in direct contact with each other, the heat exchange performance is good, and since the particles 1a composed of the heat storage body 1 are partially fixed to each other, no deviation occurs even during transportation or when a large amount of heat transfer medium is received for a long time. .
【0020】[0020]
【実施例】以下、本発明の実施例と比較例を挙げる。EXAMPLES Examples of the present invention and comparative examples will be described below.
【0021】実施例1 結晶化度40%未満の低結晶性ポリオレフィンとして、
結晶化度6%のアタクチックポリプロピレン(住友化学
株式会社製:スミチックSS−30B、密度0.84g
/cm3 、融点170℃)を10重量%、結晶化度40
%以上の結晶性ポリオレフィンとして、結晶化度45%
の直鎖低密度ポリエチレン(住友化学株式会社製:スミ
カセンαFZ201−0、密度0.912g/cm3 、
結晶化部の融点120℃)を20重量%、有機系蓄熱材
としてパラフィン140品(日本精蝋株式会社製:14
0F、融点60℃)を70重量%の配合比率で配合して
成形材料とした。この成形材料を140℃に加熱しなが
ら混練した溶融物を冷却し、切断し、厚さ2mm、直径
2mmの円筒形の蓄熱体の粒子を作製した。Example 1 As a low crystalline polyolefin having a crystallinity of less than 40%,
Atactic polypropylene with a crystallinity of 6% (Sumitomo Chemical Co., Ltd .: Sumitic SS-30B, density 0.84 g)
/ Cm 3 , melting point 170 ° C.) 10% by weight, crystallinity 40
% Or more crystalline polyolefin, crystallinity 45%
Linear low-density polyethylene (Sumitomo Chemical Co., Ltd .: Sumikasen αFZ201-0, density 0.912 g / cm 3 ,
20% by weight of crystallization part melting point 120 ° C., 140 paraffin as an organic heat storage material (manufactured by Nippon Seiro Co., Ltd .: 14)
0F, melting point 60 ° C.) was mixed at a mixing ratio of 70% by weight to obtain a molding material. This molding material was heated to 140 ° C. while the kneaded melt was cooled and cut to prepare cylindrical heat storage particles having a thickness of 2 mm and a diameter of 2 mm.
【0022】これら蓄熱体の粒子を長さ300mm、幅
150mmの容器に入れ温度70℃の接触圧で加圧し、
粒子の一部が互いに固着した熱交換素子を得た。熱交換
素子の厚みは15mm、蓄熱体の占める容積率は65%
であった。Particles of these heat storage bodies were placed in a container having a length of 300 mm and a width of 150 mm and pressurized with a contact pressure of 70 ° C.,
A heat exchange element in which some of the particles were fixed to each other was obtained. The thickness of the heat exchange element is 15 mm, and the volume ratio occupied by the heat storage body is 65%.
Met.
【0023】上記熱交換素子を内部が長さ320mm、
幅150mm、厚み15mmのハウジングに収納した。
ハウジングの前後の端面には入口と出口を設けてある。
これを熱交換器とした。The inside of the heat exchange element has a length of 320 mm,
It was stored in a housing having a width of 150 mm and a thickness of 15 mm.
An inlet and an outlet are provided on the front and rear end faces of the housing.
This was used as a heat exchanger.
【0024】実施例2 実施例1と同様にして作製した蓄熱体の粒子を長さ30
0mm、幅150mmの容器に入れ、温度150℃の雰
囲気で10秒間放置し、粒子の一部が互いに固着した熱
交換素子を得た。熱交換素子の厚みは15mm、蓄熱体
の占める容積率は65%であった。上記熱交換素子を実
施例1と同様のハウジングに収納し熱交換器を得た。Example 2 Particles of a heat storage material produced in the same manner as in Example 1 were made to have a length of 30.
It was placed in a container having a width of 0 mm and a width of 150 mm and allowed to stand in an atmosphere at a temperature of 150 ° C. for 10 seconds to obtain a heat exchange element in which some particles were fixed to each other. The thickness of the heat exchange element was 15 mm, and the volume ratio occupied by the heat storage body was 65%. The heat exchange element was housed in the same housing as in Example 1 to obtain a heat exchanger.
【0025】比較例1 実施例1と同様にして作製した溶融物を冷却し、切断
し、厚さ15mm、長さ300mm、幅150mmの平
板な蓄熱体を得た。この蓄熱体に前後端面を貫通する半
径6mmの貫通孔を7本あけ流路とし、熱交換素子とし
た。蓄熱体の占める容積率は65%であった。上記熱交
換素子を実施例1と同様のハウジングに収納し熱交換器
を得た。Comparative Example 1 The melt produced in the same manner as in Example 1 was cooled and cut to obtain a flat heat storage material having a thickness of 15 mm, a length of 300 mm and a width of 150 mm. Seven through-holes having a radius of 6 mm, which penetrate the front and rear end faces, were formed in the heat storage body as flow paths to form a heat exchange element. The volume ratio occupied by the heat storage body was 65%. The heat exchange element was housed in the same housing as in Example 1 to obtain a heat exchanger.
【0026】得た実施例1〜2の熱交換器に長時間多量
の熱媒を通し、偏りを検査した。熱媒に30℃の水を用
い、5リットル/分で5時間通したが、熱交換素子が偏
ったり形状が変形することはなかった。A large amount of heating medium was passed through the obtained heat exchangers of Examples 1 and 2 for a long time, and the deviation was inspected. Water of 30 ° C. was used as a heat medium and passed at 5 liter / min for 5 hours, but the heat exchange element was not biased or deformed.
【0027】次に実施例1〜2と比較例1の熱交換性能
を評価した。熱交換素子を65℃に加熱した後に、熱媒
として温度30℃の水を入口より1リットル/分の流速
で通し、出口の水温が50℃になる迄の時間を測定し
た。結果は実施例1は10秒、実施例2は11秒、比較
例1は18秒であり、実施例の熱交換性能が良好に保持
されていることが確認できた。Next, the heat exchange performances of Examples 1 and 2 and Comparative Example 1 were evaluated. After heating the heat exchange element to 65 ° C., water having a temperature of 30 ° C. as a heat medium was passed through the inlet at a flow rate of 1 liter / min, and the time until the water temperature at the outlet reached 50 ° C. was measured. The results were 10 seconds for Example 1, 11 seconds for Example 2, and 18 seconds for Comparative Example 1, and it was confirmed that the heat exchange performance of the Example was maintained well.
【0028】[0028]
【表1】 [Table 1]
【0029】[0029]
【発明の効果】本発明の請求項1に係る熱交換素子は、
上記構成からなるので、蓄熱体1と熱媒が直接接触する
ため熱交換性能が良いと共に、輸送による衝撃や、長時
間多量の熱媒流を受けても偏りを発生することがなく、
形状がいつまでも保持される。その結果、長期間にわた
り良好な熱交換性能が保持される。The heat exchange element according to claim 1 of the present invention comprises:
Since it has the above-mentioned configuration, the heat storage body 1 and the heat medium are in direct contact with each other, so that the heat exchange performance is good, and there is no bias even when receiving a shock due to transportation or a large amount of heat medium flow for a long time.
The shape is retained forever. As a result, good heat exchange performance is maintained for a long period of time.
【0030】本発明の請求項2に係る熱交換素子は、上
記効果に加えて、熱交換素子の作製が容易にできる。In the heat exchange element according to the second aspect of the present invention, in addition to the above effects, the heat exchange element can be easily manufactured.
【0031】本発明の請求項3に係る熱交換素子は、上
記効果に加えて、熱交換素子を構成する蓄熱体の形状保
持力を高めることができる。In addition to the above effects, the heat exchange element according to the third aspect of the present invention can enhance the shape retention force of the heat storage body constituting the heat exchange element.
【図1】本発明の一実施例に係る蓄熱素子を使用した熱
交換器の透視した斜視図である。FIG. 1 is a transparent perspective view of a heat exchanger using a heat storage element according to an embodiment of the present invention.
【図2】図1に示す熱交換器の断面図である。FIG. 2 is a cross-sectional view of the heat exchanger shown in FIG.
1 蓄熱体 1a 粒子 2 流路 3 熱交換素子 4 ハウジング 5 入口 6 出口 1 heat storage body 1a particle 2 flow path 3 heat exchange element 4 housing 5 inlet 6 outlet
───────────────────────────────────────────────────── フロントページの続き (72)発明者 椿 健治 大阪府門真市大字門真1048番地松下電工株 式会社内 (72)発明者 薮ノ内 伸晃 大阪府門真市大字門真1048番地松下電工株 式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Kenji Tsubaki 1048, Kadoma, Kadoma City, Osaka Prefecture Matsushita Electric Works Co., Ltd. (72) Nobuaki Yabunouchi, 1048, Kadoma, Kadoma City, Osaka Within
Claims (4)
フィンからなる基質と、この基質に担持された、固相−
液相間を可逆的に相転移する有機系蓄熱材を構成材料と
する蓄熱体(1)、及び、この蓄熱体(1)に直接接触
する熱媒の流路(2)を備える熱交換素子であって、上
記蓄熱体(1)が互いに一部を固着した粒子(1a)の
集合体であり、これら粒子(1a)間の空隙を流路
(2)とすることを特徴とする熱交換素子。1. A substrate comprising a low crystalline polyolefin having a crystallinity of less than 40%, and a solid phase-supported on the substrate.
A heat exchange element including a heat storage body (1) having an organic heat storage material that reversibly undergoes a phase transition between liquid phases as a constituent material, and a flow path (2) for a heat medium that is in direct contact with the heat storage body (1). In addition, the heat storage body (1) is an assembly of particles (1a) in which some of the particles are fixed to each other, and a void between these particles (1a) is used as a flow path (2). element.
着させたものであることを特徴とする請求項1記載の熱
交換素子。2. The heat exchange element according to claim 1, wherein the aggregate is obtained by fusing particles (1a) of a heat storage body.
の結晶性ポリオレフィンを構成材料とすることを特徴と
する請求項1又は請求項2記載の熱交換素子。3. The heat exchange element according to claim 1 or 2, wherein the substrate further comprises a crystalline polyolefin having a crystallinity of 40% or more as a constituent material.
ボン、結晶性脂肪酸、及び結晶性脂肪酸エステルから選
ばれる少なくとも1種であることを特徴とする請求項1
乃至請求項3いずれか記載の熱交換素子。4. The organic heat storage material is at least one selected from crystalline hydrocarbons, crystalline fatty acids, and crystalline fatty acid esters.
A heat exchange element according to claim 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7163338A JPH0914877A (en) | 1995-06-29 | 1995-06-29 | Heat exchange element |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7163338A JPH0914877A (en) | 1995-06-29 | 1995-06-29 | Heat exchange element |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0914877A true JPH0914877A (en) | 1997-01-17 |
Family
ID=15771973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7163338A Withdrawn JPH0914877A (en) | 1995-06-29 | 1995-06-29 | Heat exchange element |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0914877A (en) |
-
1995
- 1995-06-29 JP JP7163338A patent/JPH0914877A/en not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20020903 |