JPH09226031A - Fire-resistant sheet - Google Patents

Fire-resistant sheet

Info

Publication number
JPH09226031A
JPH09226031A JP3586096A JP3586096A JPH09226031A JP H09226031 A JPH09226031 A JP H09226031A JP 3586096 A JP3586096 A JP 3586096A JP 3586096 A JP3586096 A JP 3586096A JP H09226031 A JPH09226031 A JP H09226031A
Authority
JP
Japan
Prior art keywords
fire
particles
resistant
layer
sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3586096A
Other languages
Japanese (ja)
Inventor
Senichi Okuyama
専一 奥山
Hiroyuki Umetsu
浩之 梅津
Hideki Takiguchi
英喜 滝口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Technical Research Inc
Original Assignee
IG Technical Research Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Technical Research Inc filed Critical IG Technical Research Inc
Priority to JP3586096A priority Critical patent/JPH09226031A/en
Publication of JPH09226031A publication Critical patent/JPH09226031A/en
Pending legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To securely, easily and safely form a thermal insulation fire-resistant layer by providing a thermal insulation fire-resistant layer composed of at least one kind or more of aluminum hydroxide particles, phenol resin particles, incombustible particles of thermal expansion properties and the like bound all together by a binder. SOLUTION: This fire-resistant sheet 1 is provided with a thermal insulation fire-resistant layer 3 formed at at least on one face of a sheet-shaped face material 2. The thermal insulation fire-resistant layer 3 is formed of at least one kind or more of aluminum hydroxide particles 4, phenol resin particles 5, incombustible particles of thermal expansion properties 6 and the like and a binder 7 for binding and integrating the particles. The aluminum hydroxide particles 4 are powdery or granular and function as a skeleton of a carbonized layer under the intense heat. The incombustible particles 6 of thermal expansion properties are one kind or more of, for example, vermiculite, carbon black, graphite and the like. The binder 7 is composed of one kind or more of phenol resins, a polyisocyanurate resin, a polyester resin, a polyurethane resin and an epoxy resin.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は耐火構造を必要とする建
築物、構築物に使用される鋼材の外周面を被覆したり、
サンドイッチパネルの耐火性の向上のために芯材に介在
させる耐火シートに関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention covers an outer peripheral surface of a steel material used for a building or a building requiring a fire-resistant structure,
The present invention relates to a fireproof sheet interposed in a core material for improving the fire resistance of a sandwich panel.

【0002】[0002]

【従来の技術】従来、耐火構造を必要とする建築物、構
築物に使用される鋼材からなる躯体は、躯体組立形成後
に現場にてロックウールを吹き付けし、耐火構造にする
のが一般的であった。また、サンドイッチパネルの耐火
性の向上には防火剤を添加する方法が採用されていた。
2. Description of the Related Art Conventionally, a structure made of steel used for a building or a structure requiring a fireproof structure is generally made to have a fireproof structure by blowing rock wool on site after the body is assembled and formed. It was In addition, a method of adding a fire retardant has been adopted to improve the fire resistance of the sandwich panel.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、上記の
ような方法では、ロックウールに吹き付け作業は危険、
汚い、きついの3K環境での作業であり、しかも、均一
にロックウールを層を形成するにはかなりの熟練を必要
とした。その上、経時的に劣化し、剥離して落下する危
険があった。また、現場で吹き付け用の機器が必要であ
り、運搬コスト等の費用がかかるものであった。さら
に、耐火用のロックウールはシート状でなく、パネル状
等の芯材に層状に正確に形成することができなかった。
However, in the above method, it is dangerous to spray rock wool.
The operation was in a dirty and harsh 3K environment, and considerable skill was required to form a uniform layer of rock wool. In addition, there was a danger that it would deteriorate with time, peel off and drop. In addition, a spraying device is needed on site, which requires transportation costs and the like. Further, the fireproof rock wool is not in a sheet form, and cannot be accurately formed in a layered form on a core material such as a panel form.

【0004】[0004]

【課題を解決するための手段】本発明はこのような欠点
を除去するために、シート状の面材の少なくとも片面に
水酸化アルミニウム粒、フェノール樹脂粒、熱膨張性で
不燃な粒子等の一種以上を接着剤でバインドした断熱耐
火層を設けた耐火シートであり、建設現場でのロックウ
ールに吹き付け作業をなくし、確実、容易に、その上安
全に耐火被覆層を鋼材外周面、あるいはパネルの面材と
芯材間、もしくは内部に一体に形成できると共に、厚み
が一定で安定した断熱耐火層を形成でき、軽量で断熱
性、施工性、耐火性のある耐火シートを提供するもので
ある。
In order to eliminate such drawbacks, the present invention is a kind of aluminum hydroxide particles, phenol resin particles, thermally expansive non-combustible particles, etc. on at least one surface of a sheet-like face material. It is a fire resistant sheet provided with an insulating fire resistant layer bound with an adhesive, eliminating the work of spraying rock wool at the construction site, and reliably, easily and safely with a fire resistant coating layer on the steel outer peripheral surface or panel. Provided is a fireproof sheet which can be integrally formed between a face material and a core material or inside, and which can form a stable heat insulating fireproof layer having a constant thickness, and which is lightweight and has heat insulating properties, workability and fire resistance.

【0005】[0005]

【実施例】以下に図面を用いて本発明に係る耐火シート
の一実施例について詳細に説明する。図1は上記耐火シ
ートの代表例を示す拡大説明図であり、1は耐火シー
ト、2はシート状の面材、3は断熱耐火層、7は接着剤
である。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is an exploded perspective view of a fireproof sheet according to the present invention. FIG. 1 is an enlarged explanatory view showing a typical example of the above fire resistant sheet, 1 is a fire resistant sheet, 2 is a sheet-shaped face material, 3 is a heat insulating fire resistant layer, and 7 is an adhesive.

【0006】すなわち、耐火シート1はシート状の面材
2の少なくとも片面上、あるいは含浸等して断熱耐火層
3を形成したものであり、高熱下で耐火断熱性を発揮し
て鋼材、パネル等を保護するものである。
That is, the fire-resistant sheet 1 is a sheet-like face material 2 on which at least one side is formed or impregnated to form a heat-insulating fire-resistant layer 3, which exhibits fire heat-insulating properties under high heat, such as steel materials and panels. Is to protect.

【0007】面材2は不燃性、可燃性のいづれでも良
く、可撓性を有するフィルム状、ネット状、織布、不織
布の構造としてものであり、主に骨格材、芯材、補強
材、防水材、クッション材、含芯材、排気材の少なくと
も一つ以上の機能を具備するものである。
The face material 2 may be incombustible or flammable, and has a flexible film-like, net-like, woven or non-woven structure, and is mainly composed of a skeleton material, a core material, a reinforcing material, It has at least one function of a waterproof material, a cushion material, a core material, and an exhaust material.

【0008】さらに詳説すると、面材2の素材としては
炭酸カルシウム、ケイ酸カルシウム、ロックウール、炭
素、グラファイト、金属、プラスチック、等の繊維状
物、植物繊維の一種以上の長、短繊維をシート状化した
ものであり、厚さは0.2〜5mm位としたものであ
る。
More specifically, as the material of the face material 2, fibrous substances such as calcium carbonate, calcium silicate, rockwool, carbon, graphite, metal, plastic, etc., and one or more long and short fibers of vegetable fiber are sheets. It is formed into a shape and has a thickness of about 0.2 to 5 mm.

【0009】断熱耐火層3は平常時は防水層、遮音層、
クッション層、耐薬品等の保護層、耐候層、接着面強化
層として機能するものであり、高熱下で不燃性の断熱層
を形成し、鋼材、パネルの温度上昇を大幅に、かつ長時
間に亘って抑制し、耐火構造の各種試験に合格し得るも
のである。
The heat-insulating refractory layer 3 is normally a waterproof layer, a sound insulation layer,
It functions as a cushion layer, a protective layer such as chemical resistance, a weather resistant layer, and an adhesive surface strengthening layer.It forms a non-combustible heat insulating layer under high heat, significantly increasing the temperature rise of steel materials and panels and for a long time. It can be suppressed over a period of time and can pass various tests of fireproof structure.

【0010】また、断熱耐火層3の構成は水酸化アルミ
ニウム4、フェノール樹脂粒5、熱膨張性で不燃な粒子
6等の少なくとも一種以上とこれらを接着、一体化する
接着剤7とから層状に、例えば0.5〜5mm位の厚さ
に形成したものであり、約100〜300℃位の断熱効
果を有するものである。
The heat-insulating refractory layer 3 is composed of at least one kind of aluminum hydroxide 4, phenol resin particles 5, thermally expansive and incombustible particles 6 and an adhesive 7 for adhering and integrating them. For example, it is formed to have a thickness of about 0.5 to 5 mm and has a heat insulating effect of about 100 to 300 ° C.

【0011】さらに説明すると、水酸化アルミニウム4
は粉状、粒状で、大きさは10〜1000μ位であり、
高熱下で結晶水を放出し周囲を冷却するものである。フ
ェノール樹脂粒5はクッション材、断熱材、耐火材とし
て機能し、大きさは10〜1000μ位であり、高熱下
では炭化するもので炭化層の骨格として機能する。
To explain further, aluminum hydroxide 4
Is powdery or granular, and the size is about 10 to 1000 μm,
It releases water of crystallization under high heat and cools the surroundings. The phenol resin particles 5 function as a cushioning material, a heat insulating material, and a refractory material, have a size of about 10 to 1000 μm, carbonize under high heat, and function as a skeleton of a carbonized layer.

【0012】熱膨張性で不燃な粒子6はクッション材、
不燃材、高熱下で不燃発泡体として機能するものであ
り、例えばバーミキュライト、カーボンブラック、グラ
ファイト等の一種以上である。熱膨張性で不燃な粒子6
は粉状、粒状、リン片状等であり、大きさは細い程良い
ものであり、約2〜1000μ位である。
The thermally expansive and non-combustible particles 6 are cushion materials,
A non-combustible material, which functions as a non-combustible foam under high heat, and is, for example, one or more of vermiculite, carbon black, graphite and the like. Thermally expansive and non-combustible particles 6
Is in the form of powder, particles, flakes, etc., and the smaller the size, the better, and it is about 2 to 1000 μm.

【0013】接着剤7は合成樹脂、塗料、等の一種から
なり、前記した水酸化アルミニウム等を面材2に接着
し、一体化すると共に、接着性、防水性、耐候性、耐薬
品性、等に優れていると共に、防火性があることが好ま
しい。具体例としてはフェノール樹脂、ポリイソシアヌ
レート、樹脂、ポリエステル樹脂、ポリウレタン樹脂、
パラフィン、エポキシ樹脂の一種以上からなり、必要に
よりポリリン酸アンモニウム、ガラス、ロックウール、
等の繊維、三酸化Sb等を添加し、より強力な炭化断熱
層、接着力強化層を形成するものである。
The adhesive 7 is made of a kind of synthetic resin, paint, etc., and is made by adhering the above-mentioned aluminum hydroxide or the like to the face material 2 so as to be integrated with each other, as well as adhesiveness, waterproofness, weather resistance, chemical resistance, It is preferable that it has excellent fire resistance. Specific examples include phenol resin, polyisocyanurate, resin, polyester resin, polyurethane resin,
Made of one or more of paraffin and epoxy resin, if necessary, ammonium polyphosphate, glass, rock wool,
And other fibers, Sb trioxide, etc. are added to form a stronger carbonized heat insulating layer and an adhesive strength layer.

【0014】[0014]

【その他の実施例】以上説明したのは本発明に係る耐火
シートの一実施例であり、図2〜図7に示すように構成
することもできる。すなわち、図2は水酸化アルミニウ
ム含有のフェノール樹脂粒8(嵩密度0.2〜0.9g
/cm3 )の吸熱ピークが異なる、例えば3種(150
〜390℃)の粒子9、10を添加し、耐熱時間を長時
間とした耐火シート1である。
[Other Embodiments] The embodiment described above is one embodiment of the fireproof sheet according to the present invention, and may be constructed as shown in FIGS. That is, FIG. 2 shows phenolic resin particles 8 containing aluminum hydroxide (bulk density 0.2 to 0.9 g).
/ Cm 3 ) have different endothermic peaks, for example, 3 types (150
(-390 ° C.) particles 9 and 10 are added, and the heat resistant sheet 1 has a long heat resistance time.

【0015】図3は面材2間に断熱耐火層3を接着剤7
を介して一体化した耐火シート1であり、層厚みとして
約5mm位であり、発泡後の総厚は30〜50mmとな
る耐火シート1である。
In FIG. 3, the heat insulating and refractory layer 3 is provided between the face materials 2 with the adhesive 7
The fire-resistant sheet 1 integrated with the heat-resistant sheet 1 having a layer thickness of about 5 mm, and the total thickness after foaming is 30 to 50 mm.

【0016】図4は鋼材11の外周面を耐火シート1で
接着剤7等を介して被覆した場合であり、図5は金属板
13間にプラスチックフォーム14を設け、このプラス
チックフォーム14と金属板13間に耐火シート1を一
体に接着剤等15を介して形成した構造のパネル12で
ある。
FIG. 4 shows the case where the outer peripheral surface of the steel material 11 is covered with the fireproof sheet 1 via the adhesive 7 or the like, and FIG. 5 shows that the plastic foam 14 is provided between the metal plates 13 and the plastic foam 14 and the metal plate are provided. It is a panel 12 having a structure in which the refractory sheet 1 is integrally formed between 13 via an adhesive agent 15.

【0017】図6(a)、(b)、および図7(a)、
(b)は耐火シート1のその他の実施例であり、図6
(a)は面材2上に細い金網16を断熱耐火層3で一体
に介在した耐火シート1、図6(b)は不燃繊維、グラ
ファイトを繊維化した糸で網状17を形成し、断熱耐火
層3に一体に介在した耐火シート1である。また、図7
(a)は面材2をネット状物で形成し、(b)図に示す
ようにこの面材2の構成材である紐の外周面を断熱耐火
層3で被覆した耐火シート1である。なお、この場合、
面材2には空隙18が形成され、これが他部材と耐火シ
ート1の接着一体化に有効に機能するものである。その
他、図2において一点鎖線で示すように接着剤7に植毛
19を形成することも可能である。
FIGS. 6A and 6B, and FIGS. 7A and 7B,
(B) is another embodiment of the fireproof sheet 1, and FIG.
(A) is a refractory sheet 1 in which a thin wire netting 16 is integrally interposed on a face material 2 by a heat insulating and fire resistant layer 3, and FIG. 6 (b) is a non-combustible fiber, and a net 17 is formed by a filamentized fiber of graphite, which is adiabatic and fire resistant. The fireproof sheet 1 is integrally interposed in the layer 3. FIG.
(A) is a fire-resistant sheet 1 in which the face material 2 is formed of a net-like material, and the outer peripheral surface of the cord, which is a constituent material of the face material 2, is covered with a heat-insulating fire-resistant layer 3 as shown in FIG. In this case,
A void 18 is formed in the face material 2, which effectively functions to bond and integrate other members with the fire resistant sheet 1. In addition, it is also possible to form the flock 19 on the adhesive 7 as shown by the dashed line in FIG.

【0018】[0018]

【発明の効果】上述したように本発明に係る耐火シート
によれば、断熱耐火層が約100〜500℃位の断熱
耐火性を発揮するため、鋼材、サンドイッチパネルの耐
火性を向上することができる。面材がシート状等であ
るため被着面に自由に接着でき、施工性が抜群である。
高熱下での断熱耐火層は吸熱温度差のある異種の粒子
を添加した場合、特に長時間に亘って耐火断熱性を発揮
できる。防水性、耐候性、耐薬品性が良く、断熱性、
防火性が劣化することがない。断熱耐火層は平常時に
クッション材、隔離材、補強材、防水材等として機能
し、高熱下で前記したような不燃性の耐火発泡断熱層を
形成し、パネル、鋼材等を耐火構造試験30分、60分
(1時間)、120分(2時間)等に合格させる主要部
材となる。等の特徴、効果がある。
As described above, according to the fire-resistant sheet of the present invention, the heat-resistant fire-resistant layer exhibits heat-resistant fire resistance of about 100 to 500 ° C., so that the fire resistance of steel materials and sandwich panels can be improved. it can. Since the face material is in the form of a sheet, it can be freely adhered to the adherend and has excellent workability.
The heat-insulating refractory layer under high heat can exhibit fire-insulating heat resistance particularly for a long time when different kinds of particles having different endothermic temperatures are added. Good water resistance, weather resistance, chemical resistance, heat insulation,
Fire resistance does not deteriorate. The heat-insulating refractory layer normally functions as a cushioning material, an isolating material, a reinforcing material, a waterproof material, etc., and forms the non-combustible fire-resistant foam heat-insulating layer under high heat as described above, and the panel, steel material, etc. are subjected to a fire-resistant structural test for 30 minutes , 60 minutes (1 hour), 120 minutes (2 hours), etc. There are features and effects such as.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に係る耐火シートの代表例を拡大して示
す拡大説明図である。
FIG. 1 is an enlarged explanatory view showing an enlarged representative example of a fireproof sheet according to the present invention.

【図2】本発明に係る耐火シートのその他の実施例を示
す拡大説明図である。
FIG. 2 is an enlarged explanatory view showing another embodiment of the fireproof sheet according to the present invention.

【図3】本発明に係る耐火シートのその他の実施例を示
す拡大説明図である。
FIG. 3 is an enlarged explanatory view showing another embodiment of the fire resistant sheet according to the present invention.

【図4】本発明に係る耐火シートを鋼材の耐火被覆とし
て利用した例を示す説明図である。
FIG. 4 is an explanatory view showing an example in which the fire resistant sheet according to the present invention is used as a fire resistant coating of steel.

【図5】本発明に係る耐火シートをパネルの芯材と面材
間に介在した場合の一例を示す説明図である。
FIG. 5 is an explanatory view showing an example of the case where the fire resistant sheet according to the present invention is interposed between the core material and the face material of the panel.

【図6】本発明に係る耐火シートのその他の実施例を示
す説明図である。
FIG. 6 is an explanatory view showing another embodiment of the fireproof sheet according to the present invention.

【図7】本発明に係る耐火シートのその他の実施例を示
す説明図である。
FIG. 7 is an explanatory view showing another embodiment of the fireproof sheet according to the present invention.

【符号の説明】[Explanation of symbols]

1 耐火シート 2 面材 3 断熱耐火層 4 水酸化アルミニウム 5 フェノール樹脂粒 6 熱膨張性で不燃な粒子 7 接着剤 8 水酸化アルミニウム含有のフェノール樹脂粒 9 粒子 10 粒子 11 鋼材 12 パネル 13 金属板 14 プラスチックフォーム 15 接着剤等 16 金網 17 網状 18 空隙 19 植毛 1 Fire-Resistant Sheet 2 Face Material 3 Insulating Fire-Resistant Layer 4 Aluminum Hydroxide 5 Phenolic Resin Particles 6 Thermally Expandable and Incombustible Particles 7 Adhesive 8 Aluminum-hydroxide-Containing Phenolic Resin Particles 9 Particles 10 Particles 11 Steel Material 12 Panel 13 Metal Plate 14 Plastic foam 15 Adhesives 16 Wire netting 17 Netting 18 Voids 19 Flocking

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 シート状の面材の少なくとも片面に水酸
化アルミニウム粒、フェノール樹脂粒、熱膨張性で不燃
な粒子等の少なくとも一種以上を接着剤でバインドした
断熱耐火層を設けたことを特徴とする耐火シート。
1. A heat-insulating refractory layer in which at least one kind of aluminum hydroxide particles, phenol resin particles, thermally expansive and non-combustible particles, etc. are bound with an adhesive on at least one surface of a sheet-like face material. And fire resistant sheet.
【請求項2】 フェノール樹脂粒の熱分解性の異なる二
種以上を混在した請求項1記載の耐火シート。
2. The fire resistant sheet according to claim 1, wherein two or more kinds of phenol resin particles having different thermal decomposability are mixed.
【請求項3】 断熱耐火層を不燃シートで一体にサンド
イッチした請求項1、2記載の耐火シート。
3. The fire-resistant sheet according to claim 1, wherein the heat-resistant fire-resistant layer is integrally sandwiched with non-combustible sheets.
【請求項4】 面材の表面に繊維が植毛されている請求
項1〜3記載の耐火シート。
4. The fire resistant sheet according to claim 1, wherein fibers are planted on the surface of the face material.
JP3586096A 1996-02-23 1996-02-23 Fire-resistant sheet Pending JPH09226031A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3586096A JPH09226031A (en) 1996-02-23 1996-02-23 Fire-resistant sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3586096A JPH09226031A (en) 1996-02-23 1996-02-23 Fire-resistant sheet

Publications (1)

Publication Number Publication Date
JPH09226031A true JPH09226031A (en) 1997-09-02

Family

ID=12453746

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3586096A Pending JPH09226031A (en) 1996-02-23 1996-02-23 Fire-resistant sheet

Country Status (1)

Country Link
JP (1) JPH09226031A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8071492B2 (en) 2001-08-20 2011-12-06 Pbi Performance Products, Inc. Textile fabric for the outer shell of a firefighter's garment
KR101187101B1 (en) * 2003-05-26 2012-10-02 세키스이가가쿠 고교가부시키가이샤 Fireproof resin sash
US9457949B1 (en) 2013-10-18 2016-10-04 William S. Hathaway, III Personalized identification system for deceased bodies
JP2025155000A (en) * 2024-03-29 2025-10-14 株式会社スローテック fireproof covering

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8071492B2 (en) 2001-08-20 2011-12-06 Pbi Performance Products, Inc. Textile fabric for the outer shell of a firefighter's garment
KR101187101B1 (en) * 2003-05-26 2012-10-02 세키스이가가쿠 고교가부시키가이샤 Fireproof resin sash
US8297013B2 (en) 2003-05-26 2012-10-30 Sekisui Chemical Co., Ltd. Fireproof resin sash
US9457949B1 (en) 2013-10-18 2016-10-04 William S. Hathaway, III Personalized identification system for deceased bodies
US10238570B2 (en) 2013-10-18 2019-03-26 William S. Hathaway, III Personalized identification system for deceased bodies
JP2025155000A (en) * 2024-03-29 2025-10-14 株式会社スローテック fireproof covering

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