JPH09314986A - Aluminum plate for ink jet recording - Google Patents
Aluminum plate for ink jet recordingInfo
- Publication number
- JPH09314986A JPH09314986A JP8133468A JP13346896A JPH09314986A JP H09314986 A JPH09314986 A JP H09314986A JP 8133468 A JP8133468 A JP 8133468A JP 13346896 A JP13346896 A JP 13346896A JP H09314986 A JPH09314986 A JP H09314986A
- Authority
- JP
- Japan
- Prior art keywords
- aluminum plate
- ink
- oxide film
- anode oxide
- anode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 37
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 238000007254 oxidation reaction Methods 0.000 abstract description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- 229920003169 water-soluble polymer Polymers 0.000 abstract description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract description 2
- 229920002472 Starch Polymers 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000005018 casein Substances 0.000 abstract description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract description 2
- 235000021240 caseins Nutrition 0.000 abstract description 2
- 229920001577 copolymer Polymers 0.000 abstract description 2
- 230000006866 deterioration Effects 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 229910052697 platinum Inorganic materials 0.000 abstract description 2
- 239000008107 starch Substances 0.000 abstract description 2
- 235000019698 starch Nutrition 0.000 abstract description 2
- 229920001059 synthetic polymer Polymers 0.000 abstract description 2
- 229920006222 acrylic ester polymer Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 238000007743 anodising Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000010407 anodic oxide Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Ink Jet (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は画像記録媒体に関す
るものであり、さらには媒体に対する記録をインクジェ
ットプリンターにより行うアルミニウム板からなる記録
媒体に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an image recording medium, and more particularly to a recording medium made of an aluminum plate for performing recording on the medium with an ink jet printer.
【０００２】[0002]
【従来の技術】インクジェットプリンターはパーソナル
コンピューター（以下パソコンと略記）の端末として今
日急速に普及してきている。また、黒単色からカラー化
が実現するとともに、画像処理技術がすすむことによ
り、見やすく工夫のこらされたデータやプレゼンテーシ
ョン資料の作成、写真や絵などを読み込んで他の情報と
組合せて表現する等、ユーザーが手軽に思うままの情報
処理を行い、そしてその内容を高精細に表出できるよう
になった。2. Description of the Related Art Ink jet printers are rapidly becoming popular as terminals for personal computers (hereinafter abbreviated as personal computers). Also, with the realization of color from a single black color and the advancement of image processing technology, data and presentation materials that have been devised so that they are easy to see can be created, photos and pictures can be read and combined with other information, etc. Users can easily process information as they want and express its contents in high definition.
【０００３】インクジェット記録は、民生用では紙、Ｏ
ＨＰ（オーバーヘッドプロジェクト）シート、ホワイト
フィルム、あるいはキャンパスペーパ等に対して印刷が
行われるが、これまでの印刷媒体は薄くてある程度自由
に曲げることができるものが主であった。Ink jet recording is made of paper, O for consumer use.
Printing is performed on an HP (overhead project) sheet, white film, campus paper, or the like, but the print media used so far are thin and can be bent freely to some extent.
【０００４】一方、インクジェット印刷ではパソコン操
作により作製した内容を直接プリンターにより印刷でき
る事から、スクリーン印刷やグラビア印刷のように版を
作製する事が不要となる。このため、今後は従来のよう
な比較的自由度のある媒体から、木やガラス、プラスチ
ック、金属といったかたい媒体へも印刷対象が広がるこ
とが予想される。On the other hand, in ink jet printing, since the contents produced by operating a personal computer can be directly printed by a printer, it is not necessary to produce a plate like screen printing or gravure printing. For this reason, in the future, it is expected that the printing target will spread from a medium having a relatively high degree of freedom as in the past to a hard medium such as wood, glass, plastic or metal.
【０００５】これらのかたい媒体は、装飾品や記念品、
オリジナルグッズ等が対象として考えられるが、とくに
さまざまな画像情報を少量ずつ印刷する場合や、短時間
で印刷物を入手したい場合にはインクジェット記録がふ
さわしいといえる。例えば、観光地の記念としてその場
で撮った写真を組み込んだ記念品や、新郎新婦の写真を
組み込んだ結婚式の引き出物等は容易に思いつくことで
ある。These hard media are used for decorations, souvenirs,
Original goods can be considered, but inkjet recording is suitable for printing various image information little by little, or when you want to obtain printed materials in a short time. For example, it is easy to come up with a souvenir that incorporates a photo taken on the spot as a memorial of a tourist spot, or a wedding gift that incorporates a photo of the bride and groom.
【０００６】かたい媒体のひとつとして金属があるが、
金属の中でもとりわけアルミニウムは軽く、さびにくい
ため、今後インクジェット記録における用途が広がって
いくことが予想される。だが、アルミニウムはそれ自体
はインクを吸収しないことから、表面に直接インクジェ
ット記録を行うことはできないので、表面にインクを吸
収することのできるインク受容層を形成しなければなら
ない。インク受容層としては水溶性ポリマーを膜状に成
形して用いられる。Metal is one of the hard media,
Among the metals, aluminum is light and rust-resistant, so it is expected that its use in inkjet recording will be expanded in the future. However, since aluminum itself does not absorb ink, it is not possible to carry out ink jet recording directly on the surface, and therefore an ink receiving layer capable of absorbing ink must be formed on the surface. As the ink receiving layer, a water-soluble polymer is formed into a film and used.
【０００７】しかしながら、本発明に先立ちアルミニウ
ム板上に上記インク受容層としてポリビニルアルコール
を成膜したところ、膜とアルミニウムの密着性は非常に
弱く、幅１８ｍｍのニチバンセロテープ（登録商標）に
よる１８０°剥離試験ではわずか８０ｇでインク受容層
がアルミニウム板からはがれた。このため、アルミニウ
ム板上に直接インク受容層を形成する方法では、インク
受容層の密着強度が弱くて、例えば周辺の紙とこすれた
り、あるいは作業中に誤って服でこすったりすると、容
易にはがれてしまう。However, when a polyvinyl alcohol film was formed as the ink receiving layer on the aluminum plate prior to the present invention, the adhesion between the film and aluminum was very weak, and 180 ° peeling was performed with Nichiban Cellotape (registered trademark) having a width of 18 mm. In the test, the ink receiving layer was peeled off from the aluminum plate with only 80 g. For this reason, in the method of directly forming the ink receiving layer on the aluminum plate, the ink receiving layer has a weak adhesion strength and is easily peeled off if it is rubbed against the surrounding paper or accidentally rubbed with clothes during the work. Will end up.
【０００８】このように、アルミニウム板はインクジェ
ット記録媒体として今後用途が広がると思われるにもか
かわらず、実用に適したものとはいえなかった。As described above, the aluminum plate is not suitable for practical use, though it is expected to be used as an ink jet recording medium in the future.
【０００９】[0009]
【発明が解決しようとする課題】本発明は前記問題点を
解決した新規のインクジェット記録用アルミニウム板を
提供することを目的とする。SUMMARY OF THE INVENTION It is an object of the present invention to provide a novel aluminum plate for ink jet recording which solves the above problems.
【００１０】[0010]
【課題を解決するための手段】前記の目的は以下の手段
によって達成される。The above object is achieved by the following means.
【００１１】すなわち、本発明は基材アルミニウム板の
表面に陽極酸化皮膜を有し、さらに、該皮膜上にインク
吸収性に優れたインク受容層を形成したことを特徴とす
るインクジェット記録用アルミニウム板を提案するもの
であり、前記陽極酸化皮膜の厚みが１０μｍ以上である
ことを含む。That is, the present invention has an aluminum plate for ink jet recording characterized by having an anodized film on the surface of a base aluminum plate, and further forming an ink receiving layer excellent in ink absorption on the film. And that the thickness of the anodized film is 10 μm or more.
【００１２】[0012]
【発明の実施の形態】以下本発明を図面を参照してさら
に詳細に説明する。図１は本発明のインクジェット記録
用アルミニウム板の一例を示す断面図である。BEST MODE FOR CARRYING OUT THE INVENTION The present invention will now be described in more detail with reference to the drawings. FIG. 1 is a sectional view showing an example of an inkjet recording aluminum plate of the present invention.
【００１３】本発明は図１のようにアルミニウム板１上
に陽極酸化皮膜２を形成してあり、さらに、該陽極酸化
皮膜２上にインク受容層３を形成してある。In the present invention, an anodized film 2 is formed on an aluminum plate 1 as shown in FIG. 1, and an ink receiving layer 3 is further formed on the anodized film 2.
【００１４】陽極酸化皮膜２をアルミニウム板１上に形
成するにはアルミニウム板１を陽極酸化液に浸漬して、
白金、鉛等をを陰極に、アルミニウム板１を陽極として
陽極酸化すればよい。陽極酸化液としてはバリアタイプ
とポアタイプがある。To form the anodized film 2 on the aluminum plate 1, the aluminum plate 1 is immersed in an anodizing solution,
Platinum, lead or the like may be used as a cathode, and the aluminum plate 1 may be used as an anode for anodic oxidation. The anodizing liquid includes a barrier type and a pore type.
【００１５】バリアタイプの陽極酸化液としては酒石酸
とエチレングリコールの混合液、硼酸等が挙げられ、こ
の陽極酸化液を用いて電圧５０〜５００Ｖ、電流密度
０．１〜２０Ａ／ｄｍ2 で陽極酸化することが好まし
い。Examples of the barrier type anodizing solution include a mixed solution of tartaric acid and ethylene glycol, boric acid and the like. Using this anodizing solution, anodizing is performed at a voltage of 50 to 500 V and a current density of 0.1 to 20 A / dm 2. Preferably.
【００１６】またポアタイプの陽極酸化液としては硫
酸、修酸、クロム酸等の酸が挙げられ、この陽極酸化液
を用いて電圧５〜５０Ｖ、電流密度０．５〜５Ａ／ｄｍ
2 の範囲で行うのが好ましい。陽極酸化皮膜２の厚みは
１０〜２５μｍの範囲が好ましい。Examples of the pore type anodic oxidation solution include acids such as sulfuric acid, oxalic acid and chromic acid. Using this anodic oxidation solution, the voltage is 5 to 50 V and the current density is 0.5 to 5 A / dm.
It is preferable to carry out in the range of 2 . The thickness of the anodized film 2 is preferably in the range of 10 to 25 μm.
【００１７】また陽極酸化皮膜２上に形成するインク受
容層としての水溶性ポリマーとしては、ポリビニルアル
コールおよびその誘導体、アクリル酸エステル重合体、
無水マレイン酸共重合体等の合成高分子、カルボキシル
メチルセルロース等のセルロース系高分子、デンプン、
カゼイン等が挙げられる。その厚みは７〜１５μｍの範
囲が好ましい。As the water-soluble polymer used as the ink receiving layer formed on the anodic oxide film 2, polyvinyl alcohol and its derivatives, acrylic acid ester polymers,
Synthetic polymers such as maleic anhydride copolymers, cellulosic polymers such as carboxymethyl cellulose, starch,
Casein etc. are mentioned. The thickness is preferably in the range of 7 to 15 μm.
【００１８】[0018]
【実施例】以下、本発明を実施例により更に具体的に説
明する。EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples.
【００１９】[0019]
【実施例１】本発明を図１に示す。図１において、１は
インクジェット記録媒体であるアルミニウム板、２はア
ルミニウム板上に形成した陽極酸化皮膜、３は陽極酸化
皮膜上に形成したインク受容層である。Example 1 The present invention is shown in FIG. In FIG. 1, 1 is an aluminum plate which is an ink jet recording medium, 2 is an anodized film formed on the aluminum plate, and 3 is an ink receiving layer formed on the anodized film.
【００２０】ここで、アルミニウム板はＪＩＳで示され
るＡ２０１７Ｐで板厚１．５ｍｍである。陽極酸化皮膜
形成に際してはアルミニウム板をアセトンで清払した
後、さらに２回、超音波洗浄機を使ってアセトン洗浄を
行った。陽極酸化は、硫酸１０％水溶液中において鉛板
を陰極とし、前記アルミニウム板を陽極として、電圧２
０Ｖ、電流密度１．５Ａ／ｄｍ2 にて６０分間陽極酸化
を行った。ここで形成された陽極酸化膜は厚み２０μｍ
である。インク受容層は、ケン化度８６〜９１ｍｏｌの
ポリビニルアルコール１０％水溶液を、バーコータによ
り陽極酸化皮膜上に塗布し、８０℃で１０分加熱乾燥し
て形成した。膜厚は１０μｍだった。Here, the aluminum plate is A2017P specified by JIS and has a plate thickness of 1.5 mm. In forming the anodic oxide film, the aluminum plate was cleaned with acetone, and then washed twice with an ultrasonic cleaner. The anodic oxidation was carried out by using a lead plate as a cathode and the aluminum plate as an anode in a 10% aqueous solution of sulfuric acid at a voltage of
Anodization was performed for 60 minutes at 0 V and a current density of 1.5 A / dm 2 . The anodic oxide film formed here has a thickness of 20 μm.
It is. The ink receiving layer was formed by coating a 10% aqueous solution of polyvinyl alcohol having a saponification degree of 86 to 91 mol on the anodized film with a bar coater and heating and drying at 80 ° C. for 10 minutes. The film thickness was 10 μm.
【００２１】本実施例で示したインク受容層についてテ
ープ剥離試験を行ったところ、８００ｇまでインク受容
層はアルミニウム板からはがれる事はなく、８００ｇを
越えると、テープがインク受容層からはがれた。さらに
密着性の強い東洋化学（株）製カラリヤンニュークロス
テープを幅２０ｍｍに切断して同様に１８０°剥離試験
を行ったところ、１５００ｇまでインク受容層ははがれ
ず、１５００ｇを越えたところで、テープが受容層から
はがれた。When a tape peeling test was performed on the ink receiving layer shown in this example, the ink receiving layer did not peel off from the aluminum plate up to 800 g, and when it exceeded 800 g, the tape peeled off from the ink receiving layer. Toray Chemical Co., Ltd. Karariyan New Cloth tape, which has a stronger adhesiveness, was cut into a width of 20 mm and similarly subjected to a 180 ° peeling test. The ink receiving layer did not peel off up to 1500 g, and when it exceeded 1500 g, The tape peeled from the receiving layer.
【００２２】本発明の詳細な検討によると、陽極酸化皮
膜の膜厚とテープ剥離強度には図２に示すような関係が
あり、皮膜膜厚が厚くなるにつれて剥離強度も向上する
ことがわかった。前述したように８００ｇを越えるとテ
ープがインク受容層からはがれてしまうのであるが、８
００ｇ程度の密着力を持つことにより多少こすれた程度
では受容層はアルミニウム板からはがれない事がわか
り、８００ｇを実用上の剥離強度のめやすとした。Detailed examination of the present invention revealed that the film thickness of the anodized film and the tape peel strength have a relationship as shown in FIG. 2, and that the peel strength improves as the film thickness increases. . As described above, if the weight exceeds 800 g, the tape will peel off from the ink receiving layer.
It was found that the receptive layer could not be peeled off from the aluminum plate even if it was rubbed to some extent by having an adhesive force of about 00 g, and 800 g was used as a target for practical peel strength.
【００２３】また、陽極酸化皮膜が１０μｍで密着強度
８００ｇが得られた。Further, an anodized film having a thickness of 10 μm and an adhesion strength of 800 g was obtained.
【００２４】[0024]
【発明の効果】以上説明したように、アルミニウム板上
に１０μｍ以上の厚みを有する陽極酸化皮膜を形成し、
さらにその上にインク受容層を形成することで、実用上
十分な密着強度を有し、また、サビ等の変質を生じるこ
とのないインクジェット記録のためのアルミニウム媒体
を得ることができる。As described above, an anodized film having a thickness of 10 μm or more is formed on an aluminum plate,
Further, by forming an ink receiving layer thereon, it is possible to obtain an aluminum medium for inkjet recording which has practically sufficient adhesion strength and does not cause deterioration such as rust.
【図１】本発明のインクジェット記録用アルミニウム板
の１例を示す断面図である。FIG. 1 is a cross-sectional view showing an example of an inkjet recording aluminum plate of the present invention.
【図２】陽極酸化皮膜の膜厚とテープ剥離強度の関係を
示すグラフである。FIG. 2 is a graph showing the relationship between the film thickness of an anodized film and tape peeling strength.
１ アルミニウム板 ２ 陽極酸化皮膜 ３ インク受容層 1 Aluminum plate 2 Anodized film 3 Ink receiving layer
Claims (2)
膜を有し、さらに該皮膜上にインク吸収性に優れたイン
ク受容層を形成したことを特徴とするインクジェット記
録用アルミニウム板。1. An aluminum plate for ink jet recording, comprising an anodized film on the surface of a base aluminum plate, and an ink receiving layer having excellent ink absorbability formed on the film.
である請求項１に記載のインクジェット記録用アルミニ
ウム板。2. The aluminum plate for inkjet recording according to claim 1, wherein the thickness of the anodized film is 10 μm or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8133468A JPH09314986A (en) | 1996-05-28 | 1996-05-28 | Aluminum plate for ink jet recording |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8133468A JPH09314986A (en) | 1996-05-28 | 1996-05-28 | Aluminum plate for ink jet recording |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH09314986A true JPH09314986A (en) | 1997-12-09 |
Family
ID=15105490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8133468A Pending JPH09314986A (en) | 1996-05-28 | 1996-05-28 | Aluminum plate for ink jet recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH09314986A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1170125A3 (en) * | 2000-07-04 | 2002-07-10 | Seiko Epson Corporation | Recording method |
| EP1197939A4 (en) * | 1999-08-23 | 2003-06-18 | Seiko Epson Corp | ORIGINAL DIAL PLATE, DIAL, AND METHOD FOR MANUFACTURING INDICATOR DEVICE |
-
1996
- 1996-05-28 JP JP8133468A patent/JPH09314986A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1197939A4 (en) * | 1999-08-23 | 2003-06-18 | Seiko Epson Corp | ORIGINAL DIAL PLATE, DIAL, AND METHOD FOR MANUFACTURING INDICATOR DEVICE |
| US6793977B2 (en) | 1999-08-23 | 2004-09-21 | Seiko Epson Corporation | Method of manufacturing a display plate and display apparatus |
| EP1170125A3 (en) * | 2000-07-04 | 2002-07-10 | Seiko Epson Corporation | Recording method |
| US6619793B2 (en) | 2000-07-04 | 2003-09-16 | Seiko Epson Corporation | Recording method |
| US6808257B2 (en) | 2000-07-04 | 2004-10-26 | Seiko Epson Corporation | Recording method |
| US6969167B2 (en) | 2000-07-04 | 2005-11-29 | Seiko Epson Corporation | Recording method |
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