JPH0948982A - Method for producing refined oil from waste plastic cracked oil - Google Patents
Method for producing refined oil from waste plastic cracked oilInfo
- Publication number
- JPH0948982A JPH0948982A JP22106595A JP22106595A JPH0948982A JP H0948982 A JPH0948982 A JP H0948982A JP 22106595 A JP22106595 A JP 22106595A JP 22106595 A JP22106595 A JP 22106595A JP H0948982 A JPH0948982 A JP H0948982A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- sulfuric acid
- refined oil
- treatment
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は廃プラスチック（こ
こで、「プラスチック」はエラストマー類、ワックス
類、グリース類等の狭義には樹脂に属しない重合体類を
も包含するものとする）、特に廃合成プラスチックの分
解によって得られる分解油から精製油を製造する方法に
関する。詳しくは、本発明は前記の分解油（油状物）を
後記の硫酸で処理して油中の窒素含有化合物を除去する
ことによる精製油の製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to waste plastics (here, "plastics" include polymers such as elastomers, waxes and greases which do not belong to resins in a narrow sense), particularly The present invention relates to a method for producing refined oil from decomposed oil obtained by decomposing waste synthetic plastics. More specifically, the present invention relates to a method for producing a refined oil by treating the above-mentioned cracked oil (oil) with sulfuric acid described below to remove nitrogen-containing compounds in the oil.
【０００２】[0002]
【従来の技術】ポリオレフィン類は分解によって容易に
油状化され得る。その結果として廃プラスチックを分解
して得られる油状物の中には往々にして窒素含有化合物
が含有される。その原因は分解原料である廃プラスチッ
ク中に往々にして含有される窒素含有重合体例えば、各
種ナイロン類、ポリウレタン類、ＡＢＳ樹脂及びＮＢＲ
に帰すことができる。Polyolefins can be easily oiled by decomposition. As a result, the oily products obtained by decomposing waste plastics often contain nitrogen-containing compounds. The cause is nitrogen-containing polymers, which are often contained in waste plastics that are decomposition raw materials, such as various nylons, polyurethanes, ABS resins and NBR.
Can be attributed to
【０００３】[0003]
【発明が解決しようとする課題】得られる油状物である
分解油の有効利用を妨げる原因となっているものは分解
原料である廃プラスチック中に通常は或割合で含有され
る窒素含有化合物であってそれがナイロン類から発生す
ることも既に判っている。The factor that hinders the effective use of the obtained oily cracked oil is the nitrogen-containing compound which is usually contained in the waste plastic as a cracking raw material in a certain ratio. It is already known that it is generated from nylons.
【０００４】しかし、上記の油状物から窒素含有化合物
を効果的で経済的に除去する方法が判らなかったことに
起因して、分解油は辛うじて燃料油として用いられて来
た程度である。However, cracked oils have barely been used as fuel oils due to the fact that a method for effectively and economically removing nitrogen-containing compounds from the above oils has not been found.
【０００５】[0005]
【課題を解決するための手段】本発明者は廃プラスチッ
クの分解によって得られる分解油から窒素含有化合物を
除去して各種の用途に用いられ得る精製油を得る為の精
製方法を広範に検討した結果、下記の精製方法を完成し
た。即ち、本発明は下記の製造方法に関する：廃プラス
チックの分解生成物である分解油を硫酸及び発煙硫酸か
ら選ばれる「硫酸」で処理することによって油中に含有
されている窒素含有化合物を除去する精製油の製造方
法。The present inventor has extensively studied a refining method for removing a nitrogen-containing compound from a cracked oil obtained by decomposing waste plastic to obtain a refined oil that can be used for various purposes. As a result, the following purification method was completed. That is, the present invention relates to the following production method: Nitrogen-containing compounds contained in oil are removed by treating decomposed oil, which is a decomposition product of waste plastic, with "sulfuric acid" selected from sulfuric acid and fuming sulfuric acid. Process for producing refined oil.
【０００６】[0006]
＜分解原料となる廃プラスチック＞本発明における分解
油の原料となる重合体廃棄物特に、廃プラスチックは各
種のものを包含しており例えば、熱可塑性樹脂及び熱硬
化性樹脂の何れをも包含し得る：熱可塑性樹脂としては
ポリオレフィン（ＰＯ）例えば、ポリエチレン（Ｐ
Ｅ）、ポリプロピレン（ＰＰ）、スチレン系樹脂例え
ば、ポリスチレン（ＰＳ）、耐衝撃性ポリスチレン（Ｈ
ＩＰＳ）、窒素含有樹脂例えば、ポリアミド樹脂（別名
「ナイロン」）、ＡＢＳ樹脂、オレフィンモノマーと小
割合の別種モノマーとの共重合樹脂例えば、エチレン−
酢酸ビニル共重合樹脂（ＥＶＡ）及び別種樹脂であるポ
リカーボネート（ＰＣ）等並びに熱硬化性樹脂であるフ
ェノール樹脂、メラミン樹脂、尿素樹脂、アルキッド樹
脂及びポリウレタン（ＰＵ）等の何れかが単独でも又は
２種以上の混合物であっても差支えない。<Waste plastic as a raw material for decomposition> Polymer waste as a raw material for decomposed oil in the present invention, in particular, waste plastic includes various kinds, for example, both thermoplastic resin and thermosetting resin are included. Obtain: As the thermoplastic resin, polyolefin (PO), for example, polyethylene (P)
E), polypropylene (PP), styrene resin such as polystyrene (PS), high impact polystyrene (H
IPS), a nitrogen-containing resin such as a polyamide resin (also known as “nylon”), an ABS resin, a copolymer resin of an olefin monomer and a small proportion of another monomer such as ethylene-
Vinyl acetate copolymer resin (EVA) and polycarbonate (PC) which are different resins, and thermosetting resins such as phenol resin, melamine resin, urea resin, alkyd resin and polyurethane (PU) alone or 2 It may be a mixture of two or more species.
【０００７】なお、本発明方法の分解原料である合成重
合体とは、合成樹脂に限らず軟質の重合体、共重合体及
びそれらの２種以上の組成物等を広範に包含する重合体
であって、その典型的例を下記に挙げる： ◆エチレン系ワックス状重合体もしくはグリース状重合
体、 ◆プロピレン系ワックス状重合体もしくはグリース状重
合体例えばアタクチックポリプロピレン又は ◆合成ゴム例えばエチレン−プロピレン共重合ゴム（Ｅ
ＰＭ）、エチレン−プロピレン−非共役ジエン共重合ゴ
ム（ＥＰＤＭ）、スチレン−ブタジエン共重合ゴム（Ｓ
ＢＲ）、ブタジエン−アクリロニトリル共重合体ゴム
（ＮＢＲ）、ポリイソプレンゴム（ＩＲ）、ブチルゴム
（ＩＩＲ）、ポリブタジエンゴム（ＢＲ）及びそれらの
架橋物（加硫物）、熱可塑性エラストマー例えばエチレ
ン−プロピレン−非共役ジエン共重合ゴム／ポリエチレ
ン組成物の部分架橋物、スチレン−ブタジエン共重合体
水素化物及び通称「石油樹脂」等の合成「炭化水素樹
脂」をも包含する。The synthetic polymer used as the decomposition raw material in the method of the present invention is not limited to synthetic resins, but is a polymer that includes a wide range of soft polymers, copolymers and compositions of two or more thereof. The typical examples are as follows: ◆ ethylene wax polymer or grease polymer, ◆ propylene wax polymer or grease polymer such as atactic polypropylene, ◆ synthetic rubber such as ethylene-propylene copolymer Polymerized rubber (E
PM), ethylene-propylene-non-conjugated diene copolymer rubber (EPDM), styrene-butadiene copolymer rubber (S
BR), butadiene-acrylonitrile copolymer rubber (NBR), polyisoprene rubber (IR), butyl rubber (IIR), polybutadiene rubber (BR) and their crosslinked products (vulcanized products), thermoplastic elastomers such as ethylene-propylene- It also includes partially crosslinked products of non-conjugated diene copolymer rubber / polyethylene compositions, styrene-butadiene copolymer hydrides and synthetic "hydrocarbon resins" such as commonly known as "petroleum resins".
【０００８】特に、分解原料中に或程度の量で低融点重
合体例えば、アタクチックポリプロピレンが共存するこ
とは本発明方法の実施にとって好ましい。その理由は分
解装置において本発明方法を実施する際に該重合体が先
ず溶融して、分解に先立って生ずるべき変化である分解
原料重合体の溶融又は細分を助ける働きをすることにあ
る。即ち、溶融した低融点重合体が本命の分解原料重合
体の表面に密着して熱エネルギーを効果的に伝達する結
果、本命重合体の溶融に必要なエネルギーを節減する役
割を果たすことが期待され得る。In particular, it is preferable for carrying out the method of the present invention that a low melting point polymer such as atactic polypropylene is present in the decomposition raw material in a certain amount. The reason is that when the method of the present invention is carried out in a cracking apparatus, the polymer is first melted and serves to aid the melting or subdividing of the cracked starting polymer which is the change which should occur prior to cracking. That is, it is expected that the melted low melting point polymer will adhere to the surface of the favorite raw material polymer for decomposition to effectively transfer heat energy, and as a result, it will play a role of saving the energy required for melting the favorite polymer. obtain.
【０００９】本発明方法の原料として特に好ましい合成
重合体はポリエチレン、ポリプロピレンなどのポリオレ
フィン及び２種以上のオレフィン重合体の組成物並びに
それらの成分モノマーの共重合体を主成分とするもので
ある。A particularly preferred synthetic polymer as a raw material for the method of the present invention comprises a composition of polyolefin such as polyethylene and polypropylene and a composition of two or more kinds of olefins and a copolymer of those component monomers as a main component.
【００１０】他方、分解原料中には多くの場合に窒素含
有重合体が混在する。混在重合体としては例えば、下記
の様な重合体（「樹脂」及び「ゴム」、別名「結晶性重
合体」及び「非晶性もしくは低結晶性重合体」を包含す
る）を挙げることができる： ◆窒素含有重合体としてポリアミド樹脂（別名「ナイロ
ン」）、ＡＢＳ樹脂、ポリウレタン類、ブタジエン−ア
クリロニトリル共重合体ゴム（ＮＢＲ）。On the other hand, a nitrogen-containing polymer is often mixed in the decomposition raw material. Examples of the mixed polymer include the following polymers (including "resin" and "rubber", also known as "crystalline polymer" and "amorphous or low crystalline polymer"). : Polyamide resin (also known as “nylon”), ABS resin, polyurethanes, butadiene-acrylonitrile copolymer rubber (NBR) as the nitrogen-containing polymer.
【００１１】本発明の＜精製油製造方法＞（「本発明の
精製方法」と略称することがある）は上記の窒素含有重
合体が通常０.１〜２０重量％、好ましくは１〜１０重
量％（全重合体量基準）混在する原料プラスチックに対
して著効を発揮する。The <refined oil production method> of the present invention (sometimes abbreviated as “refining method of the present invention”) contains the above nitrogen-containing polymer in an amount of usually 0.1 to 20% by weight, preferably 1 to 10% by weight. % (Based on the total amount of polymer) It is extremely effective against mixed raw material plastics.
【００１２】＜精製処理用の「硫酸」＞本発明の精製方
法において用いられる「硫酸」は濃度５０〜１００容量
％の硫酸及び濃度１００容量％を超える発煙硫酸から選
ばれるものである。ここで、発煙硫酸とは濃硫酸に更に
三酸化硫黄（ＳＯ3）を溶解させたもので、通常は三酸
化硫黄含有量２５％又は６０％のものが提供されてい
る。その理由はこれらが液状を保持していることにある
とされている。とはいえ、本発明の精製方法における発
煙硫酸が上記の２種類の濃度のものに限定される訳では
ない。<Sulfuric Acid for Purification Treatment> The “sulfuric acid” used in the purification method of the present invention is selected from sulfuric acid having a concentration of 50 to 100% by volume and fuming sulfuric acid having a concentration of more than 100% by volume. Here, fuming sulfuric acid is a solution in which sulfur trioxide (SO 3 ) is further dissolved in concentrated sulfuric acid, and is usually provided with a sulfur trioxide content of 25% or 60%. It is said that the reason for this is that they hold a liquid state. However, the fuming sulfuric acid in the refining method of the present invention is not limited to the above two concentrations.
【００１３】本発明の精製方法において所期の効果を発
現させるには上記の硫酸を分解油１００容量当たり通常
０.１〜１００容量／(処理１回)、好ましくは０.５〜５
０容量／(処理１回)の割合で加えて通常は２０〜５０℃
で接触処理を行なわせる。In order to bring out the desired effect in the refining method of the present invention, the above-mentioned sulfuric acid is usually used in an amount of 0.1 to 100 volume / (one treatment) per 100 volume of cracked oil, preferably 0.5 to 5
Add to the ratio of 0 volume / (treatment once), usually 20 ~ 50 ℃
Contact treatment is performed with.
【００１４】＜操作条件＞本発明の精製方法は上記の分
解油１００容量当たりに硫酸を０.１〜１００容量／(処
理１回)、好ましくは０.５〜５０容量／(処理１回)の割
合で通常２〜６回、好ましくは３〜５回接触させると共
に、反応系を常温０〜１００℃、好ましくは１０〜５０
℃に通常１min〜３h／(処理１回)、好ましくは５min〜
１h／(処理１回)攪拌して窒素含有化合物を除去する方
法である。<Operating conditions> In the refining method of the present invention, sulfuric acid is added in an amount of 0.1 to 100 volume / (one treatment), preferably 0.5 to 50 volume / (one treatment) per 100 volume of the cracked oil. Is usually 2 to 6 times, preferably 3 to 5 times, and the reaction system is at room temperature 0 to 100 ° C., preferably 10 to 50.
Usually 1 min to 3 h / (1 treatment), preferably 5 min to
In this method, the nitrogen-containing compound is removed by stirring for 1 h / (one treatment).
【００１５】上記の本発明の精製操作は各種の反応方式
（装置）を用いて行なうことができ例えば、槽型（バッ
チ）反応方式又は交流（２以上の流れが交差）接触方式
もしくは向流接触方式等を用いることができる。これら
の接触方式においては攪拌機構、スクレーパー機構等を
併用することが好ましい。The above refining operation of the present invention can be carried out by using various reaction systems (apparatuses), for example, a tank type (batch) reaction system, an alternating current (crossing two or more streams) contact system, or countercurrent contact. A method or the like can be used. In these contact methods, it is preferable to use a stirring mechanism, a scraper mechanism and the like together.
【００１６】本発明の精製方法によって精製された油状
物は次に、ナフサクラッキングと同一の処理によって石
油化学原料として要求される高純度のエチレン、プロピ
レン、1-ブテン、ブタジエン、イソプレン、ベンゼン、
トルエン、キシレンその他の不飽和炭化水素へ変換され
得る。変換によって得られる不飽和炭化水素の中でも、
エチレン及びプロピレンが広汎な製品の原料となり得る
点で好ましい。The oil refined by the refining method of the present invention is then subjected to the same treatment as naphtha cracking to obtain high-purity ethylene, propylene, 1-butene, butadiene, isoprene, benzene, which is required as a petrochemical raw material.
It can be converted to toluene, xylene and other unsaturated hydrocarbons. Among the unsaturated hydrocarbons obtained by conversion,
Ethylene and propylene are preferable because they can be used as raw materials for a wide variety of products.
【００１７】本発明の精製方法によって達成された効果
を確認する為の定量分析は下記の分析装置を用いて行な
った： ◆窒素含有化合物の定量：微量全窒素分析装置（三菱化
学社製）。Quantitative analysis for confirming the effect achieved by the purification method of the present invention was carried out using the following analyzers: ◆ Quantification of nitrogen-containing compounds: trace total nitrogen analyzer (manufactured by Mitsubishi Chemical Corporation).
【００１８】[0018]
【発明の効果】本発明の精製方法によれば、(１)廃プラ
スチックの分解によって生成する分解油から効果的にし
かも経済的に窒素含有化合物を除去して精製油を得るこ
とができる、(２)更にその精製油をスチームクラッキン
グ処理することによって石油化学原料に使用可能な純度
のエチレン、プロピレン等の1-オレフィン、ブタジエ
ン、イソプレン等の共役ジオレフィンを再生することも
できる。EFFECTS OF THE INVENTION According to the refining method of the present invention, (1) a refined oil can be obtained by effectively and economically removing nitrogen-containing compounds from a decomposed oil produced by decomposing waste plastic. 2) Further, by subjecting the refined oil to steam cracking treatment, 1-olefins such as ethylene and propylene having a purity usable for petrochemical raw materials, and conjugated diolefins such as butadiene and isoprene can be regenerated.
【００１９】[0019]
【実施例１】精製装置として不働態化処理された鋼製の
反応器（容量１００ml） 内に廃ポリプロピレンの熱分
解油（窒素含有量４７０ppm）及び工業用硫酸（濃度９
８容量％）１vol％（熱分解油基準）を装入して２５℃
温で３０min攪拌下に接触させる処理を３回繰り返し
た。得られた処理済み油を分析した結果、窒素含有量１
５ppmであることが判った。Example 1 As a refining device, a passivated steel reactor (capacity 100 ml) was used, and pyrolysis oil of waste polypropylene (nitrogen content 470 ppm) and industrial sulfuric acid (concentration 9) were used.
8 vol%) 1 vol% (based on pyrolysis oil) is charged at 25 ℃
The treatment of contacting with stirring for 30 minutes at temperature was repeated 3 times. As a result of analyzing the obtained treated oil, the nitrogen content was 1
It was found to be 5 ppm.
【００２０】[0020]
【実施例２】精製装置として不働態化処理された鋼製の
反応器（容量１００ml）内に廃ポリプロピレンの熱分解
油（窒素含有量４７０ppm）及び工業用硫酸（濃度６７
容量％）１vol％（熱分解油基準）を装入して３０℃で
２０min攪拌下に接触させる処理を３回繰り返した。得
られた処理済み油を分析した結果、窒素含有量９０ppm
であることが判った。Example 2 A pyrolysis oil of waste polypropylene (nitrogen content: 470 ppm) and industrial sulfuric acid (concentration: 67) were placed in a passivated steel reactor (volume: 100 ml) as a refining device.
(Vol%) 1 vol% (based on pyrolysis oil) was charged and contacted with stirring at 30 ° C. for 20 minutes was repeated 3 times. Analysis of the resulting treated oil showed a nitrogen content of 90 ppm
Was found.
【００２１】[0021]
【実施例３】精製装置として不働態化処理された鋼製の
反応器（容量１００ml）内に廃ポリプロピレンの熱分解
油（窒素含有量１１０ppm）及び工業用硫酸（濃度８０
容量％）１vol％（熱分解油基準）を装入して５０℃で
２０min攪拌下に接触させる処理を３回繰り返した。得
られた処理済み油を分析した結果、窒素含有量９ppmで
あることが判った。Example 3 A pyrolysis oil of waste polypropylene (nitrogen content: 110 ppm) and industrial sulfuric acid (concentration: 80) were placed in a steel reactor (capacity: 100 ml) that had been passivated as a refining device.
(Vol%) 1 vol% (based on pyrolysis oil) was charged and contacted with stirring at 50 ° C. for 20 minutes was repeated 3 times. Analysis of the resulting treated oil revealed a nitrogen content of 9 ppm.
【００２２】[0022]
【実施例４】精製装置として不働態化処理された鋼製の
反応器（容量１００ml）内に廃ポリプロピレンの熱分解
油（窒素含有量１５００ppm）及び工業用硫酸（濃度８
０容量％）１vol％（熱分解油基準）を装入して３０℃
で３０min攪拌下に接触させる処理を３回繰り返した。
得られた処理済み油を分析した結果、窒素含有量２２０
ppmであることが判った。[Example 4] As a refining device, a pyrolyzed oil of waste polypropylene (nitrogen content 1500 ppm) and industrial sulfuric acid (concentration 8) were placed in a passivated steel reactor (capacity 100 ml).
0 vol%) 1vol% (pyrolysis oil standard)
The treatment of contacting with stirring for 30 minutes was repeated 3 times.
Analysis of the resulting treated oil showed a nitrogen content of 220
It was found to be ppm.
【００２３】[0023]
【実施例５】実施例３において製造された精製油を水蒸
気で１０容量倍に希釈し、得られた混合気体を温度８０
０℃、平均反応時間０.５minの条件下でスチームクラッ
キングした結果、エチレン１９重量％及びプロピレン２
１重量％が得られた。Example 5 The refined oil produced in Example 3 was diluted with water vapor to a volume of 10 times, and the resulting mixed gas was heated to a temperature of 80.
As a result of steam cracking under conditions of 0 ° C. and an average reaction time of 0.5 min, ethylene 19% by weight and propylene 2
1% by weight was obtained.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ０８Ｊ 11/00 Ｃ０８Ｊ 11/00 11/10 11/10 11/14 11/14 Ｃ１０Ｇ 11/20 9279−4Ｈ Ｃ１０Ｇ 11/20 // Ｃ１０Ｇ 1/10 ＺＡＢ 9547−4Ｈ 1/10 ＺＡＢ (72)発明者 廣 渡 紀 之 山口県玖珂郡和木町和木六丁目１番２号 三井石油化学工業株式会社内─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical display location C08J 11/00 C08J 11/00 11/10 11/10 11/14 11/14 C10G 11/20 9279 -4H C10G 11/20 // C10G 1/10 ZAB 9547-4H 1/10 ZAB (72) Inventor Noriyuki Hiroto 6-2 Waki, Waki-cho, Kuga-gun, Yamaguchi Mitsui Petrochemical Industry Co., Ltd.
Claims (6)
油を硫酸で処理することによって油中に含有されている
窒素含有化合物を除去する精製油の製造方法。1. A method for producing a refined oil, which comprises treating a decomposed oil, which is a decomposition product of waste plastic, with sulfuric acid to remove nitrogen-containing compounds contained in the oil.
求項１に記載の精製油の製造方法。2. The method for producing a refined oil according to claim 1, wherein the treatment is performed at a temperature of 0 to 100 ° C.
００容量％の硫酸を用いる請求項１又は２に記載の精製
油の製造方法。3. The concentration of sulfuric acid for treatment is 50 to 1
The method for producing a refined oil according to claim 1 or 2, wherein 00% by volume of sulfuric acid is used.
求項１又は２に記載の精製油の製造方法。4. The method for producing a refined oil according to claim 1, wherein fuming sulfuric acid is used as the treating sulfuric acid.
０.１〜１００容量／(処理１回)である請求項１〜４の
何れかに記載の精製油の製造方法。5. The method for producing a refined oil according to claim 1, wherein the amount of sulfuric acid used is 0.1 to 100 volume / (one treatment) per 100 volume of cracked oil.
をエチレン製造プラントにおいてナフサ分解と同一条件
下にクラッキング処理するエチレン及びプロピレン等の
石油化学原料の製造方法。6. A method for producing a petrochemical raw material such as ethylene and propylene, in which the refined oil obtained in any one of claims 1 to 5 is cracked in an ethylene production plant under the same conditions as naphtha cracking.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22106595A JPH0948982A (en) | 1995-08-07 | 1995-08-07 | Method for producing refined oil from waste plastic cracked oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22106595A JPH0948982A (en) | 1995-08-07 | 1995-08-07 | Method for producing refined oil from waste plastic cracked oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0948982A true JPH0948982A (en) | 1997-02-18 |
Family
ID=16760948
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22106595A Pending JPH0948982A (en) | 1995-08-07 | 1995-08-07 | Method for producing refined oil from waste plastic cracked oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0948982A (en) |
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| JP2023508356A (en) * | 2019-12-23 | 2023-03-02 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular economy of waste plastics into polyethylene via refineries and crude units |
| JP2023508355A (en) * | 2019-12-23 | 2023-03-02 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular economy of waste plastics into polyethylene and chemicals via refineries and crude units |
| JP2023508352A (en) * | 2019-12-23 | 2023-03-02 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular economy of waste plastics into polyethylene and lubricants via crude and isomerization dewaxing units |
| JP2023522976A (en) * | 2020-04-22 | 2023-06-01 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular Economy of Waste Plastics to Polypropylene Via Petroleum Refining with Pyrolysis Oil Filtration and Metal Oxide Treatment |
| JP2023522977A (en) * | 2020-04-22 | 2023-06-01 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular economy of waste plastics into polyethylene via petroleum refining with pyrolysis oil filtration and metal oxide treatment |
| FR3141182A1 (en) * | 2022-10-25 | 2024-04-26 | Totalenergies Onetech | Process for purifying a plastic liquefaction oil composition |
| US11999920B2 (en) | 2020-09-14 | 2024-06-04 | Ecolab Usa Inc. | Cold flow additives for plastic-derived synthetic feedstock |
| US12031097B2 (en) | 2021-10-14 | 2024-07-09 | Ecolab Usa Inc. | Antifouling agents for plastic-derived synthetic feedstocks |
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-
1995
- 1995-08-07 JP JP22106595A patent/JPH0948982A/en active Pending
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|---|---|---|---|---|
| JP2023508356A (en) * | 2019-12-23 | 2023-03-02 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular economy of waste plastics into polyethylene via refineries and crude units |
| JP2023508355A (en) * | 2019-12-23 | 2023-03-02 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular economy of waste plastics into polyethylene and chemicals via refineries and crude units |
| JP2023508352A (en) * | 2019-12-23 | 2023-03-02 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular economy of waste plastics into polyethylene and lubricants via crude and isomerization dewaxing units |
| US12319877B2 (en) | 2019-12-23 | 2025-06-03 | Chevron U.S.A. Inc. | Circular economy for plastic waste to polypropylene and lubricating oil via refinery FCC and isomerization dewaxing units |
| JP2023522976A (en) * | 2020-04-22 | 2023-06-01 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular Economy of Waste Plastics to Polypropylene Via Petroleum Refining with Pyrolysis Oil Filtration and Metal Oxide Treatment |
| JP2023522977A (en) * | 2020-04-22 | 2023-06-01 | シェブロン ユー．エス．エー． インコーポレイテッド | Circular economy of waste plastics into polyethylene via petroleum refining with pyrolysis oil filtration and metal oxide treatment |
| US11999920B2 (en) | 2020-09-14 | 2024-06-04 | Ecolab Usa Inc. | Cold flow additives for plastic-derived synthetic feedstock |
| US12503663B2 (en) | 2020-09-14 | 2025-12-23 | Ecolab Usa Inc. | Cold flow additives for plastic-derived synthetic feedstock |
| US12304888B2 (en) | 2021-03-10 | 2025-05-20 | Ecolab Usa Inc. | Stabilizer additives for plastic-derived synthetic feedstock |
| US12031097B2 (en) | 2021-10-14 | 2024-07-09 | Ecolab Usa Inc. | Antifouling agents for plastic-derived synthetic feedstocks |
| FR3141182A1 (en) * | 2022-10-25 | 2024-04-26 | Totalenergies Onetech | Process for purifying a plastic liquefaction oil composition |
| WO2024089319A1 (en) * | 2022-10-25 | 2024-05-02 | Totalenergies Onetech | Method for the purification of a plastic liquefaction oil composition |
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