JPH101401A - Freshness preservation of cut flower and freshness preserving material therefor - Google Patents
Freshness preservation of cut flower and freshness preserving material thereforInfo
- Publication number
- JPH101401A JPH101401A JP15076296A JP15076296A JPH101401A JP H101401 A JPH101401 A JP H101401A JP 15076296 A JP15076296 A JP 15076296A JP 15076296 A JP15076296 A JP 15076296A JP H101401 A JPH101401 A JP H101401A
- Authority
- JP
- Japan
- Prior art keywords
- freshness
- activated carbon
- cut
- water
- fibrous activated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 37
- 238000004321 preservation Methods 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 97
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000011148 porous material Substances 0.000 claims abstract description 18
- 229940100890 silver compound Drugs 0.000 claims abstract description 15
- 150000003379 silver compounds Chemical class 0.000 claims abstract description 15
- 229910052709 silver Inorganic materials 0.000 claims abstract description 14
- 239000004332 silver Substances 0.000 claims abstract description 14
- 235000015097 nutrients Nutrition 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 230000014759 maintenance of location Effects 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 15
- 239000005977 Ethylene Substances 0.000 abstract description 15
- 230000032683 aging Effects 0.000 abstract description 10
- 239000005556 hormone Substances 0.000 abstract description 10
- 229940088597 hormone Drugs 0.000 abstract description 10
- 238000007598 dipping method Methods 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000000050 nutritive effect Effects 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 25
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 11
- -1 silver thiosulfate anion Chemical class 0.000 description 9
- 238000003756 stirring Methods 0.000 description 7
- 240000006497 Dianthus caryophyllus Species 0.000 description 6
- 235000009355 Dianthus caryophyllus Nutrition 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 4
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 229920002978 Vinylon Polymers 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 230000001851 biosynthetic effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002532 enzyme inhibitor Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 239000011295 pitch Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000029058 respiratory gaseous exchange Effects 0.000 description 3
- 229910001923 silver oxide Inorganic materials 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- NQRKYASMKDDGHT-UHFFFAOYSA-N (aminooxy)acetic acid Chemical compound NOCC(O)=O NQRKYASMKDDGHT-UHFFFAOYSA-N 0.000 description 2
- USGUVNUTPWXWBA-JRIXXDKMSA-N (e,2s)-2-amino-4-(2-aminoethoxy)but-3-enoic acid Chemical compound NCCO\C=C\[C@H](N)C(O)=O USGUVNUTPWXWBA-JRIXXDKMSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 241000735332 Gerbera Species 0.000 description 2
- 240000006568 Lathyrus odoratus Species 0.000 description 2
- SOWBFZRMHSNYGE-UHFFFAOYSA-N Monoamide-Oxalic acid Natural products NC(=O)C(O)=O SOWBFZRMHSNYGE-UHFFFAOYSA-N 0.000 description 2
- 241000233855 Orchidaceae Species 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 238000009960 carding Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RNAMYOYQYRYFQY-UHFFFAOYSA-N 2-(4,4-difluoropiperidin-1-yl)-6-methoxy-n-(1-propan-2-ylpiperidin-4-yl)-7-(3-pyrrolidin-1-ylpropoxy)quinazolin-4-amine Chemical compound N1=C(N2CCC(F)(F)CC2)N=C2C=C(OCCCN3CCCC3)C(OC)=CC2=C1NC1CCN(C(C)C)CC1 RNAMYOYQYRYFQY-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 241000109329 Rosa xanthina Species 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical group [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000002817 coal dust Substances 0.000 description 1
- 239000011300 coal pitch Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229940125532 enzyme inhibitor Drugs 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000009758 senescence Effects 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は,収穫したり,花瓶
等に生けたバラ,ラン,カーネーション,スイートピ
ー,ガーベラ等の切り花を,鮮度よく保存することがで
きる切り花の鮮度保持方法と鮮度保持材に関するもので
ある。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cut flower freshness preserving method and a freshness preserving material for preserving cut flowers such as roses, orchids, carnations, sweet pea, gerberas, etc. harvested or laid in vases. It is about.
【0002】[0002]
【従来の技術】花きの多くは,切り花として収穫される
と,老化ホルモンとして知られているエチレンを生成
し,このエチレンが花きの開花及び老化を促進させる。
特に,バラ,ラン,カーネーション,スイートピー,ガ
ーベラ等は,エチレンによって著しく老化を促進させら
れる。2. Description of the Related Art When flowers are harvested as cut flowers, they produce ethylene known as aging hormone, which promotes flowering and senescence of flowers.
In particular, rose, orchid, carnation, sweet pea, gerbera, etc. are markedly accelerated by ethylene.
【0003】エチレンの作用を阻害するかあるいは生合
成を阻害する物質が知られており,そのうちのいくつか
は切り花の品質保持剤として利用されている。作用阻害
剤としては,チオ硫酸銀アニオン複合体が主に使用さ
れ,また,生合成酵素阻害剤としては,アミノエトキシ
ビニルグリシン,アミノオキシ酢酸等が主に使用されて
いる。[0003] Substances that inhibit the action of ethylene or inhibit biosynthesis are known, and some of them are used as quality preservatives for cut flowers. As the action inhibitor, a silver thiosulfate anion complex is mainly used, and as the biosynthetic enzyme inhibitor, aminoethoxyvinylglycine, aminooxyacetic acid, and the like are mainly used.
【0004】チオ硫酸銀アニオン複合体は,安価で,か
つ多くの切り花の品質保持に高い効果があることから広
く利用されている。しかし,その主成分が銀イオンであ
ることから,環境汚染を引き起こす可能性があり,その
使用が問題視されつつある。そのためチオ硫酸銀アニオ
ン複合体に代わる薬剤として,アミノエトキシビニルグ
リシン,アミノオキシ酢酸等の生合成酵素阻害剤が用い
られているが,これらの生合成酵素阻害剤は,チオ硫酸
銀アニオン複合体に比べると高価であるだけではなく,
効果を示す花きの種類が少ないという問題がある。The silver thiosulfate anion complex is widely used because it is inexpensive and has a high effect on maintaining the quality of many cut flowers. However, since its main component is silver ion, it may cause environmental pollution, and its use is being regarded as a problem. Therefore, biosynthetic enzyme inhibitors such as aminoethoxyvinylglycine and aminooxyacetic acid have been used as an alternative to the silver thiosulfate anion complex. Not only is it more expensive,
There is a problem that there are few types of flowers that show an effect.
【0005】また,切り花を保存する水には,エチレン
作用阻害剤や生合成酵素阻害剤以外にも,栄養剤や殺菌
剤等が配合されている。栄養剤として,一般的には,オ
リゴ糖の一種であるスクロースが利用されており,スク
ロースで切り花の吸水量を低下させ,呼吸量を増加させ
て鑑賞期間の延長を図っている。殺菌剤は,切り花の切
り口付近の導管を細菌が閉塞して吸水を妨げるというベ
ントネック現象を引き起こし,花持ちが短くなるのを防
止するために添加されている。[0005] Water for storing cut flowers contains nutrients and fungicides in addition to ethylene action inhibitors and biosynthetic enzyme inhibitors. Sucrose, which is a kind of oligosaccharide, is generally used as a nutrient, and sucrose reduces the amount of water absorbed by cut flowers and increases the amount of respiration to extend the viewing period. Bactericides are added to prevent short-lived flowers, causing a bent neck phenomenon in which bacteria block the conduits near the cut ends of cut flowers and hinder water absorption.
【0006】さらに,生合成されたエチレン等の老化ホ
ルモンを,粒状活性炭で物理的に吸着して,切り花の花
持ちを長くする方法も利用されている。しかしながら,
この方法でも,粒状活性炭とともに,鮮度保持のために
エチレン作用阻害剤や栄養剤,殺菌剤等が使用されるた
め,栄養剤等の成分がミクロ孔とマクロ孔を有する粒状
活性炭に吸着され,粒状活性炭でエチレンを有効に吸着
することが困難であった。また,活性炭は,細菌の増殖
を促進させる可能性があり,それが切り花の鮮度保持に
悪影響を与えるという問題もある。Further, a method has also been used in which biosynthesized aging hormone such as ethylene is physically adsorbed by granular activated carbon to prolong the flower life of cut flowers. However,
In this method, too, since ethylene action inhibitors, nutrients, bactericides, etc. are used to maintain freshness together with granular activated carbon, nutrients and other components are adsorbed on the granular activated carbon having micropores and macropores, and granular activated carbon is absorbed. It was difficult to adsorb ethylene effectively with activated carbon. Activated carbon also has the problem that it may promote the growth of bacteria, which adversely affects the freshness of cut flowers.
【0007】[0007]
【発明が解決しようとする課題】本発明は,上記の問題
を解決し,種々の切り花を鮮度よく保存することができ
る切り花の鮮度保持方法と, この方法で使用する鮮度保
持材を提供することを技術的な課題とするものである。SUMMARY OF THE INVENTION The present invention solves the above-mentioned problems and provides a method for preserving the freshness of cut flowers which can preserve various cut flowers with good freshness, and a freshness preserving material used in this method. Is a technical issue.
【0008】[0008]
【課題を解決するための手段】本発明者らは,上記の課
題を解決するために鋭意検討した結果,切り花を保存す
るに際し,繊維状活性炭を浸漬した水中に切り口側を浸
漬すれば,栄養剤であるスクロースをほとんど吸着する
ことなく,エチレン等の老化ホルモンを効率的に吸着,
除去することができ,また,繊維状活性炭に銀や無機の
銀化合物を添着させれば,より確実にベントネック現象
を抑制できることを見出して本発明に到達した。Means for Solving the Problems The present inventors have conducted intensive studies in order to solve the above-mentioned problems. As a result, when preserving cut flowers, if the cut side is immersed in water in which fibrous activated carbon is immersed, nutrients can be obtained. Efficiently adsorbs aging hormones such as ethylene with little adsorption of sucrose
The present inventors have found that the vent neck phenomenon can be more reliably suppressed if silver or an inorganic silver compound is added to the fibrous activated carbon.
【0009】すなわち,本発明は,次の構成を有するも
のである。 (1) 切り口側を水中あるいは栄養剤を添加した水中に浸
漬して切り花の保存するに際し,繊維状活性炭を主成分
とする鮮度保持材を浸漬した水中で保存することを特徴
とする切り花の鮮度保持方法。 (2) 比表面積が 500〜2000m2/g,細孔直径30Å以下の細
孔の占める容積の割合が全細孔容積の90%以上である繊
維状活性炭を主成分としたものであることを特徴とする
切り切り花の鮮度保持材。 (3) 銀及び/又は無機の銀化合物を含有する上記(2) 記
載の切り花の鮮度保持材。That is, the present invention has the following configuration. (1) The freshness of cut flowers, characterized in that when the cut side is immersed in water or a water supplemented with nutrients, the cut flowers are preserved in water immersed in a freshness-maintaining material mainly composed of fibrous activated carbon. Retention method. (2) It must be based on fibrous activated carbon whose specific surface area is 500-2000 m 2 / g and the proportion of the volume occupied by pores with a pore diameter of 30 mm or less is 90% or more of the total pore volume. A feature that keeps cut flowers fresh. (3) The material for retaining freshness of cut flowers according to the above (2), which contains silver and / or an inorganic silver compound.
【0010】[0010]
【発明の実施の形態】以下,本発明について詳細に説明
する。本発明の切り花の鮮度保持材は,繊維状活性炭を
主成分とするシートあるいは成形体であり,繊維状活性
炭としては,石炭ピッチ系,石油ピッチ系,レーヨン
系,フェノール繊維系,ポリアクリロニトリル繊維系,
あるいはビニロン系等のものを使用することができる。
本発明で使用する繊維状活性炭の比表面積は,BET法
による測定値で,500〜2000m2/gのものが好ましい。比
表面積が500m2/g未満になると,細孔が小さくなり,エ
チレン等の老化ホルモンの吸着量が低下しやすくなる。
また,比表面積が2000m2/gを超えると細孔が大きくなり
すぎ,花きに有用な養分まで吸着されやすくなり,それ
にともないエチレン等の老化ホルモンの吸着量が低下し
やすくなる。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail. The freshness preserving material for cut flowers of the present invention is a sheet or a molded body containing fibrous activated carbon as a main component. Examples of the fibrous activated carbon include coal pitch-based, petroleum pitch-based, rayon-based, phenol fiber-based, and polyacrylonitrile fiber-based. ,
Alternatively, a vinylon type or the like can be used.
The specific surface area of the fibrous activated carbon used in the present invention is preferably from 500 to 2000 m 2 / g as measured by the BET method. When the specific surface area is less than 500 m 2 / g, pores become small, and the amount of adsorbed aging hormone such as ethylene tends to decrease.
On the other hand, when the specific surface area exceeds 2000 m 2 / g, the pores become too large, so that nutrients useful for flowering are easily adsorbed, and accordingly, the adsorption of aging hormone such as ethylene tends to decrease.
【0011】さらに,繊維状活性炭は,B.J.H法
(Barrett,Joyner,Halendaらの方法)で求められる細孔
分布において,細孔直径30Å以下の細孔の占める容積の
割合が,全細孔容積の90%以上であることが好ましい。
細孔容積が90%未満になると,花きに有用な養分を吸着
する大孔径の細孔が多くなり,例えば一般に使用される
粒状や粉末状活性炭のように細孔直径30Å以上の細孔が
20〜30%存在すると,有用な養分までも吸着し,エチレ
ン等の老化ホルモンの選択吸着性が低下する。Further, fibrous activated carbon is manufactured by B.I. J. In the pore distribution obtained by the H method (the method of Barrett, Joyner, Halenda et al.), The proportion of the volume occupied by pores having a pore diameter of 30 ° or less is preferably 90% or more of the total pore volume.
When the pore volume is less than 90%, the number of large pores that absorb nutrients useful for flowering increases, and for example, pores with a pore diameter of 30 mm or more such as commonly used granular or powdered activated carbon are used.
When present in an amount of 20 to 30%, even useful nutrients are adsorbed, and the selective adsorption of aging hormone such as ethylene is reduced.
【0012】本発明の切り花の鮮度保持材の形状として
は,繊維状活性炭の原綿を織布や不織布で包装したも
の,繊維状活性炭をシート状に形成したもの,前記シー
トを波形状やハニカム状に成形したもの,繊維状活性炭
とバインダーを水中に分散させ,この分散液を金型に導
入して円筒状あるいは円柱状に成形したもの,繊維状活
性炭を含有したスライバーを球状あるいは円筒状等に成
形したもの,繊維状活性炭と他の素材を水中で攪拌する
ことにより塊状物としたもの等を用いることができる。
これらの中では,シート状,球状,円筒状及び塊状物
が,製造コストと取り扱い性の点で優れている。[0012] The shape of the freshness retaining material for cut flowers of the present invention is as follows: fibrous activated carbon raw cotton wrapped with woven or nonwoven fabric, fibrous activated carbon formed into a sheet shape, and the sheet is corrugated or honeycomb-shaped. , A fibrous activated carbon and a binder dispersed in water, and this dispersion is introduced into a mold to form a cylindrical or cylindrical shape. A sliver containing fibrous activated carbon is formed into a spherical or cylindrical shape. A molded product, a material obtained by stirring fibrous activated carbon and another material into water, and the like can be used.
Among these, sheets, spheres, cylinders, and lump are excellent in terms of manufacturing cost and handleability.
【0013】上記のシート状や塊状物等の成形体を成形
する際に,繊維状活性炭とともに用いる他の素材として
は,低融点ポリエステル繊維,低融点ポリエステルを鞘
部分,高融点ポリエステルを芯部分とする複合繊維,ポ
リオレフィン繊維,ビニロン繊維,ポリエチレン繊維,
ポリプロピレン繊維,ポリエチレンを鞘部分,ポリプロ
ピレンを芯部分とする複合繊維等のバインダー繊維,ガ
ラス繊維やセラミック繊維等の無機繊維,綿,麻等の天
然繊維が挙げられる。繊維状活性炭にこれらの一種又は
二種以上を混合するが,混合割合は繊維状活性炭20〜90
重量%,他素材80〜10重量%が好ましい。繊維状活性炭
の量が20重量%未満になると,活性炭としての吸着効果
が低下しやすい。また,繊維状活性炭の量が90重量%を
超えると,シートや塊状物等の成形体に成形し難くな
り,形状安定性も悪くて炭塵が生じやすくなる。Other materials used together with the fibrous activated carbon when forming the above-mentioned molded article such as a sheet or lump are low-melting polyester fiber, low-melting polyester as a sheath, and high-melting polyester as a core. Composite fiber, polyolefin fiber, vinylon fiber, polyethylene fiber,
Examples thereof include binder fibers such as polypropylene fibers, composite fibers having polyethylene as a sheath portion and polypropylene as a core portion, inorganic fibers such as glass fibers and ceramic fibers, and natural fibers such as cotton and hemp. One or more of these are mixed with the fibrous activated carbon, but the mixing ratio is 20 to 90 fibrous activated carbon.
% By weight and 80 to 10% by weight of other materials are preferred. When the amount of fibrous activated carbon is less than 20% by weight, the adsorption effect as activated carbon tends to decrease. On the other hand, if the amount of the fibrous activated carbon exceeds 90% by weight, it becomes difficult to form into a molded article such as a sheet or a lump, the shape stability is poor, and coal dust is liable to be generated.
【0014】本発明の切り花の鮮度保持方法は,必要に
応じて栄養剤を添加した水中に,上記した繊維状活性炭
を主成分とする鮮度保持材を浸漬し,この水中に,切り
口側を浸漬して切り花を保存するものである。本発明で
使用する鮮度保持材は,粒状活性炭に比較してミクロ孔
の比率が高い繊維状活性炭を主成分としているので,切
り口側を浸漬して切り花を保存するに際し,花きに有用
な養分を吸着することなく,エチレン等の老化ホルモン
を効率的に吸着除去することが可能となり,花持ちを長
くすることができる。また,本発明で用いる鮮度保持材
は,繊維状活性炭を主成分としているので,エチレン等
の老化ホルモン,切り花の茎から分泌する有害物質の吸
着除去だけでなく,水中の溶存酸素を維持することも可
能であり,このため,切り花の呼吸量を増加させること
によって花持ちを長くすることができる。According to the method for preserving freshness of cut flowers of the present invention, the freshness preserving material containing fibrous activated carbon as a main component is immersed in water to which a nutrient is added as required, and the cut side is immersed in the water. And save the cut flowers. Since the freshness preserving material used in the present invention is mainly composed of fibrous activated carbon having a higher micropore ratio than granular activated carbon, when preserving cut flowers by immersing the cut side, nutrients useful for flowers can be obtained. Without adsorbing, aging hormones such as ethylene can be efficiently adsorbed and removed, and the flower life can be prolonged. In addition, since the freshness preserving material used in the present invention is mainly composed of fibrous activated carbon, it is necessary to not only adsorb and remove aging hormones such as ethylene and harmful substances secreted from cut flower stems, but also maintain dissolved oxygen in water. It is also possible to increase the flower life by increasing the respiration of cut flowers.
【0015】本発明の切り花の鮮度保持方法において,
繊維状活性炭を主成分とする鮮度保持材を水中で長期間
使用すると,水中に細菌が繁殖してベントネック現象を
引き起こす問題が生じる場合がある。このような問題の
発生を防ぐには,銀又は無機の銀化合物あるいは銀と無
機の銀化合物の両方を含有する鮮度保持材を使用すれば
よい。すなわち,銀及び/又は無機の銀化合物を含有す
る鮮度保持材を使用して切り花を保存すれば,養分を含
んだ水中で保存する場合も,銀の抗菌作用で細菌の増殖
を抑制することができるため,より簡便,かつ安全にベ
ントネック現象を抑制することが可能となり,切り花の
鑑賞期間をより長くすることができる。In the method for maintaining freshness of cut flowers according to the present invention,
If a freshness-maintaining material containing fibrous activated carbon as a main component is used in water for a long period of time, there may be a problem that bacteria grow in the water and cause a vent neck phenomenon. In order to prevent such a problem from occurring, a freshness maintaining material containing silver or an inorganic silver compound or both silver and an inorganic silver compound may be used. In other words, if cut flowers are preserved using a freshness-preserving material containing silver and / or an inorganic silver compound, even when preserved in water containing nutrients, the growth of bacteria can be suppressed by the antibacterial effect of silver. Therefore, the bent neck phenomenon can be more easily and safely suppressed, and the period for viewing cut flowers can be further lengthened.
【0016】鮮度保持材に銀及び/又は無機の銀化合物
を含有させる方法としては,難水溶性銀化合物を0.01〜
10重量%添着した繊維状活性炭や,銀を含有する原料繊
維から得られた繊維状活性炭を使用したり,繊維状活性
炭と抗菌性銀化合物を含有させたバインダー繊維を用い
てシート状や塊状物等の成形体を形成すればよい。As a method for incorporating silver and / or an inorganic silver compound into the freshness maintaining material, a sparingly water-soluble silver compound is used in an amount of from 0.01 to 0.01.
Use fibrous activated carbon impregnated with 10% by weight, fibrous activated carbon obtained from silver-containing raw material fibers, or sheet or aggregate using fibrous activated carbon and binder fibers containing antibacterial silver compound. And the like may be formed.
【0017】また,鮮度保持材に含有させる銀及び/又
は無機の銀化合物としては,難水溶性銀化合物が好まし
く,難水溶性銀化合物を含有した鮮度保持材を使用すれ
ば,より安価,かつ簡易に安定した抗菌作用が長期的に
得られ,一層花持ちを長くすることができる。ここで,
難溶解性銀化合物としては,塩化銀,酸化銀が簡易に得
られるので好ましい。The silver and / or inorganic silver compound to be contained in the freshness-maintaining material is preferably a sparingly water-soluble silver compound. If a freshness-maintaining material containing a sparingly water-soluble silver compound is used, it is cheaper and more expensive. Simple and stable antibacterial action can be obtained for a long period of time, and flower life can be further lengthened. here,
As the hardly soluble silver compound, silver chloride and silver oxide can be easily obtained, which is preferable.
【0018】[0018]
【実施例】次に,本発明を実施例により具体的に説明す
る。Next, the present invention will be described in detail with reference to examples.
【0019】実施例1 比表面積1150m2/gのピッチ系繊維状活性炭とユニチカ社
製ポリエステル系複合繊維「メルティ」をカーディング
マシーンで混合して,繊維状活性炭混率60重量%,目付
75g/m2,厚み 1.2mmの繊維状活性炭シートからなる切り
花の鮮度保持材を製造した。EXAMPLE 1 A pitch-based fibrous activated carbon having a specific surface area of 1150 m 2 / g and a polyester-based composite fiber “Melty” manufactured by Unitika Ltd. were mixed with a carding machine to obtain a fibrous activated carbon content of 60% by weight and a basis weight.
A cut flower freshness preserving material consisting of a fibrous activated carbon sheet having a thickness of 75 g / m 2 and a thickness of 1.2 mm was manufactured.
【0020】実施例2 比表面積1150m2/gのピッチ系繊維状活性炭に酸化銀を0.
5重量%添着したものと,実施例1で使用したポリエス
テル系複合繊維をカーディングマシーンで混合して,活
性炭混率60重量%,目付75g/m2,厚み 1.2mmの繊維状活
性炭シートからなる切り花の鮮度保持材を製造した。Example 2 Silver oxide was added to pitch-based fibrous activated carbon having a specific surface area of 1150 m 2 / g.
A cut flower consisting of a fibrous activated carbon sheet having a carbon content of 60% by weight, a basis weight of 75 g / m 2 , and a thickness of 1.2 mm was prepared by mixing the fiber impregnated with 5% by weight and the polyester composite fiber used in Example 1 with a carding machine. Was produced.
【0021】実施例3 繊維長5mm,比表面積1150m2/gのピッチ系繊維状活性炭
300gと,単糸繊度が3デニールで,繊維長5mmのビニロ
ン繊維200gとを攪拌槽内の水 100リットル中に分散さ
せ,パドル型の羽を持つ攪拌機で攪拌を続けた。約4時
間攪拌を続けた結果,多数の球状の塊が生成した。そこ
に,単糸繊度6デニールで,繊維長5mmのポリエステル
系サイドバイサイド型複合未延伸繊維(重合度 110のポ
リエチレンテレフタレート/重合度80のポリエチレンテ
レフタレート)500g を加え,攪拌を続けた。さらに,約
6時間攪拌を続けた結果,上記の繊維塊を包括するよう
な形で球状の塊を生成した。その後,攪拌槽内にスチー
ムを吹き込んで水温を90℃まで上昇させ,複合繊維を収
縮させて最大直径4〜6mmの球状をした成型体からなる
切り花の鮮度保持材を得た。Example 3 Pitch-based fibrous activated carbon having a fiber length of 5 mm and a specific surface area of 1150 m 2 / g
300 g and 200 g of vinylon fiber having a single fiber fineness of 3 denier and a fiber length of 5 mm were dispersed in 100 liters of water in a stirring tank, and stirring was continued with a stirrer having paddle type blades. As a result of continuing the stirring for about 4 hours, many spherical lumps were formed. To this was added 500 g of a polyester-based side-by-side composite undrawn fiber (polyethylene terephthalate having a degree of polymerization of 110 / polyethylene terephthalate having a degree of polymerization of 80) having a denier of 6 denier and a fiber length of 5 mm, and stirring was continued. Furthermore, as a result of continuing stirring for about 6 hours, a spherical lump was generated in such a manner as to cover the above-mentioned fiber lump. Thereafter, steam was blown into the stirring tank to raise the water temperature to 90 ° C., and the composite fiber was contracted to obtain a cut flower freshness preserving material consisting of a spherical molded body having a maximum diameter of 4 to 6 mm.
【0022】実施例4,比較例1 実施例1〜3で得られたシート及び成型体からなる鮮度
保持材を用い,次の方法でカーネーション切り花の花持
ちを調べた。鮮度保持材として,繊維状活性炭シートは
20mm2 板にカットしたもの,繊維状活性炭塊は直径5mm
のもの10粒を用い,水道水5リットルを入れたガラス容
器に,これらの鮮度保持剤を浸漬し,開花したカーネー
ション5本をさした。この容器を,25℃前後に加温した
恒温室の直射日光の当たらない場所で保管した。また,
比較例1として,鮮度保持剤を浸漬しない以外は上記と
同様の方法でカーネーションの保存を行った。なお,切
り花の花持ちの評価は,経過日数1,9,13日に, それ
ぞれしおれた花の累計本数を計数し,同様の試験を繰り
返してそれぞれ4回行った。評価結果を表1に示す。Example 4, Comparative Example 1 Using the sheets obtained in Examples 1 to 3 and the freshness-maintaining material composed of a molded product, the flowering of cut carnation flowers was examined by the following method. As a freshness preserving material, fibrous activated carbon sheet
Cut into 20mm 2 plates, fibrous activated carbon ingot 5mm in diameter
These freshness-preserving agents were immersed in a glass container containing 5 liters of tap water using 10 grains of the carnation, and 5 carnations that had bloomed were pointed out. The container was stored in a constant temperature room heated to about 25 ° C. in a place free from direct sunlight. Also,
As Comparative Example 1, carnation was preserved in the same manner as above, except that the freshness preserving agent was not immersed. In addition, the evaluation of the flower life of the cut flowers was carried out by counting the total number of withered flowers on the days 1, 9 and 13 elapsed, and repeating the same test four times each. Table 1 shows the evaluation results.
【0023】[0023]
【表1】 [Table 1]
【0024】表1から明らかなように,実施例1〜3で
得られた鮮度保持材を浸漬した水中で保存した場合,鮮
度保持材を浸漬しないで保存した比較例1と比較して,
切り花のしおれ本数を少なくすることができた。特に,
酸化銀を添着した繊維状活性炭をを主成分とする実施例
2の鮮度保持材を使用した場合,切り花のしおれ本数を
一層少なくすることができた。As is clear from Table 1, when the freshness-maintaining materials obtained in Examples 1 to 3 were stored in water immersed therein, compared with Comparative Example 1 in which the freshness-maintaining materials were stored without immersion,
The number of wilted cut flowers was reduced. Especially,
When the freshness preserving material of Example 2 mainly comprising fibrous activated carbon impregnated with silver oxide was used, the number of wilted cut flowers could be further reduced.
【0025】[0025]
【発明の効果】本発明の切り花の鮮度保持材を使用して
切り花を保存すれば,切り花の花持ちを悪くするエチレ
ン等の老化ホルモンを,花きに有用な養分を吸着するこ
となく,効率的に除去することができ,また,水中の溶
存酸素を維持することも可能であり,このため,切り花
の呼吸量を増加させることによって花持ちを長くするこ
とができる。さらに,鮮度保持材として,銀及び/又は
無機の銀化合物を含有するものを使用すれば,銀の抗菌
作用で細菌の増殖を抑制することができるため,より簡
便,かつ安全な方法でベントネック現象を抑制すること
が可能となり,切り花を一層鮮度よく保持することがで
きる。According to the present invention, if cut flowers are preserved using the cut flower freshness preserving material, aging hormones such as ethylene, which make cut flowers less durable, can be efficiently used without adsorbing nutrients useful for flowers. It is also possible to maintain dissolved oxygen in water, so that the flower life can be prolonged by increasing the respiration of cut flowers. Furthermore, if a material containing silver and / or an inorganic silver compound is used as a freshness preserving material, the growth of bacteria can be suppressed by the antibacterial effect of silver. The phenomenon can be suppressed, and the cut flowers can be kept more fresh.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 桜谷 敏子 京都府宇治市宇治小桜23番地 ユニチカ株 式会社中央研究所内 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Toshiko Sakuraya 23 Uji Kozakura, Uji-city, Kyoto Prefecture Unitika Research Laboratory
Claims (3)
た水中に浸漬して切り花を保存するに際し,繊維状活性
炭を主成分とする鮮度保持材を浸漬した水中で保存する
ことを特徴とする切り花の鮮度保持方法。1. A cut flower, wherein the cut side is immersed in water or water to which a nutrient is added, and the cut flower is preserved in water immersed in a freshness-maintaining material containing fibrous activated carbon as a main component. Freshness retention method.
Å以下の細孔の占める容積の割合が全細孔容積の90%以
上である繊維状活性炭を主成分としたものであることを
特徴とする切り切り花の鮮度保持材。2. A specific surface area of 500 to 2000 m 2 / g and a pore diameter of 30
。 A cut flower freshness preserving material characterized in that the main component is fibrous activated carbon in which the ratio of the volume occupied by the following pores is 90% or more of the total pore volume.
請求項2記載の切り花の鮮度保持材。3. The material for retaining freshness of cut flowers according to claim 2, which contains silver and / or an inorganic silver compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15076296A JPH101401A (en) | 1996-06-12 | 1996-06-12 | Freshness preservation of cut flower and freshness preserving material therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15076296A JPH101401A (en) | 1996-06-12 | 1996-06-12 | Freshness preservation of cut flower and freshness preserving material therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH101401A true JPH101401A (en) | 1998-01-06 |
Family
ID=15503867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15076296A Pending JPH101401A (en) | 1996-06-12 | 1996-06-12 | Freshness preservation of cut flower and freshness preserving material therefor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH101401A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006199592A (en) * | 2005-01-18 | 2006-08-03 | Aoyama Eco System:Kk | Life-prolonging material for cut flower |
| WO2015114959A1 (en) * | 2014-02-03 | 2015-08-06 | 株式会社炭化 | Freshness retaining agent, method for manufacturing same, gas purification device and gas purification system |
| CN107926937A (en) * | 2017-11-22 | 2018-04-20 | 四川农业大学 | A kind of method for extending azalea branch fresh keeping time |
-
1996
- 1996-06-12 JP JP15076296A patent/JPH101401A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006199592A (en) * | 2005-01-18 | 2006-08-03 | Aoyama Eco System:Kk | Life-prolonging material for cut flower |
| WO2015114959A1 (en) * | 2014-02-03 | 2015-08-06 | 株式会社炭化 | Freshness retaining agent, method for manufacturing same, gas purification device and gas purification system |
| JPWO2015114959A1 (en) * | 2014-02-03 | 2017-03-23 | 株式会社炭化 | Freshness-preserving agent, method for producing the same, gas purification device, and gas purification system |
| US10098365B2 (en) | 2014-02-03 | 2018-10-16 | Tanka Co., Ltd. | Freshness retaining agent, method for manufacturing the same, gas purification device, and gas purification system |
| CN107926937A (en) * | 2017-11-22 | 2018-04-20 | 四川农业大学 | A kind of method for extending azalea branch fresh keeping time |
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