JPH10194926A - Rhigotic composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a rhigotic composition especially for lip, capable of enhancing an effect for providing the cold feeling without increasing a formulating amount of a material for providing the cold feeling, excellent in feeling in use and hardly stimulating the sin by using two kinds of specific materials providing cold feeling in combination. SOLUTION: This rhigotic composition is obtained by formulating one or more kinds of polyhydric alcohols having endothermic heat of dissolution in water, and one or more kinds of menthol derivatives. The polyhydric alcohols are preferably erythritol and/or fructose. The menthol derivative is preferably 3-1-menthoxypropane-1,2-diol. The formulating amount of the polyhydric alcohols in the composition is preferably 0.01-10wt.%, and that of the menthol derivative is preferably 0.01-5wt.%. The composition is suitable for a rouge, a lipstick, etc.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a cooling sensation composition, particularly to a cooling sensation composition for lips.
The present invention relates to a cooling sensation composition having excellent usability and little skin irritation, particularly to a cooling sensation composition for lips.

[0002]

2. Description of the Related Art Heretofore, it has been conventionally practiced to cool a hot face or body or the like with cold water or wind when the summer is hot or after sports. Further, in order to obtain a refreshing sensation, cosmetics or the like containing alcohol or menthol have been applied to the body or sprayed with an aerosol.

[0003] However, alcohol, menthol,
It has been found that the cooling sensation substance such as gas contained in the aerosol causes irritation to the skin when the composition containing a large amount is repeatedly applied. Therefore, it is not preferable to mix a large amount of gas or the like mixed in alcohol, menthol, or aerosol, although it has a cooling effect. Further, in the case of sensitive skin such as lips, it is not particularly preferable, and there is no skin currently used for lips.

[0004]

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to develop a cooling sensation composition with less skin irritation by increasing the cooling sensation effect without increasing the amount of the cooling sensation substance. Things.

[0005]

Means for Solving the Problems The present inventors have made intensive studies to solve the above-mentioned problems, and as a result, by blending a polyhydric alcohol whose dissolution in water is endothermic with a menthol derivative. , Increased cooling effect, and even skin,
In particular, they have found that a substance with little irritation to the lips can be obtained, and have completed the present invention. That is, the present invention

[0006] A cooling sensation composition according to claim 1, characterized in that it contains one or more polyhydric alcohols which are endothermic in water and one or more menthol derivatives. It is.

The cooling sensation composition according to claim 1, wherein the polyhydric alcohol which dissolves in water is endothermic is erythritol and / or fructose.

[0008] In claim 3, the menthol derivative is 3
The cooling sensation composition according to claim 1 or 2, which is {l-menthoxypropane} 1,2 diol.

A cooling sensation for lips according to claim 4, characterized in that it contains one or more polyhydric alcohols whose endothermic properties in water are endothermic and one or more menthol derivatives. A composition.

[0010] In a fifth aspect of the present invention, there is provided the cool sensation composition for a lip according to the fourth aspect, wherein the polyhydric alcohol which is endothermic in water is erythritol and / or fructose.

[0011] In claim 6, the menthol derivative is 3
The cool sensation composition for a lip according to claim 4 or 5, which is {l-menthoxypropane} 1,2 diol.

[0012]

Embodiments of the present invention will be described below. The polyhydric alcohol having endothermic dissolution in water used in the present invention may be a commonly available one as long as its dissolution in water is endothermic, and may be used alone or in combination. Specific examples include fructose and erythritol.

The amount of the polyhydric alcohol used in the present invention is preferably 0.01 to 10% by weight.
If it is less than 0.01% by weight, the effect of improving the refreshing feeling and skin irritation is low, and if it exceeds 10% by weight, the obtained cosmetic is sticky and the usability is remarkably deteriorated.

The menthol derivative used in the present invention may be a commonly available one, and may be used alone or in combination. For example, 3-l-menthoxypropane {1,2-diol, l-menthyl-
3-hydroxybutyrate, l-methoxy-3 {l-menthoxypropane {2} ol, l-alkoxy-3}
l-menthoxypropane {2} ol;
In particular, 3-l-menthoxypropane {1,2} diol is preferable in that the effects of the present invention can be further exhibited.

The compounding amount of the menthol derivative is 0.0
1-5% by weight is preferred. If it is less than 0.01% by weight, the cooling sensation effect is small, and if it exceeds 5% by weight, the obtained cosmetics may be sticky or the like, impairing the usability or raising concerns about safety.

The cosmetic of the present invention may contain, in addition to the above essential components, components commonly used in cosmetics, quasi-drugs and the like as long as the effects of the present invention are not impaired. For example, water, oil, humectant, surfactant, dispersant, powder,
Preservatives, fragrances, drugs, thickeners, lower alcohols and the like can be mentioned.

In the present invention, the composition is most characteristic when it is made into a lip composition, and the form is not particularly limited, but includes lipsticks, lipsticks and the like which are generally known. In addition, components constituting the lip composition are not particularly limited, and general components are used.

The components constituting the lip composition include, for example, oil classifications such as cyclic polysiloxanes such as decamethylcyclopentasiloxane and octamethylcyclotetrasiloxane, dimethylpolysiloxane, and methylphenylpolysiloxane. , A chain polysiloxane such as methyl hydrogen polysiloxane, a silicone resin forming a three-dimensional network structure, a silicone oil such as a silicone rubber, a silicone wax, a fluorine-based oil such as a fluorocarbon, isopropyl myristate, 2-ethylhexane Cetyl acid, octyl dodecyl myristate,
2-ethylhexyl palmitate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isosetyl stearate, Cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol hexa-2-ethylhexanoate, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisostearyl malate, di- 2-glyceryl heptylundecanoate, tri
Trimethylolpropane-2-ethylhexanoate, trimethylolpropane triisostearate, pentaerythritol tetra-2-ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl triisopalmitate, trimethylolpropane triisostearate, tritriol Glycerin myristate, glyceride tri-2-heptylundecanoate, castor oil fatty acid methyl, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl
-L-glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate,
Di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, acetic acid Synthetic ester oils such as amyl and triethyl citrate, ozokerite, paraffin, ceresin, microcrystalline wax, petrolatum, liquid paraffin, hydrocarbon oils such as squalane, squalene, pristane, avocado oil, camellia oil, turtle oil, macadamia nut oil, corn Oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil,
Liquid natural animal and vegetable oils such as eno oil, soybean oil, peanut oil, teaseed oil, kaya oil, rice bran oil, cinnamon oil, Japanese kiri oil, jojoba oil, germ oil, camellia oil, cacao butter, coconut oil, horse fat, hardened Solid oils such as coconut oil, palm oil, beef tallow, sheep tallow, hardened tallow, palm kernel oil, lard, beef bone tallow, mokuro kernel oil, hardened oil, beef tallow, mokuro, hardened castor oil, etc., cetostearyl alcohol, etc. High alcohol, candelilla wax, carnauba wax, beeswax, cotton wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, isopropyl lanolin fatty acid, hexyl laurate, reduced lanolin, Jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate Over DOO, POE cholesterol ether, lanolin fatty acid polyethylene glycol, waxes such as POE hydrogenated lanolin alcohol ether.

Examples of the humectant include polyhydric alcohols such as polyethylene glycol, dynamite glycerin, 1,3-butylene glycol, dipropylene glycol, propylene glycol, and diglycerin (EO) PO adduct, xylitol, sorbitol, and maltitol. Water-soluble polymers such as saccharides, hyaluronic acid, chondroitin sulfate, mucoitin sulfate, caronic acid, atelocollagen,
Sodium lactate, sodium citrate, sodium glutamate, salt, magnesium chloride, bile salts, sodium 2-pyrrolidone carboxylate, salts such as dl-pyrrolidone carboxylate,
Plant extracts such as Izayobara extract, Achillea millefolium extract, and melilot extract, and short-chain soluble collagen.

The powder components include talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, phlogopite, biotite, litthic mica, permiculite,
Magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate, (calcium gypsum), calcium phosphate , Fluorine apatite, hydroxyapatite, ceramic powder, metal soap (zinc myristate, calcium palmitate, aluminum stearate), inorganic powder such as boron nitride, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, Organic powders such as polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, and inorganic white such as titanium dioxide and zinc oxide. Pigments, iron oxide (red iron oxide),
Inorganic red pigments such as iron titanate, inorganic brown pigments such as γ-iron oxide, yellow iron oxide, inorganic yellow pigments such as loess black iron oxide, carbon black, inorganic black pigments such as lower titanium oxide, Inorganic purple pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine blue and dark blue; titanium oxide coated mica; titanium oxide coated bismuth oxychloride , Titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, pearl pigments such as fish scale foil, aluminum powder,
Metal powder pigments such as copper powder, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red 220
No. Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401
No. 3, and organic pigments such as Blue No. 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230
No. Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3
Organic pigments such as zirconium, barium or aluminum lakes such as No. 1 and Blue No. 1, and natural pigments such as chlorophyll and β-carotene. Further, a powder which has been subjected to a hydrophobic treatment such as a silicone treatment, a fatty acid soap treatment, or a dextrin fatty acid treatment may be used. Note that these exemplified components are not limited to the cool sensation composition for lips, but are also blended with other cool sensation compositions.

[0021]

Next, the present invention will be described in more detail with reference to examples. The present invention is not limited by this. All amounts are by weight.

Example 1 Lipstick (Blending%) (1) Liquid paraffin 53.24 (2) Castor oil 10.0 (3) Decamethylpentacyclosiloxane 10.0 (4) Silicone resin 10.0 (5) Octyl methoxycinnamate 2.0 (6) Candelilla wax 3.0 (7) Carnauba wax 5.0 (8) 12-hydroxystearic acid 0.1 (9) Diisostearyl malate 1.0 (10) Titanium dioxide 0.5 (11) Iron oxide red 0.3 (12) Iron oxide yellow 1.0 (13) Red No. 204 0.7 (14) Red 202 No. 0.01 (15) Erythritol 3.0 (16) 3 {L-menthoxypropane {1,2} diol 0.1 (17) Perfume 0.05 (Production method) After dissolving (1) to (9), stirring and mixing other powder, perfume, etc., mold And cooled to give a lipstick.

Comparative Example 1 Lipstick Example 1 (15) was replaced with liquid paraffin (Production method) A lipstick was produced in the same manner as in Example 1.

Comparative Example 2 Lipstick Example 1 (16) was replaced with liquid paraffin (Production method) A lipstick was produced in the same manner as in Example 1.

Comparative Example 3 Lipstick Example 1 (15) and (16) were replaced with liquid paraffin (Production method) A lipstick was produced in the same manner as in Example 1.

Comparative Example 4 Lipstick Example 1 (16) was replaced with 1-menthol (Production method) A lipstick was produced in the same manner as in Example 1.

Comparative Example 5 Lipstick Example 1 (15) was replaced with glycerin (Production method) A lipstick was produced in the same manner as in Example 1.

Example 2 Lip Cream (Blending%) (1) Solid paraffin 8.0 (2) Castor oil 22.4 (3) Lanolin 12.0 (4) Beeswax 5.0 (5) Candelilla wax 10 0.0 (6) Carnauba wax 7.0 (7) Cetyl 2-ethylhexanoate 20.0 (8) Isopropyl myristate 10.0 (9) Fructose 5.0 (10) l-menthyl-3-hydroxybutyrate 0 0.3 (11) 3-l-menthoxypropane {1,2-diol 0.2 (12) Fragrance 0.1 (Production method) A lip balm was obtained in the same manner as in Example 1.

Example 3 Sunscreen Oil (Blending%) (1) Octyldimethyl paraaminobenzoic acid 7.0 (2) Castor oil 82.75 (3) Isocetyl alcohol 10.0 (4) Tocopherol acetate 0.1 (5) dibutyl hydroxytoluene 0.02 (6) erythritol 0.01 (7) fructose 0.01 (8) 3-l-menthoxypropane {1,2-diol 0.01 (9) fragrance 0.1 ( Production method) (1) and (2) are stirred and dissolved at 70 ° C. After cooling, (3) to (9) were dissolved by stirring and filled in a container to obtain a sunscreen oil.

Example 4 Aerosol Emulsion (Blending%) Undiluted Solution (1) Squalane 2.0 (2) 80 mol of phorolioxyethylene Addition-hardened castor oil 1.0 (3) Dimethylpolysiloxane (6cs) 3.0 (4) ) Decamethylpentacyclosiloxane 5.0 (5) Octyl methoxycinnamate 0.1 (6) Propylene glycol 3.0 (7) Methyl paraben 0.1 (8) Ethanol 5.0 (9) Fructose 10.0 (10 3) l-menthoxypropane {1,2-diol 2.5 (11) l-methoxy-3 l-menthoxypropane {2} ol 2.5 (12) ion-exchanged water 65.8 gas composition ( 13) L. P. G (4.0 kg / cm ² ) 70.0 (14) Dimethyl ether 30.0 (Production method) After emulsifying (1) to (5) in (6), (7) to
With respect to 80 parts of the stock solution obtained by adding (12), (1)
3) Purging 20 parts of the gas of (14) to obtain an aerosol emulsion.

COMPARATIVE EXAMPLE 6 Aerosol emulsion Produced in the same manner as in Example 4 except that (10) and (11) of Example 4 were replaced with l-menthol.

Example 5 Eye Shadow (Blending%) (1) Talc 51.55 (2) Mica 15.0 (3) Sericite 5.0 (4) Iron oxide red 2.0 (5) Iron oxide yellow 5.0 (6) Iron oxide black 0.3 (7) Pearl agent 6.0 (8) Polymethyl methacrylate spherical powder 2.0 (9) 6,6-nylon 2.0 (10) Erythritol 0.5 ( 11) l-Alkoxy-3 {l-menthoxypropane} 2-ol 0.3 (12) 3-l-menthoxypropane {1,2-diol 0.2 (13) Liquid paraffin 6.0 (14) Dimethylpolysiloxane (20cs) 2.0 (15) Sorbitan sesquioleate 2.0 (16) Vitamin E 0.05 (17) Fragrance 0.1 (Production method) (1) to (12) are mixed, and 13)-(1)
7) was melted, mixed and pulverized, and poured into a compact medium dish to obtain an eye shadow.

Example 6 Oily Two-Layer Dispersion Foundation (Blending%) (1) Octamethylcyclotetrasiloxane 35.99 (2) Squalane 2.0 (3) Fluorocarbon 2.0 (4) Octylmethoxycinnamate 0 (5) Sorbitan sesquioleate 2.0 (6) Polyoxyethylene 50 mol addition dimethylpolysiloxane 1.0 (7) Siliconized iron oxide red 0.8 (8) Siliconized iron oxide yellow 2.0 (9) ) Silicone treated iron oxide black 0.1 (10) Silicone treated mica 5.0 (11) Silicone treated talc 15.0 (12) Silicone treated zinc white 2.0 (13) Silicone treated fine particle titanium dioxide 10.0 (14) ) Siliconized titanium dioxide 10.0 (15) Fructose 2.0 (16) 3-l-menthoxypropane 1,2 Diol 0.1 (17) geranyl alcohol denatured alcohol 99% 5.0 (18) l-menthol 0.01 dissolving (Production Method) (1) to (6), (7) - (18)
After stirring and mixing, the mixture was filled in a container to obtain an oily two-layer dispersion foundation.

Effect test The effect of the cooling sensation composition of the present invention applied to the outer skin was evaluated by skin irritation and refreshing sensation. Samples (Examples 1 to 6 and Comparative Examples 1 to 6) were prepared using a panel of 25 men and women, and were used for skin (Examples 3 to 6 and Comparative Example 6) or lips (Examples 1 and 2 and Comparative Examples 1 to 5). ), After applying the sample twice a day for three consecutive days,
The irritation to the skin or lips and its refreshing feeling were determined. Each criterion was as follows.

Skin irritation A : No tingling or tightness was observed on the skin (lips). ：: Slight tingling and tightness were recognized on the skin (lips). ◇: Slight tingling and tightness were recognized on the skin (lips). Δ: Swelling and tightness were recognized on the skin (lips). ×: Very irritating and tight feeling on the skin (lips).

Cool feeling ：: Very refreshing feeling was recognized on the skin (lips). ：: Refreshing feeling was recognized on the skin (lips). ◇: Refreshing feeling was recognized on the skin (lips). Δ: Refreshing feeling was slightly recognized on the skin (lips). X: No refreshing feeling was recognized on the skin (lips) at all.

The evaluation of irritation and refreshing feeling is shown below.
(The figures in the table indicate the number of people evaluated.)

[0038]

[Table] ────────────────────────────── Skin irritation Cool feeling ◎ ○ ◇ △ × ◎ ○ ◇ △ × ── ──────────────────────────── Example 1 48 2 10 32 7 1 Comparative Example 1 32 15 3 5 21 22 2 Comparative Example 2 44 6 18 10 22 Comparative Example 3 47 2 1 3 47 Comparative Example 4 29 18 1 2 2 37 11 Comparative Example 5 42 8 3 10 26 11 Example 2 49 1 24 23 3 Example 3 43 5 2 33 15 2 Example Example 4 40 9 1 46 4 Comparative Example 6 4 12 34 47 3 Example 5 45 2 3 30 17 3 Example 6 50 28 11 11 ─────────────────── ───────────

Example 7 Lipstick (Blending%) (1) Liquid paraffin 53.33 (2) Castor oil 10.0 (3) Decamethylpentacyclosiloxane 10.0 (4) Silicone resin 10.0 (5) Octyl methoxycinnamate 2.0 (6) Candelilla wax 3.0 (7) Carnauba wax 5.0 (8) 12-hydroxystearic acid 0.1 (9) Diisostearyl malate 1.0 (10) Titanium dioxide 0.5 (11) Iron oxide red 0.3 (12) Iron oxide yellow 1.0 (13) Red No. 204 0.7 (14) Red 202 No. 0.01 (15) Erythritol 3.0 (16) 3 {L-menthoxypropane {1,2} diol 0.01 (17) Perfume 0.05 (Production method) After dissolving (1) to (9), stirring and mixing other powder, perfume, etc., mold And cooled to give a lipstick.

Example 8 Lipstick (Blending%) (1) Liquid paraffin 48.34 (2) Castor oil 10.0 (3) Decamethylpentacyclosiloxane 10.0 (4) Silicone resin 10.0 (5) Octyl methoxycinnamate 2.0 (6) Candelilla wax 3.0 (7) Carnauba wax 5.0 (8) 12-hydroxystearic acid 0.1 (9) Diisostearyl malate 1.0 (10) Titanium dioxide 0.5 (11) Iron oxide red 0.3 (12) Iron oxide yellow 1.0 (13) Red No. 204 0.7 (14) Red 202 No. 0.01 (15) Erythritol 3.0 (16) 3 {L-menthoxypropane} 1,2-diol 2.5 (17) l-methoxy-3 {l-menthoxypropane {2} ol 2.5 (18) Fragrance 0.05 (production method) (1) Dissolve ~ (9) and other End, were mixed with stirring perfumes to give the lipstick was cooled poured into a mold.

Example 9 Lipstick (Blending%) (1) Liquid paraffin 52.84 (2) Castor oil 10.0 (3) Decamethylpentacyclosiloxane 10.0 (4) Silicone resin 10.0 (5) Octyl methoxycinnamate 2.0 (6) Candelilla wax 3.0 (7) Carnauba wax 5.0 (8) 12-hydroxystearic acid 0.1 (9) Diisostearyl malate 1.0 (10) Titanium dioxide 0.5 (11) Iron oxide red 0.3 (12) Iron oxide yellow 1.0 (13) Red No. 204 0.7 (14) Red 202 No. 0.01 (15) Erythritol 3.0 (16) l -Alkoxy-3─-menthoxypropane─2─ol 0.3 (17) 3─l-menthoxypropane─1,2─diol 0.2 (18) Fragrance 0.05 (Production method) (1) Dissolve ~ (9) and other After stirring and mixing the powder, flavor and the like, the mixture was poured into a mold and cooled to obtain a lipstick.

Example 10 Lipstick (Blending%) (1) Liquid paraffin 53.24 (2) Castor oil 10.0 (3) Decamethylpentacyclosiloxane 10.0 (4) Silicone resin 10.0 (5) Octyl methoxycinnamate 2.0 (6) Candelilla wax 3.0 (7) Carnauba wax 5.0 (8) 12-hydroxystearic acid 0.1 (9) Diisostearyl malate 1.0 (10) Titanium dioxide 0.5 (11) Iron oxide red 0.3 (12) Iron oxide yellow 1.0 (13) Red No. 204 0.7 (14) Red 202 No. 0.01 (15) Erythritol 3.0 (16) 3 {L-menthoxypropane {1,2} diol 0.1 (17) Perfume 0.05 (Production method) After dissolving (1) to (9), stirring and mixing other powder, perfume, etc., mold And cooled to give a lipstick.

[0043]

According to the present invention, a cooling sensation composition having an excellent cooling sensation effect and little skin irritation, in particular, a cooling sensation composition for lips can be obtained.

Claims (6)

[Claims] 1. A cooling sensation composition comprising one or more polyhydric alcohols which are endothermic in water and one or more menthol derivatives. 2. The cooling sensation composition according to claim 1, wherein the polyhydric alcohol which dissolves in water is endothermic is erythritol and / or fructose. 3. The method according to claim 1, wherein the menthol derivative is 3-l-menthoxypropane {1,2} diol.
The described cooling sensation composition 4. A cooling sensation composition for lips, comprising one or more polyhydric alcohols which dissolve in water is endothermic and one or more menthol derivatives. 5. The cool sensation composition for a lip according to claim 4, wherein the polyhydric alcohol which is endothermic in water is erythritol and / or fructose. 6. The menthol derivative according to claim 4 or 5, wherein the menthol derivative is 3-l-menthoxypropane {1,2-diol.
A cooling sensation composition for lips according to the description