JPH10237389A - Glazing agent of leather shoes - Google Patents
Glazing agent of leather shoesInfo
- Publication number
- JPH10237389A JPH10237389A JP9060025A JP6002597A JPH10237389A JP H10237389 A JPH10237389 A JP H10237389A JP 9060025 A JP9060025 A JP 9060025A JP 6002597 A JP6002597 A JP 6002597A JP H10237389 A JPH10237389 A JP H10237389A
- Authority
- JP
- Japan
- Prior art keywords
- wax
- leather shoes
- perfluoroalkyl group
- polymer
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010985 leather Substances 0.000 title claims abstract description 37
- 239000001993 wax Substances 0.000 claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims abstract description 23
- 229920000642 polymer Polymers 0.000 claims abstract description 13
- 239000004203 carnauba wax Substances 0.000 claims abstract description 8
- 235000013869 carnauba wax Nutrition 0.000 claims abstract description 8
- 238000002844 melting Methods 0.000 claims abstract description 7
- 230000008018 melting Effects 0.000 claims abstract description 7
- 239000012170 montan wax Substances 0.000 claims abstract description 6
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 5
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 5
- 238000005498 polishing Methods 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 239000012176 shellac wax Substances 0.000 claims description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
- 239000003921 oil Substances 0.000 abstract description 10
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000003373 anti-fouling effect Effects 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 125000005647 linker group Chemical group 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 241000283153 Cetacea Species 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000012179 bayberry wax Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000010416 shoe-polishing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は革靴の仕上げ工程の
最終工程ポリッシングや靴磨きに用いられる艶出し剤に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a polishing agent used in polishing and polishing of shoes in the final step of finishing leather shoes.
【０００２】[0002]
【従来の技術】従来の革靴の仕上げ工程での目潰しやポ
リッシングに使用する艶出し剤として、カルナバワック
スなどの植物系天然ワックス，モンタンワックスなどの
鉱物系ワックス，マイクロクリスタリンワックスなどの
石油系天然ワックス，モンタンワックスをベースとする
合成エステルワックス等のワックス類が使用されてい
る。又、靴磨きにはこれらのワックス類に油と水とを加
えた乳化性クリームも使用されている。2. Description of the Related Art As a polishing agent used for crushing and polishing in a conventional leather shoe finishing process, a vegetable-based natural wax such as carnauba wax, a mineral-based wax such as montan wax, and a petroleum-based natural wax such as microcrystalline wax. And waxes such as synthetic ester waxes based on montan wax. For shoe polishing, emulsifying creams obtained by adding oil and water to these waxes are also used.
【０００３】[0003]
【発明が解決しようとする課題】これらの艶出し剤は天
然皮革に対して優れた艶を与え、ある程度撥水性もあ
り、皮革を保護する役目も果たしているが、油性の汚れ
に対しては弱く、一度油がしみこむと取り去ることがで
きず、油性の汚れに対して保護する効果が全くなかっ
た。本発明は泥水や油性の汚れに対して防汚性を有する
艶出し剤を提供することにより、艶出し効果に加えて防
汚性をも付与した革靴を得ることを課題とするものであ
る。These polishes provide excellent luster to natural leather, have some water repellency, and also serve to protect leather, but are weak against oily stains. Once the oil had soaked, it could not be removed and had no protective effect against oily stains. An object of the present invention is to provide a polisher having antifouling properties against muddy water and oily dirt, thereby obtaining leather shoes having an antifouling property in addition to the polisher effect.
【０００４】[0004]
【課題を解決するための手段】本発明の革靴用艶出し剤
は、ワックスにパーフルオロアルキル基を側鎖に有する
ポリマーを含むことを第１の特徴とする。又、本発明の
革靴用艶出し剤は、ＪＩＳ Ｋ−２２３５で測定した融
点が６０℃以上のワックスにパーフルオロアルキル基を
側鎖に有するアクリル酸共重合体を含むことを第２の特
徴とする。The first feature of the polishing agent for leather shoes of the present invention is that the wax contains a polymer having a perfluoroalkyl group in a side chain. The second feature of the polishing agent for leather shoes of the present invention is that a wax having a melting point of 60 ° C. or higher as measured by JIS K-2235 contains an acrylic acid copolymer having a perfluoroalkyl group in a side chain. I do.
【０００５】本発明の革靴用艶出し剤において、必須成
分として用いられるワックスとしては、例えばカルナバ
ワックス，キャンテリラワックス，シュガーワックス，
ライスワックス，木ロウ，ベイベリーワックス，オーキ
ュリーワックス，エスパルトワックスなどの植物系天然
ワックス，ミツロウ，こん虫ロウ，鯨ロウ，セラックロ
ウ，ラノリンワックスなどの動物系天然ワックス，パラ
フィンワックス，マイクロクリスタリンワックスなどの
石油系天然ワックス，モンタンワックス，オゾケライト
ワックス，セレシンなどの鉱物系天然ワックス，ヘキス
トワックス，ポリエチレンワックス，カルボワックス，
カスターワックス，フィッシャトロプッシュワックス，
サゾールワックスなどの合成ワックスが挙げられる。The wax used as an essential component in the polishing agent for leather shoes of the present invention includes, for example, carnauba wax, canterilla wax, sugar wax,
Vegetable natural waxes such as rice wax, wood wax, bayberry wax, ocully wax, espart wax, animal natural waxes such as beeswax, insect wax, whale wax, shellac wax, lanolin wax, paraffin wax, microcrystalline wax Mineral waxes such as petroleum natural wax, montan wax, ozokerite wax, ceresin, etc., Hoechst wax, polyethylene wax, carbowax,
Caster wax, fishertro push wax,
Synthetic waxes such as Sasol wax are exemplified.
【０００５】これらのワックスの中で、特に好ましいの
はＪＩＳ Ｋ−２２３５で測定した融点が６０℃以上の
カルナバワックス，モンタンワックス，マイクロクリス
タリンワックス，セラックロウパラフィンワックス，合
成エステルワックスの中から選ばれる少なくとも１つで
ある。Among these waxes, particularly preferred are those selected from carnauba wax, montan wax, microcrystalline wax, shellac wax paraffin wax, and synthetic ester wax having a melting point of 60 ° C. or higher as measured by JIS K-2235. At least one.
【０００６】前記ワックスはそれぞれ単独で用いても良
いし、２種以上組み合わせて使用しても良い。ＪＩＳ
Ｋ−２２３５で測定した融点が６０℃以上のワックスを
革靴用仕上げ剤として用いれば革の表面に厚くて丈夫な
ワックス被膜を作ることができ、傷や汚れに対して強
い。The above waxes may be used alone or in combination of two or more. JIS
If a wax having a melting point of 60 ° C. or higher as measured by K-2235 is used as a finishing agent for leather shoes, a thick and durable wax film can be formed on the surface of the leather, and is resistant to scratches and stains.
【０００７】本発明の革靴用艶出し剤には、撥水，撥油
性を付与するためにパーフルオロアルキル基を側鎖に有
するポリマーを使用する。パーフルオロアルキル基を有
するポリマーを固体表面に被覆すると、表面エネルギー
は著しく低くなり、高度の撥水，撥油性を示すようにな
る。パーフルオロアルキル基を有するポリマーの構造
は、図１に示すようなポリマー主鎖の側鎖に極性基や結
合基を介してパーフルオロアルキル基が結合されている
構造を有するのが好ましいとされている。As the polishing agent for leather shoes of the present invention, a polymer having a perfluoroalkyl group in a side chain is used for imparting water repellency and oil repellency. When a polymer having a perfluoroalkyl group is coated on a solid surface, the surface energy is remarkably reduced, and the solid surface exhibits high water and oil repellency. It is considered that the structure of the polymer having a perfluoroalkyl group preferably has a structure in which a perfluoroalkyl group is bonded to a side chain of a polymer main chain via a polar group or a bonding group as shown in FIG. I have.
【０００８】図１のＡは、被処理物に対する親和性を与
え、又、有機溶剤などへの溶解性を増すための極性基で
あり、Ｂはこの極性基とパーフルオロアルキル基を結ぶ
ために必要な結合基である。その結合基Ｂとしては−Ｓ
Ｏ2 Ｎ（Ｒ）（ＣＨ2 ）m −か−ＣＨ2 −或いは−ＣＨ
2 ＣＨ2 −が用いられる。又、パーフルオロアルキル基
の長さは重要であり、低エネルギー表面を効果的に形成
するように炭素数が７以上の直鎖のパーフルオロアルキ
ル基が使用される。前記のパーフルオロアルキル基をも
つポリマーは撥水性だけでなく、通常の炭化水素に対す
る撥油性も発揮するようになる。FIG. 1A shows a polar group for imparting an affinity to an object to be treated and increasing the solubility in an organic solvent and the like, and B shows a polar group for connecting this polar group to a perfluoroalkyl group. It is a necessary linking group. The bonding group B is -S
O 2 N (R) (CH 2) m - or -CH 2 - or -CH
2 CH 2 -is used. The length of the perfluoroalkyl group is important, and a linear perfluoroalkyl group having 7 or more carbon atoms is used so as to effectively form a low energy surface. The polymer having a perfluoroalkyl group exhibits not only water repellency but also oil repellency to ordinary hydrocarbons.
【０００９】被覆物が皮革である場合には、パーフルオ
ロアルキル基を有するアクリル酸の共重合体かメタクリ
ル酸の共重合体が使用される。そのうちでもアクリル酸
の共重合体は屈曲性が大きいので動的な力が加わる革靴
用の艶出し剤として好ましい。When the coating is leather, a copolymer of acrylic acid or methacrylic acid having a perfluoroalkyl group is used. Among them, the copolymer of acrylic acid is preferable as a polishing agent for leather shoes to which a dynamic force is applied because of its great flexibility.
【００１０】本発明の革靴用の艶出し剤を製造する場
合、ワックスにパーフルオロアルキル基を有するポリマ
ーを混合するが、混合の方法としてワックスを加熱溶融
して、その中に前記ポリマーをエマルジョンにしたもの
を攪拌して、水分を蒸発しながら混合すると良い。When the polishing agent for leather shoes of the present invention is produced, a polymer having a perfluoroalkyl group is mixed with wax. As a mixing method, the wax is heated and melted, and the polymer is formed into an emulsion therein. It is advisable to stir and mix while evaporating the water.
【００１１】このようにして混合された艶出し剤は、型
の中に流し込み、冷却して固形状物に加工される。本発
明の革靴用艶出し剤は、起毛布を多数積層した研磨布を
回転機に取り付けた研磨機の起毛面に塗布された後、革
靴の革の表面をこの研磨機で磨くことにより塗布され
る。The polishing agent mixed in this way is poured into a mold, cooled and processed into a solid. The polishing agent for leather shoes of the present invention is applied to the raised surface of a polishing machine in which a plurality of brushed cloths are stacked on a rotating machine, and then applied by polishing the leather surface of the shoe with this polishing machine. You.
【００１２】本発明の艶出し剤において、パーフルオロ
アルキル基を側鎖に有するアクリル酸の共重合体を使用
した場合、塗布後、加熱することにより革に強固に密着
し、加熱前に比べ撥水性や撥油性が増す。In the polishing agent of the present invention, when a copolymer of acrylic acid having a perfluoroalkyl group in the side chain is used, it is firmly adhered to leather by heating after application, and is repellent compared to before heating. Increases water and oil repellency.
【００１３】[0013]
【艶出し剤の製造】実施例に使用するワックスは、ＪＩ
Ｓ Ｋ−２２３５で測定した融点８０〜８６℃のカルナ
バワックスを用いる。又、パーフルオロアルキル基を有
するポリマーには炭素数８のパーフルオロアルキル基を
側鎖に有するアクリル酸エチルの共重合体をエマルジョ
ンした共栄社化学株式会社製，商品名ライトガードＦＲ
５２０（固形分２４％）を使用する。カルナバワックス
を所定量計量し、容器の中で１００℃前後に加熱，溶融
させ、前記エマルジョンを同重量部混合し、水分を加熱
蒸発させた後、型に流し込み自然冷却させ、型から抜
き、実施例の艶出し剤を製造した。この艶出し剤の配合
は表１の通りである。[Manufacture of polishing agent] The wax used in the examples is JI
Carnauba wax having a melting point of 80 to 86 ° C. measured by SK-2235 is used. Further, the polymer having a perfluoroalkyl group is a light guard FR (trade name, manufactured by Kyoeisha Chemical Co., Ltd.) prepared by emulsifying a copolymer of ethyl acrylate having a perfluoroalkyl group having 8 carbon atoms in the side chain.
520 (24% solids) is used. A predetermined amount of carnauba wax is weighed, heated and melted at about 100 ° C. in a container, mixed with the same weight part of the emulsion, heated and evaporated, poured into a mold, allowed to cool naturally, and removed from the mold. Example polishes were prepared. Table 1 shows the composition of the polishing agent.
【００１４】[0014]
【表１】 [Table 1]
【００１５】[0015]
【実施例の艶出し剤で仕上げした革靴】この艶出し剤を
起毛布を、多数積層して研磨材とした研磨機に擦りつ
け、仕上げ後の革靴をこの研磨機で目潰し、ポリッシン
グした。さらに革靴の１２０℃で１分加熱した後、再度
研磨機にてポリッシングを行い、実施例の革靴を得た。Leather shoes finished with the glazing agent of the examples: A large number of brushed cloths were rubbed with a polisher as an abrasive, and the finished leather shoes were crushed and polished with the polisher. Further, after the leather shoes were heated at 120 ° C. for 1 minute, polishing was performed again with a polishing machine to obtain leather shoes of the examples.
【００１６】[0016]
【比較例の艶出し剤で仕上げした革靴】比較例として、
カルナバワックスのみを別の研磨機に擦りつけ、仕上後
の別の革靴をこの研磨機で目潰し、ポリッシングを行
い、比較例の革靴を得た。[Leather shoes finished with the polishing agent of the comparative example] As a comparative example,
Only carnauba wax was rubbed against another polishing machine, and another finished leather shoe was crushed with this polishing machine and polished to obtain a leather shoe of a comparative example.
【００１７】[0017]
【実施例と比較例の革靴の性能比較】実施例と比較例の
革靴とを外観，撥水性，撥油性の３項目について比較を
行い表２に示した。表２より本発明の艶出し剤で革靴を
仕上げすることにより油性の汚れに対しても防汚性のあ
る革靴が得られた。Performance Comparison of Leather Shoes of Example and Comparative Example Table 2 shows a comparison of the appearance, water repellency and oil repellency of the leather shoes of the example and the comparative example. As shown in Table 2, by finishing leather shoes with the polishing agent of the present invention, leather shoes having antifouling properties against oily stains were obtained.
【００１８】[0018]
【表２】 ここで＊１はＪＩＳ Ｌ１０９２スプレー法による。＊
２はＡＡＴＣＣ No,118 撥油性試験法による。[Table 2] Here, * 1 is based on JIS L1092 spray method. *
2 is based on AATCC No. 118 oil repellency test method.
【００１９】[0019]
【発明の効果】本発明の革靴用艶出し剤を用いて革靴の
目潰し、ポリッシングを行なうと、優れた艶感が得られ
ると共に、水や油に対して防汚性のある革靴に仕上げる
ことができた。When the leather shoes are crushed and polished using the polishing agent for leather shoes of the present invention, an excellent luster can be obtained and the leather shoes can be finished to have antifouling properties against water and oil. did it.
─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成９年４月２４日[Submission date] April 24, 1997
【手続補正２】[Procedure amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】図面の簡単な説明[Correction target item name] Brief description of drawings
【補正方法】追加[Correction method] Added
【補正内容】[Correction contents]
【図面の簡単な説明】[Brief description of the drawings]
【図１】 パーフルオロアルキル基含有化合物を固体表
面に処理した概念図である。FIG. 1 is a conceptual diagram in which a perfluoroalkyl group-containing compound is treated on a solid surface.
【符号の説明】 Ａ．極性基 Ｂ．結合基[Explanation of Codes] Polar group B. Linking group
Claims (4)
鎖に有するポリマーを含むことを特徴とする革靴用艶出
し剤。1. A polishing agent for leather shoes, wherein the wax contains a polymer having a perfluoroalkyl group in a side chain.
６０℃以上のワックスにパーフルオロアルキル基を側鎖
に有するアクリル酸共重合体を含むことを特徴とする革
靴用艶出し剤。2. A polishing agent for leather shoes, wherein a wax having a melting point of 60 ° C. or higher as measured by JIS K-2235 contains an acrylic acid copolymer having a perfluoroalkyl group in a side chain.
６０℃以上のワックスがカルナバワックス，モンタンワ
ックス，マイクロクリスタリンワックス，セラックロ
ウ，パラフィンワックス，合成エステルワックスの中か
ら選ばれた少なくとも１種である請求項２記載の革靴用
艶出し剤。3. The wax having a melting point of at least 60 ° C. measured according to JIS K-2235 is at least one selected from carnauba wax, montan wax, microcrystalline wax, shellac wax, paraffin wax and synthetic ester wax. Item 4. A polishing agent for leather shoes according to Item 2.
の直鎖のパーフルオロアルキル基である請求項１又は２
記載の革靴用艶出し剤。4. The method according to claim 1, wherein the perfluoroalkyl group is a linear perfluoroalkyl group having 7 or more carbon atoms.
A glazing agent for leather shoes as described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9060025A JPH10237389A (en) | 1997-02-26 | 1997-02-26 | Glazing agent of leather shoes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9060025A JPH10237389A (en) | 1997-02-26 | 1997-02-26 | Glazing agent of leather shoes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH10237389A true JPH10237389A (en) | 1998-09-08 |
Family
ID=13130127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9060025A Pending JPH10237389A (en) | 1997-02-26 | 1997-02-26 | Glazing agent of leather shoes |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH10237389A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1149922A1 (en) * | 2000-04-25 | 2001-10-31 | Granger's International Ltd. | Leather treatment |
| CN1309794C (en) * | 2005-04-18 | 2007-04-11 | 蒋发学 | Preservative agent for shining leather and stone |
| JP2011144380A (en) * | 2003-07-29 | 2011-07-28 | Three M Innovative Properties Co | Composition, wipe and method for cleaning base material, protecting base material and glossing base material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6390588A (en) * | 1986-10-06 | 1988-04-21 | Daikin Ind Ltd | Water and oil repellent |
| JPS6399285A (en) * | 1986-05-28 | 1988-04-30 | Daikin Ind Ltd | Water and oil repellent |
| JPH021795A (en) * | 1988-03-08 | 1990-01-08 | Asahi Glass Co Ltd | Water and oil repellent |
| JPH06322213A (en) * | 1993-05-11 | 1994-11-22 | Asahi Glass Co Ltd | Water-repellent oil-repellent composition and article coated therewith |
| JPH0931415A (en) * | 1995-07-24 | 1997-02-04 | Koronbusu:Kk | Waterproof shoe cream manufacturing method |
-
1997
- 1997-02-26 JP JP9060025A patent/JPH10237389A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6399285A (en) * | 1986-05-28 | 1988-04-30 | Daikin Ind Ltd | Water and oil repellent |
| JPS6390588A (en) * | 1986-10-06 | 1988-04-21 | Daikin Ind Ltd | Water and oil repellent |
| JPH021795A (en) * | 1988-03-08 | 1990-01-08 | Asahi Glass Co Ltd | Water and oil repellent |
| JPH06322213A (en) * | 1993-05-11 | 1994-11-22 | Asahi Glass Co Ltd | Water-repellent oil-repellent composition and article coated therewith |
| JPH0931415A (en) * | 1995-07-24 | 1997-02-04 | Koronbusu:Kk | Waterproof shoe cream manufacturing method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1149922A1 (en) * | 2000-04-25 | 2001-10-31 | Granger's International Ltd. | Leather treatment |
| JP2011144380A (en) * | 2003-07-29 | 2011-07-28 | Three M Innovative Properties Co | Composition, wipe and method for cleaning base material, protecting base material and glossing base material |
| CN1309794C (en) * | 2005-04-18 | 2007-04-11 | 蒋发学 | Preservative agent for shining leather and stone |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3847622A (en) | Polish | |
| CN105324103B (en) | Nail paint with enhanced adhesion | |
| CA1202451A (en) | Leather treatment composition | |
| Kamely | “Fatliquors” for leathers: an application of microemulsion—a review | |
| FR2496113A1 (en) | COATING COMPOSITIONS FOR FLEXIBLE CARRIERS BASED ON POLYESTER RESINS CURABLE BY VAPOR PERMEATION | |
| US4284668A (en) | Paint sealant with Teflon T.F.E | |
| EP1183315A1 (en) | Polish composition and method of use | |
| JPS6036600A (en) | Liquid protector for shoe and leather | |
| CH647251A5 (en) | NON - STICK COMPOSITION BASED ON WAX IN ORGANIC SOLVENT MEDIUM. | |
| JP2010540486A (en) | Method for removing water-insoluble substance from substrate surface | |
| JPH10237389A (en) | Glazing agent of leather shoes | |
| US5614005A (en) | Water resistant shoe polish | |
| EP1874262B1 (en) | Aqueous nail varnish composition | |
| US2371473A (en) | Wax composition | |
| US6258882B1 (en) | Wax-resin surface polishes | |
| JP2848657B2 (en) | Buffing composition | |
| AU2001294071A1 (en) | Polish compositions | |
| JP3875400B2 (en) | Water and oil repellent composition | |
| KR102890227B1 (en) | Composition for cleaning and polishing and method for manufacturing the same | |
| US2536349A (en) | Self-polishing wax composition | |
| JP3041964B2 (en) | Surfactants, antifouling agents and polishing agents | |
| JP2021084975A (en) | Surface treatment abrasive grains, polishing material, and polishing material production method | |
| US1690680A (en) | Composition for polishing surfaces composed of cellulose-ester compositions | |
| US2483701A (en) | Polishing composition | |
| US2862900A (en) | Resin-fortified wax polish compositions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20041021 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20041124 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20050322 |