JPH1121768A - Wrinkle-proofing spray for domestic purpose - Google Patents
Wrinkle-proofing spray for domestic purposeInfo
- Publication number
- JPH1121768A JPH1121768A JP21795597A JP21795597A JPH1121768A JP H1121768 A JPH1121768 A JP H1121768A JP 21795597 A JP21795597 A JP 21795597A JP 21795597 A JP21795597 A JP 21795597A JP H1121768 A JPH1121768 A JP H1121768A
- Authority
- JP
- Japan
- Prior art keywords
- wrinkle
- resin
- effect
- spray
- home
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007921 spray Substances 0.000 title claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 46
- 239000011347 resin Substances 0.000 claims abstract description 46
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims abstract description 34
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229940015043 glyoxal Drugs 0.000 claims abstract description 17
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 12
- 230000000694 effects Effects 0.000 claims abstract description 11
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 8
- 229920002678 cellulose Polymers 0.000 claims abstract description 3
- 239000001913 cellulose Substances 0.000 claims abstract description 3
- 230000001153 anti-wrinkle effect Effects 0.000 claims description 18
- 238000005406 washing Methods 0.000 claims description 13
- 229920001296 polysiloxane Polymers 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 230000037330 wrinkle prevention Effects 0.000 claims description 8
- 238000010409 ironing Methods 0.000 claims description 7
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 230000009477 glass transition Effects 0.000 claims description 2
- 238000003672 processing method Methods 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 abstract description 15
- 239000004744 fabric Substances 0.000 description 8
- 229920001807 Urea-formaldehyde Polymers 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 230000037303 wrinkles Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 3
- XYOSFLPUWVWHOA-UHFFFAOYSA-N 2-ethylidenepropane-1,3-diol;urea Chemical compound NC(N)=O.CC=C(CO)CO XYOSFLPUWVWHOA-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 2
- 229950005308 oxymethurea Drugs 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WVJOGYWFVNTSAU-UHFFFAOYSA-N dimethylol ethylene urea Chemical compound OCN1CCN(CO)C1=O WVJOGYWFVNTSAU-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- -1 fluororesins Polymers 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【０００１】[0001]
【利用分野】本発明はカッターシャツ等の衣料品に対し
て、着用時の型くずれや洗濯後の小じわの発生を抑える
ことを可能とした、家庭において手軽に使用できる、ホ
ルマリンを含まずまた発生しない、安全な防しわ用ハン
ドスプレーに関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention makes it possible to suppress the occurrence of deformation of clothes such as cutter shirts and the occurrence of fine wrinkles after washing. The present invention relates to a safe hand spray for wrinkle prevention.
【０００２】[0002]
【従来の技術】 カッターシャツ等に対して多用される
綿素材は、肌ざわりが良くまた汗をよく吸う快適な素材
であるが、反面着用時や洗濯後に型くずれやしわの発生
が起きやすい。そのため一般の家庭においては、綿シャ
ツがしわになった場合その都度アイロンがけを行うこと
を余儀なくされて、これにはたいへん手間がかかった。
このような問題点を解消するために、「形態安定加工シ
ャツ」あるいは「形状記憶シャツ」と称する綿シャツが
市販されている。（以下 部を「形態安定加工シャ
ツ」と呼ぶ）2. Description of the Related Art A cotton material frequently used for a cutter shirt or the like is a comfortable material that has a good texture and absorbs sweat well, but on the other hand, it tends to lose its shape when worn or after washing. Therefore, in a general household, when a cotton shirt becomes wrinkled, it has to be ironed each time, and this takes a lot of trouble.
In order to solve such problems, a “shape stable machining system”
Cotton shirts called "jacks" or "shape memory shirts" are commercially available. (Less than Part is called "morphologically stable shirt"
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、これら
の「形態安定加工シャツ」は専門工場において工業的規
模で、ホルマリンガスや液体アンモニアのような薬品を
用いて、特別な装置により製造されているものである。
これらの薬品は有害かつ危険であり使用には特別な装置
を必要とするため、一般家庭において使用することはで
きない。However, these "morphologically stable shirts" are manufactured on an industrial scale in specialized factories on special scale, using chemicals such as formalin gas and liquid ammonia. It is.
These chemicals are harmful and dangerous and require special equipment for use, so they cannot be used in ordinary households.
【０００４】また公開特許公報 特開平８−２４６３５
１「防シワ加工方法およびアイロン」に記載されている
ような、アイロンを使用する方法で使用されるグリオキ
ザール系樹脂をはじめとする一般に防縮樹脂と呼ばれる
メチロール化された尿素系樹脂はホルマリンを発生する
性質を持っているため有害性が高い。防しわ効果につい
ても単にグリオキザール系樹脂を使用しただけでは効果
不十分であり、防しわ効果を上げようとして使用するグ
リオキザール樹脂の濃度を上げると、綿シャツ自体が固
くなり着心地が悪くなり、使用できなくなるとともに発
生するホルマリンの量も増大する。[0004] Further, Japanese Patent Laid-Open Publication No. Hei 8-24635
1 A methylolated urea resin generally called a shrink-proof resin including a glyoxal resin used in a method using an iron as described in “Anti-wrinkle processing method and iron” generates formalin. Highly harmful due to its properties. Regarding the anti-wrinkle effect, simply using glyoxal resin is not enough.If the concentration of the glyoxal resin used to increase the anti-wrinkle effect is increased, the cotton shirt itself becomes hard and the comfort becomes poor, and it is used. As it becomes impossible, the amount of formalin generated also increases.
【０００５】なおグリオキザール系樹脂の中で、メチロ
ール化されていない、いわゆる非ホルマリン型グリオキ
ザール樹脂と呼ばれる防縮樹脂が知られているが、単に
この非ホルマリン型グリオキザール樹脂のみにより防し
わ効果を得ようとした場合、一般のグリオキザール系樹
脂と比較すると、ホルマリンは発生しないが、綿素材と
の反応性が低いために十分に綿素材と反応させて一般の
グリオキザール樹脂と同等の防シワ効果を得ようとする
と、触媒としてホウフッ化亜鉛のような強い金属触媒を
用いる必要があり、使用触媒の面で有害性に問題が生じ
る。しかし触媒に塩化マグネシウムのような比較的有害
性の低い金属触媒を用いた場合は、セルロースと非ホル
マリン型グリオキザール樹脂との反応率が低いために、
防しわ効果が一般のグリオキザール系樹脂を使用した場
合よりもさらに劣ることになる。[0005] Among the glyoxal resins, a shrink-proof resin which is not methylolated and is called a so-called non-formalin type glyoxal resin is known. When compared to a general glyoxal resin, formalin does not occur, but because of its low reactivity with the cotton material, it is sufficiently reacted with the cotton material to obtain the same wrinkle prevention effect as the general glyoxal resin. Then, it is necessary to use a strong metal catalyst such as zinc borofluoride as the catalyst, and there is a problem of harm in terms of the catalyst used. However, when a relatively harmful metal catalyst such as magnesium chloride is used as the catalyst, the reaction rate between cellulose and the non-formalin glyoxal resin is low,
The anti-wrinkle effect is even worse than when a general glyoxal resin is used.
【０００６】このため一般消費者が家庭において安全か
つ手軽に、着用時や洗濯後の型くずれやしわの発生を防
止できるよい方法がなかった。[0006] For this reason, there has been no good method by which general consumers can safely and easily prevent the occurrence of shape collapse and wrinkles during wearing and after washing at home.
【０００７】[0007]
【課題を解決するための手段】本発明者らは、家庭にお
いて一般消費者が防しわに対して有効な処理を手軽に行
うためには、非ホルマリン型グリオキザール樹脂／塩化
マグネシウムの他に、さらにホルマリンを含まない有害
性の低い薬品で防しわに効果のある薬品を併用すること
により、防しわ効果を十分高めたハンドスプレーがあれ
ば可能になると考え本発明をなすに至ったものである。Means for Solving the Problems The present inventors have found that, in order for ordinary consumers to easily carry out an effective treatment against wrinkles at home, in addition to a non-formalin type glyoxal resin / magnesium chloride, The present invention is thought to be possible if a hand spray with a sufficiently high anti-wrinkle effect can be obtained by using a low-harmful chemical that does not contain formalin and has a high anti-wrinkle effect.
【０００８】[0008]
【作用】本発明は小型のハンドスプレー器および防しわ
剤により構成される。ハンドスプレー器は一度に約０．
５ｃｃ以上程度を噴霧できればよく、高圧ガスの用いら
れたスプレーでもあるいは霧吹きでもよく、機構は問わ
ない。The present invention comprises a small hand sprayer and an anti-wrinkle agent. The hand sprayer is approx.
It is only necessary to spray about 5 cc or more, and a spray using high pressure gas or a mist spray may be used, and the mechanism is not limited.
【０００９】防しわ剤は、非ホルマリン型グリオキザー
ル樹脂および触媒に塩化マグネシウム、およびさらにこ
れに併用する防しわ効果を高めることのできる樹脂によ
り構成される。The anti-wrinkle agent is composed of a non-formalin type glyoxal resin, magnesium chloride as a catalyst, and a resin which is used in combination therewith and which can enhance the anti-wrinkle effect.
【００１０】防しわ効果を高めることのできる樹脂と
は、非ホルマリン型グリオキザール樹脂／塩化マグネシ
ウムと併用した場合に、洗濯収縮率３％以上の生地に対
しては洗濯収縮を緩和し洗濯収縮率を３％以下に抑える
ことのできる樹脂、あるいは生地を畳んだり強く揉んだ
りした場合に、生地に強い折れ跡ができるのを防ぐこと
のできる樹脂、の２系統の性質の樹脂を言い、いずれの
場合もホルマリンを含んでいたり発生したりしない様な
樹脂であることとする。The resin capable of enhancing the anti-wrinkle effect means that when used in combination with a non-formalin-type glyoxal resin / magnesium chloride, a fabric having a washing shrinkage of 3% or more can reduce washing shrinkage and reduce the washing shrinkage. A resin that can be suppressed to 3% or less, or a resin that can prevent the fabric from forming strong fold marks when folded or rubbed strongly. Is a resin which does not contain or generate formalin.
【００１１】このような樹脂には、ウレタン樹脂、アク
リル樹脂、酢酸ビニール樹脂、ポリアミド樹脂、ポリエ
ステル樹脂、フッ素樹脂、シリコーン樹脂などが含まれ
る。これらの中で洗濯収縮率を３％以下に抑える樹脂の
作用は、硬い樹脂で織物の糸自身および結節部を固めた
り、あるいは撥水性を有する樹脂で親水性の綿素材を疎
水性化、または非膨潤性化としたり、またその樹脂自身
の反発弾性により効果をもたらしていると考えられる。
また生地に強い折れ跡のできるのを防ぐことのできる樹
脂とは、逆に柔らかい樹脂でかつ弾力の強い樹脂による
反発効果や、柔軟効果をもたらす樹脂で生地が折れ曲が
った時に織物の結節を滑らすことにより応力を緩和し効
果をもたらすものと考えられる。[0011] Such resins include urethane resins, acrylic resins, vinyl acetate resins, polyamide resins, polyester resins, fluororesins, silicone resins and the like. Among these, the action of the resin that suppresses the washing shrinkage rate to 3% or less is to harden the yarn itself and the knot portion of the woven fabric with a hard resin, or to make a hydrophilic cotton material hydrophobic with a water-repellent resin, or It is considered that the resin is made non-swellable and the effect is brought about by the resilience of the resin itself.
In addition, a resin that can prevent strong fold marks on the fabric is a soft resin and a resilience effect by a resin with strong elasticity, and a resin that brings a softening effect, sliding the knot of the fabric when the fabric is bent It is considered that the stress is reduced and the effect is brought about.
【００１２】なお本発明では、セルロースの防縮樹脂と
して多用される一般のグリオキザール樹脂、ジメチロー
ル尿素樹脂、エーテル化ジメチロール尿素樹脂、ジメチ
ロールエチレン尿素樹脂、ジメチロールプロピレン尿素
樹脂、ジメチロールトリアゾン樹脂、ジメチロールウロ
ン樹脂等のようなメチロール化された尿素系樹脂や、ト
リメチロールメラミン樹脂、ヘキサメチロールメラミン
樹脂のようなメラミン樹脂はホルマリンを発生するため
有害なので使用しない。In the present invention, general glyoxal resins, dimethylol urea resins, etherified dimethylol urea resins, dimethylol ethylene urea resins, dimethylol propylene urea resins, dimethylol propylene urea resins, dimethylol triazones, Methylolated urea resins such as methyloluron resin and melamine resins such as trimethylolmelamine resin and hexamethylolmelamine resin are not used because they generate harmful formalin.
【００１３】着用時の防しわを重視する場合には、非ホ
ルマリン型グリオキザール樹脂／塩化マグネシウムと併
用して防しわ効果を高める樹脂は、上記の樹脂の中で柔
軟作用をもった樹脂であれば良く、シリコーンが好適に
用いられる。シリコーンは綿織物の結節部のすべりを向
上させることにより、応力の集中を防ぎ着用時に生地に
強い折れ後ができない様にして防しわ性をさらに向上さ
せると共に、スプレーした時にアイロンがけ時のすべり
を向上させアイロンがけをしやすくする。シリコーンは
ジメチルシリコーンやアミノシリコーン、エポキシシリ
コーンなどの変成シリコーンの乳化物でも良いが、スプ
レー適性を考慮すると沈殿によるノズルつまりを防ぐた
めにグリコール変成シリコーンのような水溶性のものを
用いるのが望ましい。When wrinkle prevention during wearing is important, a resin which enhances the wrinkle prevention effect in combination with a non-formalin type glyoxal resin / magnesium chloride is a resin having a soft action among the above resins. Well, silicone is preferably used. Silicone improves the slippage of the knotted part of the cotton fabric, preventing stress concentration and preventing the fabric from breaking strongly when worn, further improving wrinkle resistance and improving slippage when ironing when sprayed To make ironing easier. The silicone may be an emulsion of a modified silicone such as dimethyl silicone, amino silicone, or epoxy silicone, but it is preferable to use a water-soluble silicone such as a glycol-modified silicone in order to prevent nozzle clogging due to precipitation in consideration of sprayability.
【００１４】また洗濯後の型くずれや防しわを重視する
場合については、非ホルマリン型グリオキザール樹脂／
塩化マグネシウムと併用する樹脂は上記の洗濯収縮率を
３％以内に抑える樹脂のいずれを用いても良いが、着用
時の防しわも重視する場合は洗濯収縮率を３％以内に抑
える樹脂としてはウレタン樹脂を使用すれば良い。しか
し、使用するウレタン樹脂が硬すぎると着用時にかえっ
てシワになりやすくなるため、１００％モジュラスが５
〜４０ｋｇｆ／ｃｍ２、ガラス転移点が−５０〜１０℃
の間にあるウレタン樹脂を用いるのが望ましい。なおウ
レタン樹脂は、エーテル系、エステル・エーテル系、ポ
リカーボネート系、エステル系、のいずれのウレタン樹
脂を使用しても良いが、水および他の薬品と配合して使
用する場合は、耐加水分解性の面からエーテル系あるい
はポリカーボネート系のウレタン樹脂を用いるのが良
い。In the case where emphasis is placed on mold collapse and wrinkle prevention after washing, a non-formalin type glyoxal resin /
As the resin used in combination with magnesium chloride, any of the above resins that suppress the washing shrinkage within 3% may be used. However, when importance is also placed on preventing wrinkles during wearing, as a resin that suppresses the washing shrinkage within 3%. Urethane resin may be used. However, if the urethane resin used is too hard, it tends to wrinkle when worn, so that the 100% modulus is 5%.
４０40 kgf / cm 2 , glass transition point -50５０10 ° C.
It is desirable to use a urethane resin between them. The urethane resin may be any of an ether type, an ester / ether type, a polycarbonate type, and an ester type, but if it is used in combination with water and other chemicals, it has hydrolysis resistance. In view of the above, it is preferable to use an ether-based or polycarbonate-based urethane resin.
【００１５】本発明のスプレーの使用方法は、綿シャツ
にスプレーにて３０ｃｍ×３０ｃｍあたり３〜１０ｃｃ
噴霧し、しかるのちアイロンの表面温度１６０〜１９０
℃、好ましくは１７０〜１８０℃にて３０〜９０秒間ア
イロンがけを行う。The method of using the spray of the present invention is as follows.
Spray and then iron surface temperature 160-190
Ironing is performed at 30 ° C., preferably 170-180 ° C. for 30-90 seconds.
【００１６】[0016]
【実施例】市販の綿１００％のワイシャツを利用して、
後ろ身頃から３０ｃｍ×３０ｃｍの大きさの生地を６枚
カットした後、次の組成の薬品をハンドスプレーにて約
２０ｃｍの距離から約７ｃｃ噴霧してからただちに表面
温度１６０〜１７０℃にて６０秒間アイロンがけを行
い、防しわに対する効果及び洗濯収縮率を比較した。表
１にその結果を示す。Example: Using a commercially available 100% cotton shirt,
After cutting 6 fabrics of 30cm x 30cm size from the back body, spray the chemical of the following composition by hand spray about 7cc from a distance of about 20cm and immediately at a surface temperature of 160-170 ° C for 60 seconds Ironing was performed, and the effect on anti-wrinkling and the shrinkage ratio of washing were compared. Table 1 shows the results.
【表１】 [Table 1]
【００１７】実施例１、及び比較例１〜５、と同様に市
販の綿１００％のワイシャツを利用して後ろ身頃から３
０ｃｍ×３０ｃｍの大きさの生地を５枚カットした後、
次の組成の薬品をハンドスプレーにて約２０ｃｍの距離
から約７ｃｃ噴霧してからただちに表面温度１６０〜１
７０℃にて６０秒間アイロンがけを行い、防しわに対す
る効果及び洗濯収縮率を比較した。表２にその結果を示
す。As in Example 1 and Comparative Examples 1 to 5, using a commercially available 100% cotton shirt, 3
After cutting 5 pieces of dough of 0cm x 30cm,
After spraying about 7 cc of a chemical of the following composition from a distance of about 20 cm with a hand spray, the surface temperature is immediately increased to 160-1.
Ironing was performed at 70 ° C. for 60 seconds to compare the effect on wrinkle prevention and the washing shrinkage. Table 2 shows the results.
【表２】 [Table 2]
【００１８】[0018]
【発明の効果】一般消費者は高価な「形態安定加工シャ
ツ」を購入することなく、自分の気に入った綿シャツに
対し防しわ加工を行うことができる。シャツの素材は綿
１００％に限らず、ポリエステル／綿、レーヨン、キュ
プラなどのセルロース系の素材に対して効果がある。According to the present invention, a general consumer can perform wrinkle-prevention processing on a cotton shirt that he or she likes without purchasing an expensive "shape-processed shirt". The material of the shirt is not limited to 100% cotton, and is effective for cellulosic materials such as polyester / cotton, rayon and cupra.
【００１９】スプレーに使用する薬品が、ホルマリンを
含まない薬品により構成されているので、有害性が低く
安全である。Since the chemical used for spraying is constituted by a chemical not containing formalin, it is safe with low harmfulness.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 高川 健二 石川県金沢市玉鉾４丁目111番地倉庫精練 株式会社内 ────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Kenji Takakawa 4-111 Tamaboko, Kanazawa-shi, Ishikawa Pref.
Claims (5)
薬品を、ハンドスプレー容器に充填し、家庭で手軽に使
用できる様にした製品。1. A product obtained by filling a hand spray container with a chemical having an anti-wrinkle effect on a cellulose material so that it can be easily used at home.
製品を使用してスプレー後、家庭アイロンがけを行い反
応させることを特長とする加工方法。2. A processing method characterized by reacting a cellulosic material by using the product according to claim 1, followed by home ironing.
型グリオキザール樹脂／塩化マグネシウムを用いてお
り、さらに防しわ効果を高めることのできる樹脂を併用
して、防しわ効果を十分に高めたスプレー用防しわ加工
剤。3. The non-formalin type glyoxal resin / magnesium chloride is used as the chemical used in claim 1, and a resin capable of improving the anti-wrinkle effect is used in combination to sufficiently enhance the anti-wrinkle effect. Anti-wrinkle agent for spray.
高めることのできる樹脂に、１００％モジュラスが５〜
４０ｋｇｆ／ｃｍ２、ガラス転移点が−５０〜１０℃の
ウレタン樹脂を用いて、洗濯後の防しわ効果だけでな
く、着用時の防しわ効果も高めたスプレー用防しわ加工
剤。4. The resin according to claim 3, which has an anti-wrinkle effect and has a 100% modulus of 5 to 5.
An anti-wrinkle agent for spraying, which uses a urethane resin having a glass transition point of −50 to 10 ° C. having a 40 kgf / cm 2 and a high wrinkle prevention effect when worn, as well as after washing.
リコーンを併用して、着用時の防しわ効果とアイロンが
け時のアイロンすべり性を向上させたスプレー用防しわ
加工剤。5. An anti-wrinkle agent for spraying, wherein a silicone is used in combination with the chemicals used in claims 3 and 4, and the anti-wrinkle effect at the time of wearing and the iron sliding property at the time of ironing are improved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21795597A JPH1121768A (en) | 1997-07-08 | 1997-07-08 | Wrinkle-proofing spray for domestic purpose |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21795597A JPH1121768A (en) | 1997-07-08 | 1997-07-08 | Wrinkle-proofing spray for domestic purpose |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH1121768A true JPH1121768A (en) | 1999-01-26 |
Family
ID=16712346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21795597A Pending JPH1121768A (en) | 1997-07-08 | 1997-07-08 | Wrinkle-proofing spray for domestic purpose |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH1121768A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1448838B1 (en) * | 2001-10-18 | 2008-11-19 | The Procter & Gamble Company | Durable press treatment of fabric |
| JP2008546919A (en) * | 2005-06-24 | 2008-12-25 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | Siloxane-containing preparations for reducing crease formation |
| JP2010509518A (en) * | 2006-11-22 | 2010-03-25 | ザ プロクター アンド ギャンブル カンパニー | Beneficial compositions and methods |
-
1997
- 1997-07-08 JP JP21795597A patent/JPH1121768A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1448838B1 (en) * | 2001-10-18 | 2008-11-19 | The Procter & Gamble Company | Durable press treatment of fabric |
| JP2008546919A (en) * | 2005-06-24 | 2008-12-25 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | Siloxane-containing preparations for reducing crease formation |
| JP2010509518A (en) * | 2006-11-22 | 2010-03-25 | ザ プロクター アンド ギャンブル カンパニー | Beneficial compositions and methods |
| JP4949480B2 (en) * | 2006-11-22 | 2012-06-06 | ザ プロクター アンド ギャンブル カンパニー | Beneficial compositions and methods |
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