JPH11314253A - Gas injection mold of thermoplastic resin - Google Patents
Gas injection mold of thermoplastic resinInfo
- Publication number
- JPH11314253A JPH11314253A JP13594898A JP13594898A JPH11314253A JP H11314253 A JPH11314253 A JP H11314253A JP 13594898 A JP13594898 A JP 13594898A JP 13594898 A JP13594898 A JP 13594898A JP H11314253 A JPH11314253 A JP H11314253A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- resin
- mold
- product
- gate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002347 injection Methods 0.000 title claims abstract description 43
- 239000007924 injection Substances 0.000 title claims abstract description 43
- 229920005992 thermoplastic resin Polymers 0.000 title claims description 26
- 229920005989 resin Polymers 0.000 claims abstract description 158
- 239000011347 resin Substances 0.000 claims abstract description 158
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 238000001746 injection moulding Methods 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 24
- 238000007599 discharging Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 abstract description 7
- 239000000243 solution Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 195
- 239000000047 product Substances 0.000 description 66
- 229920001971 elastomer Polymers 0.000 description 15
- 239000005060 rubber Substances 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000004898 kneading Methods 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 229920005672 polyolefin resin Polymers 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229920005637 ethylene/1-butene copolymer elastomer Polymers 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- UHNWOJJPXCYKCG-UHFFFAOYSA-L magnesium oxalate Chemical compound [Mg+2].[O-]C(=O)C([O-])=O UHNWOJJPXCYKCG-UHFFFAOYSA-L 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/1703—Introducing an auxiliary fluid into the mould
- B29C45/1704—Introducing an auxiliary fluid into the mould the fluid being introduced into the interior of the injected material which is still in a molten state, e.g. for producing hollow articles
- B29C45/1711—Introducing an auxiliary fluid into the mould the fluid being introduced into the interior of the injected material which is still in a molten state, e.g. for producing hollow articles and removing excess material from the mould cavity by the introduced fluid, e.g. to an overflow cavity
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、艶むらやヒケがな
く高い製品外観を備えた成形品を、工業的な生産性の低
下を起こさずに安定してガス射出成形することができる
ガス射出成形用金型、及びそれを用いた中空部を有する
熱可塑性樹脂成形品の製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a gas injection molding method capable of stably performing a gas injection molding of a molded article having a high appearance without gloss unevenness or sink marks without lowering industrial productivity. The present invention relates to a molding die and a method for producing a thermoplastic resin molded article having a hollow portion using the same.
【0002】[0002]
【従来の技術】熱可塑性樹脂の射出成形品を製造する
際、成形品の部位によって肉厚に差がある場合、厚肉部
と薄肉部の収縮率の違いから、厚肉部の表面にヒケや反
り等の変形を生じやすい。このようなヒケ等の発生を防
止する手段として、厚肉部にガスを圧入して部分中空製
品とする方法がある。このようにガスを圧入して中空部
を形成しつつ射出成形する方法を、総称してガス射出成
形法という。2. Description of the Related Art When manufacturing an injection molded article of a thermoplastic resin, if there is a difference in wall thickness depending on a part of the molded article, a difference in shrinkage rate between a thick part and a thin part causes a surface of the thick part to have a sink mark. Deformation such as warpage is likely to occur. As a means for preventing the occurrence of such sink marks and the like, there is a method in which a gas is press-fitted into a thick portion to make a partially hollow product. The method of injection molding while forming a hollow portion by press-fitting a gas in this way is collectively referred to as a gas injection molding method.
【0003】熱可塑性樹脂のガス射出成形法は、金型に
射出圧入された溶融樹脂内部に、樹脂に対して不活性な
ガスを圧入して成形品内部に中空部を形成し、溶融樹脂
内部から金型キャビティ面に一様なガス圧力を付与さ
せ、ヒケやそり等の変形のない成形品を得る方法であ
る。ここで、従来、中空率を向上させるために溶融樹脂
の最終充填部近傍に樹脂溜まりを設ける手法が採られ、
その際ガス保圧を十分かけて中空率を保持していた。[0003] In the gas injection molding method of a thermoplastic resin, an inert gas is injected into a molten resin injected into a mold to form a hollow portion inside the molded product, and a hollow portion is formed inside the molten resin. In this method, a uniform gas pressure is applied to the surface of the mold cavity to obtain a molded product without deformation such as sink marks and warpage. Here, conventionally, a technique of providing a resin pool near the final filling portion of the molten resin to improve the hollow ratio has been adopted,
At that time, the hollow ratio was maintained by sufficiently applying a gas holding pressure.
【0004】しかしながら、このような従来のガス射出
成形法では、ガスを圧入した際にガスの通り道となる体
積収縮の大きい厚肉部(ガスチャンネル部)と該ガスチ
ャンネル部上面の有効面に艶むらが生じるため、製品品
質として満足のいくものが得られなかった。すなわち、
ガスチャンネル部にガスが圧入されると、ガスは高圧に
保持されているため、その他の部分よりも強く金型に押
しつけられる。そのため、その部分だけ転写性が向上
し、結果として製品全体に転写むら、艶むらが生じると
いう欠点があった。However, in such a conventional gas injection molding method, when a gas is injected, a thick portion (gas channel portion) having a large volume shrinkage, which serves as a passage of the gas, and a glossy surface on the upper surface of the gas channel portion. Due to unevenness, satisfactory product quality could not be obtained. That is,
When the gas is press-fitted into the gas channel portion, the gas is held at a high pressure, and thus is pressed against the mold more strongly than the other portions. For this reason, there is a disadvantage that the transferability is improved only in that portion, and as a result, transfer unevenness and gloss unevenness occur on the entire product.
【0005】そこで、ガスチャンネル部とその他の部分
とが同じ圧力で金型に接し均一な転写性が保持されるよ
うガス圧を制御する必要があるが、従来は、かかるガス
圧の制御のために、ガスを圧入するタイミングやガス
量、金型の圧縮速度等の初期条件を様々に変えて最適の
条件を見い出し精密に実施しなければならないため、多
大な労力を必要とし、生産性が著しく低いものであっ
た。Therefore, it is necessary to control the gas pressure so that the gas channel portion and the other portions come into contact with the mold at the same pressure to maintain uniform transferability. In addition, the initial conditions such as gas injection timing, gas volume, mold compression speed, etc. must be changed in various ways to find optimal conditions and implement them precisely, requiring a great deal of labor and significantly increasing productivity. It was low.
【0006】[0006]
【発明が解決しようとする課題】本発明は、ヒケや反り
等のない部分中空射出成形品を、製品表面の艶むらを解
消し、かつ工業的な生産性の低下を起こさずに成形でき
る機構を持ったガス射出成形用金型及びそれを用いたガ
ス射出成形方法を提供することを課題とする。SUMMARY OF THE INVENTION An object of the present invention is to provide a mechanism capable of forming a partially hollow injection-molded article free from sink marks and warpage without eliminating gloss unevenness on the surface of the product and without reducing industrial productivity. It is an object of the present invention to provide a gas injection molding die having the above and a gas injection molding method using the same.
【0007】[0007]
【課題を解決するための手段】本発明者は、鋭意検討し
た結果、ガス射出成形用金型のガスゲートと樹脂溜まり
部との間にガス放出機構を設けることにより上記課題を
解決できることを見出し、本発明に到達した。As a result of diligent studies, the present inventor has found that the above problem can be solved by providing a gas discharge mechanism between a gas gate of a gas injection mold and a resin reservoir. The present invention has been reached.
【0008】すなわち、本発明は、キャビティ型、コア
型、及び前記キャビティ型とコア型との間に形成され溶
融樹脂が充填される製品キャビティ部から構成され、樹
脂ゲートと、ガスゲートと、溶融樹脂の最終充填部に設
けられた樹脂溜まり部とを有する熱可塑性樹脂のガス射
出成形用金型であって、前記ガスゲートと樹脂溜まり部
との間にガス放出機構を設けたことを特徴とするガス射
出成形用金型を提供する。That is, the present invention comprises a cavity mold, a core mold, and a product cavity formed between the cavity mold and the core mold and filled with a molten resin. A gas injection molding die of a thermoplastic resin having a resin reservoir provided in a final filling portion of the resin, wherein a gas discharge mechanism is provided between the gas gate and the resin reservoir. Provide an injection mold.
【0009】また、本発明は、前記樹脂溜まり部が溶融
樹脂の最終充填部であって前記製品キャビティ部の外側
に設けられており、且つ前記ガス放出機構が該樹脂溜ま
り部と製品キャビティ部との間に設けられていることを
特徴とする前記ガス射出成形用金型を提供する。Further, according to the present invention, the resin reservoir is a final filling portion of the molten resin and is provided outside the product cavity, and the gas discharge mechanism is provided between the resin reservoir and the product cavity. The gas injection molding die is provided between the molds.
【0010】また、本発明は、中空部を有する熱可塑性
樹脂成形品の製造方法であって、前記ガス射出成形用金
型を用い、以下に示す(a)〜(c)の工程を含むガス
射出成形を行うことを特徴とする熱可塑性樹脂成形品の
製造方法を提供する。 (a)樹脂ゲートから溶融樹脂を製品キャビティ部へ射
出充填する射出充填工程 (b)ガスゲートからガスを溶融樹脂内へ圧入するガス
圧入工程 (c)前記ガス圧入工程で圧入されたガスをガス放出機
構により放出するガス放出工程The present invention also relates to a method for producing a thermoplastic resin molded article having a hollow portion, wherein the method comprises the following steps (a) to (c) using the gas injection mold. Provided is a method for producing a thermoplastic resin molded product, which is characterized by performing injection molding. (A) an injection filling step of injecting and filling a molten resin into a product cavity from a resin gate; (b) a gas injection step of injecting a gas from a gas gate into the molten resin; and (c) releasing the gas injected in the gas injection step. Gas release process released by mechanism
【0011】また、本発明は、前記ガス放出工程におい
て、ガスの放出を、前記ガス射出成形用金型の樹脂溜ま
り部へ溶融樹脂が完全に充填される前に行うことを特徴
とする前記熱可塑性樹脂成形品の製造方法を提供する。In the present invention, in the gas releasing step, the gas is released before the molten resin is completely filled in the resin reservoir of the gas injection molding die. Provided is a method for producing a plastic resin molded article.
【0012】[0012]
【発明の実施の形態】以下、本発明の実施の形態につい
て説明する。Embodiments of the present invention will be described below.
【0013】(1)ガス射出成形用金型 熱可塑性樹脂の射出成形に用いられる金型は、通常、凹
型(キャビティ型)と凸型(コア型)の2枚組からな
り、これら両金型を合わせた際に、溶融樹脂が充填され
製品が成形される製品キャビティ部が形成されるように
なっている。よって、本発明のガス射出成形用金型は、
基本的には、キャビティ型とコア型と製品キャビティ部
とから構成される。(1) Mold for Gas Injection Molding A mold used for injection molding of a thermoplastic resin usually comprises two sets of a concave mold (cavity mold) and a convex mold (core mold). When they are combined, a product cavity portion in which the molten resin is filled and a product is molded is formed. Therefore, the mold for gas injection molding of the present invention,
Basically, it is composed of a cavity mold, a core mold and a product cavity.
【0014】キャビティ型とコア型は、一般的に、固定
側と可動側に分かれており、固定側は成形機の固定側ダ
イプレートに固定され、可動側は可動側ダイプレートに
取り付けられる。通常の金型では固定側がキャビティ
型、可動側がコア型になっているものが多い。キャビテ
ィ型及びコア型は、鋼鉄或いは鉄を主成分とするステン
レス等の合金、アルミニウム合金、ニッケル合金、亜鉛
合金、銅合金等の金属材料から形成されている。The cavity mold and the core mold are generally divided into a fixed side and a movable side. The fixed side is fixed to a fixed side die plate of a molding machine, and the movable side is attached to a movable side die plate. In many ordinary dies, the fixed side is a cavity type and the movable side is a core type in many cases. The cavity mold and the core mold are formed from a metal material such as an alloy such as stainless steel containing iron or iron as a main component, an aluminum alloy, a nickel alloy, a zinc alloy, and a copper alloy.
【0015】金型には溶融樹脂を製品キャビティ部へ射
出注入するための樹脂ゲートが設けられている。そし
て、可動側を前進させてキャビティ型とコア型とを閉じ
て型締めし、両金型の間に形成された製品キャビティ部
に、前記樹脂ゲートから射出される熱可塑性樹脂を充填
することにより、製品が成形される。射出成形後は、可
動側を後退させてキャビティ型とコア型とを型開きし、
成形品を取り出す。樹脂ゲートの位置は、所望する成形
品の設計に応じて適宜決定することができ、またそのゲ
ート数も金型内に1点のみならず2点以上設けて多点ゲ
ートとすることもできる。The mold is provided with a resin gate for injecting molten resin into the product cavity. Then, the movable side is advanced, the cavity mold and the core mold are closed and the mold is closed, and the product cavity formed between the two molds is filled with a thermoplastic resin injected from the resin gate. , The product is molded. After injection molding, retract the movable side to open the cavity mold and core mold,
Take out the molded product. The position of the resin gate can be appropriately determined according to the design of a desired molded product, and the number of gates is not limited to one in the mold, but may be two or more to form a multipoint gate.
【0016】本発明のガス射出成形用金型には、前記樹
脂ゲートに加え、ガスゲートが設けられている。本発明
のガス射出成形用金型を、以下、図面に基づいて説明す
る。図1は本発明の金型の一例における断面の概略図を
示す。図1中、1はキャビティ型、2はコア型、3は前
記キャビティ型とコア型との間に形成され溶融樹脂が充
填される製品キャビティ部、4は樹脂ゲート、5はガス
ゲートである。The gas injection mold according to the present invention is provided with a gas gate in addition to the resin gate. Hereinafter, a gas injection molding die according to the present invention will be described with reference to the drawings. FIG. 1 is a schematic cross-sectional view of an example of the mold of the present invention. In FIG. 1, 1 is a cavity mold, 2 is a core mold, 3 is a product cavity portion formed between the cavity mold and the core mold and filled with molten resin, 4 is a resin gate, and 5 is a gas gate.
【0017】ガス射出成形においては、キャビティ型1
とコア型2とを閉じて型締めし、次いで樹脂ゲート4か
ら溶融樹脂を射出して前記キャビティ型1とコア型2と
の間に形成された製品キャビティ部3に充填した後、ガ
スゲート5からガスを前記溶融樹脂内へ圧入して成形品
内部に中空部が形成されるようにする。ガスは用いる熱
可塑性樹脂に対して不活性なものであればよく、例えば
窒素ガス等が用いられる。In gas injection molding, the cavity mold 1 is used.
And the core mold 2 are closed and clamped, and then the molten resin is injected from the resin gate 4 to fill the product cavity 3 formed between the cavity mold 1 and the core mold 2 and then the gas gate 5 A gas is pressed into the molten resin so that a hollow portion is formed inside the molded product. The gas may be any gas that is inert to the thermoplastic resin used, for example, nitrogen gas or the like.
【0018】圧入されたガスは、該ガス体に対して抵抗
の小さい方向に流動するため、冷却速度が遅く溶融粘度
が低くなっている成形品の厚肉部(体積収縮率の大きい
部位)に選択的に導入される。このようなガスの通り道
となる製品部位をガスチャンネル(図1中、8)とい
う。Since the injected gas flows in the direction of low resistance to the gas, the cooling rate is low and the melt viscosity is low. Introduced selectively. The product part which becomes such a gas passage is called a gas channel (8 in FIG. 1).
【0019】ガスチャンネルは、樹脂ゲート位置及びガ
スゲート位置、成形品の形状、肉厚等によって左右され
るため、通常はこれらを考慮し、成形品内に所望のガス
チャンネルが形成されるように製品設計を行う。ガスゲ
ートの位置は、所望する成形品のガスチャンネルの設計
に応じて適宜決定することができ、またそのゲート数も
金型内に1点のみならず2点以上設けることもできる。Since the gas channel depends on the resin gate position, the gas gate position, the shape and the thickness of the molded article, and the like, usually these are taken into consideration so that the desired gas channel is formed in the molded article. Do the design. The position of the gas gate can be appropriately determined according to the design of the gas channel of a desired molded product, and the number of gates can be provided not only at one point but also at two or more points in the mold.
【0020】ガスを圧入して射出成形する方法として
は、ショートショット法及びフルショット法が挙げられ
る。ショートショット法では、射出工程において溶融樹
脂を完全に充填することなくショートショット状態にて
射出停止し、次いでガスを圧入した後、ガス圧力にて溶
融樹脂を未充填部分に押し出しながら製品キャビティ部
を充填する。As a method of injection molding by injecting a gas, there are a short shot method and a full shot method. In the short shot method, injection is stopped in a short shot state without completely filling the molten resin in the injection step, and then gas is injected, and then the product cavity is extruded by gas pressure while extruding the molten resin to an unfilled portion. Fill.
【0021】フルショット法では、射出工程において製
品キャビティ部を溶融樹脂でフル充填した後、樹脂の射
出を停止し、その後加圧ガスを圧入し、樹脂の冷却収縮
による体積収縮分をガス圧にて中空化する。成形品中の
ガスチャンネル部の体積収縮が大きいため、圧入された
ガスはガスチャンネル部を中空化していく。In the full shot method, after the product cavity is fully filled with the molten resin in the injection step, the injection of the resin is stopped, and then pressurized gas is injected, and the volume shrinkage due to the cooling shrinkage of the resin is reduced to the gas pressure. To make it hollow. Since the volume shrinkage of the gas channel portion in the molded article is large, the press-fitted gas hollows the gas channel portion.
【0022】いずれの方法においても、製品キャビティ
部に充填された溶融樹脂が冷却により体積収縮してヒケ
等を発生するおそれのある工程において、ガスチャンネ
ル内部にガスを圧入し、樹脂を体積収縮部に押し出して
その体積収縮分だけ該ガスチャンネル部を中空化すると
ともに、成形品内部からキャビティ表面に向けてガス圧
を一様に作用させて成形品を加圧することにより、ヒ
ケ、そり等の変形のない成形品を得ることができる。In any of the methods, in a process in which the molten resin filled in the product cavity portion may contract in volume due to cooling and cause sink marks or the like, a gas is injected into the gas channel to reduce the volume of the resin in the volume contraction portion. And pressurize the molded product by applying a uniform gas pressure from the interior of the molded product to the cavity surface, thereby deforming sink marks, warpage, etc. A molded article free from defects can be obtained.
【0023】ガスチャンネル内の溶融樹脂は、加圧ガス
体により流動し、製品キャビティ部内へ充填される。ガ
スは体積収縮の大きい製品部位に導入されるが、ガスは
高圧に保持されているため、ガスチャンネル内のヒケ収
縮分を補って中空化するだけでなくガスチャンネル周囲
の基本肉厚部へも溶融溶融樹脂を押し出す。The molten resin in the gas channel flows by the pressurized gas and is filled in the product cavity. The gas is introduced into the product part where the volume contraction is large, but since the gas is kept at a high pressure, it not only compensates for the shrinkage in the gas channel and hollows it out, but also to the basic thick part around the gas channel. Extrudes molten resin.
【0024】したがって、基本肉厚部の樹脂の体積収縮
分は、ガスチャンネル内の樹脂を周囲に押し出すことに
より補われる。すなわち、成形機の保圧工程にて樹脂の
体積収縮分を射出シリンダー内の樹脂で補うのではな
く、ガス圧によりガスチャンネル内の樹脂を押し出しフ
ル充填することにより補うことができる。なお、ガスチ
ャンネル内の溶融樹脂はガスにより先端部分へも押し出
される。Therefore, the volume shrinkage of the resin in the basic thick portion is compensated by extruding the resin in the gas channel to the surroundings. That is, the volume shrinkage of the resin is not compensated for by the resin in the injection cylinder in the pressure holding step of the molding machine, but can be compensated for by extruding the resin in the gas channel by gas pressure and fully filling the resin. The molten resin in the gas channel is also pushed out to the tip by the gas.
【0025】<樹脂溜まり部>本発明のガス射出成形用
金型には、溶融樹脂の最終充填部に相当する部分に樹脂
溜まり部が設けられている。溶融樹脂を射出注入した後
ガスを圧入すると、ガスはガスチャンネル内、すなわち
体積収縮の大きい厚肉部の方向に流れて中空部を形成す
るが、通常はガスに押し出された樹脂がガスチャンネル
内を先に流動しキャビティ内を充填していくため、ガス
チャンネルが製品末端部にあたる溶融樹脂の最終充填部
の近傍まで設計されている場合、ガスにより先端部分に
押し出された樹脂が該先端で溜まることによりその部分
だけ中空化せず、ガスチャンネルすべてに中空部を形成
できないことがある。<Resin Reservoir> The resin mold for gas injection molding of the present invention is provided with a resin reservoir at a portion corresponding to the final filling portion of the molten resin. When the gas is injected after injection of the molten resin, the gas flows in the gas channel, that is, in the direction of the thick portion having a large volume shrinkage, and forms a hollow portion. Usually, the resin extruded by the gas flows into the gas channel. When the gas channel is designed close to the final filling part of the molten resin, which is the end of the product, the resin extruded to the tip by the gas accumulates at the tip because the gas flows first and fills the cavity. As a result, a hollow portion may not be formed in all the gas channels without hollowing only that portion.
【0026】この場合、ガスに押されたガスチャンネル
先端の樹脂が中空化を妨げないように、該樹脂が避難で
きる場所として、溶融樹脂の最終充填部に別途樹脂溜ま
り部を設ける。これにより、ガスチャンネルすべてに中
空部を形成することが可能となり、中空率を上げること
ができる。In this case, a resin reservoir is separately provided in the final filling portion of the molten resin as a place where the resin can be evacuated so that the resin at the tip of the gas channel pressed by the gas does not prevent hollowing. This makes it possible to form a hollow portion in all of the gas channels, thereby increasing the hollow ratio.
【0027】上記図1中、6は樹脂溜まり部である。樹
脂ゲート4から溶融樹脂を射出注入し、次いでガスゲー
ト5からガスを圧入すると、射出された溶融樹脂は、製
品キャビティ部3内を徐々に充填しつつ、ガス体によっ
ても押されて製品末端部にあたる溶融樹脂の最終充填部
7へと流動していく。一方、圧入されたガスは、溶融樹
脂内のガスチャンネル部8を通り、該ガスチャンネル部
8を中空化しつつ溶融樹脂の最終充填部7へ向けて進行
する。In FIG. 1, reference numeral 6 denotes a resin reservoir. When molten resin is injected and injected from the resin gate 4 and then gas is injected from the gas gate 5, the injected molten resin gradually pushes the product cavity portion 3 and is pushed by the gas to hit the end of the product. The molten resin flows toward the final filling section 7. On the other hand, the injected gas passes through the gas channel portion 8 in the molten resin and advances toward the final filling portion 7 of the molten resin while hollowing the gas channel portion 8.
【0028】ここで、該最終充填部に樹脂溜まり部が設
けられていると、ガス圧により押されて最終充填部7に
溜まりつつあった溶融樹脂は、該最終充填部7に留まら
ず、そこから製品キャビティ部外側の樹脂溜まり部6へ
押し出されるため、ガスは樹脂に妨げられることなく最
終充填部7に到達することができ、該最終充填部まで中
空化することができる。Here, if a resin pool is provided in the final filling section, the molten resin that has been accumulated in the final filling section 7 due to being pressed by gas pressure does not stay in the final filling section 7, Is pushed out to the resin reservoir 6 outside the product cavity, the gas can reach the final filling portion 7 without being hindered by the resin, and the gas can be hollowed up to the final filling portion.
【0029】樹脂溜まり部は、上記図1の例のように、
溶融樹脂の最終充填部7であって製品キャビティ部3の
外側に設置されているのが好ましい。すなわち、金型の
製品キャビティ部における製品末端部に相当する部分の
外側に、例えばオーバーフロータブなどを連結し、樹脂
溜まり部とする。これにより成形された製品は、その製
品末端部の外側に樹脂溜まり状物が形成されているが、
それを切除することにより樹脂溜まり状物の残存しない
最終製品を得ることができる。この場合、図1のよう
に、金型の設計によっては製品と該製品外部の樹脂溜ま
りとを同じ金型内で成形できるように、製品キャビティ
部と樹脂溜まり部とを一体化した金型を用いることもで
きる。As shown in the example of FIG.
It is preferable that the final filling portion 7 of the molten resin is provided outside the product cavity portion 3. That is, for example, an overflow tab or the like is connected to the outside of a portion corresponding to the end of the product in the product cavity of the mold to form a resin reservoir. In the product formed by this, a resin pool is formed outside the end of the product,
By cutting it off, it is possible to obtain a final product in which no resin pool remains. In this case, as shown in FIG. 1, depending on the design of the mold, a mold in which a product cavity portion and a resin reservoir portion are integrated so that a product and a resin reservoir outside the product can be molded in the same mold. It can also be used.
【0030】樹脂溜まり部の構成はこれに限られず、例
えば製品内部に樹脂溜まりを形成するように金型を設計
することもできる。この場合は、製品内部のガスチャン
ネル末端に樹脂溜まりが形成されるようにする。The configuration of the resin reservoir is not limited to this. For example, a mold can be designed so that a resin reservoir is formed inside a product. In this case, a resin pool is formed at the end of the gas channel inside the product.
【0031】<ガス放出機構>本発明のガス射出成形用
金型は、前記ガスゲートと樹脂溜まり部との間に、ガス
の圧入工程における所定の段階でガスの放出を行うため
のガス放出機構を設けたことを特徴とする。このように
射出成形工程の所定の段階で圧入ガスを放出することに
より、ガスチャンネル内のガス圧力を制御し、金型キャ
ビティ面への加圧を均一にして転写むら、艶むらを解消
することができる。<Gas Release Mechanism> The gas injection mold according to the present invention has a gas release mechanism for releasing gas at a predetermined stage in the gas injection process between the gas gate and the resin reservoir. It is characterized by having been provided. By discharging the pressurized gas at a predetermined stage of the injection molding process, the gas pressure in the gas channel is controlled, and the pressure on the mold cavity surface is made uniform to eliminate transfer unevenness and gloss unevenness. Can be.
【0032】図2は、図1における樹脂溜まり部近傍の
拡大図であり、ガス放出機構の一例を示す。図2中、1
0は中空部、11は樹脂溜まり未充填部である。この例
ではガス放出機構として撃ち抜きピン12を用い、溶融
樹脂が樹脂溜まり部6に一定量充填された時点でピンを
撃ち込み、再度抜くことにより、ガスが解放される。FIG. 2 is an enlarged view of the vicinity of the resin reservoir in FIG. 1 and shows an example of a gas release mechanism. In FIG. 2, 1
Reference numeral 0 denotes a hollow portion, and reference numeral 11 denotes an unfilled portion where the resin is accumulated. In this example, a shooting pin 12 is used as a gas release mechanism, and when the molten resin is filled into the resin reservoir 6 in a certain amount, the pin is shot and discharged again to release the gas.
【0033】ガスの放出は、ガス圧入工程の完了前にお
ける任意の段階で行うことができるが、溶融樹脂が樹脂
溜まり部6へ充填を開始した後、完全に充填される前ま
での間に行うのが好ましい。樹脂溜まり部へ溶融樹脂が
完全に充填される前であれば、ガス圧が充填方向へ向け
られ、ガスチャンネル内の樹脂を周囲の金型に必要以上
に強く押しつけることがないため、この時点でガスを解
放すれば全体として転写むらや艶むらが生じにくい。一
方、樹脂溜まり部へ溶融樹脂が完全に充填されると、ガ
ス圧によりガスチャンネル部のみが周囲の金型に強く押
されるため、転写むらや艶むらが生じる。よって、樹脂
溜まり部へ溶融樹脂が完全に充填された後にガスを解放
しても、転写むらや艶むらが生じるのを防ぐことができ
ない。The gas can be released at any stage before the completion of the gas injection step, but after the molten resin starts to be filled into the resin reservoir 6 and before it is completely filled. Is preferred. If the resin pool is not completely filled with the molten resin, the gas pressure will be directed to the filling direction, and the resin in the gas channel will not be pressed against the surrounding mold more than necessary. If the gas is released, transfer unevenness and gloss unevenness hardly occur as a whole. On the other hand, when the molten resin is completely filled in the resin reservoir, only the gas channel portion is strongly pushed by the surrounding mold due to the gas pressure, so that uneven transfer and uneven gloss occur. Therefore, even if the gas is released after the molten resin is completely filled in the resin reservoir, it is not possible to prevent transfer unevenness and gloss unevenness from occurring.
【0034】かかるガス放出のタイミングを知る方法と
しては、例えば樹脂溜まり部6に圧力センサー13を設
置して圧力を感知させる方法をとることもでき、またあ
らかじめ樹脂溜まり部6に所定量の樹脂が充填される条
件を見出した後その条件に従ってガス放出を行う方法を
とってもよい。例えば、樹脂溜まり部の内圧が10〜5
00kg/cm2、さらには50〜200kg/cm2程
度となったときにガスを放出するのが好ましい。As a method of knowing the timing of such gas release, for example, a method of installing a pressure sensor 13 in the resin reservoir 6 and sensing the pressure can be adopted. After finding the filling condition, a method of releasing gas according to the condition may be adopted. For example, when the internal pressure of the resin reservoir is 10 to 5
It is preferable to release gas when the pressure becomes about 00 kg / cm 2 , more preferably about 50 to 200 kg / cm 2 .
【0035】ガス放出機構は、図2では製品キャビティ
部の末端にあたる溶融樹脂の最終充填部7と樹脂溜まり
部6との間の連結部に設けられている。このように、ガ
ス放出機構は、ガスチャンネルの末端部、すなわち溶融
樹脂の最終充填部となる製品末端部に相当する製品キャ
ビティ部から樹脂溜まり部への連結部に設けるのが好ま
しい。ただし、これに限られるものではなく、ガスゲー
ト5と樹脂溜まり部6との間の任意の位置に設けること
ができる。例えば、製品キャビティ部3内のガスチャン
ネル8の任意の位置に設けることもできる。The gas releasing mechanism is provided at the connection between the final filling portion 7 of the molten resin and the resin reservoir 6 at the end of the product cavity in FIG. As described above, the gas release mechanism is preferably provided at the end of the gas channel, that is, at the connection from the product cavity to the resin reservoir corresponding to the end of the product to be the final filling portion of the molten resin. However, the present invention is not limited to this, and it can be provided at any position between the gas gate 5 and the resin reservoir 6. For example, it can be provided at an arbitrary position of the gas channel 8 in the product cavity 3.
【0036】ガス放出機構の構造は、上述した撃ち抜き
ピンを用いるものに限られず、例えば製品キャビティ部
3の任意の位置にガス放出用の開閉弁を設けることもで
きる。また、溶融樹脂の最終充填部近傍に薄肉部を設
け、一定圧以上でガスが注入されると破裂するように設
計し、結果的にガスを放出できるようにしてもよい。ま
た、金型内で樹脂溜まり部に通じるガスチャンネル部を
剪断させ、ガスチャンネル内のガスを逃がす方法が挙げ
られる。The structure of the gas releasing mechanism is not limited to the one using the above-described shooting pin. For example, an on-off valve for releasing gas may be provided at an arbitrary position in the product cavity 3. Further, a thin portion may be provided in the vicinity of the final filling portion of the molten resin so as to be designed to burst when gas is injected at a certain pressure or more, so that the gas can be released as a result. In addition, there is a method in which the gas channel portion communicating with the resin reservoir portion in the mold is sheared to release the gas in the gas channel.
【0037】<熱可塑性樹脂>本発明のガス射出成形用
金型によって射出成形しうる熱可塑性樹脂としては、ポ
リオレフィン系樹脂、ポリアミド樹脂、ポリカーボネー
ト樹脂、ポリエステル樹脂等が挙げられる。これらのう
ちポリオレフィン系樹脂が、無塗装外装部品に多く使用
されており有用である。<Thermoplastic resin> Examples of the thermoplastic resin that can be injection-molded by the gas injection mold of the present invention include polyolefin resins, polyamide resins, polycarbonate resins, polyester resins and the like. Of these, polyolefin resins are often used for unpainted exterior parts and are useful.
【0038】ポリオレフィン系樹脂としては、低圧法ポ
リエチレン、中圧法ポリエチレン、高圧法ポリエチレ
ン、線状低密度ポリエチレン等のエチレン単独重合体、
或いはエチレン・プロピレン共重合体等のエチレン系樹
脂;立体規則性ポリプロピレン等のポリプロピレン単独
重合体、或いはプロピレン・エチレン共重合体等のプロ
ピレン系樹脂;立体規則性ポリ−1−ブテン、立体規則
性ポリ−4−メチル−1−ペンテン等のその他のα−オ
レフィン系樹脂;等を挙げることができる。Examples of the polyolefin resin include ethylene homopolymers such as low pressure polyethylene, medium pressure polyethylene, high pressure polyethylene, and linear low density polyethylene;
Or an ethylene-based resin such as an ethylene-propylene copolymer; a polypropylene homopolymer such as a stereoregular polypropylene, or a propylene-based resin such as a propylene-ethylene copolymer; a stereoregular poly-1-butene, a stereoregular poly Other α-olefin-based resins such as -4-methyl-1-pentene; and the like.
【0039】これらの中でも、エチレン単独重合体又は
エチレン・プロピレン共重合体等のエチレン系樹脂、プ
ロピレン単独重合体又はプロピレン・エチレン共重合体
等のプロピレン系樹脂を用いることが好ましい。Among these, it is preferable to use an ethylene resin such as an ethylene homopolymer or an ethylene / propylene copolymer, and a propylene resin such as a propylene homopolymer or a propylene / ethylene copolymer.
【0040】本発明において用いる熱可塑性樹脂には、
無機充填剤やゴム成分などの他の添加剤を必要に応じて
配合してもよい。具体的には、無機充填剤としては、酸
化カルシウム、酸化マグネシウム、シリカ、酸化チタ
ン、水酸化アルミニウム、水酸化マグネシウム、水酸化
カルシウム、塩基性炭酸マグネシウム、炭酸カルシウ
ム、硫酸バリウム、タルク、クレー、マイカ、ゼオライ
ト、繊維状チタン酸カリウム、繊維状マグネシウムオキ
サルフェート、繊維状ホウ酸アルミニウムなどのウィス
カー類及び炭素繊維、ガラス繊維等を挙げることができ
る。該無機充填剤の配合量は熱可塑性樹脂100重量部
に対して、一般に1〜60重量部、好ましくは20〜6
0重量部である場合に、本発明の効果を顕著に発揮する
ことができる。The thermoplastic resin used in the present invention includes:
Other additives such as an inorganic filler and a rubber component may be blended as required. Specifically, examples of the inorganic filler include calcium oxide, magnesium oxide, silica, titanium oxide, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, basic magnesium carbonate, calcium carbonate, barium sulfate, talc, clay, and mica. Whisker, such as zeolite, zeolite, fibrous potassium titanate, fibrous magnesium oxalate, and fibrous aluminum borate; carbon fiber; glass fiber; The amount of the inorganic filler is generally 1 to 60 parts by weight, preferably 20 to 6 parts by weight, per 100 parts by weight of the thermoplastic resin.
When the amount is 0 parts by weight, the effects of the present invention can be remarkably exhibited.
【0041】ゴム成分としては、エチレン・プロピレン
共重合ゴム(EPM)、エチレン・1−ブテン共重合ゴ
ム、エチレン・プロピレン・1−ブテン共重合ゴム、エ
チレン・プロピレン・非共役ジエン共重合ゴム(EPD
M)、エチレン・1−ブテン・非共役ジエン共重合ゴ
ム、エチレン・プロピレン・1−ブテン・非共役ジエン
共重合ゴム等のポリオレフィン系ゴム、スチレン・ブタ
ジエン共重合体等のスチレン系ゴム等を挙げることがで
きる。これらゴム成分の中でも、エチレン・プロピレン
共重合ゴム(EPM)、エチレン・プロピレン・非共役
ジエン共重合ゴム(EPDM)等のポリオレフィン系ゴ
ムを用いることが好ましい。これらゴム成分は、100
℃で測定したムーニー粘度(ML1+4)が、通常10〜
200、好ましくは30〜150の範囲のものが使用さ
れる。該ゴム成分の配合量は熱可塑性樹脂100重量部
に対して一般に1〜40重量部、好ましくは10〜40
重量部である場合に、本発明の効果を顕著に発揮するこ
とができる。As rubber components, ethylene-propylene copolymer rubber (EPM), ethylene / 1-butene copolymer rubber, ethylene / propylene / 1-butene copolymer rubber, ethylene / propylene / non-conjugated diene copolymer rubber (EPD)
M), polyolefin-based rubber such as ethylene / 1-butene / non-conjugated diene copolymer rubber, ethylene / propylene / 1-butene / non-conjugated diene copolymer rubber, and styrene-based rubber such as styrene / butadiene copolymer. be able to. Among these rubber components, it is preferable to use a polyolefin rubber such as an ethylene / propylene copolymer rubber (EPM) and an ethylene / propylene / non-conjugated diene copolymer rubber (EPDM). These rubber components are 100
Mooney viscosity (ML 1 + 4 ) measured at 10 ° C.
Those having a range of 200, preferably 30 to 150 are used. The amount of the rubber component is generally 1 to 40 parts by weight, preferably 10 to 40 parts by weight, per 100 parts by weight of the thermoplastic resin.
When the amount is part by weight, the effects of the present invention can be remarkably exhibited.
【0042】その他の添加剤としては、着色するための
顔料及び顔料分散剤や、更に性能の向上を図るために配
合する酸化防止剤、帯電防止剤、光安定剤、紫外線吸収
剤、中和剤、金属腐食抑制剤、滑剤、難燃剤、核剤、分
散剤、加工性安定剤、流動性改良剤等を挙げることがで
きる。Other additives include pigments and pigment dispersants for coloring, and antioxidants, antistatic agents, light stabilizers, ultraviolet absorbers, and neutralizing agents to be added for further improving the performance. Metal corrosion inhibitors, lubricants, flame retardants, nucleating agents, dispersants, processability stabilizers, flow improvers and the like.
【0043】(2)熱可塑性樹脂成形品の製造方法 本発明においては、上記ガス射出成形用金型を用いてガ
ス射出成形を行うことにより、中空部を有する熱可塑性
樹脂成形品を製造することができる。(2) Method for producing thermoplastic resin molded article In the present invention, a thermoplastic resin molded article having a hollow portion is produced by performing gas injection molding using the above-mentioned gas injection molding die. Can be.
【0044】<原材料の調製>原材料の調製は、上記熱
可塑性樹脂に必要に応じて添加剤を添加し、十分に混合
することによって行われる。混合は、通常の混練機、例
えば一軸又は二軸の押出機、バンバリーミキサー、スー
パーミキサー、ロール、ブラベンダープラストグラフ、
ニーダーなどを用いて混練することにより行うのが好ま
しく、より好ましくは押出機、特に二軸押出機を用いて
混練する。混練条件は、用いる樹脂に応じて適宜選択で
きるが、一般に、常圧下で180〜260℃、好ましく
は190〜230℃にて行われる。<Preparation of Raw Materials> Raw materials are prepared by adding additives to the above-mentioned thermoplastic resin as necessary and mixing them well. Mixing is performed by using a conventional kneader, for example, a single-screw or twin-screw extruder, a Banbury mixer, a super mixer, a roll, a Brabender plastograph,
The kneading is preferably performed by kneading using a kneader or the like, and more preferably using an extruder, particularly a twin-screw extruder. The kneading conditions can be appropriately selected according to the resin used, but generally, the kneading is carried out under normal pressure at 180 to 260 ° C, preferably 190 to 230 ° C.
【0045】<ガス射出成形>本発明の製造方法は、以
下に示す(a)〜(c)の工程を含むガス射出成形を行
うことを特徴とする。 (a)樹脂ゲートから溶融樹脂を製品キャビティ部へ射
出充填する射出充填工程 (b)ガスゲートからガスを溶融樹脂内へ圧入するガス
圧入工程 (c)前記ガス圧入工程で圧入されたガスをガス放出機
構により放出するガス放出工程<Gas Injection Molding> The production method of the present invention is characterized by performing gas injection molding including the following steps (a) to (c). (A) an injection filling step of injecting and filling a molten resin into a product cavity from a resin gate; (b) a gas injection step of injecting a gas from a gas gate into the molten resin; and (c) releasing the gas injected in the gas injection step. Gas release process released by mechanism
【0046】(a)射出充填工程 射出充填工程においては、本発明の前記金型のキャビテ
ィ型とコア型とを閉じ(型締)、そこに形成された製品
キャビティ部内へ、上記方法で調整された原材料の熱可
塑性樹脂を樹脂ゲートから射出充填する。この場合の成
形条件は特に限定されず、目的とする成形品の大きさや
厚み等に応じて適宜選択できるが、樹脂温度は180〜
250℃、金型温度は20〜60℃程度とするのが好ま
しい。また射出圧力は、好ましくは100〜1500k
g/cm2、より好ましくは300〜900kg/cm2
程度である。(A) Injection and filling step In the injection and filling step, the cavity mold and the core mold of the mold of the present invention are closed (mold clamping), and the product is adjusted by the above-described method into the product cavity formed therein. The raw material thermoplastic resin is injected and filled from the resin gate. The molding conditions in this case are not particularly limited and can be appropriately selected depending on the size and thickness of the target molded product, but the resin temperature is 180 to
It is preferable that the temperature is 250 ° C. and the mold temperature is about 20 to 60 ° C. The injection pressure is preferably 100 to 1500 k.
g / cm 2 , more preferably 300 to 900 kg / cm 2
It is about.
【0047】(b)ガス圧入工程 ガス圧入工程においては、上記射出充填工程につづい
て、製品キャビティ内へ充填された溶融樹脂内にガスを
圧入する。ガスは所定のガスチャンネル内へ導入され、
ガスチャンネル内の溶融樹脂を周囲へ押し出す。(B) Gas Injection Step In the gas injection step, gas is injected into the molten resin filled in the product cavity, following the injection filling step. The gas is introduced into a predetermined gas channel,
The molten resin in the gas channel is extruded to the surroundings.
【0048】このときの圧入するガスの圧力は特に限定
されないが、好ましくは500kg/cm2以下、より
好ましくは100〜200kg/cm2程度である。[0048] Although the pressure of the gas to be pressed at this time is not particularly limited, it is preferably 500 kg / cm 2 or less, more preferably 100 to 200 kg / cm 2 approximately.
【0049】ガスを圧入する時期についていえば、溶融
樹脂の射出が終了し成形機の射出圧力が降下すると同時
にガスを圧入し、ガス圧で樹脂を流動させるようにする
のが好ましい。射出圧力の降下後ガスの圧入まで長く経
過すると、ガス圧により樹脂が再流動されるまでの時間
がかかりすぎ、フローマークが発生する場合がある。Regarding the timing for injecting the gas, it is preferable that the injection of the molten resin is completed and the injection pressure of the molding machine is lowered, and at the same time, the gas is injected and the resin is caused to flow at the gas pressure. If a long time elapses until the gas is injected after the injection pressure drops, it takes too much time until the resin reflows due to the gas pressure, and a flow mark may be generated.
【0050】(c)ガス放出工程 ガス放出工程では、前記ガス圧入工程で圧入されたガス
を、ガス放出機構により放出する。(C) Gas Release Step In the gas release step, the gas injected in the gas injection step is released by a gas release mechanism.
【0051】上述した図2の例でいえば、前記射出充填
工程及び次いでガス圧入工程により、中空部10を有す
る製品9が形成されると同時に、ガスにより押し出され
たガスチャンネル内の溶融樹脂が、最終充填部7から樹
脂溜まり部6へ充填される。樹脂溜まり部6への充填が
進行すると、充填が完了する前に圧力センサー13が樹
脂溜まり部内のガス圧を感知し、ガスを放出するタイミ
ングを知ることができる。In the example of FIG. 2 described above, by the injection filling step and then the gas injection step, the product 9 having the hollow portion 10 is formed, and at the same time, the molten resin in the gas channel extruded by the gas is removed. Then, the resin is filled from the final filling section 7 into the resin storage section 6. As the filling of the resin reservoir 6 progresses, the pressure sensor 13 detects the gas pressure in the resin reservoir before the filling is completed, and can know the timing of releasing the gas.
【0052】次に、撃ち抜きピン12を、樹脂溜まり部
6と最終充填部7との間の連結部に撃ち込み、再度抜く
ことにより、ガスを解放する。Next, the gas is released by shooting the shooting pin 12 into the connecting portion between the resin reservoir 6 and the final filling portion 7 and pulling it out again.
【0053】その後、通常の射出成形と同様に、樹脂の
冷却後、キャビティ型とコア型とを型開きし、金型から
成形品を取り出す。After the resin is cooled, the cavity mold and the core mold are opened, and the molded product is taken out of the mold as in the case of ordinary injection molding.
【0054】(3)熱可塑性樹脂成形品の用途 本発明の製造方法で得られる熱可塑性樹脂成形品は、中
空部を有するものであれば特に限定されないが、具体的
にはオーディオパネルなどの家電部品や、インスツルメ
ントパネル、コンソールボックス、アシストグリップ、
サイドモールなどの自動車内装部品等が挙げられる。(3) Use of Thermoplastic Resin Molded Product The thermoplastic resin molded product obtained by the production method of the present invention is not particularly limited as long as it has a hollow portion. Parts, instrument panels, console boxes, assist grips,
Automobile interior parts such as side moldings.
【0055】[0055]
【実施例】以下に、実施例を挙げて本発明を具体的に説
明するが、本発明はこれらの実施例にのみ限定されるも
のではない。なお、以下の実施例及び比較例における物
性の評価は以下に示す方法によって実施した。EXAMPLES Hereinafter, the present invention will be described specifically with reference to examples, but the present invention is not limited to these examples. The evaluation of the physical properties in the following Examples and Comparative Examples was performed by the following methods.
【0056】(1)艶むら 得られた成形品の外観について、一般部とガスチャンネ
ル部との差を目視により観察し、以下の基準で評価し
た。 ○:一般部とガスチャンネル部の外観が同じで境界が判
別できない。 △:ヒケはあるがガスチャンネル部の外観は若干改良さ
れている。 ×:ガスチャンネル部分と一般部とがはっきり判別でき
る。 (2)ヒケ 得られた成形品の外観を目視により観察し、以下の基準
で評価した。 ○:ヒケは見られない。 △:艶むらは若干よいが、ガスチャンネル部にヒケが見
られる。 ×:明らかにガスチャンネル部にヒケが見られる。(1) Uneven gloss The appearance of the obtained molded article was visually observed for the difference between the general part and the gas channel part, and evaluated according to the following criteria. :: The general portion and the gas channel portion have the same appearance, and the boundary cannot be determined. Δ: There is sink mark, but the appearance of the gas channel is slightly improved. X: The gas channel portion and the general portion can be clearly distinguished. (2) Sinking The appearance of the obtained molded article was visually observed and evaluated according to the following criteria. :: No sink marks are observed. Δ: The glossiness is slightly good, but sink marks are observed in the gas channel portion. ×: Sink is clearly seen in the gas channel portion.
【0057】<実施例1、比較例1〜2>熱可塑性樹脂
として、ポリオレフィン樹脂をベースにゴム30重量%
及びタルク10重量%が配合された成形材料を用い、こ
れを原材料として、ガス射出成形を行った。用いた金型
は、図1及び図2に示したものである。<Example 1, Comparative Examples 1-2> As a thermoplastic resin, a polyolefin resin was used as a base and rubber was 30% by weight.
Gas injection molding was performed using a molding material containing 10% by weight of talc and talc as a raw material. The mold used was that shown in FIGS.
【0058】まず、キャビティ型1とコア型2を閉じ、
製品キャビティ部3に溶融混練した原材料を樹脂ゲート
4から射出注入した。樹脂温度は240℃、金型温度は
50℃、射出圧力は1200kg/cm2とした。First, the cavity mold 1 and the core mold 2 are closed,
Raw materials melt-kneaded into the product cavity 3 were injected and injected from the resin gate 4. The resin temperature was 240 ° C., the mold temperature was 50 ° C., and the injection pressure was 1200 kg / cm 2 .
【0059】次いで、ガスゲートから窒素ガスをガス圧
130kg/cm2にて圧入した。その後、樹脂溜まり
部6に溶融樹脂が充填を開始したのち、完全に充填され
る前に(残圧が10kg/cm2程度となった時点
で)、撃ち抜きピン12を連結部へ撃ち込み、すばやく
抜いてガスを解放した。樹脂が冷却した後、キャビティ
型とコア型とを型開きし、成形品を取り出した。Next, nitrogen gas was injected from the gas gate at a gas pressure of 130 kg / cm 2 . Thereafter, after the filling of the molten resin into the resin reservoir 6 and before the resin is completely filled (when the residual pressure becomes about 10 kg / cm 2 ), the shooting pin 12 is shot into the connecting portion and quickly. The gas was released to release the gas. After the resin had cooled, the cavity mold and the core mold were opened, and the molded product was taken out.
【0060】得られた成形品について、表面の艶むらと
ヒケとを観察し、上記基準にて評価した。結果を表1に
示す。The resulting molded article was observed for uneven gloss and sink marks on the surface, and evaluated according to the above criteria. Table 1 shows the results.
【0061】<比較例1>樹脂溜まり部6に溶融樹脂が
完全に充填された後に撃ち抜きピンを撃ち込んでガスを
解放した他は、実施例1と同様にして成形品を成形し
た。評価結果を表1に示す。<Comparative Example 1> A molded product was formed in the same manner as in Example 1 except that the gas was released by firing a shooting pin after the molten resin was completely filled in the resin reservoir 6. Table 1 shows the evaluation results.
【0062】<比較例2>撃ち抜きピンを撃ち込んでガ
スを解放する工程を行わなかった他は、実施例1と同様
にして成形品を成形した。評価結果を表1に示す。<Comparative Example 2> A molded product was formed in the same manner as in Example 1 except that the process of releasing gas by firing a shooting pin was not performed. Table 1 shows the evaluation results.
【0063】<比較例3>樹脂溜まり部を設けず、溶融
樹脂を製品キャビティ部に充填しガスを圧入した後に撃
ち抜きピンを撃ち込んでガスを解放した他は、実施例1
と同様にして成形品を成形した。評価結果を表1に示
す。<Comparative Example 3> Example 1 was repeated except that the resin pool was not provided, the molten resin was filled in the product cavity, the gas was press-fitted, and then the gas was released by shooting with a shooting pin.
A molded article was molded in the same manner as described above. Table 1 shows the evaluation results.
【0064】[0064]
【表1】 [Table 1]
【0065】[0065]
【発明の効果】本発明のガス射出成形用金型を用いるこ
とにより、ヒケや反り等の変形のない部分中空成形品
を、転写むらや艶むらを生じることなく、かつ高い工業
的生産性をもって成形することができる。According to the gas injection molding die of the present invention, a partially hollow molded article having no deformation such as sink marks and warpage can be produced with high industrial productivity without causing transfer unevenness and gloss unevenness. Can be molded.
【図1】 本発明のガス射出成形用金型の一例の断面の
概略図である。FIG. 1 is a schematic cross-sectional view of an example of a gas injection mold according to the present invention.
【図2】 図1のガス射出成形用金型における樹脂溜ま
り部近傍の拡大図である。FIG. 2 is an enlarged view of the vicinity of a resin reservoir in the gas injection mold of FIG.
1・・・キャビティ型 2・・・コア型 3・・・製品キャビティ部 4・・・樹脂ゲート 5・・・ガスゲート 6・・・樹脂溜まり部 7・・・溶融樹脂の最終充填部 8・・・ガスチャンネル 9・・・製品 10・・・中空部 11・・・樹脂溜まり未充填部 12・・・ガス放出機構 13・・・圧力センサー DESCRIPTION OF SYMBOLS 1 ... Cavity type 2 ... Core type 3 ... Product cavity part 4 ... Resin gate 5 ... Gas gate 6 ... Resin pool part 7 ... Final filling part of molten resin 8.・ Gas channel 9 ・ ・ ・ Product 10 ・ ・ ・ Hollow part 11 ・ ・ ・ Resin pool unfilled part 12 ・ ・ ・ Gas release mechanism 13 ・ ・ ・ Pressure sensor
Claims (4)
ティ型とコア型との間に形成され溶融樹脂が充填される
製品キャビティ部から構成され、樹脂ゲートと、ガスゲ
ートと、溶融樹脂の最終充填部に設けられた樹脂溜まり
部とを有する熱可塑性樹脂のガス射出成形用金型であっ
て、前記ガスゲートと樹脂溜まり部との間にガス放出機
構を設けたことを特徴とする、ガス射出成形用金型。1. A resin mold comprising a cavity mold, a core mold, and a product cavity formed between the cavity mold and the core mold and filled with a molten resin. A gas injection molding die of a thermoplastic resin having a resin reservoir provided in the gas injection molding, wherein a gas discharge mechanism is provided between the gas gate and the resin reservoir. Mold.
填部であって前記製品キャビティ部の外側に設けられて
おり、且つ前記ガス放出機構が、該樹脂溜まり部と製品
キャビティ部との間に設けられていることを特徴とす
る、請求項1記載のガス射出成形用金型。2. The method according to claim 2, wherein the resin reservoir is a final filling portion of the molten resin and is provided outside the product cavity, and the gas discharge mechanism is provided between the resin reservoir and the product cavity. The mold for gas injection molding according to claim 1, wherein the metal mold is provided in a mold.
造方法であって、請求項1又は2記載のガス射出成形用
金型を用い、以下に示す(a)〜(c)の工程を含むガ
ス射出成形を行うことを特徴とする、熱可塑性樹脂成形
品の製造方法。 (a)樹脂ゲートから溶融樹脂を製品キャビティ部へ射
出充填する射出充填工程 (b)ガスゲートからガスを溶融樹脂内へ圧入するガス
圧入工程 (c)前記ガス圧入工程で圧入されたガスをガス放出機
構により放出するガス放出工程3. A method for producing a thermoplastic resin molded article having a hollow portion, wherein the steps (a) to (c) shown below are performed using the mold for gas injection molding according to claim 1 or 2. A method for producing a thermoplastic resin molded article, characterized by performing gas injection molding containing the same. (A) an injection filling step of injecting and filling a molten resin into a product cavity from a resin gate; (b) a gas injection step of injecting a gas from a gas gate into the molten resin; and (c) releasing the gas injected in the gas injection step. Gas release process released by mechanism
を、前記ガス射出成形用金型の樹脂溜まり部へ溶融樹脂
が完全に充填される前に行うことを特徴とする、請求項
3記載の熱可塑性樹脂成形品の製造方法。4. The gas discharging step according to claim 3, wherein the discharging of the gas is performed before the molten resin is completely filled in the resin reservoir of the gas injection molding die. A method for producing a thermoplastic resin molded product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13594898A JPH11314253A (en) | 1998-05-01 | 1998-05-01 | Gas injection mold of thermoplastic resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13594898A JPH11314253A (en) | 1998-05-01 | 1998-05-01 | Gas injection mold of thermoplastic resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11314253A true JPH11314253A (en) | 1999-11-16 |
Family
ID=15163594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13594898A Pending JPH11314253A (en) | 1998-05-01 | 1998-05-01 | Gas injection mold of thermoplastic resin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11314253A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002533560A (en) * | 1998-12-24 | 2002-10-08 | ズニクス・サーファス・ナノテクノロジース・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Super-loose surface |
-
1998
- 1998-05-01 JP JP13594898A patent/JPH11314253A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002533560A (en) * | 1998-12-24 | 2002-10-08 | ズニクス・サーファス・ナノテクノロジース・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Super-loose surface |
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