JPH11315436A - Polyester fine fiber yarn and method for producing the same - Google Patents
Polyester fine fiber yarn and method for producing the sameInfo
- Publication number
- JPH11315436A JPH11315436A JP12051998A JP12051998A JPH11315436A JP H11315436 A JPH11315436 A JP H11315436A JP 12051998 A JP12051998 A JP 12051998A JP 12051998 A JP12051998 A JP 12051998A JP H11315436 A JPH11315436 A JP H11315436A
- Authority
- JP
- Japan
- Prior art keywords
- yarn
- polyester
- fiber yarn
- thick
- dyed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
(57)【要約】
【課題】 生産に際して大掛かりな設備や煩雑な管理が
必要でないポリエステル太細繊維であって、しかも濃染
部と淡染部とのコントラストが大きなポリエステル太細
繊維糸、及び該ポリエステル太細繊維糸を容易に高生産
し得る方法を提供すること。
【解決手段】 全フィラメントのうちの80重量%以上
が細部をなしている淡染部と、同じく60重量%以上が
太部をなしている濃染部とからなり、太さ斑の変動係数
CVが1〜3%であり、沸水収縮率(BWS)が3%以
下のポリエステル太細繊維糸、及び流体処理による交絡
部を5〜20個/mの割合で有するポリエステル未延伸
糸に、加熱摩擦抵抗ピンによる加熱延伸処理と、これに
続く緩和熱処理とを施すポリエステル太細繊維糸の製造
方法。(57) [Problem] To provide a polyester fine fiber which does not require large-scale equipment and complicated management in production, and has a large contrast between a deeply dyed portion and a lightly dyed portion; To provide a method capable of easily and highly producing polyester thick fiber yarn. SOLUTION: 80% by weight or more of all the filaments are composed of a lightly dyed portion forming details, and 60% by weight or more of a deeply dyed portion forming a thick portion. Is between 1 and 3%, the polyester thin fiber yarn having a boiling water shrinkage (BWS) of 3% or less, and the polyester unstretched yarn having a entangled portion by fluid treatment at a rate of 5 to 20 / m. A method for producing a polyester thick fiber yarn which is subjected to a heat drawing treatment with a resistance pin and a relaxation heat treatment subsequent thereto.
Description
【0001】[0001]
【発明の属する技術分野】本発明は、衣料用途やインテ
リア用途等の布帛にしたときに、濃染部の中に淡染部が
カスリ調に存在する外観を呈する布帛になるポリエステ
ル太細繊維糸、及びその製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a polyester thick fiber yarn which, when made into a fabric for use in clothing or interior use, has a light-colored portion present in the deeply-colored portion in a lustrous appearance. And a method for producing the same.
【0002】[0002]
【従来の技術】繊維そのものの濃淡染色化手段として従
来から半延伸条件を採用してなる太細繊維糸があり、該
太細繊維糸による布帛には、太部と細部の染着性の差に
基づく濃淡の染色効果に起因する霜降り調の外観が得ら
れることが知られている。2. Description of the Related Art As a means for dyeing light and shade of a fiber itself, there is a thick and thin fiber yarn conventionally employing a semi-drawing condition. It is known that a marbling-like appearance resulting from a tint effect based on color can be obtained.
【0003】しかしながら上記の半延伸条件を採用して
なる太細繊維糸は、これを布帛にしたときに微細な分散
状態を示してしまい、しかも細部に十分な配向を伴った
延伸領域が形成されないために、該細部に延伸糸と同等
の淡色染色性が具備されておらず、十分なコントラスト
をなす濃淡の染色性が十分に表現され得ない。[0003] However, a thick and thin fiber yarn obtained by employing the above-mentioned semi-drawing condition shows a finely dispersed state when it is made into a fabric, and a drawn region with a sufficient orientation is not formed in detail. For this reason, the detail does not have the same light-colored dyeing property as that of the drawn yarn, and the light-and-shade dyeing property that provides a sufficient contrast cannot be sufficiently expressed.
【0004】十分なコントラストを有する濃淡の染色効
果を得るためには、マルチフィラメント糸を形成する各
フィラメントの太部及び細部が、それぞれ濃染部と淡染
部とに集中して存在することが必要であり、例えば特開
昭59−137523号公報には、間欠的に水付与した
未延伸糸を熱処理した後、これを仮撚加工することによ
って太細繊維糸を得る方法が記載されている。又、特開
平7−229030号公報には、太細繊維糸を形成して
いる太部の比率が細部の比率よりも大きくなっている太
細繊維糸の濃染布帛にすることにより、濃染部の中に淡
染部がカスリ調に存在する外観を呈する布帛になること
が開示されている。[0004] In order to obtain a light and shade dyeing effect having a sufficient contrast, the thick and fine parts of each filament forming the multifilament yarn may be concentrated in the deep and lightly dyed parts, respectively. For example, JP-A-59-137523 describes a method for obtaining a thick fiber yarn by heat-treating an undrawn yarn intermittently applied with water and then false-twisting the undrawn yarn. . Japanese Patent Application Laid-Open No. 7-229030 discloses a deep-dyeing fabric of a fine fiber yarn in which the ratio of the thick portion forming the fine fiber yarn is larger than the ratio of the details. It is disclosed that a lightly dyed portion is present in the portion as a cloth having an appearance in which the portion is lightly applied.
【0005】しかしながら前者の特開昭59−1375
23号公報によるものは、糸条に対して水をランダムに
間欠付与するための煩雑な管理が必要であり、しかも斑
付与の周期が時間に支配されるため生産性を高めること
が困難であり、かつ仮撚加工を必須にしているために工
程が煩雑である。又、後者の特開平7−229030号
公報によるものは、延伸領域にある被延伸糸の引取速度
をランダムに変化させることによって斑を付与するもの
であるために、前者と同様に煩雑な管理が必要であり、
しかも生産性が低い。[0005] However, the former Japanese Patent Application Laid-Open No. 59-1375.
According to No. 23, complicated management for randomly and intermittently applying water to the yarn is required, and it is difficult to increase the productivity because the period of the mottling is controlled by time. In addition, the process is complicated because false twisting is indispensable. In the latter Japanese Patent Application Laid-Open No. Hei 7-229030, since unevenness is imparted by randomly changing the take-up speed of the yarn to be drawn in the drawing area, complicated management is required similarly to the former. Required,
Moreover, productivity is low.
【0006】[0006]
【発明が解決しようとする課題】これに対して本発明者
は、太細を有するポリエステル繊維糸について鋭意検討
した結果、濃染部と淡染部との周期がランダムであり、
かつ濃染部と淡染部とのコントラストが大きなポリエス
テル太細繊維糸であって、該太細繊維糸による濃染布帛
にすることにより濃染部の中に淡染部がカスリ調に存在
する外観を呈する布帛になるポリエステル太細繊維糸、
及び該ポリエステル太細繊維糸を高生産し得る製造方法
を見い出した。On the other hand, the present inventors have made intensive studies on thick and thin polyester fiber yarns. As a result, the cycle between the deeply dyed portion and the lightly dyed portion is random,
In addition, the contrast between the deep-colored portion and the light-colored portion is a polyester thick fiber yarn having a large contrast, and the light-colored portion is present in the deep-colored portion in a crisp tone by forming a deep-colored fabric using the thick fiber yarn. Polyester thin fiber yarn to be a fabric showing appearance,
And a production method capable of producing the polyester thick and thin fiber yarns with high productivity.
【0007】従って本発明の目的は、大掛かりな設備や
煩雑な管理を必要とすることなく生産し得るポリエステ
ル太細繊維糸であって、濃染部と淡染部との周期がラン
ダムであり、かつ濃染部と淡染部とのコントラストが大
きなポリエステル太細繊維糸、及び該ポリエステル太細
繊維糸を容易、かつ確実に高生産し得る方法を提供する
ことにある。Accordingly, an object of the present invention is to provide a polyester thick and thin fiber yarn which can be produced without requiring large-scale equipment and complicated management, wherein the cycle between the deeply dyed portion and the lightly dyed portion is random, Another object of the present invention is to provide a polyester thick and thin fiber yarn having a large contrast between a deeply dyed portion and a lightly dyed portion, and a method for easily and reliably producing the polyester thick and thin fiber yarn at a high rate.
【0008】[0008]
【課題を解決するための手段】上記の目的は、以下に記
載する本発明のポリエステル太細繊維糸及びその製造方
法によって解決される。すなわち本発明のポリエステル
太細繊維糸は、長さ方向に太細を有するマルチフィラメ
ント糸からなるポリエステル太細繊維糸であって、該ポ
リエステル太細繊維糸は、全フィラメントのうちの80
重量%以上が細部をなしている淡染部と、同じく全フィ
ラメントのうちの60重量%以上が太部をなしている濃
染部とからなり、しかも前記淡染部の長さが10〜40
mmであり、かつ淡染部の比率が濃染部の比率よりも小
さく、更に太さ斑の変動係数CVが1〜3%であり、沸
水収縮率(BWS)が3%以下であるポリエステル太細
繊維糸からなる。SUMMARY OF THE INVENTION The above-mentioned object is achieved by the following polyester thick fiber yarn of the present invention and a method for producing the same. That is, the polyester thick fiber yarn of the present invention is a polyester thick fiber yarn composed of a multifilament yarn having a thickness in the length direction, and the polyester thick fiber yarn comprises 80% of the total filaments.
More than 60% by weight of all filaments consist of a thick dyed part which is thick, and the length of the light dyed part is 10 to 40%.
mm, the ratio of lightly dyed portions is smaller than the ratio of darkly dyed portions, the coefficient of variation CV of thickness unevenness is 1 to 3%, and the boiling water shrinkage (BWS) is 3% or less. Consists of fine fiber yarn.
【0009】又本発明のポリエステル太細繊維糸の製造
方法は、上記の構成によるポリエステル太細繊維糸の製
造方法であって、30×10-3以上の複屈折率(△n)
を有し、かつ流体処理により付与された交絡部を5〜2
0個/mの割合で具備するポリエステル未延伸糸に、下
記の〜式を満足する条件下での加熱摩擦抵抗ピンに
よる加熱延伸処理と、該加熱延伸処理に続く緩和熱処理
とを連続して施すことによりポリエステル太細繊維糸を
得る方法である。The method for producing a polyester thick fiber yarn of the present invention is a method for producing a polyester thick fiber yarn having the above constitution, and has a birefringence (Δn) of 30 × 10 -3 or more.
And the entangled portion given by the fluid treatment is 5-2
The polyester unstretched yarn provided at a rate of 0 yarns / m is continuously subjected to a heat stretching treatment with a heat friction resistance pin under conditions satisfying the following formulas and a relaxation heat treatment following the heating stretching treatment. This is a method for obtaining a polyester fine fiber yarn.
【0010】 MDR×0.45≦DR≦MDR×0.50 1≦RR≦10 Tg≦TP≦Tc Tc≦THP≦Tm [但し、上記の〜式において、DRは延伸倍率、M
DRは未延伸糸の最大延伸倍率、RRは緩和熱処理領域
での緩和率(%)、TPは延伸領域における摩擦抵抗ピ
ンの温度(℃)、THPは緩和熱処温度(℃)、Tgは
未延伸糸のガラス転移温度(℃)、Tcは未延伸糸の結
晶化温度(℃)、Tmは未延伸糸の融点(℃)を表わ
す。]MDR × 0.45 ≦ DR ≦ MDR × 0.50 1 ≦ RR ≦ 10 Tg ≦ TP ≦ Tc Tc ≦ THP ≦ Tm [where, in the above formulas, DR is a stretching ratio, M
DR is the maximum draw ratio of the undrawn yarn, RR is the relaxation rate (%) in the relaxation heat treatment region, TP is the temperature (° C.) of the frictional resistance pin in the draw region, THP is the relaxation heat treatment temperature (° C.), and Tg is not. The glass transition temperature (° C.) of the drawn yarn, Tc represents the crystallization temperature (° C.) of the undrawn yarn, and Tm represents the melting point (° C.) of the undrawn yarn. ]
【0011】[0011]
【発明の実施の形態】本発明のポリエステル太細繊維
糸、つまりマルチフィラメント糸を形成している全フィ
ラメントのうちの80重量%以上が細部をなしている淡
染部と、同じく全フィラメントのうちの60重量%以上
が太部をなしている濃染部とからなり、しかも前記淡染
部の長さが10〜40mmであり、かつ淡染部の比率が
濃染部の比率よりも小さく、更に太さ斑の変動係数CV
が1〜3%であり、沸水収縮率(BWS)が3%以下で
あるポリエステル太細繊維糸において、該ポリエステル
太細繊維糸の各フィラメントを形成するポリエステル
は、エチレンテレフタレートやブチレンテレフタレート
を主たる繰り返し単位とするポリエステルであり、具体
的にはポリエチレンテレフタレート、ポリブチレンテレ
フタレート、5モル%未満の共重合成分を共重合させた
共重合ポリエステル、少量のブレンド成分を含有するポ
リエステル混合物等であり、特に好ましくはポリエチレ
ンテレフタレートである。BEST MODE FOR CARRYING OUT THE INVENTION The polyester thick and thin fiber yarn of the present invention, that is, a lightly dyed portion in which at least 80% by weight of all the filaments forming the multifilament yarn form details, 60% by weight or more of the thick-colored portion is a thick portion, and the light-colored portion is 10 to 40 mm in length, and the ratio of the light-colored portion is smaller than the ratio of the dark-colored portion, Furthermore, the coefficient of variation CV of thickness unevenness
Is 1 to 3%, and the polyester forming each filament of the polyester thin fiber yarn having a boiling water shrinkage (BWS) of 3% or less is mainly composed of ethylene terephthalate or butylene terephthalate. Polyester as a unit, specifically, polyethylene terephthalate, polybutylene terephthalate, a copolymerized polyester obtained by copolymerizing less than 5 mol% of a copolymer component, a polyester mixture containing a small amount of a blend component, and the like, and particularly preferred. Is polyethylene terephthalate.
【0012】これらの各フィラメントの断面形状は、丸
断面、或いは三角、多葉、扁平等の異型断面のいずれで
あってもよく、特に限定されるものではない。The cross-sectional shape of each of these filaments may be any of a round cross-section or an irregular cross-section such as triangular, multi-lobed, or flat, and is not particularly limited.
【0013】本発明のポリエステル太細繊維糸をなすマ
ルチフィラメント糸は、上記の通り、長さ方向に淡染部
と濃染部とが交互に繰り返して形成されており、しかも
上記淡染部は全フィラメントのうちの80重量%以上が
淡染色性を示す細部で形成されており、又濃染部は全フ
ィラメントのうちの60重量%以上が濃染色性を示す太
部で形成されている。As described above, the multifilament yarn forming the polyester thick fiber yarn of the present invention is formed by alternately repeating lightly dyed portions and deeply dyed portions in the length direction. 80% by weight or more of all the filaments are formed with details showing light dyeing, and the deeply dyed portion is formed with 60% by weight or more of all filaments with a thick part showing deep dyeing.
【0014】ここで、淡染部が該淡染部を形成する全フ
ィラメントの80重量%未満が淡染色性を示す細部から
なるものになったり、或いは濃染部が該濃染部を形成す
る全フィラメントの60重量%未満が濃染色性を示す太
部からなるものになったりすると、濃染部と淡染部との
コントラストが小さくなり、濃染部の中に淡染部によっ
て形成されるカスリ調の外観が不鮮明なものになる。In this case, the lightly dyed portion is made up of details showing a light dyeing property in an amount of less than 80% by weight of the total filaments forming the lightly dyed portion, or the deeply dyed portion forms the deeply dyed portion. When less than 60% by weight of all the filaments are composed of thick portions exhibiting deep dyeing properties, the contrast between the deeply dyed portions and the lightly dyed portions is reduced, and the lightly dyed portions are formed in the deeply dyed portions. The hazy appearance becomes unclear.
【0015】又上記の淡染部の長さは10mm〜40m
mであることが必要である。淡染部の長さが10mm未
満になると、該淡染部の存在が不鮮明になり、又淡染部
の長さが40mmを越えるようになると、淡染部が長く
なり過ぎてカスリ調の外観を呈しなくなる。The length of the lightly dyed portion is 10 mm to 40 m.
m. When the length of the lightly-colored portion is less than 10 mm, the existence of the lightly-colored portion becomes unclear, and when the length of the lightly-colored portion exceeds 40 mm, the lightly-colored portion becomes too long, resulting in a lustrous appearance. No longer appear.
【0016】更に良好なカスリ調の外観が得られるよう
にするために、本発明のポリエステル太細繊維糸は、淡
染部の比率が濃染部の比率よりも小さいことを必要とす
る。淡染部と濃染部との比率は、後述する糸斑測定にお
ける中心値からの偏りをヒストグラム化し、中心値より
も繊度の太い部分を濃染部とすると共に、中心値よりも
繊度の細い部分を淡染部とし、このヒストグラムの面積
比が淡染部と濃染部との比率である。[0016] In order to obtain an even better brushed appearance, the polyester thick fiber yarn of the present invention requires that the proportion of lightly dyed parts be smaller than the proportion of deeply dyed parts. The ratio between the lightly-stained portion and the deeply-stained portion is represented by a histogram of the deviation from the center value in the yarn spot measurement described below, and a portion having a fineness greater than the center value is defined as a densely-stained portion, and a portion having a smaller fineness than the center value. Is a lightly-stained portion, and the area ratio of the histogram is the ratio between the lightly-stained portion and the deeply-stained portion.
【0017】更に又本発明のポリエステル太細繊維糸
は、該繊維糸の沸水収縮率(BWS)が3%以下である
ことが必要である。通常のポリエステル太細繊維糸は、
太部の熱収縮率が高く、太細繊維糸が沸水収縮する際に
濃染色性を示す太部が収縮してより太くなり、そして短
くなる。このために濃染部のカスリ調が目立つ外観にな
ってしまう。これに対して、太部の沸水収縮率を低くし
ておく、つまり濃染部の収縮を抑えておけば、濃染部の
中に淡染部がカスリ調に存在する外観が得られるポリエ
ステル太細繊維糸になる。Further, the polyester thick fiber yarn of the present invention needs to have a boiling water shrinkage (BWS) of 3% or less. Normal polyester fine fiber yarn,
The heat shrinkage of the thick portion is high, and when the thick fiber yarn shrinks with boiling water, the thick portion showing deep dyeability shrinks to become thicker and shorter. For this reason, the appearance of the brilliant color of the deeply dyed portion becomes conspicuous. On the other hand, if the boiled water shrinkage of the thick portion is kept low, that is, if the shrinkage of the deeply dyed portion is suppressed, the polyester dye can be obtained in which the lightly dyed portion is present in the deeply dyed portion in a crisp tone. It becomes a fine fiber yarn.
【0018】なお、沸水収縮率(BWS)が3%を越え
ると、濃染部が高収縮部になっているために、該濃染部
がコブ状に強調されてしまい、濃染部の中に淡染部がカ
スリ調に存在する外観を呈するという本発明の目的とは
その濃淡の外観が逆転したカスリ調になってしまう。When the boiling water shrinkage (BWS) exceeds 3%, the deeply dyed portion becomes a high shrinkage portion, so that the deeply dyed portion is emphasized in a bumpy manner, and In contrast to the object of the present invention in which the lightly-colored portion presents an appearance in which the light-colored portion is present in a lustrous manner, the appearance of the light and shade is reversed to a lustrous appearance.
【0019】更に本発明のポリエステル太細繊維糸は、
該繊維糸の太さ斑の変動係数CVが1〜3%であること
が必要である。この変動係数CVが1%未満になると、
濃淡染色による霜降り効果はあるものの、太部が分散さ
れて明瞭な濃淡表現が得られなくなる。又該繊維糸の太
さ斑の変動係数CVが3%を越えると、不自然な斑が生
成することになり、高品質のものにならない。Further, the polyester fine fiber yarn of the present invention is
It is necessary that the coefficient of variation CV of the thickness unevenness of the fiber yarn is 1 to 3%. When the coefficient of variation CV is less than 1%,
Although there is a marbling effect due to the light and shade dyeing, the thick part is dispersed and a clear light and shade expression cannot be obtained. On the other hand, if the variation coefficient CV of the thickness unevenness of the fiber yarn exceeds 3%, unnatural unevenness is generated, and high quality is not obtained.
【0020】上記の太さ斑の変動係数CVは、計測器工
業株式会社製のイーブネステスターKET−80Cを用
いて、糸速8m/分、チャートスピード50cm/分の
条件下で、ウースターノルマル値を測定して得られた数
値であり、平均値からの偏りの大きさを示す指標となる
ものである。The above coefficient of variation CV of the thickness unevenness was measured using an EVENESTESTER KET-80C manufactured by Keisoku Kogyo Co., Ltd. under the conditions of a yarn speed of 8 m / min and a chart speed of 50 cm / min. And is an index indicating the magnitude of deviation from the average value.
【0021】上記構成からなる本発明のポリエステル太
細繊維糸は、更にこれを加工して紡績糸や仮撚加工糸等
の任意の糸条形態にもなし得る。The polyester thick and thin fiber yarn of the present invention having the above-mentioned structure can be further processed into an arbitrary yarn form such as a spun yarn or a false twisted yarn.
【0022】又、本発明のポリエステル太細繊維糸に対
するアルカリ減量処理の後処理を行なう場合には、糸条
形態のままで該処理を行なうことも可能であるが、製織
又は製編によって織物や編物の形態にした後に、通常の
ポリエステル繊維製の布帛になされているアルカリ減量
処理を施すことが好ましい。When the polyester thin fiber yarn of the present invention is subjected to the post-treatment of the alkali weight reduction treatment, the treatment can be carried out in the form of a thread. After the knitted fabric is formed, it is preferable to perform an alkali weight reduction treatment performed on an ordinary polyester fiber fabric.
【0023】本発明のポリエステル太細繊維糸の製造方
法は、上記構成を具備するポリエステル太細繊維糸の製
造方法であって、30×10-3以上の複屈折率(△n)
を有し、かつ流体処理により付与された交絡部を5〜2
0個/mの割合で具備するポリエステル未延伸糸に、下
記の〜式を満足する条件下での加熱摩擦抵抗ピンに
よる加熱延伸処理と、該熱延伸処理に続く緩和熱処理と
を連続して施すことにより、ポリエステル太細繊維糸を
得るものである。The method for producing a polyester fine fiber yarn according to the present invention is a method for producing a polyester thick fiber yarn having the above-mentioned structure, and has a birefringence (Δn) of 30 × 10 −3 or more.
And the entangled portion given by the fluid treatment is 5-2
The polyester unstretched yarn provided at a rate of 0 yarns / m is continuously subjected to a heat drawing treatment with a heat friction resistance pin under conditions satisfying the following formulas and a relaxation heat treatment following the heat drawing treatment. Thereby, a polyester thick fiber yarn is obtained.
【0024】 MDR×0.45≦DR≦MDR×0.50 1≦RR≦10 Tg≦TP≦Tc Tc≦THP≦Tm [但し、上記の〜式において、DRは延伸倍率、M
DRは未延伸糸の最大延伸倍率、RRは緩和熱処理領域
での緩和率(%)、TPは延伸領域における摩擦抵抗ピ
ンの温度(℃)、THPは緩和熱処温度(℃)、Tgは
未延伸糸のガラス転移温度(℃)、Tcは未延伸糸の結
晶化温度(℃)、Tmは未延伸糸の融点(℃)を表わ
す。]MDR × 0.45 ≦ DR ≦ MDR × 0.50 1 ≦ RR ≦ 10 Tg ≦ TP ≦ Tc Tc ≦ THP ≦ Tm [where, in the above formulas, DR is a draw ratio, M
DR is the maximum draw ratio of the undrawn yarn, RR is the relaxation rate (%) in the relaxation heat treatment region, TP is the temperature (° C.) of the frictional resistance pin in the draw region, THP is the relaxation heat treatment temperature (° C.), and Tg is not. The glass transition temperature (° C.) of the drawn yarn, Tc represents the crystallization temperature (° C.) of the undrawn yarn, and Tm represents the melting point (° C.) of the undrawn yarn. ]
【0025】上記の条件による加熱摩擦抵抗ピンによる
加熱延伸処理と、それに続く緩和熱処理とを施すとき
に、被処理糸として複屈折率(△n)が30×10-3未
満の未延伸糸を使用すると、太部の沸水収縮率が低いも
のを得るのが困難になる。又太部の沸水収縮率を低下さ
せる目的でもって緩和熱処理温度を高温に設定すると、
太部が熱脆化して該部の繊維強度が低下するため、実用
に耐えられない繊維糸になる。When a heat drawing process using a heat friction resistance pin under the above conditions and a subsequent relaxation heat treatment are performed, an undrawn yarn having a birefringence (Δn) of less than 30 × 10 −3 is used as a yarn to be processed. If used, it becomes difficult to obtain a thick part having a low boiling water shrinkage. When the relaxation heat treatment temperature is set to a high temperature for the purpose of reducing the boiling water shrinkage of the thick part,
Since the thick portion is thermally embrittled and the fiber strength of the portion is reduced, the fiber yarn becomes unpractical.
【0026】上記の加熱摩擦抵抗ピンによる加熱延伸処
理を行なう際の延伸領域での延伸倍率(DR)を、未延
伸糸の最大延伸倍率(MDR)のO.50倍よりも高く
設定すると、淡染部の比率が濃染部の比率よりも大きく
なり、目的とする濃染部の中に淡染部がカスリ調に存在
する外観が得られなくなる。又、この延伸倍率(DR)
を、淡染部の比率が濃染部の比率よりも小さくなるよう
に設定した上で、未延伸糸をそのまま供給して加熱延伸
処理と緩和熱処理とを施しても、目的とする濃染部と淡
染部とのコントラストの大きな太細繊維糸にはならな
い。The draw ratio (DR) in the drawing region when performing the heat drawing treatment with the above-mentioned heat friction resistance pin is set to the maximum draw ratio (MDR) of the undrawn yarn. If it is set to be higher than 50 times, the ratio of the lightly dyed portion becomes larger than the ratio of the deeply dyed portion, and it becomes impossible to obtain an appearance in which the lightly dyed portion is present in the intended deeply dyed portion in a crisp tone. Also, this draw ratio (DR)
After setting the ratio of the lightly dyed portion to be smaller than the ratio of the deeply dyed portion, even if the undrawn yarn is supplied as it is and subjected to the heat drawing treatment and the relaxation heat treatment, the intended darkly dyed portion is obtained. It does not become a thick and thin fiber yarn with a large contrast between the fiber and the lightly dyed part.
【0027】しかしながら、上記の加熱延伸処理と緩和
熱処理とを施す被処理糸としての未延伸糸に、予めエア
ー等の流体処理による交絡部を形成しておくことによ
り、加熱擦過抵抗体を介して斑延伸するときに発生する
延伸ネックの生成を制御することができ、これによって
延伸部である細部の発現頻度及び長さを制御し、目的と
する濃染部と淡染部とのコントラストの大きな太細繊維
糸を得ることができるが、これによっても延伸倍率を未
延伸糸の最大延伸倍率(MDR)の0.45倍よりも低
く設定すると、目的とする濃染部と淡染部とのコントラ
ストの大きな太細繊維糸にはならない。However, by forming a entangled portion by a fluid treatment such as air in advance on an undrawn yarn as a yarn to be subjected to the above-mentioned heat drawing treatment and relaxation heat treatment, the heat rubbing resistance can be obtained. It is possible to control the generation of a stretch neck which occurs when spot stretching is performed, thereby controlling the frequency and length of details of the stretched portion, and providing a large contrast between the intended deeply dyed portion and the lightly dyed portion. A thick and thin fiber yarn can be obtained. However, if the draw ratio is set to be lower than 0.45 times the maximum draw ratio (MDR) of the undrawn yarn, the desired thick dyeing part and light dyeing part can be obtained. It does not become a thick fiber yarn with high contrast.
【0028】加熱延伸処理とそれに続く緩和熱処理を施
すための未延伸糸に付与する交絡部の数が1m当たり2
0個を越えると、延伸部からなる細部と未延伸部からな
る太部の発生頻度が多くなるために、染色後の外観が賑
やかになってしまし、目的とする濃染部の中に淡染部が
カスリ調に存在する外観のものにならない。又交絡部の
数が1m当たり5個未満になると、大部分が選択的な延
伸を施された部分にならないために、全体的に同じ太さ
の繊維糸になってしまい、同様に目的とする濃染部の中
に淡染部がカスリ調に存在する外観のものにはならな
い。The number of entangled portions to be applied to the undrawn yarn for performing the heat drawing treatment and the subsequent relaxation heat treatment is 2 / m.
If it exceeds 0, the appearance after dyeing becomes lively due to the increased frequency of the details consisting of the stretched part and the thick part consisting of the unstretched part. The dyed part does not have a hazy appearance. If the number of entangled portions is less than 5 per m, most of the entangled portions do not become selectively stretched portions, so that fiber yarns having the same thickness as a whole are obtained. The appearance is such that the lightly dyed portion is present in the deeply dyed portion in a lustrous manner.
【0029】交絡部の間隔は、ROTHSCHILD MESSINSTRUM
ENTE社製 自動ヤーンエンタングルメントテスター (Ne
edle Pull Tester R-2040)を用いて、下記の式で示すト
リップレベルテンションの条件で測定した数値である。 トリップレベルテンション=(D×0.2 )+D/F+振
動幅 [但し、式中Dは糸束のデニール、Fは糸束を形成する
フィラメント数、振動幅はD×0.02である。]The interval of the confounding part is ROTHSCHILD MESSINSTRUM
ENTE automatic yarn entanglement tester (Ne
This is a value measured using the edle Pull Tester R-2040) under the trip level tension conditions shown in the following equation. Trip level tension = (D × 0.2) + D / F + vibration width [where D is the denier of the yarn bundle, F is the number of filaments forming the yarn bundle, and the vibration width is D × 0.02. ]
【0030】次に、本発明のポリエステル太細繊維糸の
製造方法工程を、図面に基づいて説明する。図1は、加
熱延伸処理とそれに続く緩和熱処理に付すための未延伸
糸、つまり30×10-3以上の複屈折率(△n)を有
し、かつ流体処理により付与された交絡部を5〜20個
/mの割合で具備するポリエステル高配向未延伸糸を得
る紡糸工程の糸道を示す概略図である。Next, the steps of the method for producing a polyester fine fiber yarn of the present invention will be described with reference to the drawings. FIG. 1 shows an undrawn yarn to be subjected to a heat drawing treatment and a subsequent relaxation heat treatment, that is, an entangled portion having a birefringence (Δn) of 30 × 10 −3 or more and imparted by a fluid treatment. It is the schematic which shows the yarn path | route of the spinning process of obtaining the polyester highly oriented undrawn yarn provided at the rate of -20 / m.
【0031】上記の図1において、紡糸ノズル1から紡
出した溶融紡出糸条2を冷却装置3からの冷風によって
冷却固化した後、該糸条2に給油装置4によって油剤を
付与し、次いで第1引き取りロール5と第2引き取りロ
ール6とからなる1対の引き取りロール間にて、一定張
力の下に、インターレース等のエアー交絡装置からなる
交絡部付与装置7によって所定の水準の交絡を付与する
ことにより、30×10-3以上の複屈折率(△n)を有
し、かつ流体処理により付与された交絡部を5〜20個
/mの割合で具備するポリエステル高配向未延伸糸8に
した後に、これを巻き取り機9によって巻き取る。In FIG. 1, after the melt spun yarn 2 spun from the spinning nozzle 1 is cooled and solidified by the cool air from the cooling device 3, an oil agent is applied to the yarn 2 by an oil supply device 4, A predetermined level of entanglement is applied between a pair of take-up rolls composed of a first take-up roll 5 and a second take-up roll 6 by a entanglement imparting device 7 composed of an air entanglement device such as an interlace under a constant tension. By doing so, a polyester highly oriented undrawn yarn 8 having a birefringence (Δn) of 30 × 10 −3 or more and having entangled portions imparted by fluid treatment at a rate of 5 to 20 pieces / m 8 Then, it is wound by a winder 9.
【0032】次に、図2は上記のポリエステル高配向未
延伸糸に、加熱摩擦抵抗ピンによる加熱延伸処理と該加
熱延伸処理に続く緩和熱処理とを連続して施すことによ
って、目的のポリエステル太細繊維糸を得るときの糸道
を示す概略図である。Next, FIG. 2 shows that the above-described highly oriented polyester unoriented yarn is continuously subjected to a heat drawing treatment using a heat friction resistance pin and a relaxation heat treatment subsequent to the heat drawing treatment, so that the desired polyester thin film is obtained. It is the schematic which shows the yarn path | route at the time of obtaining a fiber yarn.
【0033】上記の図2において、給糸ロール10に供
給した上記のポリエステル高配向未延伸糸8を、給糸ロ
ール10と延伸ロール11との間に設置してある加熱摩
擦抵抗ピン12に1回旋回させつつ、該ポリエステル高
配向未延伸糸8に斑延伸を施す。In FIG. 2 described above, the above-described polyester highly oriented undrawn yarn 8 supplied to the yarn supply roll 10 is applied to a heating friction resistance pin 12 provided between the yarn supply roll 10 and the drawing roll 11 by one. While being swirled twice, the polyester highly oriented undrawn yarn 8 is subjected to spot drawing.
【0034】次いで、この斑延伸を施した後のポリエス
テル繊維糸13に緩和熱処理を施して目的のポリエステ
ル太細繊維糸14にし、続いて該ポリエステル太細繊維
糸14を巻き取りロール15を経由して巻き取り装置1
6によって巻き取る。なお、上記の図示実施例において
は、延伸ロール11と巻き取りロール15との間に熱板
17を設置して、この熱板17によって緩和熱処理を施
している。Next, the polyester fiber yarn 13 after the spot stretching is subjected to a relaxation heat treatment to obtain a desired polyester fine fiber yarn 14, and then the polyester thick fiber yarn 14 is passed through a winding roll 15. Winding device 1
Wind up with 6. In the illustrated embodiment, a hot plate 17 is provided between the stretching roll 11 and the take-up roll 15, and the hot plate 17 performs a relaxation heat treatment.
【0035】本発明のポリエステル太細繊維糸の製造方
法工程の実施例をより具体的に説明する。先ず、30×
10-3以上の複屈折率(△n)を有し、かつ流体処理に
より付与された交絡部を5〜20個/mの割合で具備す
るポリエステル高配向未延伸糸を、表面が梨地面になっ
ている摩擦抵抗加熱ピン12によって屈曲走行させ、常
温の延伸ロール11によって熱延伸する。Examples of the method for producing a polyester thick fiber yarn of the present invention will be described more specifically. First, 30x
A polyester highly oriented undrawn yarn having a birefringence (Δn) of 10 −3 or more and having entangled portions imparted by a fluid treatment at a rate of 5 to 20 pieces / m, a surface of It is bent and run by the frictional resistance heating pin 12 and is hot stretched by the stretching roll 11 at room temperature.
【0036】上記の摩擦抵抗加熱ピン12は、その表面
がJIS B0601で表示される表面粗度2〜30R
z、好ましくは2〜15Rzの梨地面になっていること
が好ましく、このような梨地面をなす加熱ピン12を用
いることにより、該加熱ピン12により屈曲走行する各
フィラメントにピン表面の微細凸部での摩擦抵抗による
ネッキング延伸を惹起させる。これに対して表面が鏡面
をなす加熱ピンを使用すると、上記の現象を生じさせ難
い。The surface of the frictional resistance heating pin 12 has a surface roughness of 2 to 30 R as indicated by JIS B0601.
z, preferably a matte surface of 2 to 15 Rz. By using the heating pin 12 forming such a matte surface, each filament that bends and travels by the heating pin 12 has a fine projection on the pin surface. Causes necking stretching due to frictional resistance. On the other hand, when a heating pin having a mirror-finished surface is used, the above-described phenomenon is unlikely to occur.
【0037】摩擦抵抗加熱ピン12の表面の梨地面は、
耐摩耗性の点からセラミックスによって形成されている
のが好ましいが、クロムメッキ等のコーティング層から
なるものであってもよい。又摩擦抵抗加熱ピンは、繊維
糸が屈曲して接触する面が上記の梨地面になっていれば
よく、例えばバー状、ロール状、リング状等の任意の形
態のものを使用し得る。The matte surface on the surface of the frictional resistance heating pin 12 is:
It is preferably formed of ceramics from the viewpoint of abrasion resistance, but may be formed of a coating layer such as chrome plating. The frictional resistance heating pin only needs to be such that the surface where the fiber yarn is bent and contacted is the above-mentioned matte surface, and for example, any shape such as a bar shape, a roll shape, and a ring shape can be used.
【0038】摩擦抵抗加熱ピン12の温度(TP)は、
該温度が高温になるほど高配向未延伸糸の延伸が容易に
なるが、ネッキングが生じ難くなる。又該摩擦抵抗加熱
ピン12の温度(TP)が低いほど延伸そのものが困難
になる。これらのことから、摩擦抵抗加熱ピン12の温
度(TP)は、前述の式の範囲内にすることが必要で
あり、特に摩擦抵抗加熱ピン12の表面温度を50〜1
20℃にすることが好ましい。The temperature (TP) of the frictional resistance heating pin 12 is
The higher the temperature, the easier the stretching of the highly oriented undrawn yarn, but the less likely it is for necking to occur. Also, the lower the temperature (TP) of the frictional resistance heating pin 12 is, the more difficult it is to perform stretching itself. From these facts, the temperature (TP) of the frictional resistance heating pin 12 needs to be within the range of the above-described equation, and particularly, the surface temperature of the frictional resistance heating pin 12 is set to 50 to 1
Preferably it is 20 ° C.
【0039】又、熱延伸工程での延伸倍率(DR)を、
上記したように未延伸糸の最大延伸倍率(MDR)の
O.50倍よりも高く設定すると、淡染部の比率が濃染
部の比率よりも大きくなり、目的とする濃染部の中に淡
染部がカスリ調に存在する外観が得られなくなり、又未
延伸糸の最大延伸倍率(MDR)の0.45倍よりも低
く設定すると、目的とする濃染部と淡染部とのコントラ
ストの大きな太細繊維糸にはならない。Further, the draw ratio (DR) in the hot stretching step is as follows:
As described above, the maximum draw ratio (MDR) of the undrawn yarn is O.D. If the setting is higher than 50 times, the ratio of the lightly dyed portion becomes larger than the ratio of the deeply dyed portion, and the appearance in which the lightly dyed portion is present in the intended deeply dyed portion cannot be obtained. If the maximum draw ratio (MDR) of the drawn yarn is set to be lower than 0.45 times, the intended thick and thin fiber yarn having a large contrast between the deeply dyed portion and the lightly dyed portion will not be obtained.
【0040】つまり、熱延伸工程での延伸倍率(DR)
を未延伸糸の最大延伸倍率(MDR)の0.50倍より
も高く設定すると、ネッキングが生じ難くなって均一な
延伸になってしまうことがあり、又未延伸糸の最大延伸
倍率(MDR)の0.45倍よりも低く設定すると、ネ
ッキング延伸が困難になり易くなる。これによって熱延
伸工程での延伸倍率(DR)は、MDR×0.45≦D
R≦MDR×0.50の範囲内にすることが必要であ
る。具体的な延伸倍率(DR)としては1.1〜1.4
であることが好ましい。That is, the draw ratio (DR) in the hot drawing process
Is set higher than 0.50 times the maximum draw ratio (MDR) of the undrawn yarn, necking is unlikely to occur, and uniform drawing may be performed. In addition, the maximum draw ratio (MDR) of the undrawn yarn When it is set to be lower than 0.45 times the necking stretching becomes difficult. Thereby, the draw ratio (DR) in the hot drawing step is MDR × 0.45 ≦ D
It is necessary to set the range of R ≦ MDR × 0.50. Specific stretching ratios (DR) are 1.1 to 1.4.
It is preferred that
【0041】熱延伸後の緩和熱処理工程は、沸水収縮率
(BWS)が3%以下のポリエステル太細繊維糸にする
ために必要であり、該緩和熱処理工程での温度(TH
P)を前述の式の範囲内にし、又該緩和熱処理工程で
の緩和率(%)RRを前述の式にすることが必要であ
って、緩和熱処理工程での温度(THP)は特に170
〜220℃の範囲が効果的である。The relaxation heat treatment step after the heat drawing is necessary to obtain a polyester thin fiber yarn having a boiling water shrinkage (BWS) of 3% or less, and the temperature (TH) in the relaxation heat treatment step is required.
P) is required to fall within the range of the above equation, and the relaxation rate (%) RR in the relaxation heat treatment step is required to be the above equation. The temperature (THP) in the relaxation heat treatment step is particularly 170
The range of -220 ° C is effective.
【0042】このような条件での緩和熱処理により、延
伸されたフィラメントの繊維構造を熱固定し、染色等の
後加工工程での熱収縮を低減させることができる。緩和
熱処理工程は、緩和状態で前記温度の雰囲気中を通過さ
せて行なってもよいが、第2図による図示実施例のよう
に、熱板17等の加熱体に接触走行させて行ってもよ
い。後者の加熱体接触方式によれば、効率的に熱処理を
行なうことができる。又ロールガイド等によって加熱体
との接触長を長く取るようにすれば、熱効率をさらに向
上させることができる。By the relaxation heat treatment under such conditions, the fiber structure of the drawn filament can be heat-set, and the heat shrinkage in a post-processing step such as dyeing can be reduced. The relaxation heat treatment step may be performed in a relaxed state by passing through an atmosphere at the above temperature, or may be performed by contacting and traveling with a heating body such as a hot plate 17 as in the embodiment shown in FIG. . According to the latter heating element contact method, heat treatment can be performed efficiently. Further, if the contact length with the heating element is increased by a roll guide or the like, the thermal efficiency can be further improved.
【0043】[0043]
【実施例】以下、本発明のポリエステル太細繊維糸及び
その製造方法の具体的な構成を、製造実施例に基づいて
説明する。 実施例1 図1に示すポリエステル高配向未延伸糸を得る紡糸工程
に従って、固有粘度0.67、融点256℃のポリエチ
レンテレフタレ−トを用いて、ホ−ル数72の丸孔ノズ
ルにより、紡糸温度290℃、引取速度2750m/分
で溶融紡糸し、これを1対の引取りロールを介して巻き
取る前に、これらの1対の引取りロール同士の間に設置
してあるインターレース交絡装置により、エアー圧力
3.0kg/cm2 、オーバーフィード率1%の条件下
での交絡処理を行なうことにより、133dtex、最
大延伸倍率(MDR)2.4、偏光顕微鏡で測定した複
屈折率(△n)0.032、未延伸糸1m当たりの交絡
数12個のポリエステル高配向未延伸糸を得た。EXAMPLES The concrete structure of the polyester thick and thin fiber yarn of the present invention and the method for producing the same will now be described based on production examples. Example 1 According to the spinning process for obtaining a highly oriented undrawn polyester yarn shown in FIG. 1, spinning was carried out using polyethylene terephthalate having an intrinsic viscosity of 0.67 and a melting point of 256 ° C. with a round hole nozzle having 72 holes. Before spinning at a temperature of 290 ° C. at a take-up speed of 2750 m / min and winding it through a pair of take-up rolls, an interlacing entanglement device installed between the pair of take-up rolls is used. Entanglement under the conditions of an air pressure of 3.0 kg / cm 2 and an overfeed rate of 1%, 133 dtex, a maximum draw ratio (MDR) of 2.4, and a birefringence (Δn) measured with a polarizing microscope. ) 0.032, a polyester highly oriented undrawn yarn having 12 entanglements per 1 m of the undrawn yarn.
【0044】次いで、このポリエステル高配向未延伸糸
を、図2に示す加熱摩擦抵抗ピンによる加熱延伸処理と
該加熱延伸処理に続く緩和熱処理工程とに従って、下記
の条件による加熱延伸処理と緩和熱処理とに付すことに
より、ポリエステル太細繊維糸を得た。得られたポリエ
ステル太細繊維糸の物性を、表1に示す。Next, this polyester highly oriented undrawn yarn is subjected to a heat drawing treatment and a relaxation heat treatment under the following conditions according to a heat drawing treatment using a heat friction resistance pin shown in FIG. 2 and a relaxation heat treatment step following the heat drawing treatment. To obtain a polyester fine fiber yarn. Table 1 shows the physical properties of the obtained polyester thick fiber yarn.
【0045】延伸速度=200m/分 延伸倍率(DR)=1.122(MDR×0.46) 摩擦抵抗ピンの温度(TP)=60℃ 熱処理領域での緩和率(RR)=1.7% 緩和熱処理の熱板の温度(THP)=185℃ 摩擦抵抗ピンと引き取りロールとの間の距離=30cmStretching speed = 200 m / min. Stretching ratio (DR) = 1.122 (MDR × 0.46) Temperature of frictional resistance pin (TP) = 60 ° C. Relaxation rate (RR) in heat treatment region = 1.7% Temperature of hot plate for relaxation heat treatment (THP) = 185 ° C. Distance between friction resistance pin and take-off roll = 30 cm
【0046】実施例2〜実施例4 インターレースのエアー圧、及び延伸条件を、表1の所
定欄に示すように一部変更する以外は、実施例1と同様
の条件で紡糸し、更に加熱延伸及び緩和熱処理を行なう
ことにより、ポリエステル太細繊維糸を得た。得られた
ポリエステル太細繊維糸の物性を、表1に示す。Examples 2 to 4 Spinning was carried out under the same conditions as in Example 1 except that the interlace air pressure and the stretching conditions were partially changed as shown in the predetermined columns of Table 1, and then the stretching was carried out by heating. By performing a relaxation heat treatment, a polyester thick fiber yarn was obtained. Table 1 shows the physical properties of the obtained polyester thick fiber yarn.
【0047】[0047]
【表1】 [Table 1]
【0048】比較例1〜比較例3 表2の所定欄に示すように、インターレースのエアー圧
を変更する以外は実施例1と同様の条件で紡糸した未延
伸糸を、実施例1と同一の延伸条件で延伸し、引き続き
実施例1と同一の緩和熱処理を行なうことにより、比較
のためのポリエステル太細繊維糸を得た。得られたポリ
エステル太細繊維糸の物性を、表2に示す。Comparative Examples 1 to 3 As shown in a predetermined column of Table 2, an undrawn yarn spun under the same conditions as in Example 1 except that the interlace air pressure was changed, was used in the same manner as in Example 1. The film was stretched under the stretching conditions and subsequently subjected to the same relaxation heat treatment as in Example 1 to obtain a polyester thick fiber yarn for comparison. Table 2 shows the physical properties of the obtained polyester fine fiber yarn.
【0049】[0049]
【表2】 [Table 2]
【0050】比較例4〜比較例5 実施例1で得られた未延伸糸を、表3の所定欄に示した
延伸条件で延伸し、引き続き実施例1と同一の緩和熱処
理を行なうことにより、比較のためのポリエステル太細
繊維糸を得た。得られたポリエステル太細繊維糸の物性
を、表3に示す。Comparative Examples 4 to 5 The undrawn yarn obtained in Example 1 was drawn under the drawing conditions shown in the predetermined column of Table 3 and subsequently subjected to the same relaxation heat treatment as in Example 1. A polyester thick fiber yarn for comparison was obtained. Table 3 shows the physical properties of the obtained polyester thick fiber yarn.
【0051】比較例6 実施例1で得られた未延伸糸を、表3の所定欄に示した
延伸条件で延伸し、続いて非緩和熱処理に付すことによ
り、ポリエステル太細繊維糸を得た。得られたポリエス
テル太細繊維糸の物性を、表3に示す。Comparative Example 6 The undrawn yarn obtained in Example 1 was drawn under the drawing conditions shown in the predetermined column of Table 3 and then subjected to a non-relaxation heat treatment to obtain a polyester thick fiber yarn. . Table 3 shows the physical properties of the obtained polyester thick fiber yarn.
【0052】[0052]
【表3】 [Table 3]
【0053】実験 経糸に通常の延伸を施した伸度30%、55.6デシテ
ックス、フィラメント数18のポリエステルマルチフィ
ラメント糸を使用し、緯糸に上記の実施例及び比較例で
得られた各ポリエステル太細繊維糸を使用し、経糸密度
75本×/吋、緯糸密度67本×/吋の平織物を、WJ
Lで作成した後、該平織物を下記の条件で染色し、染色
後の布帛の濃淡斑の外観を目視によって判定した。Experiment Using a polyester multifilament yarn having an elongation of 30%, 55.6 dtex and 18 filaments obtained by subjecting a warp to normal stretching, the polyester yarn obtained in the above Examples and Comparative Examples was used as a weft. Using a fine fiber yarn, a plain woven fabric having a warp density of 75 yarns / inch and a weft density of 67 yarns / inch is manufactured by WJ
L, the plain woven fabric was dyed under the following conditions, and the appearance of light and dark spots of the dyed fabric was visually determined.
【0054】浴比=1:100 染料=チバ・ガイギー製「テラシール・ネービーブル
ー」 染料濃度=1.0wt% 染色温度=98℃ 染色時間=60分Bath ratio = 1: 100 Dye = "Terasil Navy Blue" manufactured by Ciba Geigy Dye concentration = 1.0 wt% Dyeing temperature = 98 ° C Dyeing time = 60 minutes
【0055】判定結果を、表1〜表3に付記した。な
お、染色後の布帛の濃淡斑の評価を、下記の6段階に区
分して表示した。 ◎・・・・・・・・非常に良好 ○・・・・・・・・良好 ○〜△・・・・概ね良好(濃淡斑の頻度がやや高い) △・・・・・・・・許容範囲である(濃淡のコントラストがやや弱い) ×・・・・・・・・不良 ××・・・・・・非常に不良The results of the judgment are shown in Tables 1 to 3. In addition, the evaluation of shading of the cloth after dyeing was classified into the following six grades and displayed. ◎ ・ ・ ・ ・ ・ ・ ・ ・ very good ○ ・ ・ ・ ・ ・ ・ ・ ・ ・ Good ○ 〜 △ ・ ・ ・ ・ Generally good (frequency of shading is slightly high) △ ・ ・ ・ ・ ・ ・ ・ Permissible It is in the range (the contrast of light and shade is slightly weak).
【0056】[0056]
【発明の効果】本発明のポリエステル太細繊維糸によれ
ば、濃染部の中に淡染部がカスリ調に存在する外観を呈
する布帛が得られ、又本発明のポリエステル太細繊維糸
は沸水収縮率が低く抑えられているので、該ポリエステ
ル太細繊維糸による布帛にソフトな風合が備わる。According to the polyester fine fiber yarn of the present invention, a fabric having an appearance in which lightly dyed portions are present in the deeply dyed portion in a lustrous manner can be obtained. Since the shrinkage of boiling water is kept low, the fabric made of the polyester thick fiber yarn has a soft feel.
【0057】又本発明のポリエステル太細繊維糸を高収
縮繊維との混繊糸にすると、特徴のある外観効果とソフ
トで膨らみ感のある織編物からなる布帛になる。When the polyester thick and thin fiber yarn of the present invention is made into a mixed yarn with a high shrinkage fiber, the fabric is made of a woven or knitted fabric having a characteristic appearance effect and a soft and swollen feeling.
【0058】更に本発明のポリエステル太細繊維糸の製
造方法によれば、上記の特性を具備するポリエステル太
細繊維糸を容易、かつ確実に高生産することができる。Further, according to the method for producing a polyester thick fiber yarn of the present invention, it is possible to easily and surely produce a polyester thick fiber yarn having the above-mentioned characteristics at a high rate.
【図1】未延伸糸を得る紡糸工程の糸道を示す概略図で
ある。FIG. 1 is a schematic view showing a yarn path in a spinning step of obtaining an undrawn yarn.
【図2】未延伸糸に加熱延伸処理と該加熱延伸処理に続
く緩和熱処理とを施すときの糸道を示す概略図である。FIG. 2 is a schematic view showing a yarn path when an undrawn yarn is subjected to a heat drawing treatment and a relaxation heat treatment following the heat drawing treatment.
1・・・・紡糸ノズル 2・・・・膨出糸条 3・・・・冷却装置 4・・・・給油装置 5・・・・第1引き取りロール 6・・・・第2引き取りロール 7・・・・交絡部付与装置 8・・・・交絡部を付与されたポリエステル高配向未延伸糸 9・・・・巻き取り機 10・・・・給糸ローラー 11・・・・延伸ローラ 12・・・・加熱摩擦抵抗ピン 13・・・・斑延伸を施した後のポリエステル繊維糸 14・・・・ポリエステル太細繊維糸 15・・・・巻き取りロール 16・・・・巻き取り装置 1 ··· Spinning nozzle 2 ··· Swelling yarn 3 ··· Cooling device 4 ··· Oil supply device 5 ··· First take-up roll 6 ··· Second take-up roll 7 ··· Entangled portion imparting device 8 ··· Highly oriented polyester unstretched yarn provided with an entangled portion 9 ··· Winding machine 10 ··· Yarn feed roller 11 ··· Stretching roller 12 ··· Heat friction resistance pin 13 ··· Polyester fiber yarn after spot stretching 14 ··· Polyester thick fiber fiber 15 ··· Winding roll 16 ··· Winding device
Claims (2)
ント糸からなるポリエステル太細繊維糸であって、該ポ
リエステル太細繊維糸は、全フィラメントのうちの80
重量%以上が細部をなしている淡染部と、同じく全フィ
ラメントのうちの60重量%以上が太部をなしている濃
染部とからなり、しかも前記淡染部の長さが10〜40
mmであり、かつ淡染部の比率が濃染部の比率よりも小
さく、更に太さ斑の変動係数CVが1〜3%であり、沸
水収縮率(BWS)が3%以下であることを特徴とする
ポリエステル太細繊維糸。1. A polyester thin fiber yarn comprising a multifilament yarn having a thickness in the length direction, wherein the polyester thick fiber yarn comprises 80% of all filaments.
More than 60% by weight of all filaments consist of a thick dyed part which is thick, and the length of the light dyed part is 10 to 40%.
mm, the ratio of lightly dyed portions is smaller than the ratio of darkly dyed portions, the variation coefficient CV of unevenness in thickness is 1 to 3%, and the boiling water shrinkage (BWS) is 3% or less. Characterized polyester thin fiber yarn.
有し、かつ流体処理により付与された交絡部を5〜20
個/mの割合で具備するポリエステル未延伸糸に、下記
の〜式を満足する条件下での加熱摩擦抵抗ピンによ
る加熱延伸処理と、該加熱延伸処理に続く緩和熱処理と
を連続して施すことを特徴とする請求項1に記載のポリ
エステル太細繊維糸の製造方法。 MDR×0.45≦DR≦MDR×0.50 1≦RR≦10 Tg≦TP≦Tc Tc≦THP≦Tm [但し、上記の〜式において、DRは延伸倍率、M
DRは未延伸糸の最大延伸倍率、RRは緩和熱処理領域
での緩和率(%)、TPは延伸領域における摩擦抵抗ピ
ンの温度(℃)、THPは緩和熱処温度(℃)、Tgは
未延伸糸のガラス転移温度(℃)、Tcは未延伸糸の結
晶化温度(℃)、Tmは未延伸糸の融点(℃)を表わ
す。]2. A entangled portion having a birefringence (Δn) of 30 × 10 −3 or more and having an entangled portion provided by a fluid treatment, has
The polyester unstretched yarn provided at a rate of 個 / m is continuously subjected to a heat stretching treatment with a heat friction resistance pin under conditions satisfying the following formulas and a relaxation heat treatment following the heat stretching treatment. The method for producing a polyester thick and thin fiber yarn according to claim 1, characterized in that: MDR × 0.45 ≦ DR ≦ MDR × 0.50 1 ≦ RR ≦ 10 Tg ≦ TP ≦ Tc Tc ≦ THP ≦ Tm [However, in the above formulas, DR is a draw ratio, M
DR is the maximum draw ratio of the undrawn yarn, RR is the relaxation rate (%) in the relaxation heat treatment region, TP is the temperature (° C.) of the frictional resistance pin in the draw region, THP is the relaxation heat treatment temperature (° C.), and Tg is not. The glass transition temperature (° C.) of the drawn yarn, Tc represents the crystallization temperature (° C.) of the undrawn yarn, and Tm represents the melting point (° C.) of the undrawn yarn. ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12051998A JPH11315436A (en) | 1998-04-30 | 1998-04-30 | Polyester fine fiber yarn and method for producing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12051998A JPH11315436A (en) | 1998-04-30 | 1998-04-30 | Polyester fine fiber yarn and method for producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH11315436A true JPH11315436A (en) | 1999-11-16 |
Family
ID=14788264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12051998A Pending JPH11315436A (en) | 1998-04-30 | 1998-04-30 | Polyester fine fiber yarn and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11315436A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2023038411A (en) * | 2021-09-07 | 2023-03-17 | 東レ株式会社 | Moire combined filament yarn and knitted or woven fabric using the same |
| JP2023048194A (en) * | 2021-09-28 | 2023-04-07 | 東レ株式会社 | Composite false twist mixed yarn and woven or knitted fabric |
-
1998
- 1998-04-30 JP JP12051998A patent/JPH11315436A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2023038411A (en) * | 2021-09-07 | 2023-03-17 | 東レ株式会社 | Moire combined filament yarn and knitted or woven fabric using the same |
| JP2023048194A (en) * | 2021-09-28 | 2023-04-07 | 東レ株式会社 | Composite false twist mixed yarn and woven or knitted fabric |
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