JPH1170335A - 有機錫スルホン酸塩触媒とその製法 - Google Patents

有機錫スルホン酸塩触媒とその製法

Info

Publication number: JPH1170335A
Authority: JP; Japan
Prior art keywords: formula; catalyst; composition; group; independently selected
Prior art date: 1997-07-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

JP10191463A

Other languages

English (en)

Japanese (ja)

Inventor

Sri Ram Seshadri

スリー・ラム・セイシャドリ

William D Honnick

ウィリアム・デイビッド・ホーニック

Melvin Hyman Gitlitz

メルビン・ハイマン・ギトリッツ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Arkema Inc

Original Assignee

Elf Atochem North America Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-07-09

Filing date

1998-07-07

Publication date

1999-03-16

1998-07-07 Application filed by Elf Atochem North America Inc filed Critical Elf Atochem North America Inc

1999-03-16 Publication of JPH1170335A publication Critical patent/JPH1170335A/ja

Status Abandoned legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 112
238000004519 manufacturing process Methods 0.000 title description 4
150000007524 organic acids Chemical class 0.000 claims abstract description 22
238000000034 method Methods 0.000 claims abstract description 15
125000000217 alkyl group Chemical group 0.000 claims abstract description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
125000003118 aryl group Chemical group 0.000 claims abstract description 13
230000003197 catalytic effect Effects 0.000 claims abstract description 10
125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 8
239000007864 aqueous solution Substances 0.000 claims abstract description 8
229910052736 halogen Inorganic materials 0.000 claims abstract description 7
150000002367 halogens Chemical class 0.000 claims abstract description 7
239000000203 mixture Substances 0.000 claims description 66
239000000376 reactant Substances 0.000 claims description 38
229920000642 polymer Polymers 0.000 claims description 22
150000001875 compounds Chemical class 0.000 claims description 19
239000007787 solid Substances 0.000 claims description 14
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 11
125000004432 carbon atom Chemical group C* 0.000 claims description 11
238000000576 coating method Methods 0.000 claims description 8
239000002798 polar solvent Substances 0.000 claims description 8
150000003839 salts Chemical class 0.000 claims description 8
239000002904 solvent Substances 0.000 claims description 8
229920000877 Melamine resin Polymers 0.000 claims description 7
229910052731 fluorine Inorganic materials 0.000 claims description 7
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 7
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 6
239000004814 polyurethane Substances 0.000 claims description 6
229920002635 polyurethane Polymers 0.000 claims description 6
229920003180 amino resin Polymers 0.000 claims description 5
239000011248 coating agent Substances 0.000 claims description 5
229910020366 ClO 4 Inorganic materials 0.000 claims description 4
239000008199 coating composition Substances 0.000 claims description 4
238000001035 drying Methods 0.000 claims description 4
235000005985 organic acids Nutrition 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
229910052794 bromium Inorganic materials 0.000 claims description 3
150000001721 carbon Chemical group 0.000 claims description 3
229910052801 chlorine Inorganic materials 0.000 claims description 3
150000002148 esters Chemical class 0.000 claims description 3
229910052740 iodine Inorganic materials 0.000 claims description 3
229910052725 zinc Inorganic materials 0.000 claims description 3
239000011701 zinc Substances 0.000 claims description 3
229920005573 silicon-containing polymer Polymers 0.000 claims 2
238000001816 cooling Methods 0.000 claims 1
238000006243 chemical reaction Methods 0.000 abstract description 41
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract description 13
238000005886 esterification reaction Methods 0.000 abstract description 11
238000006116 polymerization reaction Methods 0.000 abstract description 8
238000006482 condensation reaction Methods 0.000 abstract description 3
239000000243 solution Substances 0.000 abstract description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 1
125000004185 ester group Chemical group 0.000 abstract 1
XSXHWVKGUXMUQE-UHFFFAOYSA-N osmium dioxide Inorganic materials O=[Os]=O XSXHWVKGUXMUQE-UHFFFAOYSA-N 0.000 abstract 1
238000009472 formulation Methods 0.000 description 29
239000010410 layer Substances 0.000 description 22
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 16
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 16
238000004458 analytical method Methods 0.000 description 13
229910052718 tin Inorganic materials 0.000 description 13
239000012948 isocyanate Substances 0.000 description 11
150000002513 isocyanates Chemical class 0.000 description 11
230000015572 biosynthetic process Effects 0.000 description 10
238000005809 transesterification reaction Methods 0.000 description 10
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 9
239000000047 product Substances 0.000 description 8
239000002253 acid Substances 0.000 description 7
JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 7
239000012975 dibutyltin dilaurate Substances 0.000 description 7
229920005862 polyol Polymers 0.000 description 7
125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 7
238000003786 synthesis reaction Methods 0.000 description 7
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
230000009977 dual effect Effects 0.000 description 6
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 6
238000010992 reflux Methods 0.000 description 6
239000010703 silicon Substances 0.000 description 6
229910052710 silicon Inorganic materials 0.000 description 6
230000032050 esterification Effects 0.000 description 5
239000000178 monomer Substances 0.000 description 5
150000003077 polyols Chemical class 0.000 description 5
238000003756 stirring Methods 0.000 description 5
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 5
-1 NO 3 Inorganic materials 0.000 description 4
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
239000004202 carbamide Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000005755 formation reaction Methods 0.000 description 4
KJIFKLIQANRMOU-UHFFFAOYSA-N oxidanium;4-methylbenzenesulfonate Chemical compound O.CC1=CC=C(S(O)(=O)=O)C=C1 KJIFKLIQANRMOU-UHFFFAOYSA-N 0.000 description 4
238000012360 testing method Methods 0.000 description 4
VNTDZUDTQCZFKN-UHFFFAOYSA-L zinc 2,2-dimethyloctanoate Chemical compound [Zn++].CCCCCCC(C)(C)C([O-])=O.CCCCCCC(C)(C)C([O-])=O VNTDZUDTQCZFKN-UHFFFAOYSA-L 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
229920005830 Polyurethane Foam Polymers 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
238000004132 cross linking Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 3
239000000049 pigment Substances 0.000 description 3
229920000728 polyester Polymers 0.000 description 3
239000011527 polyurethane coating Substances 0.000 description 3
239000011496 polyurethane foam Substances 0.000 description 3
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
239000006260 foam Substances 0.000 description 2
230000036571 hydration Effects 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
150000007974 melamines Chemical class 0.000 description 2
239000012046 mixed solvent Substances 0.000 description 2
KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
XGJZQNMUVTZITK-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexamethoxy-1,3,5-triazine-2,4,6-triamine Chemical compound CON(OC)C1=NC(N(OC)OC)=NC(N(OC)OC)=N1 XGJZQNMUVTZITK-UHFFFAOYSA-N 0.000 description 1
GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
239000005046 Chlorosilane Substances 0.000 description 1
239000004971 Cross linker Substances 0.000 description 1
229920003270 Cymel® Polymers 0.000 description 1
241000255925 Diptera Species 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
AFVFQIVMOAPDHO-UHFFFAOYSA-M Methanesulfonate Chemical compound CS([O-])(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-M 0.000 description 1
KYIMHWNKQXQBDG-UHFFFAOYSA-N N=C=O.N=C=O.CCCCCC Chemical compound N=C=O.N=C=O.CCCCCC KYIMHWNKQXQBDG-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
240000007594 Oryza sativa Species 0.000 description 1
235000007164 Oryza sativa Nutrition 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
102000001708 Protein Isoforms Human genes 0.000 description 1
108010029485 Protein Isoforms Proteins 0.000 description 1
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
101150081243 STA1 gene Proteins 0.000 description 1
WFWLQNSHRPWKFK-UHFFFAOYSA-N Tegafur Chemical compound O=C1NC(=O)C(F)=CN1C1OCCC1 WFWLQNSHRPWKFK-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000003158 alcohol group Chemical group 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
238000013459 approach Methods 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
CWZPGMMKDANPKU-UHFFFAOYSA-L butyl-di(dodecanoyloxy)tin Chemical compound CCCC[Sn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O CWZPGMMKDANPKU-UHFFFAOYSA-L 0.000 description 1
150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
239000013626 chemical specie Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
239000011247 coating layer Substances 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000002917 insecticide Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000003607 modifier Substances 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000012074 organic phase Substances 0.000 description 1
150000002923 oximes Chemical class 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
239000005076 polymer ester Substances 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
239000012260 resinous material Substances 0.000 description 1
235000009566 rice Nutrition 0.000 description 1
125000005372 silanol group Chemical group 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
150000003606 tin compounds Chemical class 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
230000007704 transition Effects 0.000 description 1
150000003673 urethanes Chemical class 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
- C08G18/246—Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2224—Compounds having one or more tin-oxygen linkages
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/8077—Oximes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Polyurethanes Or Polyureas (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Paints Or Removers (AREA)

JP10191463A 1997-07-09 1998-07-07 有機錫スルホン酸塩触媒とその製法 Abandoned JPH1170335A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US5203197P	1997-07-09	1997-07-09
US60/052031		1997-07-09

Publications (1)

Publication Number	Publication Date
JPH1170335A true JPH1170335A (ja)	1999-03-16

Family

ID=21974980

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP10191463A Abandoned JPH1170335A (ja)	1997-07-09	1998-07-07	有機錫スルホン酸塩触媒とその製法

Country Status (18)

Country	Link
US (1)	US5981685A (de)
EP (1)	EP0890576B1 (de)
JP (1)	JPH1170335A (de)
KR (1)	KR19990013711A (de)
CN (1)	CN1657170A (de)
AR (1)	AR022999A1 (de)
AT (1)	ATE310741T1 (de)
AU (1)	AU746489B2 (de)
BR (1)	BR9802400A (de)
CA (1)	CA2238020A1 (de)
CO (2)	CO5040167A1 (de)
DE (1)	DE69832439T2 (de)
ES (1)	ES2252816T3 (de)
MY (1)	MY114952A (de)
SG (1)	SG65076A1 (de)
TR (1)	TR199801311A2 (de)
TW (1)	TW376394B (de)
ZA (1)	ZA985973B (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2245326C (en) *	1997-09-29	2005-04-05	Elf Atochem North America, Inc.	Heterogeneous organotin catalysts
US6187376B1 (en)	1998-10-01	2001-02-13	Basf Corporation	Method for improving the adhesion of a repair coating to a previously coated substrate
DE10141237A1 (de) *	2001-08-23	2003-03-13	Wacker Chemie Gmbh	Vernetzbare Massen auf der Basis von Organosiliciumverbingungen
DE10151477A1 (de) *	2001-10-18	2003-05-15	Wacker Chemie Gmbh	Vernetzbare Massen auf der Basis von Organosiliciumverbindungen
US20070138692A1 (en) *	2002-09-06	2007-06-21	Ford James D	Process for forming clear, wettable silicone hydrogel articles
WO2006007407A1 (en) *	2004-06-16	2006-01-19	E.I. Dupont De Nemours And Company	Air-activated organotin catalysts for polyurethane synthesis
US7919423B2 (en)	2005-06-16	2011-04-05	E. I. Du Pont De Nemours And Company	Air activated organotin catalysts for polyurethane synthesis
DE102008021980A1 (de)	2008-05-02	2009-11-05	Bayer Materialscience Ag	Neue Katalysatoren und deren Einsatz bei der Herstellung von Polyurethanen
EP2990381A1 (de) *	2014-08-29	2016-03-02	Covestro Deutschland AG	Verfahren zur Herstellung von Zinnverbindungen
KR101827596B1 (ko) *	2014-12-31	2018-02-09	롯데첨단소재(주)	주석 화합물, 이의 제조방법 및 이를 이용한 디알킬 카보네이트로부터 방향족 카보네이트를 제조하는　방법
WO2020211035A1 (en) *	2019-04-18	2020-10-22	Dow Global Technologies Llc	Adhesive composition

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5606103A (en) *	1993-09-03	1997-02-25	Cps Chemical Company, Inc.	Organotin catalyzed transesterification
AU1861095A (en) *	1994-03-03	1995-09-18	Nippon Paint Co., Ltd.	Coating composition, process for forming cured film and coated article
US5770672A (en) *	1997-04-03	1998-06-23	Elf Atochem North America, Inc.	Catalyst for low temperature cure of blocked isocyanates

1998
- 1998-06-09 US US09/093,930 patent/US5981685A/en not_active Expired - Fee Related
- 1998-06-23 SG SG1998001497A patent/SG65076A1/en unknown
- 1998-06-23 CA CA002238020A patent/CA2238020A1/en not_active Abandoned
- 1998-06-23 AU AU73104/98A patent/AU746489B2/en not_active Ceased
- 1998-06-24 TW TW087110169A patent/TW376394B/zh active
- 1998-06-26 EP EP98305074A patent/EP0890576B1/de not_active Expired - Lifetime
- 1998-06-26 AT AT98305074T patent/ATE310741T1/de not_active IP Right Cessation
- 1998-06-26 ES ES98305074T patent/ES2252816T3/es not_active Expired - Lifetime
- 1998-06-26 DE DE69832439T patent/DE69832439T2/de not_active Expired - Fee Related
- 1998-07-06 BR BR9802400A patent/BR9802400A/pt not_active IP Right Cessation
- 1998-07-07 ZA ZA9805973A patent/ZA985973B/xx unknown
- 1998-07-07 JP JP10191463A patent/JPH1170335A/ja not_active Abandoned
- 1998-07-08 MY MYPI98003113A patent/MY114952A/en unknown
- 1998-07-08 TR TR1998/01311A patent/TR199801311A2/xx unknown
- 1998-07-08 AR ARP980103324A patent/AR022999A1/es active IP Right Grant
- 1998-07-09 CN CN2004101022714A patent/CN1657170A/zh active Pending
- 1998-07-09 KR KR1019980027560A patent/KR19990013711A/ko not_active Abandoned
- 1998-10-01 CO CO98038744A patent/CO5040167A1/es unknown
- 1998-10-01 CO CO98038744D patent/CO5040168A1/es unknown

Also Published As

Publication number	Publication date
CN1657170A (zh)	2005-08-24
ZA985973B (en)	1999-08-03
AR022999A1 (es)	2002-09-04
TR199801311A3 (tr)	1999-01-18
CA2238020A1 (en)	1999-01-09
TR199801311A2 (xx)	1999-01-18
TW376394B (en)	1999-12-11
AU7310498A (en)	1999-01-21
SG65076A1 (en)	1999-05-25
EP0890576A3 (de)	2000-11-08
ES2252816T3 (es)	2006-05-16
US5981685A (en)	1999-11-09
EP0890576A2 (de)	1999-01-13
BR9802400A (pt)	1999-06-01
KR19990013711A (ko)	1999-02-25
AU746489B2 (en)	2002-05-02
MY114952A (en)	2003-02-28
ATE310741T1 (de)	2005-12-15
DE69832439T2 (de)	2006-07-13
EP0890576B1 (de)	2005-11-23
CO5040167A1 (es)	2001-05-29
CO5040168A1 (es)	2001-05-29
DE69832439D1 (de)	2005-12-29

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