JPS5459213A - Oxidative synthesis of ester compounds - Google Patents

Oxidative synthesis of ester compounds

Info

Publication number
JPS5459213A
JPS5459213A JP10832978A JP10832978A JPS5459213A JP S5459213 A JPS5459213 A JP S5459213A JP 10832978 A JP10832978 A JP 10832978A JP 10832978 A JP10832978 A JP 10832978A JP S5459213 A JPS5459213 A JP S5459213A
Authority
JP
Japan
Prior art keywords
formula
alcohol
compound
ester compounds
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10832978A
Other languages
Japanese (ja)
Other versions
JPS5628902B2 (en
Inventor
Masanao Matsui
Tomoya Ogawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RIKEN
Original Assignee
RIKEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RIKEN filed Critical RIKEN
Priority to JP10832978A priority Critical patent/JPS5459213A/en
Publication of JPS5459213A publication Critical patent/JPS5459213A/en
Publication of JPS5628902B2 publication Critical patent/JPS5628902B2/ja
Granted legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain ester compounds economically in two steps; i.e. the reaction of a primary (secondary) alcohol with bis (tri-n-lower alkyl Sn) oxide, followed by the oxidation with an oxidizer such as haloamides using an aldehyde.
CONSTITUTION: A saturated aliphatic primary alcohol of formula I (R1=saturated aliphatic primary alkyl) or a secondary alcohol of formula II (R=alicyclic alkyl, etc.) is made to react with a molar equivalent or a small excess of bes (tri-n-lower alkyl Sn) oxide in an aprotic solvent, e.g. benzene, carbon tetrachloride, etc., at 0W200°C to afford the corresponding alkoxy Sn alkoxylate. After or without isolation, the compound is subjected to the oxidation with a molar equevalent or a small excess of a haloamide oxidizer, e.g. N-bromoacetamide, in the presence of an aldehyde compound, e.g. formaldehyde, in a non-polar solvent at- 50W100°C to produce an ester compound of formula IV or formula V.
COPYRIGHT: (C)1979,JPO&Japio
JP10832978A 1978-09-04 1978-09-04 Oxidative synthesis of ester compounds Granted JPS5459213A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10832978A JPS5459213A (en) 1978-09-04 1978-09-04 Oxidative synthesis of ester compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10832978A JPS5459213A (en) 1978-09-04 1978-09-04 Oxidative synthesis of ester compounds

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP12802375A Division JPS5251309A (en) 1975-10-24 1975-10-24 Oxidative synthesis of aldehydes, ketones and esters

Publications (2)

Publication Number Publication Date
JPS5459213A true JPS5459213A (en) 1979-05-12
JPS5628902B2 JPS5628902B2 (en) 1981-07-04

Family

ID=14481930

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10832978A Granted JPS5459213A (en) 1978-09-04 1978-09-04 Oxidative synthesis of ester compounds

Country Status (1)

Country Link
JP (1) JPS5459213A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012020984A (en) * 2010-07-16 2012-02-02 Nippon Surfactant Kogyo Kk Ester derivative and cosmetic containing the ester derivative, external preparation, coating material and ink composition

Also Published As

Publication number Publication date
JPS5628902B2 (en) 1981-07-04

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