JPS5497592A - Improved zeolite adsorber and its manufacture and uses - Google Patents
Improved zeolite adsorber and its manufacture and usesInfo
- Publication number
- JPS5497592A JPS5497592A JP424478A JP424478A JPS5497592A JP S5497592 A JPS5497592 A JP S5497592A JP 424478 A JP424478 A JP 424478A JP 424478 A JP424478 A JP 424478A JP S5497592 A JPS5497592 A JP S5497592A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- zeolite
- treated
- type zeolite
- isomers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910021536 Zeolite Inorganic materials 0.000 title abstract 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 9
- 239000010457 zeolite Substances 0.000 title abstract 9
- 238000004519 manufacturing process Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 150000007522 mineralic acids Chemical class 0.000 abstract 3
- 150000007524 organic acids Chemical class 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052593 corundum Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- 239000012013 faujasite Substances 0.000 abstract 2
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
- -1 K-Ba Chemical class 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 238000010306 acid treatment Methods 0.000 abstract 1
- 230000004913 activation Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain denatured zeolite having greatly improved selective adsorbability for aromatic C8 hydrocarbons by treating faujasite type zeolite with an inorganic acid and/or an organic acid.
CONSTITUTION: A faujasite type zeolite, particularly Y-type zeolite of a SiO2/ Al2O3 molar ratio of 3 to 5, is brought into contact with an aqueous solution of an inorganic acid and/or an organic acid under the condition of pH 0.5 to 4.0 and 10 to 90°C. As the inorganic acid, hydrochloric acid may be cited, and also as the organic acid, acetic acid may be cited. The acid treatment increases the SiO2/ Al2O3 molar ratio of Y-type zeolite to 4.5 to 7.5. Then, the zeolite treated with the acid is substituted with combined ions, e.g., K-Ba, etc., to confer upon it a selective adsorbability for p-xylene suitable for the separation of isomers, and then the zeolite thus treated is treated by heating at more than 100°C, particularly at 300 to 600°C for activation. The zeolite is then used for the separation of isomers.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP424478A JPS5497592A (en) | 1978-01-20 | 1978-01-20 | Improved zeolite adsorber and its manufacture and uses |
| GB7901075A GB2013641B (en) | 1978-01-20 | 1979-01-11 | Zeolite adsorbent and method of preparing same |
| DE19792901081 DE2901081C2 (en) | 1978-01-20 | 1979-01-12 | Modified zeolite with a faujasite structure, process for its preparation and use |
| FR7901254A FR2415076A1 (en) | 1978-01-20 | 1979-01-18 | ZEOLITHE ADSORBANT AND ITS PREPARATION PROCESS |
| NL7900468A NL7900468A (en) | 1978-01-20 | 1979-01-19 | ZEOLIETADSORBENS AND THE METHOD FOR MANUFACTURE THEREOF. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP424478A JPS5497592A (en) | 1978-01-20 | 1978-01-20 | Improved zeolite adsorber and its manufacture and uses |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5497592A true JPS5497592A (en) | 1979-08-01 |
Family
ID=11579124
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP424478A Pending JPS5497592A (en) | 1978-01-20 | 1978-01-20 | Improved zeolite adsorber and its manufacture and uses |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5497592A (en) |
| DE (1) | DE2901081C2 (en) |
| FR (1) | FR2415076A1 (en) |
| GB (1) | GB2013641B (en) |
| NL (1) | NL7900468A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104628010A (en) * | 2013-11-08 | 2015-05-20 | 中国石油天然气股份有限公司 | Modification treatment method of Y-type zeolite |
| JP2021195300A (en) * | 2020-06-11 | 2021-12-27 | 東ソー株式会社 | Crystalline aluminosilicate and method of producing zeolite using the same |
| JP2023540227A (en) * | 2020-08-26 | 2023-09-22 | 中国石油化工股▲ふん▼有限公司 | Composite adsorbent and its application for separating ethylbenzene by adsorption distillation |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA805231B (en) * | 1980-05-19 | 1981-08-26 | Mobil Oil Corp | Low acidity alkali metal containing zeolites |
| DE3120891A1 (en) * | 1981-05-26 | 1982-12-23 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | METHOD FOR REMOVAL OR PARTIAL REMOVAL OF INTERESTING SUBSTANCES CONTAINED IN A FLOWING WATER, AND DEVICE FOR IMPLEMENTING THE METHOD |
| FR2540093B1 (en) * | 1983-02-02 | 1987-01-23 | Rhone Poulenc Spec Chim | PROCESS FOR THE PREPARATION OF AN ALKALINE SILICO-ALUMINATE FOR USE IN TOOTHPASTE COMPOSITIONS |
| SE8402393D0 (en) * | 1983-06-09 | 1984-05-03 | Sten Andersson | SET TO CLEAN AIR AND WATER FROM THE CALVET |
| DE69025088T2 (en) * | 1989-04-24 | 1996-06-13 | Kanebo Ltd | Stabilized, synthetic zeolite and process for its production |
| US5443812A (en) * | 1989-04-24 | 1995-08-22 | Kanebo Ltd. | Stabilized synthetic zeolite and a process for the preparation thereof |
| US5206195A (en) * | 1990-05-31 | 1993-04-27 | Kanebo Ltd. | Stablized synthetic zeolite and a process for the preparation thereof |
| US5200168A (en) * | 1992-01-31 | 1993-04-06 | Mobil Oil Corp. | Process for the dealumination of zeolite Beta |
| US5676914A (en) * | 1994-04-26 | 1997-10-14 | Competitive Technologies, Inc. | Method for the destruction of methylene iodide |
| DE102017207817A1 (en) * | 2017-05-09 | 2018-11-15 | Clariant International Ltd | Zeolite-containing adsorbent for the selective separation of isomers from aromatic hydrocarbon mixtures, its preparation and use |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5220455A (en) * | 1975-08-11 | 1977-02-16 | Sanyo Electric Co Ltd | Heating hot-water delivery device |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE644432A (en) * | 1964-02-27 | |||
| FR1427463A (en) * | 1964-03-23 | 1966-02-04 | Socony Mobil Oil Co | Process for preparing zeglitic-type materials with a high silica content |
| US3488146A (en) * | 1967-09-01 | 1970-01-06 | Mobil Oil Corp | Method for preparing crystalline aluminosilicates of improved stability |
| US3686343A (en) * | 1970-10-01 | 1972-08-22 | Exxon Research Engineering Co | Paraxylene recovery with zeolite adsorbent |
| JPS51106688A (en) * | 1975-03-17 | 1976-09-21 | Toray Industries | |
| DE2617571A1 (en) * | 1975-04-24 | 1976-11-11 | Grace W R & Co | PROCESS FOR MANUFACTURING ZEOLITHES WITH HIGH SILICON OXIDE-ALUMINUM OXIDE RATIO |
-
1978
- 1978-01-20 JP JP424478A patent/JPS5497592A/en active Pending
-
1979
- 1979-01-11 GB GB7901075A patent/GB2013641B/en not_active Expired
- 1979-01-12 DE DE19792901081 patent/DE2901081C2/en not_active Expired
- 1979-01-18 FR FR7901254A patent/FR2415076A1/en active Granted
- 1979-01-19 NL NL7900468A patent/NL7900468A/en not_active Application Discontinuation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5220455A (en) * | 1975-08-11 | 1977-02-16 | Sanyo Electric Co Ltd | Heating hot-water delivery device |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104628010A (en) * | 2013-11-08 | 2015-05-20 | 中国石油天然气股份有限公司 | Modification treatment method of Y-type zeolite |
| JP2021195300A (en) * | 2020-06-11 | 2021-12-27 | 東ソー株式会社 | Crystalline aluminosilicate and method of producing zeolite using the same |
| JP2023540227A (en) * | 2020-08-26 | 2023-09-22 | 中国石油化工股▲ふん▼有限公司 | Composite adsorbent and its application for separating ethylbenzene by adsorption distillation |
| US12441672B2 (en) | 2020-08-26 | 2025-10-14 | China Petroleum & Chemical Corporation | Composite adsorbent for separation of ethylbenzene by adsorption distillation and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2013641A (en) | 1979-08-15 |
| FR2415076A1 (en) | 1979-08-17 |
| NL7900468A (en) | 1979-07-24 |
| DE2901081C2 (en) | 1986-03-27 |
| FR2415076B1 (en) | 1983-04-08 |
| GB2013641B (en) | 1982-07-21 |
| DE2901081A1 (en) | 1979-08-02 |
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