JPS55155001A - Polymerization of vinyl monomer - Google Patents
Polymerization of vinyl monomerInfo
- Publication number
- JPS55155001A JPS55155001A JP6235079A JP6235079A JPS55155001A JP S55155001 A JPS55155001 A JP S55155001A JP 6235079 A JP6235079 A JP 6235079A JP 6235079 A JP6235079 A JP 6235079A JP S55155001 A JPS55155001 A JP S55155001A
- Authority
- JP
- Japan
- Prior art keywords
- water
- polymerization
- vinyl monomer
- amine compound
- polymerizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000178 monomer Substances 0.000 title abstract 4
- 229920002554 vinyl polymer Polymers 0.000 title abstract 4
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title abstract 3
- -1 amine compound Chemical class 0.000 abstract 3
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 239000012736 aqueous medium Substances 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 125000002091 cationic group Chemical group 0.000 abstract 2
- SMBYUOXUISCLCF-UHFFFAOYSA-N n-ethyl-n-methylpropan-1-amine Chemical compound CCCN(C)CC SMBYUOXUISCLCF-UHFFFAOYSA-N 0.000 abstract 1
- VPBGHVQBNSIGHJ-UHFFFAOYSA-N n-ethylethanamine;n-methylbutan-1-amine Chemical compound CCNCC.CCCCNC VPBGHVQBNSIGHJ-UHFFFAOYSA-N 0.000 abstract 1
- UVBMZKBIZUWTLV-UHFFFAOYSA-N n-methyl-n-propylpropan-1-amine Chemical compound CCCN(C)CCC UVBMZKBIZUWTLV-UHFFFAOYSA-N 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/004—Scale prevention in a polymerisation reactor or its auxiliary parts by a prior coating on the reactor walls
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Abstract
PURPOSE: To prevent sticking of scales, in the polymerization of a vinyl monomer in an aqueous medium, by polymerizing the vinyl polymer in a polymerizer, which is coated with an aqueous solution containing a water-soluble anionic dye, a water- soluble cationic dye and an amine compound.
CONSTITUTION: In the polymerization of a vinyl monomer in an aqueous medium, the inside wall of the polymerizer and the other parts, with which the monomer comes into contact, are previously coated with an aqueous solution containing (A) a water-soluble anionic dye, (B) a water-soluble cationic dye and (C) a 1W6C secondary amine compound, and dried. The secondary or tertiary amine compound is diethylamine methylbutylamine, methylethylpropylamine, methyldipropylamine, etc.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6235079A JPS55155001A (en) | 1979-05-21 | 1979-05-21 | Polymerization of vinyl monomer |
| FR8011206A FR2457168B1 (en) | 1979-05-21 | 1980-05-20 | PROCESS FOR PREVENTING THE FORMATION OF DEPOSITS DURING POLYMERIZATION IN AQUEOUS MEDIA OF ETHYLENICALLY UNSATURATED MONOMERS |
| GB8016611A GB2049472B (en) | 1979-05-21 | 1980-05-20 | Method for preventing polymer scale deposition in the polymerization of an ethylenically unsaturated monomer in an aqueous medium |
| DE19803019389 DE3019389A1 (en) | 1979-05-21 | 1980-05-21 | METHOD FOR SUPPRESSING THE FORMATION OF POLYMER CRUST |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6235079A JPS55155001A (en) | 1979-05-21 | 1979-05-21 | Polymerization of vinyl monomer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS55155001A true JPS55155001A (en) | 1980-12-03 |
Family
ID=13197577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6235079A Pending JPS55155001A (en) | 1979-05-21 | 1979-05-21 | Polymerization of vinyl monomer |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS55155001A (en) |
| DE (1) | DE3019389A1 (en) |
| FR (1) | FR2457168B1 (en) |
| GB (1) | GB2049472B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5978210A (en) * | 1982-10-27 | 1984-05-07 | Toyo Soda Mfg Co Ltd | Nonaqueous polymerization of vinyl chloride |
| JPH02138303A (en) * | 1988-08-19 | 1990-05-28 | Shin Etsu Chem Co Ltd | Method for preventing polymer scale adhesion |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58210902A (en) * | 1982-05-31 | 1983-12-08 | Shin Etsu Chem Co Ltd | Polymerization of vinyl monomer |
| PH26338A (en) * | 1988-08-10 | 1992-04-29 | Shinetsu Chemical Co | Method of preventing polymer scale formation |
| MX170464B (en) * | 1988-08-19 | 1993-08-23 | Shinetsu Chemical Co | METHOD TO PREVENT THE FORMATION OF FLAKES |
| JP2678702B2 (en) * | 1992-02-20 | 1997-11-17 | 信越化学工業株式会社 | Polymer scale adhesion inhibitor and method for producing polymer using the same |
| US5654198A (en) * | 1995-06-05 | 1997-08-05 | National Starch And Chemical Investment Holding Corporation | Detectable water-treatment polymers and methods for monitoring the concentration thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5223187A (en) * | 1975-08-14 | 1977-02-21 | Shin Etsu Chem Co Ltd | Process for polymerizing vinyl monomers |
| JPS5316788A (en) * | 1976-07-30 | 1978-02-16 | Shin Etsu Chem Co Ltd | Preparation of polymer |
| JPS548690A (en) * | 1977-06-20 | 1979-01-23 | Goodrich Co B F | Method of preventing polymer from adhering on inner surface of polymerization reactor |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE91560C (en) * | 1970-05-07 | |||
| DK303077A (en) * | 1976-08-16 | 1978-02-17 | Goodrich Co B F | POLYMERIZATION REACTION CONTAINER AND PROCEDURE FOR PRACTICALLY ELIMINATING THE CONSTRUCTION OF POLYMERS ON ITS INTERIOR SURFACES |
| US4105840A (en) * | 1977-06-20 | 1978-08-08 | The B. F. Goodrich Company | Internally coated reaction vessel for use in olefinic polymerization |
-
1979
- 1979-05-21 JP JP6235079A patent/JPS55155001A/en active Pending
-
1980
- 1980-05-20 GB GB8016611A patent/GB2049472B/en not_active Expired
- 1980-05-20 FR FR8011206A patent/FR2457168B1/en not_active Expired
- 1980-05-21 DE DE19803019389 patent/DE3019389A1/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5223187A (en) * | 1975-08-14 | 1977-02-21 | Shin Etsu Chem Co Ltd | Process for polymerizing vinyl monomers |
| JPS5316788A (en) * | 1976-07-30 | 1978-02-16 | Shin Etsu Chem Co Ltd | Preparation of polymer |
| JPS548690A (en) * | 1977-06-20 | 1979-01-23 | Goodrich Co B F | Method of preventing polymer from adhering on inner surface of polymerization reactor |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5978210A (en) * | 1982-10-27 | 1984-05-07 | Toyo Soda Mfg Co Ltd | Nonaqueous polymerization of vinyl chloride |
| JPH02138303A (en) * | 1988-08-19 | 1990-05-28 | Shin Etsu Chem Co Ltd | Method for preventing polymer scale adhesion |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2457168A1 (en) | 1980-12-19 |
| GB2049472B (en) | 1983-04-27 |
| GB2049472A (en) | 1980-12-31 |
| FR2457168B1 (en) | 1986-05-16 |
| DE3019389A1 (en) | 1980-12-04 |
| DE3019389C2 (en) | 1988-11-17 |
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