JPS5517332A - Geometrical isomers of 5, 5, 8, 8-tetramethyl-or 2, 5, 5, 8, 8- pentamethyl-decalin,their preparation and use - Google Patents
Geometrical isomers of 5, 5, 8, 8-tetramethyl-or 2, 5, 5, 8, 8- pentamethyl-decalin,their preparation and useInfo
- Publication number
- JPS5517332A JPS5517332A JP8994278A JP8994278A JPS5517332A JP S5517332 A JPS5517332 A JP S5517332A JP 8994278 A JP8994278 A JP 8994278A JP 8994278 A JP8994278 A JP 8994278A JP S5517332 A JPS5517332 A JP S5517332A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- decalin
- tetramethyl
- pentamethyl
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- FKLJPTJMIBLJAV-UHFFFAOYSA-N Compound IV Chemical compound O1N=C(C)C=C1CCCCCCCOC1=CC=C(C=2OCCN=2)C=C1 FKLJPTJMIBLJAV-UHFFFAOYSA-N 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000002304 perfume Substances 0.000 abstract 2
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 abstract 1
- BWPHCHITVFALRH-UHFFFAOYSA-N 2,5,5,8,8-pentamethyl-1,2,3,4,4a,6,7,8a-octahydronaphthalene Chemical compound CC1CC2C(CCC(C2CC1)(C)C)(C)C BWPHCHITVFALRH-UHFFFAOYSA-N 0.000 abstract 1
- GEQXWZHSHLJVDZ-UHFFFAOYSA-N 5,5,8,8-tetramethyl-1,2,3,4,4a,6,7,8a-octahydronaphthalen-2-ol Chemical compound C1C(O)CCC2C(C)(C)CCC(C)(C)C21 GEQXWZHSHLJVDZ-UHFFFAOYSA-N 0.000 abstract 1
- 241000402754 Erythranthe moschata Species 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000002537 cosmetic Substances 0.000 abstract 1
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- -1 methylmagnesium halide Chemical class 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
Abstract
NEW MATERIAL:Geometrical isomers of 5, 5, 8, 8-tetramethyl-or 2, 5, 5, 8, 8- pentamethyl-decalin I [ Q is O, CH3 and OR (R is H or 1-8C alkyl), H and OH].
EXAMPLE: Geometrically isomeric 2-hydroxy-5, 5, 8, 8-tetramethyl-decalin.
USE: It has musk, amber, woody and camphor-perfume and useful as an agent for importing lasting perfume, a modifier, or their intermediates used in various fields including table luxuries, cosmetics, etc.,
PREPARATION: The desired compound V is prepared by (1) reducing a compound II with hydrogen in the presence a reducing catalyst, (2) oxidizing the resulting compound III with an oxidant to afford the compound IV, and (3) reacting the compound IV with a methylmagnesium halide.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8994278A JPS6054936B2 (en) | 1978-07-25 | 1978-07-25 | Geometrically isomeric 5,5,8,8-tetramethyl- or 2,5,5,8,8-pentamethyl-decalins, their preparation and use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8994278A JPS6054936B2 (en) | 1978-07-25 | 1978-07-25 | Geometrically isomeric 5,5,8,8-tetramethyl- or 2,5,5,8,8-pentamethyl-decalins, their preparation and use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5517332A true JPS5517332A (en) | 1980-02-06 |
| JPS6054936B2 JPS6054936B2 (en) | 1985-12-03 |
Family
ID=13984748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8994278A Expired JPS6054936B2 (en) | 1978-07-25 | 1978-07-25 | Geometrically isomeric 5,5,8,8-tetramethyl- or 2,5,5,8,8-pentamethyl-decalins, their preparation and use |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6054936B2 (en) |
-
1978
- 1978-07-25 JP JP8994278A patent/JPS6054936B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6054936B2 (en) | 1985-12-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1313646A (en) | Process for producing 3-phenyl pentenals | |
| JPS57176982A (en) | Dioxolanylazetidinone compound, its preparation and use | |
| GB1521181A (en) | Ketolactones and their manufacture | |
| JPS54145646A (en) | Tricyclic alpha,beta-unsaturated aldehyde | |
| JPS54125606A (en) | Preparation of ethylene glycol | |
| JPS54148768A (en) | Novel tricyclic alpha,beta-unsaturated ketone | |
| JPS5742643A (en) | 6,10,14,18-tetramethyl-5,9,13,17-nonadecatetraene-2-ol | |
| JPS54128507A (en) | Preparation of ethylene glycol | |
| JPS55108898A (en) | 25-hydroxy-24-oxocholesterol derivative and its preparation | |
| DE59906394D1 (en) | LIQUID FORMULATION OF TETRABUTYLAMMONIUM PHENOLATE | |
| ES485993A1 (en) | Aldehydes, their preparation and their use as perfumes. | |
| JPS5536432A (en) | 11-methyl-cis-9-12-tridecadienyl acetate | |
| JPS5517361A (en) | 7-methylene-cis-decalin-2-one | |
| JPS5470208A (en) | Geometrical isomers 5-octene-1-ols, thir preparation, and utilization | |
| JPS5552347A (en) | Stabilized polyphenylene oxide resin composition | |
| JPS55108883A (en) | Ethyl-(gamma-acetamino-gamma-ethoxycarbonyl-gamma-cyanopropyl- methyl) phosphinate and its preparation | |
| JPS5536438A (en) | Beta-ionone derivative and its preparation | |
| JPS55108899A (en) | 25-brom-24-oxocholesterol derivative and its preparation | |
| JPS5363302A (en) | Preparation of olefin compounds | |
| JPS5527121A (en) | Novel estradiol compound, its preparation and anti-tumor agent containing the same | |
| JPS5334751A (en) | Preparation of d-damascone | |
| JPS5481253A (en) | 2-methyl-2-hydroxyperhydrotriquinacene | |
| JPS55108829A (en) | Tricyclic spiro-alcohol | |
| JPS56167635A (en) | Alpha,beta-dihydropolyprenylcarboxylic acid and its derivative | |
| JPS54109972A (en) | Preparation of 4-(s)-5-methoxycarbonyl-1-(s)-hy droxypentyl-5-(r)-hydroxymethyl-imidazolidinone and its derivative |