JPS552607A - Preparation of bistriorganosilylacetylene - Google Patents
Preparation of bistriorganosilylacetyleneInfo
- Publication number
- JPS552607A JPS552607A JP7399278A JP7399278A JPS552607A JP S552607 A JPS552607 A JP S552607A JP 7399278 A JP7399278 A JP 7399278A JP 7399278 A JP7399278 A JP 7399278A JP S552607 A JPS552607 A JP S552607A
- Authority
- JP
- Japan
- Prior art keywords
- dimethy1
- imidazolidinone
- bistriorganosilylacetylene
- triorganochlorosilane
- metallic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012429 reaction media Substances 0.000 abstract 3
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000000382 dechlorinating effect Effects 0.000 abstract 2
- 229950011008 tetrachloroethylene Drugs 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Chemical group 0.000 abstract 1
Abstract
PURPOSE: To prepare the title compound, economically, by reacting tetrachloroethylene with a triorganochlorosilane in the presence of a metallic dechlorinating agent using 1,3-dimethy1-2-imidazolidinone as a harmless, effective reaction medium.
CONSTITUTION: Bistriorganosilylacetylene is prepared by reacting tetrachloroethylene with a triorganochlorosilane of formula R3SiCl (R is alkyl, vinyl, etc.) in the presence of a metallic dechlorinating agent using 1,3-dimethy1-2-imidazolidinone of formula as a reaction medium, pref. at 60-120°C. 1,3-Dimethy1-2-imidazolidinone has very high safety, and gives the title compound most economically compared with the conventional reaction media.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP53073992A JPS5941996B2 (en) | 1978-06-19 | 1978-06-19 | Method for producing pistriorganosilylacetylene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP53073992A JPS5941996B2 (en) | 1978-06-19 | 1978-06-19 | Method for producing pistriorganosilylacetylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS552607A true JPS552607A (en) | 1980-01-10 |
| JPS5941996B2 JPS5941996B2 (en) | 1984-10-11 |
Family
ID=13534114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP53073992A Expired JPS5941996B2 (en) | 1978-06-19 | 1978-06-19 | Method for producing pistriorganosilylacetylene |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5941996B2 (en) |
-
1978
- 1978-06-19 JP JP53073992A patent/JPS5941996B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5941996B2 (en) | 1984-10-11 |
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