JPS5589332A - Production of polyester - Google Patents
Production of polyesterInfo
- Publication number
- JPS5589332A JPS5589332A JP13536078A JP13536078A JPS5589332A JP S5589332 A JPS5589332 A JP S5589332A JP 13536078 A JP13536078 A JP 13536078A JP 13536078 A JP13536078 A JP 13536078A JP S5589332 A JPS5589332 A JP S5589332A
- Authority
- JP
- Japan
- Prior art keywords
- esterification
- glycols
- mole
- effected
- conducted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 title abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 4
- 150000001463 antimony compounds Chemical class 0.000 abstract 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 2
- 230000032050 esterification Effects 0.000 abstract 2
- 238000005886 esterification reaction Methods 0.000 abstract 2
- 150000002334 glycols Chemical class 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract 2
- 239000011574 phosphorus Substances 0.000 abstract 2
- -1 phosphorus compound Chemical class 0.000 abstract 2
- 238000006068 polycondensation reaction Methods 0.000 abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
Abstract
PURPOSE: The esterification of terephthalic acid with glycols is conducted in the presence of a phosphorus compound with a specific structure, then an antimony compound is added, and the polycondensation reaction is effected, thus producing polyester with high heat stability, transparency and excellent color.
CONSTITUTION: The esterification of (A) difunctional carboxylic acids mainly containing terephthalic acid with (B) glycols is conducted in the presence of (C) a phosphorus compound of the formula (n is 1 or 2, preferably 2; R1 and R3 are H, monovalent hydrocarbyl; R2 is divalent hydrocarbyl, preferably CH2, CH2CH2, C6H4), wherein C/A is 0.2×10-4W20×10-4 by mole. Then, an antimony compound as antimony trioxide (D) is added to the product and the polycondensation reaction is effected, wherein D/A is 1×10-4W10×10-4 by mole.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13536078A JPS5589332A (en) | 1978-11-02 | 1978-11-02 | Production of polyester |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13536078A JPS5589332A (en) | 1978-11-02 | 1978-11-02 | Production of polyester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5589332A true JPS5589332A (en) | 1980-07-05 |
Family
ID=15149913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13536078A Pending JPS5589332A (en) | 1978-11-02 | 1978-11-02 | Production of polyester |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5589332A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7459113B2 (en) | 2004-03-08 | 2008-12-02 | Eastman Chemical Company | Process of making a container from polyester polymer particles having a small surface to center intrinsic-viscosity gradient |
| US7935399B2 (en) | 2004-09-02 | 2011-05-03 | Grupo Petrotemex, S.A. De C.V. | Low melting polyester polymers |
| US8022168B2 (en) | 2004-09-02 | 2011-09-20 | Grupo Petrotexmex, S.A. de C.V. | Spheroidal polyester polymer particles |
| US8987408B2 (en) | 2005-06-16 | 2015-03-24 | Grupo Petrotemex, S.A. De C.V. | High intrinsic viscosity melt phase polyester polymers with acceptable acetaldehyde generation rates |
-
1978
- 1978-11-02 JP JP13536078A patent/JPS5589332A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7459113B2 (en) | 2004-03-08 | 2008-12-02 | Eastman Chemical Company | Process of making a container from polyester polymer particles having a small surface to center intrinsic-viscosity gradient |
| US7935399B2 (en) | 2004-09-02 | 2011-05-03 | Grupo Petrotemex, S.A. De C.V. | Low melting polyester polymers |
| US8022168B2 (en) | 2004-09-02 | 2011-09-20 | Grupo Petrotexmex, S.A. de C.V. | Spheroidal polyester polymer particles |
| US8987408B2 (en) | 2005-06-16 | 2015-03-24 | Grupo Petrotemex, S.A. De C.V. | High intrinsic viscosity melt phase polyester polymers with acceptable acetaldehyde generation rates |
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