JPS565328A - Selective molybdenum extraction from waste catalyst for desulfurization - Google Patents
Selective molybdenum extraction from waste catalyst for desulfurizationInfo
- Publication number
- JPS565328A JPS565328A JP7879879A JP7879879A JPS565328A JP S565328 A JPS565328 A JP S565328A JP 7879879 A JP7879879 A JP 7879879A JP 7879879 A JP7879879 A JP 7879879A JP S565328 A JPS565328 A JP S565328A
- Authority
- JP
- Japan
- Prior art keywords
- component
- ammonia
- desulfurization
- waste catalyst
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000006477 desulfuration reaction Methods 0.000 title abstract 3
- 230000023556 desulfurization Effects 0.000 title abstract 3
- 239000002699 waste material Substances 0.000 title abstract 3
- 238000000605 extraction Methods 0.000 title abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title 1
- 229910052750 molybdenum Inorganic materials 0.000 title 1
- 239000011733 molybdenum Substances 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 6
- 238000000034 method Methods 0.000 abstract 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000000284 extract Substances 0.000 abstract 2
- 238000002386 leaching Methods 0.000 abstract 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000001099 ammonium carbonate Substances 0.000 abstract 1
- 235000012501 ammonium carbonate Nutrition 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
PURPOSE: To enhance Mo extraction efficiency by a method wherein a waste catalyst for desulfurization is oxidized and calcined, and is treated with leaching process using aqueous ammonia and aqueous solution of the ammonium salt at a specific temperature under O2 partial pressure, so that Mo component is selectively extracted.
CONSTITUTION: Desulfurization waste catalyst is oxidized and roasted to remove deposited oil and sulfur component. The roasted product is treated with pressurized leaching using aqueous solution of ammonia and ammonia salt or two or more of ammonia salt (preferably ammonium sulfate dissolved into aqueous ammonia or ammonium carbonate solution), at a temperature higher than 110°C under oxygen partial pressure of more than 1kg/cm2 for 30min or more. This selectively extracts Mo component in high yield of about 97% or more but does not dissolve any of Al component constituting catalyst carrier. In contrast with conventional method, this process extracts little V component, simplifies Mo purification process, and provides extracted liquid easy to filter allowing Mo acid to be easily separated by precipitation by common method.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54078798A JPS5814367B2 (en) | 1979-06-22 | 1979-06-22 | Selective extraction method of molybdenum from desulfurization waste catalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP54078798A JPS5814367B2 (en) | 1979-06-22 | 1979-06-22 | Selective extraction method of molybdenum from desulfurization waste catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS565328A true JPS565328A (en) | 1981-01-20 |
| JPS5814367B2 JPS5814367B2 (en) | 1983-03-18 |
Family
ID=13671874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54078798A Expired JPS5814367B2 (en) | 1979-06-22 | 1979-06-22 | Selective extraction method of molybdenum from desulfurization waste catalyst |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5814367B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007032228A1 (en) * | 2005-09-16 | 2007-03-22 | Mitsubishi Rayon Co., Ltd. | Methods for recovery of molybdenum and process for preparation of catalysts |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS498491A (en) * | 1972-05-17 | 1974-01-25 |
-
1979
- 1979-06-22 JP JP54078798A patent/JPS5814367B2/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS498491A (en) * | 1972-05-17 | 1974-01-25 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007032228A1 (en) * | 2005-09-16 | 2007-03-22 | Mitsubishi Rayon Co., Ltd. | Methods for recovery of molybdenum and process for preparation of catalysts |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5814367B2 (en) | 1983-03-18 |
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