JPS57100101A - Emulsifier for emulsion polymerization - Google Patents
Emulsifier for emulsion polymerizationInfo
- Publication number
- JPS57100101A JPS57100101A JP17777780A JP17777780A JPS57100101A JP S57100101 A JPS57100101 A JP S57100101A JP 17777780 A JP17777780 A JP 17777780A JP 17777780 A JP17777780 A JP 17777780A JP S57100101 A JPS57100101 A JP S57100101A
- Authority
- JP
- Japan
- Prior art keywords
- emulsifier
- alkali salt
- emulsion polymerization
- succinic acid
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003995 emulsifying agent Substances 0.000 title abstract 3
- 238000007720 emulsion polymerization reaction Methods 0.000 title abstract 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract 6
- 239000001384 succinic acid Substances 0.000 abstract 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 239000000344 soap Substances 0.000 abstract 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical group 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000005060 rubber Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
PURPOSE: To prepare an emulsifier for the emulsion polymerization of rubbers, ABS resins, etc., having excellent characteristics and replaceable to a resin acid soap, by using a half-amide alkali salt or a half-ester alkali salt of succinic acid having a specific hydrocarbon substituent groups, as an active component.
CONSTITUTION: The objective emulsifier is composed mainly of a succinic acid half-amide alkali salt of formulaI[R1 is 10W25C hydrocarbon group; R2 and R3 are H, 1W4C alkyl, or form 5- or 6-membered heaterocyclic ring together with N atom when R2 and R3 are bonded; X is alkali metal atom or (substituted) ammonium salt]or a succinic acid half-ester alkali salt of formula II (R4 is 1W 8C alkyl).
EFFECT: The agent remarkably promotes the emulsion polymerization reaction and considerably shortens the polymerization time as compared with a resin acid soap.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17777780A JPS57100101A (en) | 1980-12-15 | 1980-12-15 | Emulsifier for emulsion polymerization |
| DE19813149201 DE3149201C2 (en) | 1980-12-15 | 1981-12-11 | Emulsifier for emulsion polymerization and use of the emulsifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17777780A JPS57100101A (en) | 1980-12-15 | 1980-12-15 | Emulsifier for emulsion polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57100101A true JPS57100101A (en) | 1982-06-22 |
| JPH0147484B2 JPH0147484B2 (en) | 1989-10-13 |
Family
ID=16036925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17777780A Granted JPS57100101A (en) | 1980-12-15 | 1980-12-15 | Emulsifier for emulsion polymerization |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS57100101A (en) |
| DE (1) | DE3149201C2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4683100A (en) * | 1984-12-20 | 1987-07-28 | Rohm And Haas Company | Copolymerizable ethylenically unsaturated surfactants for latex preparation |
| DE3509822A1 (en) * | 1985-03-19 | 1986-09-25 | Bayer Ag, 5090 Leverkusen | AMINO AMBER ACID DERIVATIVES AND THEIR USE AS EMULSIFIERS FOR POLYMER DISPERSIONS |
| AU6394799A (en) * | 1998-10-15 | 2000-05-01 | S.C. Johnson Commercial Markets, Inc. | Amine-modified polymers as highly-efficient emulsion polymer stabilizer resins |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4923290A (en) * | 1972-06-23 | 1974-03-01 |
-
1980
- 1980-12-15 JP JP17777780A patent/JPS57100101A/en active Granted
-
1981
- 1981-12-11 DE DE19813149201 patent/DE3149201C2/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4923290A (en) * | 1972-06-23 | 1974-03-01 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3149201A1 (en) | 1982-07-15 |
| DE3149201C2 (en) | 1986-08-14 |
| JPH0147484B2 (en) | 1989-10-13 |
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