JPS5820719A - Compound represented by formula tmgazno4 and having hexagonal lamellar structure, and its preparation - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a compound having a hexagonal layered structure that is hydrogen bombed with 6 m Ga ZnO4, and a method for producing the same.

A compound having a hexagonal layered structure represented by YFe204 was synthesized by Keito Motoide et al., and its existence is already known. This compound vilJ is Y j
+ iI' e jl + H' e J +042-
Shown with 1tL↓Uni, the demon's bivalent Iman and 3tib Io/
is surrounded by five-coordinated mature ions, and yttrium (Y) is a compound that has six-coordinated at-chord ions around it, and is magnetic.

Kinoe 1311 is the above-mentioned, Ya + p e2 + peX
+ 'I'm' in place of Y3+ in the 02-compound,
z1!+ instead of k'e''(Ga"w instead of j'e3+) IM changed compound d and -
Nimeru Book @ Hv'lin to provide a 1-0 courageous exit
The compound mr shown by ua Zn04, this Q compound, thulium is Tm" ion, and gallium is (ja' + helmet ship Zn"+), HA Tm"Ua", +
This crystal can be used as a bow.
As shown in Figure 1, it is said to have a crystalline layered structure.

The wax-sized circles represent sales, and the small black circles represent gallium and zinc. It is divided into Gariyamu and one other island, Ranodam.

! ! The trivalent ion of IL and potassium is.

It is depressed by a five-coordinated m-ion. Crystallographically, they occupy the same position. t, Tsurikumu Den, 6 placement O years old, chest 4) 9 is divine. -Ion Demerit#
It has a dense structure. 8% t and U indicate the position within the unit cell.

As shown in Table 1, the relative radiation %l (to) is as shown in table 1.

Part 1 Part T+n da &no4 The faction # is l bow m and riri 1, and the melting wave is 11-.

In the grid, a is interpreted as the following and &).

, 1. l =, i, a3uuu ±uuoo+
(X)C, +=23.066 ±α(
J(J6 (Xn) This compound* is a compound useful as a dipping sauce material and a soba broth.

This 1L-&bi is linearly served by the medical method Vζ and served 4
, J ゛41t^Thuricum ('rm) is like 1L Thulium (1 stone 20j and gold llI4 galiwaum, mei is fermented potassium (Ua2 (J, l/or kC)
Compounds that are decomposed into 7J lithium oxide (UA2U;,) and MJL lead phosphorus (Zn (J)) or zinc oxide (Ua2U;) that are decomposed by heating.
Mix the raw compounds with t, thulium, potassium, and subcontractors so that the ratio is 1 x 1, and then remove the oxidizing atmosphere in the atmosphere at a temperature of 13 tJO℃ or higher. 41 Rirui tyo Gaku2mu V Yohi blood supply p1 valley trivalent ion Buddha employment s2m ion Buddha - Yoshi filtration original d Kaede's 1:2 °1j The starting material used in the present invention is % You can use riim04 for now, but luckily the chemical reaction between the starting materials 2 is carried out in KA, and #i is small in diameter.
In particular, it is preferable that the value is less than lOFm.

9. When using it as a conductor material, it is preferable to avoid contamination with impurities, so it is preferable to start with a high degree of openness.
Thoroughly combine this raw material with 70 baskets of F1, airsour, or acetone.

The mixing ratio of these materials is such that the ratio of thulium, gallium, and zinc is 1:1:1.

If this ratio t is removed, the target compound f: Samurai will not be produced. This mixture was heated to 1,300°C or higher under an atmosphere of 1,300°C or more, so that the mixture could be reduced from the trivalent ionic layer and the 2m ionic layer. Heat at once. m fever
The Zn04 compound is #&
It showed a color and was found to have a crystalline structure by cross-gid X@ diffraction method. The crystal structure line has already been obtained by Oboro Honde.
It turned out to be the same type as Fez04. The starting sample and the reaction product were weighed closely in one tank, and the resulting nine samples were chemically and assayed as zinc oxide (ZnO).
Powder i, molar ratio -t' 1 to 1 to 2 (0 ratio 11
Ethyl alcohol was added to the milk wFPI3 and mixed thoroughly to obtain 11 particles with an average particle diameter of several pm.

The mixture was poured into a platinum crucible and % IJ! tsO
The sample was placed in a 7 liter oven set at ℃ and heated for 2 days, after which the sample was taken out of the oven and cooled down to temperature. The nine samples obtained were -Ga Zn04 and 6p1
Yf'@, u, which has already been reported - crystallographically,
Isomorphism indicates the purchase of powder crystal ♀ 7C.

[Brief explanation of the drawing]

1st Cabinet e, the picture of my graduate brother Akira'■blind Ga 1an04 Ayu Akira. Regional University Maru is #1! The nest and middle circle indicate thulium, and the small black circle indicates zinc and potassium. i, ;+i” Reihi, writing) 1.-!

Claims (1)

[Scope of Claims] A compound exhibiting a layered structure of hexagonal crystal threads represented by '11~n Ua Zn04. 2 Thulium metal (Tm) 4Q thulium carbide (
T+r+2 (J3j or a compound that is decomposed into dithulium dissulfate ('rm, o3) when heated,
Metallic gallium (Ga) 6 or gallium oxide ('d1
1.203) %h or by heating) a compound that decomposes into gallium oxide (GaO) and submium (Z
n) Zinc oxide (ZnO) or '7
It is decomposed by AIM and becomes ZnO
) with a compound that produces thulium, gallium, and zinc in an atomic ratio of 1:1:1, and
Heating in the atmosphere at a temperature above ℃, in a cough-like atmosphere, or in an atmosphere where gallium and zinc are in the ionic state, and divalent ions/states are not changed from the iIL state. A method for producing a compound having a hexagonal lamellar structure represented by Zn04.