JPS58501816A - 硫化物の製造用の流動溶融層法 - Google Patents
硫化物の製造用の流動溶融層法Info
- Publication number
- JPS58501816A JPS58501816A JP82503499A JP50349982A JPS58501816A JP S58501816 A JPS58501816 A JP S58501816A JP 82503499 A JP82503499 A JP 82503499A JP 50349982 A JP50349982 A JP 50349982A JP S58501816 A JPS58501816 A JP S58501816A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- alkali metal
- reaction
- compound
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 68
- 238000004519 manufacturing process Methods 0.000 title description 11
- 230000008569 process Effects 0.000 title description 10
- 150000003568 thioethers Chemical class 0.000 title 1
- 239000007789 gas Substances 0.000 claims description 100
- 238000006243 chemical reaction Methods 0.000 claims description 74
- 150000003464 sulfur compounds Chemical class 0.000 claims description 42
- 239000003638 chemical reducing agent Substances 0.000 claims description 37
- 150000001875 compounds Chemical class 0.000 claims description 36
- 229910052783 alkali metal Inorganic materials 0.000 claims description 32
- 150000003839 salts Chemical class 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
- 229910052799 carbon Inorganic materials 0.000 claims description 24
- 239000007787 solid Substances 0.000 claims description 24
- 229910001868 water Inorganic materials 0.000 claims description 24
- 239000000047 product Substances 0.000 claims description 22
- 241001474791 Proboscis Species 0.000 claims description 18
- 239000003513 alkali Substances 0.000 claims description 18
- 239000003575 carbonaceous material Substances 0.000 claims description 17
- 239000000155 melt Substances 0.000 claims description 17
- 150000001340 alkali metals Chemical class 0.000 claims description 16
- 229910052977 alkali metal sulfide Inorganic materials 0.000 claims description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
- 230000009467 reduction Effects 0.000 claims description 14
- 229910052717 sulfur Inorganic materials 0.000 claims description 14
- 239000011593 sulfur Substances 0.000 claims description 14
- 230000001590 oxidative effect Effects 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 12
- 239000012159 carrier gas Substances 0.000 claims description 12
- 239000001569 carbon dioxide Substances 0.000 claims description 11
- 239000000446 fuel Substances 0.000 claims description 11
- 229910052737 gold Inorganic materials 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 11
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 10
- -1 fur compound Chemical class 0.000 claims description 9
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 9
- 239000010931 gold Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000002485 combustion reaction Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 5
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 5
- 239000003610 charcoal Substances 0.000 claims description 5
- 235000010265 sodium sulphite Nutrition 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 210000002700 urine Anatomy 0.000 claims 2
- 229940126062 Compound A Drugs 0.000 claims 1
- 206010011224 Cough Diseases 0.000 claims 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims 1
- 208000008454 Hyperhidrosis Diseases 0.000 claims 1
- 241000556720 Manga Species 0.000 claims 1
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 claims 1
- 229910052785 arsenic Inorganic materials 0.000 claims 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
- 229940125782 compound 2 Drugs 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000029142 excretion Effects 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 238000002791 soaking Methods 0.000 claims 1
- 239000012265 solid product Substances 0.000 claims 1
- 208000013460 sweaty Diseases 0.000 claims 1
- 125000000101 thioether group Chemical group 0.000 claims 1
- 229940065278 sulfur compound Drugs 0.000 description 31
- 239000007788 liquid Substances 0.000 description 20
- 238000006722 reduction reaction Methods 0.000 description 16
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 11
- 239000003245 coal Substances 0.000 description 11
- 238000010791 quenching Methods 0.000 description 11
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 230000000171 quenching effect Effects 0.000 description 9
- 239000000376 reactant Substances 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 239000003546 flue gas Substances 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 230000008018 melting Effects 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 239000012768 molten material Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
- 239000002956 ash Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 229910052979 sodium sulfide Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- 230000002745 absorbent Effects 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 150000002927 oxygen compounds Chemical class 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 4
- 150000004763 sulfides Chemical class 0.000 description 4
- 241000282472 Canis lupus familiaris Species 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- 150000001339 alkali metal compounds Chemical class 0.000 description 3
- 239000000567 combustion gas Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 239000002006 petroleum coke Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 238000005987 sulfurization reaction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910013868 M2SO4 Inorganic materials 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000010883 coal ash Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 239000013256 coordination polymer Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- UTLZBWAGLRNNAY-UHFFFAOYSA-J thorium(4+);dicarbonate Chemical compound [Th+4].[O-]C([O-])=O.[O-]C([O-])=O UTLZBWAGLRNNAY-UHFFFAOYSA-J 0.000 description 2
- 238000013519 translation Methods 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000282693 Cercopithecidae Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 240000005109 Cryptomeria japonica Species 0.000 description 1
- 241000252233 Cyprinus carpio Species 0.000 description 1
- 241000283074 Equus asinus Species 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 241001164593 Merica Species 0.000 description 1
- 241000238413 Octopus Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 208000010513 Stupor Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- KZNMRPQBBZBTSW-UHFFFAOYSA-N [Au]=O Chemical class [Au]=O KZNMRPQBBZBTSW-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001486 argon compounds Chemical class 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000011335 coal coke Substances 0.000 description 1
- 239000003250 coal slurry Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- BBLSYMNDKUHQAG-UHFFFAOYSA-L dilithium;sulfite Chemical compound [Li+].[Li+].[O-]S([O-])=O BBLSYMNDKUHQAG-UHFFFAOYSA-L 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- XTHCSHLLMNWUNM-UHFFFAOYSA-N disodium sulfuric acid sulfide Chemical compound S(=O)(=O)(O)O.[Na+].[S-2].[Na+] XTHCSHLLMNWUNM-UHFFFAOYSA-N 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 210000001061 forehead Anatomy 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 150000002344 gold compounds Chemical class 0.000 description 1
- 229910001922 gold oxide Inorganic materials 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 210000002414 leg Anatomy 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000007578 melt-quenching technique Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000019086 sulfide ion homeostasis Effects 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- FZUJWWOKDIGOKH-UHFFFAOYSA-N sulfuric acid hydrochloride Chemical compound Cl.OS(O)(=O)=O FZUJWWOKDIGOKH-UHFFFAOYSA-N 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- YJIBHPVNTVUEPU-UHFFFAOYSA-N thorium(iv) sulfide Chemical compound S=[Th]=S YJIBHPVNTVUEPU-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
- C01B17/24—Preparation by reduction
- C01B17/26—Preparation by reduction with carbon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/12—Combustion of pulp liquors
- D21C11/125—Decomposition of the pulp liquors in reducing atmosphere or in the absence of oxidants, i.e. gasification or pyrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Treating Waste Gases (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Glass Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31464381A | 1981-10-26 | 1981-10-26 | |
| US314643DEEDK | 1981-10-26 | ||
| PCT/US1982/001460 WO1983001437A1 (en) | 1981-10-26 | 1982-10-12 | Flowing melt layer process for production of sulfides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS58501816A true JPS58501816A (ja) | 1983-10-27 |
Family
ID=23220815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP82503499A Pending JPS58501816A (ja) | 1981-10-26 | 1982-10-12 | 硫化物の製造用の流動溶融層法 |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0091948A4 (it) |
| JP (1) | JPS58501816A (it) |
| KR (1) | KR880001606B1 (it) |
| AU (1) | AU552817B2 (it) |
| BR (1) | BR8207941A (it) |
| CA (1) | CA1211273A (it) |
| ES (1) | ES8308803A1 (it) |
| FI (1) | FI72496C (it) |
| IT (1) | IT1158024B (it) |
| WO (1) | WO1983001437A1 (it) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014169196A (ja) * | 2013-03-01 | 2014-09-18 | Nippon Chem Ind Co Ltd | 硫化リチウムの製造方法及び無機固体電解質の製造方法 |
| JP2014169197A (ja) * | 2013-03-01 | 2014-09-18 | Nippon Chem Ind Co Ltd | 硫化リチウムの製造方法及び無機固体電解質の製造方法 |
| JP2014201510A (ja) * | 2013-04-09 | 2014-10-27 | 古河機械金属株式会社 | 硫化リチウムの製造方法 |
| JP2015074567A (ja) * | 2013-10-07 | 2015-04-20 | 古河機械金属株式会社 | 硫化リチウムの製造方法 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4865750A (en) * | 1986-05-02 | 1989-09-12 | Engineered Systems International, Inc. | Methods for reducing anions in process chemicals |
| CA1278919C (en) * | 1986-05-02 | 1991-01-15 | Mel Systems, Inc. | Reduction burning and compositions therefore |
| DE4135720C2 (de) * | 1991-10-30 | 1994-09-22 | Metallgesellschaft Ag | Verfahren zur Spaltung von Natriumsulfat oder Kaliumsulfat enthaltenden Stoffen |
| KR100407194B1 (ko) * | 2001-02-14 | 2003-11-28 | 가야에이엠에이 주식회사 | 금속 황화물의 제조방법 |
| KR100407195B1 (ko) * | 2001-02-14 | 2003-11-28 | 가야에이엠에이 주식회사 | 금속 황화물의 제조방법 |
| CN109373335B (zh) * | 2018-09-19 | 2020-06-23 | 杭州典范科技有限公司 | 旋风炉及含盐废液燃烧处理方法和硫化碱制备方法 |
| CN115536224B (zh) * | 2022-09-28 | 2023-08-18 | 中建安装集团有限公司 | 矿化再生微粉-工业废渣协同固化淤泥自动化设备及方法 |
| CN116425121B (zh) * | 2023-05-22 | 2024-07-05 | 南风化工(运城)集团有限公司 | 一种硫化钠的生产方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB159202A (en) * | 1920-02-20 | 1922-03-02 | Lucien Paul Basset | Process for the manufacture of sulphides of alkaline and earthly-alkaline metals |
| US2261995A (en) * | 1938-07-08 | 1941-11-11 | John E Greenawalt | Method of burning black liquor |
| NL82616C (it) * | 1947-10-08 | |||
| US2590905A (en) * | 1947-10-15 | 1952-04-01 | Canada Paper Company | Apparatus for concentrating residual pulp liquor by direct contact with flue gases |
| US2678615A (en) * | 1949-12-20 | 1954-05-18 | Rosenblad Corp | Method for burning sticky, watercontaining liquid fuel |
| DE1517155A1 (de) * | 1959-05-29 | 1969-04-24 | Billeruds Ab | Verfahren zum Vergasen alkalihaltiger Sulfitablaugen |
| FR1425104A (fr) * | 1964-02-26 | 1966-01-14 | Billeruds Ab | Procédé de récupération de soude à partir de liqueur de cellulose épuisée, à base de sodium |
| SE378119B (it) * | 1972-04-04 | 1975-08-18 | Angpanneforeningen | |
| GB2017281B (en) * | 1978-03-23 | 1982-07-21 | Asahi Engineering | Method and apparatus for treating water solution of waste material containing salt having smelt-water explosion characteristics |
| US4241041A (en) * | 1979-01-22 | 1980-12-23 | Mei Systems Inc. | Methods for the recovery of sulfur components from flue gas and recycle sodium sulfite by reduction-smelting and carbonating to strip hydrogen sulfide |
| US4243645A (en) * | 1979-09-21 | 1981-01-06 | Westinghouse Electric Corp. | All dry solid potassium seed regeneration system for magnetohydrodynamic power generation plant |
-
1982
- 1982-10-12 WO PCT/US1982/001460 patent/WO1983001437A1/en not_active Ceased
- 1982-10-12 EP EP19820903536 patent/EP0091948A4/en not_active Withdrawn
- 1982-10-12 AU AU91293/82A patent/AU552817B2/en not_active Ceased
- 1982-10-12 BR BR8207941A patent/BR8207941A/pt unknown
- 1982-10-12 JP JP82503499A patent/JPS58501816A/ja active Pending
- 1982-10-13 CA CA000413359A patent/CA1211273A/en not_active Expired
- 1982-10-25 ES ES516814A patent/ES8308803A1/es not_active Expired
- 1982-10-25 IT IT49353/82A patent/IT1158024B/it active
- 1982-10-26 KR KR8204813A patent/KR880001606B1/ko not_active Expired
-
1983
- 1983-06-22 FI FI832296A patent/FI72496C/fi not_active IP Right Cessation
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014169196A (ja) * | 2013-03-01 | 2014-09-18 | Nippon Chem Ind Co Ltd | 硫化リチウムの製造方法及び無機固体電解質の製造方法 |
| JP2014169197A (ja) * | 2013-03-01 | 2014-09-18 | Nippon Chem Ind Co Ltd | 硫化リチウムの製造方法及び無機固体電解質の製造方法 |
| JP2014201510A (ja) * | 2013-04-09 | 2014-10-27 | 古河機械金属株式会社 | 硫化リチウムの製造方法 |
| JP2015074567A (ja) * | 2013-10-07 | 2015-04-20 | 古河機械金属株式会社 | 硫化リチウムの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU9129382A (en) | 1983-05-05 |
| AU552817B2 (en) | 1986-06-19 |
| IT8249353A0 (it) | 1982-10-25 |
| FI72496C (fi) | 1987-06-08 |
| FI72496B (fi) | 1987-02-27 |
| BR8207941A (pt) | 1983-09-20 |
| ES516814A0 (es) | 1983-10-01 |
| EP0091948A1 (en) | 1983-10-26 |
| KR840001931A (ko) | 1984-06-07 |
| IT1158024B (it) | 1987-02-18 |
| EP0091948A4 (en) | 1984-02-07 |
| FI832296A0 (fi) | 1983-06-22 |
| KR880001606B1 (ko) | 1988-08-25 |
| ES8308803A1 (es) | 1983-10-01 |
| WO1983001437A1 (en) | 1983-04-28 |
| CA1211273A (en) | 1986-09-16 |
| FI832296L (fi) | 1983-06-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4198380A (en) | Absorption of sulfur oxides from hot gases | |
| US4423702A (en) | Method for desulfurization, denitrifaction, and oxidation of carbonaceous fuels | |
| JPS58501816A (ja) | 硫化物の製造用の流動溶融層法 | |
| US3729551A (en) | Conversion of calcium sulfate to calcium oxide and elemental sulfur | |
| JPS6013401B2 (ja) | 液状銑鉄及び還元ガスを発生させる方法及び装置 | |
| PL103562B1 (pl) | Sposob wytwarzania gazu syntezowego | |
| CS265234B2 (en) | Method for reducing smelting of iron ores | |
| JPS59197724A (ja) | プロセス排ガスの後燃焼浄化方法 | |
| PL127771B1 (en) | Method of manufacture of directly reduced iron together with gasification of coal in fluidized bed | |
| US4522685A (en) | Method of operating a spent pulping liquor combustion apparatus | |
| US3542511A (en) | Removal of sulfur dioxide from waste gases | |
| US4969931A (en) | Process for the preparation of synthesis gas | |
| JPH0331833B2 (it) | ||
| US4526760A (en) | Recovery of heat and chemical values from spent pulping liquors | |
| ES2397447A1 (es) | Dispositivo reactor dual de gasificación-pirólisis. | |
| JPS5910326A (ja) | 熱ガスからの硫黄酸化物除去方法 | |
| US4198385A (en) | Reduction of sodium sulfate to sodium sulfide | |
| US4441959A (en) | Recovery of heat and chemical values from spent pulping liquors | |
| US5984987A (en) | Black liquor gasification process | |
| JP2671980B2 (ja) | 廃棄物処理 | |
| AU9405798A (en) | Process of reducing ilmenite | |
| CA1126508A (en) | Method and apparatus for the continuous recovery of heavy-metal phases | |
| RU2422538C2 (ru) | Способ металлургической многоцелевой газификации твердого топлива | |
| JPH0724251A (ja) | 運搬床における、細かい粒度の吸収剤粒子を伴なう流出物の脱硫を含む、熱発生方法および装置 | |
| JPH07257907A (ja) | 硫酸の処理 |