JPS5862093A - Recording medium - Google Patents

Recording medium

Info

Publication number
JPS5862093A
JPS5862093A JP56161265A JP16126581A JPS5862093A JP S5862093 A JPS5862093 A JP S5862093A JP 56161265 A JP56161265 A JP 56161265A JP 16126581 A JP16126581 A JP 16126581A JP S5862093 A JPS5862093 A JP S5862093A
Authority
JP
Japan
Prior art keywords
metal
layer
recording medium
recording
organic material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP56161265A
Other languages
Japanese (ja)
Inventor
Yasuyuki Goto
康之 後藤
Seiya Ogawa
小川 清也
Nagaaki Etsuno
越野 長明
Hironori Goto
後藤 広則
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujitsu Ltd
Original Assignee
Fujitsu Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujitsu Ltd filed Critical Fujitsu Ltd
Priority to JP56161265A priority Critical patent/JPS5862093A/en
Publication of JPS5862093A publication Critical patent/JPS5862093A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/243Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
    • G11B2007/24302Metals or metalloids
    • G11B2007/24316Metals or metalloids group 16 elements (i.e. chalcogenides, Se, Te)
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/246Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
    • G11B7/248Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes porphines; azaporphines, e.g. phthalocyanines
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/249Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing organometallic compounds
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/253Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
    • G11B7/2533Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates comprising resins

Landscapes

  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Read Only Memory (AREA)
  • Optical Record Carriers And Manufacture Thereof (AREA)

Abstract

PURPOSE:To obtain a recording medium having a high light sensitivity and useful for an optic disk, by providing a recording layer comprising a metal and an organic material on a substrate, wherein the metal is so distributed that its amount is larger on the substrate side and the surface side while the organic material is so distributed that its amount is larger in a central part of the layer. CONSTITUTION:The recording medium consists of a plastic substrate 1, a tellurium layer (8mm. in thickness) 2, a copper phthalocyanine layer (20mm. in thickness) 3 and a tellurium layer (22mm. in thickness) 4. Tellurium (Te) used as a metal may be replaced by a metal having a low melting point and a low thermal conductivity such as Bi, In, Se, As, InGa and InSn or other similar metal. Copper phthalocyanine used as an organic material may be replaced by a material having a low melting point or a low boiling point or sublimable, such as fluorescein. The optic disk produced by using said recording medium comprises a pair of recording disks 5, 6 faced to each other through spacers 7, 8, and recording layers 5a, 6a provided on the faced surface side of the disks 5, 6.

Description

【発明の詳細な説明】 本発明は記録媒体に関し、とくに高す光感度を有する光
ディスクに用いられる記録媒体に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a recording medium, and particularly to a recording medium used in an optical disk having high photosensitivity.

光デイスク用記録媒体(以下記録媒体という)は基板面
上に、記録層として、ビスマス(Bi)やテルル(Te
)のような単体の薄膜を蒸着技術等にょシ形成していた
。そしてこの記録層にレーザビームのような光ビームを
照射して情報の記録、再生を行う。
An optical disk recording medium (hereinafter referred to as a recording medium) has a recording layer of bismuth (Bi) or tellurium (Te) on a substrate surface.
) was formed using vapor deposition technology. Then, this recording layer is irradiated with a light beam such as a laser beam to record and reproduce information.

しかし豐これらの記録媒体では、現在の半導体レーザを
用いて、情報の記録を行うには、感度の点から不十分で
あり、高品位の再生tW報を得ることが困難であった。
However, these recording media have insufficient sensitivity to record information using current semiconductor lasers, and it has been difficult to obtain high-quality reproduction tW information.

本発明はかかる点に鑑みなされたもので、記録時におい
て十分を感度を有する光デイスク用記録媒体を提供する
ことを目的とする。以下図面を参照しながら本発明の好
ましb実施例につhて説明する。
The present invention has been made in view of the above, and an object of the present invention is to provide a recording medium for an optical disc that has sufficient sensitivity during recording. Preferred embodiments of the present invention will be described below with reference to the drawings.

gt図は本発明の一実施例構成図であって、lはプラス
チック基板、2はテルル(Te)層(層厚8關)。
Figure gt is a configuration diagram of an embodiment of the present invention, where l is a plastic substrate, 2 is a tellurium (Te) layer (layer thickness: 8 mm).

3は、銅フタロシアニン層(層厚zowsL 4はテル
ル(Te)層(層厚22n)である。
3 is a copper phthalocyanine layer (layer thickness zowsL) 4 is a tellurium (Te) layer (layer thickness 22n).

なおTeの融点は450°C9銅フタロシアニンの昇華
点は400〜42G″Cである。このような薄膜層は蒸
着技術により容易に形成できる。
Note that the melting point of Te is 450° C.9 The sublimation point of copper phthalocyanine is 400 to 42 G″C. Such a thin film layer can be easily formed by vapor deposition technology.

第2図Ca)(b)はこのようにして形成された記録媒
体を用いていわゆるエアーサンドイッチ構成とした光デ
ィスクである。
FIGS. 2(a) and 2(b) show an optical disk having a so-called air sandwich structure using the recording medium thus formed.

第2図(a)To3において、5.6は1対の記録円盤
であってスペーサ7.8を介して対向して配置され、記
録層5a、6aは、これら記録円盤5.6の対向面側に
設けられる。
In FIG. 2(a) To3, 5.6 is a pair of recording disks, which are arranged facing each other with a spacer 7.8 in between, and the recording layers 5a and 6a are the opposing surfaces of these recording disks 5.6. installed on the side.

この光ディスクを用いて、半導体レーザで情報の書込み
、読出しを行なった。光ディスクi1800rpmで回
転させ、情報を記録したがこの時、レーザノくワーの値
はディスク面上で3.3tnW *また再生信号のシ偶
値は40dBであり非常に良質の信号を得九。Teの代
わりにBi、In、Se、A@、InGa、In8nの
ような低融点で低熱伝導性のものを用いてもよい。
Using this optical disc, information was written and read using a semiconductor laser. The optical disk was rotated at 1,800 rpm and information was recorded.At this time, the laser power output on the disk surface was 3.3 tnW *The signal value of the reproduced signal was 40 dB, and a very high quality signal was obtained. Instead of Te, materials having a low melting point and low thermal conductivity such as Bi, In, Se, A@, InGa, and In8n may be used.

また有機材料として銅フタロシアニンの代わりにフルオ
レセインなどの低融点、低沸点あるいは昇華性のもので
あってもよい。
Further, instead of copper phthalocyanine, the organic material may be a low melting point, low boiling point, or sublimable material such as fluorescein.

このように情報書込みにおける高感度化の理由は。What is the reason for the increased sensitivity in writing information?

書込み時における光ビーム照射による熱によって昇華性
を有する有機材料層の有機材の高蒸発性により金属の溶
融除去が助長されるためと考えられる。
This is thought to be because the high evaporability of the organic material in the organic material layer, which has sublimation properties, facilitates the melting and removal of the metal due to the heat generated by the light beam irradiation during writing.

また有4N 寸書のもつ低熱伝導性もその理由の1つと
して考えられる。
In addition, the low thermal conductivity of the 4N size sheet is considered to be one of the reasons for this.

積層構造(Cおいては基板領から金属、有機物金属の順
に主成分が分布するものが特に高感度であった。これは
金寓によって有機物を、挾むことによって有機物に効率
よく熱が伝わり、高蒸発性、昇華性が十分発現されたた
めと考えられる。
The laminated structure (C) in which the main components were distributed in the order of metal and organic metal from the substrate area was particularly sensitive. This is thought to be because high evaporation and sublimation properties were sufficiently expressed.

以上の説明から明らかなように1本発明に係る記録媒体
1−t、記録層として、低融点、低沸点、あるいは昇華
性の有機材料含有層の両側に金属含有層を配した構成で
ちるため、光書込み時の感度が高くなり、半導体レーザ
でも情報の書込み読出しが可能であり、光デイスク装置
が小型になる利点がある。
As is clear from the above description, the recording medium 1-t according to the present invention has a structure in which metal-containing layers are arranged on both sides of a low-melting point, low-boiling point, or sublimable organic material-containing layer as a recording layer. This has the advantage that the sensitivity during optical writing is increased, information can be written and read using a semiconductor laser, and the optical disk device becomes smaller.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は9本発明の一実施例構成図、第2図は9本発明
に係る光デイスク構成図である。 1;プラスチック基板、2:テルル層、3;鋼フタロシ
アニン1,4;テルル層。 第 1 図 第 Z 閉
FIG. 1 is a block diagram of an embodiment of the present invention, and FIG. 2 is a block diagram of an optical disk according to the present invention. 1: Plastic substrate, 2: Tellurium layer, 3: Steel phthalocyanine 1, 4: Tellurium layer. Figure 1 Z Closed

Claims (2)

【特許請求の範囲】[Claims] (1)基板と、該基板上に形成された記録層とを有し。 該記録層に光ビームを照射して情報の書込み、読出しを
行うようにした記録媒体において、前記記録層は金属お
よび有機材料とを含み、かつ、#金属は前記基板側およ
び前記記鋒層表面側で最も多く、#記録層中心部では少
なくなる如く分布し、前記有機材料は、前記中心部で最
も多く、該中心部両側部では少なくなる如く分布せしめ
たことを特徴とする記録媒体。
(1) It has a substrate and a recording layer formed on the substrate. In the recording medium in which information is written and read by irradiating the recording layer with a light beam, the recording layer includes a metal and an organic material, and the metal is on the substrate side and on the surface of the recording layer. A recording medium characterized in that the organic material is distributed such that it is most abundant at the center of the recording layer and is least present on both sides of the center.
(2)前記金属が低融点、低熱伝導性を有するものであ
り、前記有機材料が低融点、低沸点、又は高昇華性を有
するものであることを特徴とする特許請求の範囲第(1
)項に記載の記録媒体。
(2) The metal has a low melting point and low thermal conductivity, and the organic material has a low melting point, a low boiling point, or a high sublimation property.
) The recording medium described in section 2.
JP56161265A 1981-10-09 1981-10-09 Recording medium Pending JPS5862093A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56161265A JPS5862093A (en) 1981-10-09 1981-10-09 Recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56161265A JPS5862093A (en) 1981-10-09 1981-10-09 Recording medium

Publications (1)

Publication Number Publication Date
JPS5862093A true JPS5862093A (en) 1983-04-13

Family

ID=15731810

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56161265A Pending JPS5862093A (en) 1981-10-09 1981-10-09 Recording medium

Country Status (1)

Country Link
JP (1) JPS5862093A (en)

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