JPS5893006A - Production of optical fiber sheet - Google Patents
Production of optical fiber sheetInfo
- Publication number
- JPS5893006A JPS5893006A JP56191281A JP19128181A JPS5893006A JP S5893006 A JPS5893006 A JP S5893006A JP 56191281 A JP56191281 A JP 56191281A JP 19128181 A JP19128181 A JP 19128181A JP S5893006 A JPS5893006 A JP S5893006A
- Authority
- JP
- Japan
- Prior art keywords
- optical fibers
- optical fiber
- array
- fiber sheet
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000013307 optical fiber Substances 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 230000005855 radiation Effects 0.000 claims description 4
- 230000001678 irradiating effect Effects 0.000 claims description 2
- 239000003999 initiator Substances 0.000 abstract description 6
- 239000011342 resin composition Substances 0.000 abstract description 6
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000178 monomer Substances 0.000 abstract description 5
- 239000000113 methacrylic resin Substances 0.000 abstract description 4
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 3
- DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 abstract description 2
- FHLPGTXWCFQMIU-UHFFFAOYSA-N [4-[2-(4-prop-2-enoyloxyphenyl)propan-2-yl]phenyl] prop-2-enoate Chemical compound C=1C=C(OC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OC(=O)C=C)C=C1 FHLPGTXWCFQMIU-UHFFFAOYSA-N 0.000 abstract description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052753 mercury Inorganic materials 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 6
- -1 Polyol acrylates Chemical class 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000001227 electron beam curing Methods 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 229920002454 poly(glycidyl methacrylate) polymer Polymers 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 1
- BGJQNPIOBWKQAW-UHFFFAOYSA-N 1-tert-butylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)(C)C BGJQNPIOBWKQAW-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 description 1
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 229930194542 Keto Natural products 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 1
- 150000008062 acetophenones Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000013308 plastic optical fiber Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical class C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4479—Manufacturing methods of optical cables
- G02B6/448—Ribbon cables
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は新規な光学繊維シートの製造法に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a novel method for manufacturing optical fiber sheets.
近年、プラスチック製の光学繊維は軽量、可撓性及び安
価であり、しかも加工がしやすいという特長を生かして
装飾用やモニター用に幅広く使われ始めている。In recent years, plastic optical fibers have begun to be widely used for decoration and monitors, taking advantage of their characteristics of being lightweight, flexible, inexpensive, and easy to process.
これらの装置に光学繊維を岨込むために・、予め光学繊
維を殉−に配列した後、接着剤で固定してシート化し、
次いでコネクターＫｍ合することが行われている。現在
一般に使われている熱硬化型の接着剤は加熱時一旦粘度
低下を来たしてから硬化するが、このように接−着剤の
粘度が低下し液状になった時点で予め均一に配列されて
いた光学繊維は配列を乱し、−七のま、ま硬化されるた
め光学線維の配列も均一性を失い、一部の繊維は配列か
ら飛び出したままで固定されるのが現状である。In order to insert optical fibers into these devices, after arranging the optical fibers in advance, they are fixed with adhesive and made into a sheet.
Next, the connector Km is mated. The thermosetting adhesives currently in common use once reduce their viscosity when heated and then harden. At present, the optical fibers are disarranged and cured for a second, so the arrangement of the optical fibers loses uniformity, and some fibers are fixed while sticking out of the arrangement.
鮮明な画瀘を伝送しようとすれば必然的により細い繊維
径の光学繊維を多数本均一に配列することが必要となる
が、加工性はそれに反比例し、１万本近い光学線維を均
一に積層しようと試みた場合幾本もの糸か飛び出した形
となって積層が実際には出来ない状況にある。In order to transmit a clear image, it is necessary to uniformly arrange a large number of optical fibers with a smaller fiber diameter, but the processability is inversely proportional to this, so it is necessary to uniformly stack nearly 10,000 optical fibers. If you try to do this, you will end up with a number of threads sticking out, making it impossible to actually stack the layers.
本発明者らは光学繊維をシート化するＫつき種々検討中
のところ、次のような方法を採用することにより上記し
たような問題点を解消しうることを見°出した。The inventors of the present invention have been investigating various ways to form optical fibers into sheets with K, and have found that the above-mentioned problems can be solved by adopting the following method.
即ち、本発明の要旨とするところは、光学線維をシート
状に配列後、放射線で硬化しうる樹脂液あるいはドライ
フィルムで端部を被覆し、次いで放射線を照射して固化
させて光学繊維−トを製造することにある。That is, the gist of the present invention is that after arranging optical fibers into a sheet, the ends are coated with a resin liquid or dry film that can be cured by radiation, and then the optical fibers are solidified by irradiation with radiation. The purpose is to manufacture.
本発明の光学繊維は無機系又はプラスチック系の芯・鞘
のステップ型光学繊維でもグレーデッド型光学繊維でも
差支えなく使用できるか、好ましくはスデヅ′プ型の鞘
がメタクリル樹脂、芯かポリスチレンもしくはポリカー
ボネート製のもの、あるいは鞘が含弗素系樹脂、芯がメ
タクリル樹脂のもの等が使用される。The optical fiber of the present invention can be used as either a step-type optical fiber or a graded-type optical fiber with an inorganic or plastic-based core and sheath. Preferably, the stepped-type sheath is made of methacrylic resin, and the core is made of polystyrene or polycarbonate. or those whose sheath is made of fluorine-containing resin and whose core is made of methacrylic resin are used.
本発明の光学繊維シートの配列は一列でもよいかそれを
順次積層したようなものであっても何ら差支えない。大
容量の光伝送を行なう時には多数本の光学繊維を何層に
も積層したシートの方か好ましい。The optical fiber sheets of the present invention may be arranged in a single row or may be sequentially laminated. When transmitting a large amount of light, it is preferable to use a sheet in which many optical fibers are laminated in many layers.
放射線硬化型の樹脂としては、例えばＩＣなどの製造に
使用されているレジストが挙げられ、フォトレジスト、
遠紫外ルジスト、電子線レジスト、Ｘ線レジストのよう
な光（紫外線）硬化型、遠紫外線硬化型、電子線硬化型
又はＸ線硬化型の樹脂が使用できる。Examples of radiation-curable resins include resists used in the manufacture of ICs, photoresists,
A light (ultraviolet) curing type, deep ultraviolet curing type, electron beam curing type, or X-ray curing type resin can be used, such as deep ultraviolet resist, electron beam resist, or X-ray resist.
光学繊維が有機重合体よりなる場合には元硬化屋の樹脂
を用いるのが望ましい。When the optical fiber is made of an organic polymer, it is desirable to use a resin produced by a former hardener.
紫外線硬化する樹脂組成は少な（とも架橋性モノマー、
光重合開始剤の２成分からなｌす、目的に応じて皮膜形
成用のペースポリマー、増感剤、密着促進剤、可塑剤等
が添加される。架橋性モノマーとしてはヘキサンジオー
ルジアクリレート、ネオペンチルグリコールジアクリレ
ート、トリメチロールプロパントリアクリレート。The resin composition that cures with UV rays is small (both crosslinking monomers and
It consists of two components: a photopolymerization initiator, and depending on the purpose, a pace polymer for film formation, a sensitizer, an adhesion promoter, a plasticizer, etc. are added. Crosslinking monomers include hexanediol diacrylate, neopentyl glycol diacrylate, and trimethylolpropane triacrylate.
ペンタエリスリトールトリアクリレート、ジペンタエリ
スリトールペンタアクリレート、ジペンタエリスリトー
ルへキサアクリレート等の多価アルコールあるいはポリ
エーテル型多ｉフルコールのアクリル酸構造を持つポリ
オールアクリレート及び多塩基酸と多価アルコールとか
ら得られるポリニスオルのアクリル構造を持つ第１）−
ｆ−ｃｒ−”ｉ”あう、□”ＩＩ：） ｘ ）＜ ’Ｐ
ヤア、ヮッー４ワウレタンアクリレート、エポキシアク
リレート。Polyol acrylates having an acrylic acid structure of polyhydric alcohols or polyether-type polyi-fluorols such as pentaerythritol triacrylate, dipentaerythritol pentaacrylate, and dipentaerythritol hexaacrylate, and polynisols obtained from polybasic acids and polyhydric alcohols. 1) with an acrylic structure of
f-cr-”i” Ai, □”II:) x ) <'P
Yaa, wow! 4 urethane acrylate, epoxy acrylate.
ポリアセタールアクリレート等が単独あるいは混合系で
用いられる。光重合開始剤としてはペンツインアルキル
エーテル、ベンゾフェノン。Polyacetal acrylate and the like can be used alone or in a mixed system. As a photopolymerization initiator, pentwin alkyl ether and benzophenone are used.
ベンジル、２・２−ジメトキシ−２−フェニルアセトフ
ェノン、２．２−ジェトキシアセトフェノン、塩素化ア
セトフェノン誘導体、２−ヒドロキシ−２−メチル−プ
ロピオフェノン、４−イソプロピル−２−ヒドロキシプ
ロピオフェノン。Benzyl, 2,2-dimethoxy-2-phenylacetophenone, 2,2-jethoxyacetophenone, chlorinated acetophenone derivatives, 2-hydroxy-2-methyl-propiophenone, 4-isopropyl-2-hydroxypropiophenone.
４．４′−ビスジエチルアミノベンゾフェノン、チオキ
サントン誘導体、α−アジロキシムエステル等が単独あ
るいは混合系で用いられるばかりでなく増感剤と組合せ
て用いられる。4.4'-Bisdiethylaminobenzophenone, thioxanthone derivatives, α-aziroxime esters, etc. are used not only alone or in a mixed system, but also in combination with a sensitizer.
ドライフィルムを使用する場合は、ドライフィルムの光
学繊維への粘着性及び硬化後の密着性を向上するための
添加剤が必要であるが、こｔＬうはβ−ヒドロキシエチ
ルアクリレート、ヒドロキシエチルメタクリレート、ヒ
ドロキシプロピルアクリレート、ペンタエリスリトール
トリアクリレート等が有効である。前記したような添加
剤は液状樹脂の密着促進にも有効である。When using a dry film, additives are required to improve the adhesion of the dry film to optical fibers and the adhesion after curing, but additives such as β-hydroxyethyl acrylate, hydroxyethyl methacrylate, Hydroxypropyl acrylate, pentaerythritol triacrylate, etc. are effective. The additives mentioned above are also effective in promoting adhesion of liquid resin.
ドライフィルムはペースポリマー、架橋性モノマー、゛
光重合開始剤を主成分としてメチルエチルケトン等の溶
剤に溶解してポリエチレンテレフタレート等のフィルム
上にロー、ルコーティング等の方法で皮膜形成したのち
、強制乾燥して溶剤を除き形成される。Dry film is made by dissolving the main ingredients of a pace polymer, a crosslinking monomer, and a photopolymerization initiator in a solvent such as methyl ethyl ketone, forming a film on a film such as polyethylene terephthalate by a method such as roll coating, and then forcing drying. It is formed by removing the solvent.
電子線硬化型の樹脂としては主Ｋ ＩＣ，ＬＳＩＫ用い
られているネガ型電子線レジストはすべて適用が可能で
ある。As the electron beam curing resin, all negative electron beam resists used in KIC and LSIK can be applied.
ポリグリシジルメタクリレート、グリシジルメタクリレ
ート／エチルアクリレート共重合体。Polyglycidyl methacrylate, glycidyl methacrylate/ethyl acrylate copolymer.
ポリグリシジルメタクリレートのメチルマレイン酸付加
物、グリシジルメタクリレート／スチレン共１合体、
クロロメチル化ポリスチレン等が用いられる。Methyl maleic acid adduct of polyglycidyl methacrylate, glycidyl methacrylate/styrene comonomer,
Chloromethylated polystyrene or the like is used.
遠紫外線硬化型の樹脂としては、例えばポリ２、ａ−シ
ｘゝロモーＮ−７’ロビルアクリレート。Examples of deep ultraviolet curable resins include poly 2, a-cylomo N-7'robyl acrylate.
無水マレイン酸トフルオロアルキルビニルエーテルの共
重合体のアリル化物、クロロメチル化ポリスチレン等の
ネガ型遠紫′外線レジストが用いられる。Negative deep ultraviolet resists such as allylated maleic anhydride trifluoroalkyl vinyl ether copolymers and chloromethylated polystyrene are used.
本発明は数百本、数千本の光学繊維から、例の影響を全
く受けることな（シートを順次積層してゆくことにより
極めて容易に均一な積層体を形成しうるものである。In the present invention, it is possible to form a uniform laminate extremely easily from hundreds or thousands of optical fibers by sequentially laminating sheets (without being affected by the examples).
以下実施例により本発明を具体的に説明する。The present invention will be specifically explained below using Examples.
実施例１
長さ２ｍ、直径０．１２５ｍのメタクリル樹脂系光学繊
維２０本を引揃えて両端部からそれぞれ２０ｃｍのとこ
ろまで次の樹脂組成物を被覆した。Example 1 Twenty methacrylic resin optical fibers having a length of 2 m and a diameter of 0.125 m were arranged and coated with the following resin composition up to 20 cm from both ends.
架橋性上ツマ−としてビスオキシエチレン化ビスフェノ
ールＡジアクリレート６０重量部、β−ヒドロキシエチ
ルアクリレート２５重量部、ペンタエリスリトールトリ
アクリレート１０重量部、光重合開始剤としてベンゾイ
ンイソブチルエーテル５重量部を混合して液状の感光性
樹脂組成物を調整した。次いで被覆部を、厚さ０．０２
５諺に被覆して３０ Ｗ／ｌ♂の高圧水銀灯で２秒照射
して該感光性樹脂層を硬化して第１図のような配列した
光学繊維（１）を硬化樹脂層（２）で被覆してなる光学
繊維シートを得た。60 parts by weight of bisoxyethylated bisphenol A diacrylate as a crosslinkable additive, 25 parts by weight of β-hydroxyethyl acrylate, 10 parts by weight of pentaerythritol triacrylate, and 5 parts by weight of benzoin isobutyl ether as a photopolymerization initiator were mixed. A liquid photosensitive resin composition was prepared. Next, the coating part was made to a thickness of 0.02
The optical fibers (1) arranged as shown in FIG. A coated optical fiber sheet was obtained.
これをコネクター（３）に把持させて、第２図に示すよ
うな光学繊維シートユニットを得た。第３図は単層シー
トを積層した複層光学繊維、シートの斜視図である。This was held by the connector (3) to obtain an optical fiber sheet unit as shown in FIG. FIG. 3 is a perspective view of a multi-layer optical fiber sheet made by laminating single-layer sheets.
実施例２
実施例１に示したものと同様の光学繊維を次に示す粘着
性を有する感光性ドライフィルム上に引揃えて配置し、
実施例１と同様に、両端部からそれぞれ２０ｃＩＬの部
分な箇所の接着を行なった。Example 2 Optical fibers similar to those shown in Example 1 were arranged on a photosensitive dry film with the following adhesive properties,
As in Example 1, adhesion was carried out at 20 cIL from both ends.
ドライフィルムは、ポリエチレンテレフタレートフィル
ム上に、次に示す組成のドープをロールコーティングし
、溶剤を強制蒸発させることにより０．０２５ｍ厚のも
のを得た。ドープはペースポリマーとしてアクリベット
ｖｌ（Ｋ （三菱レイヨン社製のアクリル系樹脂）６０
重量部、ＩＩＩ：
架橋性モノマーとしてポリエチレングリコールジアクリ
レート１５重量部及びペンタエリスリトールトリアクリ
レート１５重量部、光重合間始剤としてｔ−ブチルアン
トラキノン０，５重量部をメチルエチルケト７１００重
量部に溶解して調整した。A dry film having a thickness of 0.025 m was obtained by roll-coating a dope having the composition shown below on a polyethylene terephthalate film and forcing the solvent to evaporate. The dope was Acryvet Vl (K (acrylic resin manufactured by Mitsubishi Rayon Co., Ltd.) 60 as a pace polymer.
Part by weight, III: Prepared by dissolving 15 parts by weight of polyethylene glycol diacrylate and 15 parts by weight of pentaerythritol triacrylate as crosslinkable monomers, and 0.5 parts by weight of t-butylanthraquinone as a photopolymerization initiator in 7100 parts by weight of methyl ethyl keto. did.
光学繊維を並ぺたドライフィルムはポリエチレンテレフ
タレートフィルムの側から３ ｍＷ／ｃｙｘ”の超高圧
水銀灯で不活性かつ雰囲気下２０秒照射して樹脂層を硬
化する。次いでポリエチレンテレフタレートフィルムを
剥離して光学繊維シートを得た。The dry film with the optical fibers is cured by irradiating the polyethylene terephthalate film side with an ultra-high pressure mercury lamp of 3 mW/cyx for 20 seconds in an inert atmosphere.Then, the polyethylene terephthalate film is peeled off and the optical fibers are removed. Got a sheet.
第１図は本発明の方法で得られる光学繊維シートの一例
を示す斜視図、第２図は本発明の方法により得られた光
学繊維シートをペースとしる。
図において（１）は光学繊維、（２）は硬化樹脂層。
（３）はコネクターを示す。
尾２［２１FIG. 1 is a perspective view showing an example of an optical fiber sheet obtained by the method of the present invention, and FIG. 2 is a perspective view showing an example of an optical fiber sheet obtained by the method of the present invention. In the figure, (1) is an optical fiber, and (2) is a cured resin layer. (3) indicates a connector. Tail 2 [21
Claims (1)
液あるいはドライフィルムで端部を被覆し、次いで放射
線を照射して固化させることを特徴とする光学繊維シー
トの製造法。A method for producing an optical fiber sheet, which comprises arranging optical fibers into a sheet, coating the ends with a resin liquid or dry film that can be cured by radiation, and then solidifying by irradiating with radiation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56191281A JPS5893006A (en) | 1981-11-27 | 1981-11-27 | Production of optical fiber sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56191281A JPS5893006A (en) | 1981-11-27 | 1981-11-27 | Production of optical fiber sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5893006A true JPS5893006A (en) | 1983-06-02 |
| JPH0371683B2 JPH0371683B2 (en) | 1991-11-14 |
Family
ID=16271943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56191281A Granted JPS5893006A (en) | 1981-11-27 | 1981-11-27 | Production of optical fiber sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5893006A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61140303U (en) * | 1985-02-22 | 1986-08-30 | ||
| FR2675621A1 (en) * | 1991-04-19 | 1992-10-23 | Swisscab E Kertscher Sa | PROCESS AND INSTALLATION FOR THE MANUFACTURE OF A FLAT CABLE, PARTICULARLY WITH OPTICAL FIBERS. |
| JP2007070112A (en) * | 2005-08-08 | 2007-03-22 | Nippon Sheet Glass Co Ltd | Rack plate with antenna for article control rack, and article control rack using the rack plate with the antenna |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54113348A (en) * | 1978-02-24 | 1979-09-04 | Nippon Telegr & Teleph Corp <Ntt> | Connection of optical fibers |
| JPS5567706A (en) * | 1978-11-15 | 1980-05-22 | Minolta Camera Co Ltd | Focusing type optical transmission body array |
| JPS5588106A (en) * | 1978-12-27 | 1980-07-03 | Sanyo Denki Kk | Controller of machine tool with tool replacing function |
-
1981
- 1981-11-27 JP JP56191281A patent/JPS5893006A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54113348A (en) * | 1978-02-24 | 1979-09-04 | Nippon Telegr & Teleph Corp <Ntt> | Connection of optical fibers |
| JPS5567706A (en) * | 1978-11-15 | 1980-05-22 | Minolta Camera Co Ltd | Focusing type optical transmission body array |
| JPS5588106A (en) * | 1978-12-27 | 1980-07-03 | Sanyo Denki Kk | Controller of machine tool with tool replacing function |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61140303U (en) * | 1985-02-22 | 1986-08-30 | ||
| FR2675621A1 (en) * | 1991-04-19 | 1992-10-23 | Swisscab E Kertscher Sa | PROCESS AND INSTALLATION FOR THE MANUFACTURE OF A FLAT CABLE, PARTICULARLY WITH OPTICAL FIBERS. |
| JP2007070112A (en) * | 2005-08-08 | 2007-03-22 | Nippon Sheet Glass Co Ltd | Rack plate with antenna for article control rack, and article control rack using the rack plate with the antenna |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0371683B2 (en) | 1991-11-14 |
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