JPS5896009A - Powdery cosmetic - Google Patents
Powdery cosmeticInfo
- Publication number
- JPS5896009A JPS5896009A JP19229581A JP19229581A JPS5896009A JP S5896009 A JPS5896009 A JP S5896009A JP 19229581 A JP19229581 A JP 19229581A JP 19229581 A JP19229581 A JP 19229581A JP S5896009 A JPS5896009 A JP S5896009A
- Authority
- JP
- Japan
- Prior art keywords
- water
- substance
- parts
- powders
- cosmetics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 18
- 239000000126 substance Substances 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims description 6
- 229920003169 water-soluble polymer Polymers 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 10
- 239000011230 binding agent Substances 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract description 3
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 abstract description 3
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 abstract description 3
- 239000000839 emulsion Substances 0.000 abstract description 3
- 239000000454 talc Substances 0.000 abstract description 3
- 229910052623 talc Inorganic materials 0.000 abstract description 3
- 235000013799 ultramarine blue Nutrition 0.000 abstract description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 238000004898 kneading Methods 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 230000020477 pH reduction Effects 0.000 abstract 1
- 230000035939 shock Effects 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 10
- 239000010445 mica Substances 0.000 description 7
- 229910052618 mica group Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 235000014593 oils and fats Nutrition 0.000 description 6
- 239000000546 pharmaceutical excipient Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- NEMFQSKAPLGFIP-UHFFFAOYSA-N magnesiosodium Chemical compound [Na].[Mg] NEMFQSKAPLGFIP-UHFFFAOYSA-N 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 241000234479 Narcissus Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- -1 propatool Chemical compound 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、粉末系のメイクアップ化粧料、特に、油脂類
、金属石余等の賦形剤を低減し又は含有しない固型粉末
化粧料に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to powder makeup cosmetics, and particularly to solid powder cosmetics containing less or no excipients such as oils and fats and metal residues.
従来の固型粉末化粧料は、油脂類、金属石余等の賦形剤
を、粉末類と混合し成型しているが、化粧料に用いられ
る粉末の中には油脂類の経時劣化を促進するものも少な
くない。Conventional solid powder cosmetics are molded by mixing excipients such as oils and fats and metal residues with powders, but some of the powders used in cosmetics promote the deterioration of oils and fats over time. There are many things to do.
又凝集力の少ないマイカ系の粉末では、成型助剤として
の油脂類も多量必要とする為、油っぽい、パクト表面が
ケーキング(表面が光る)するといった欠点があった。In addition, mica-based powders with low cohesive force require a large amount of oils and fats as molding aids, so they have the drawbacks of being oily and causing caking (shining) on the pact surface.
本発明者らは、上記欠点を回避し、しかも安定性、使用
性にすぐれた固型粉末化粧料につき鋭意研究の結果、粉
末と、水溶性高分子、水分散性高分子、水膨潤性物質の
一種又は二種以上と混合し、さらに水及び又は含水アル
コール(炭素数3以下の脂肪族アルコールで含水率10
%以上)を加え混練した後、所望の形に成型、乾燥すれ
ば、凝集力の小さな成型性の著しく悪い粉末でも水溶性
高分子、水分散性高分子、水膨潤性物質等が粘結剤とし
て作用し、油脂、金属石余等の賦形剤の量を低減できる
ばかりではなく・全く賦形剤を含有しない処方系でも、
所望の形状に成形でき、しかも、その乾燥品は、耐衝撃
性にすぐれ、油脂等を全く含まないので経時による酸敗
劣化もない。As a result of intensive research into solid powder cosmetics that avoid the above drawbacks and are excellent in stability and usability, the present inventors have discovered powders, water-soluble polymers, water-dispersible polymers, and water-swellable substances. and water and/or hydrous alcohol (an aliphatic alcohol with a carbon number of 3 or less with a water content of 10).
% or more), knead it, mold it into the desired shape, and dry it. Even if the powder has low cohesive force and extremely poor moldability, water-soluble polymers, water-dispersible polymers, water-swellable substances, etc. can be used as a binder. Not only can it reduce the amount of excipients such as oils and fats and metal residues, but it can also reduce the amount of excipients, even in formulations that do not contain any excipients.
It can be molded into a desired shape, and the dried product has excellent impact resistance and does not contain any oil or fat, so it does not deteriorate or become rancid over time.
さらに、湿式1程による製造とも相俟って“粉っぽさ9
の少ないすぐれた使用性の固型粉末化粧料を得ることが
できることを見い出し本発明を完成するに至った。ここ
でいう粉末類とは、化粧料に常用される粉末群で、タル
ク、カオリン、マイカ、炭酸カルシウム、酸化チタン、
亜鉛華、群青、酸化鉄、等の無機系粉末、赤色202号
、赤色204号、赤色226号、黄色401号、青色4
04号等に代表される有機系色素をさす。又粘結剤とし
て用いる水溶性高分子の具体例はカルボキシメチルセル
ロース、メチルセルロース、ハイドロキシエチルセルロ
ース等のセルロース誘導体、ポリビニルアルコール、ポ
リビニルピロリドン等、水分散性高分子とは、酢酸ビニ
ルエマルジョン、アクリル系エマルジョン等、水膨潤性
物質とはマグネシウムアルミニウムシリケート、ナトリ
ウムマグネシウムシリケート等がある。Furthermore, combined with the manufacturing process using a wet process, it has a powdery consistency of 9.
The present inventors have discovered that it is possible to obtain a solid powder cosmetic with excellent usability and little oxidation, and have completed the present invention. The powders mentioned here are a group of powders commonly used in cosmetics, including talc, kaolin, mica, calcium carbonate, titanium oxide,
Inorganic powders such as zinc white, ultramarine blue, iron oxide, etc., Red No. 202, Red No. 204, Red No. 226, Yellow No. 401, Blue 4
Refers to organic dyes such as No. 04. Specific examples of water-soluble polymers used as binders include cellulose derivatives such as carboxymethyl cellulose, methyl cellulose, and hydroxyethyl cellulose, polyvinyl alcohol, and polyvinylpyrrolidone. Water-dispersible polymers include vinyl acetate emulsions, acrylic emulsions, etc. Examples of water-swellable substances include magnesium aluminum silicate and sodium magnesium silicate.
又、本発明の水及び又は含水アルコール(炭素数3以下
の脂肪族アルコールで含水率10%以上)中、含水アル
コールはメタノール、エタノール、プロパツール、イソ
プロパツール等から選ばれる。含水アルコールの含水率
10%以上としたことは、水溶性高分子、水分散性高分
子、水膨潤性物質との粘結性を満足させるための最適な
:iiである。Further, among the water and/or hydrous alcohol (aliphatic alcohol having 3 or less carbon atoms and a water content of 10% or more) of the present invention, the hydrous alcohol is selected from methanol, ethanol, propatool, isopropanol, and the like. Setting the water content of the hydrous alcohol to 10% or more is optimal for satisfying caking properties with water-soluble polymers, water-dispersible polymers, and water-swellable substances.
混合量としては乾燥組成物に対し15〜100%の範囲
が、成型性、作業性、乾燥性等の観点からも好ましい。The mixing amount is preferably in the range of 15 to 100% based on the dry composition from the viewpoint of moldability, workability, drying properties, etc.
さらに本発明の化粧料に、通常の化粧料に使用される、
油脂、香料、薬剤、紫外線吸収剤等を添加する事は、本
発明の趣旨を逸脱するものではない。なお、本発明で用
いる粘結剤の中、水溶性高分子、水分散性高分子につい
ては、乾燥後、皮膜を形成する為、表面を、研磨する工
程を要するので、水膨潤性物質を用いる事が好ましい、
以下に実施例を示す。Furthermore, the cosmetics of the present invention include the following:
Adding oils and fats, fragrances, drugs, ultraviolet absorbers, etc. does not depart from the spirit of the present invention. Among the binders used in the present invention, water-soluble polymers and water-dispersible polymers require a surface polishing process to form a film after drying, so water-swellable substances are used. things are favorable,
Examples are shown below.
実施例(1) アイシャドウ
マイカ80部、群青13部、酸化鉄昧)3部、酸化鉄(
至)2部、ナトリウムマグネシウムシリケ−)28部及
びカルボキシメチルセルロースのNaMIN 02部を
均一に混合し、水仙部を加え混練する。混線物の一定量
を中皿に充填し圧縮成型し、37°Cで乾燥する。Example (1) 80 parts of eyeshadow mica, 13 parts of ultramarine blue, 3 parts of iron oxide, iron oxide (
2 parts of sodium magnesium silicate), 28 parts of sodium magnesium silicate, and 2 parts of NaMIN (carboxymethyl cellulose) are mixed uniformly, and narcissus is added and kneaded. A certain amount of the mixed material is filled into a medium tray, compression molded, and dried at 37°C.
実施例(2)頬 紅
マイカ35部、チタン−マイカ系合成パール剤60部、
赤色226号4部及びポリビニルアルコール1部を均一
に混合し、水50部の混合溶媒100部中に分散し、中
皿に流し込み充填する。50 ”cで乾燥後表面を研摩
し商品とする。Example (2) Cheeks 35 parts of red mica, 60 parts of titanium-mica synthetic pearl agent,
4 parts of Red No. 226 and 1 part of polyvinyl alcohol are uniformly mixed, dispersed in 100 parts of a mixed solvent of 50 parts of water, and poured into a medium plate to fill the mixture. After drying at 50"c, the surface is polished and used as a product.
実m 例(3) ファウンディションカオリン]5部
、マイカ5o部、酸化チタン加部・亜鉛華35部、酸化
鉄1o部、ポリビニルピロリドン1部、香料02部、薬
剤03部を均一に混合しエタノール工部と水15部を加
え混合後、半球型のオジーブに押出し成型し、37°C
で乾燥する。Example (3) 5 parts of foundation kaolin, 5 parts of mica, 35 parts of titanium oxide/zinc white, 1 part of iron oxide, 1 part of polyvinylpyrrolidone, 02 parts of fragrance, and 03 parts of medicine were mixed uniformly and mixed with ethanol. Add 15 parts of water and 15 parts of water, mix, extrude into a hemispherical shape, and heat at 37°C.
Dry with.
実施例(4) 固型白粉
タルク70部、マイカ乙部、酸化鉄2部、マグネシウム
アルミニウムシリケート3部を均一に混合し、水15部
加え混合した後、中皿に圧縮成型し、室温で乾燥する。Example (4) 70 parts of solid white powder talc, 1 part of mica, 2 parts of iron oxide, and 3 parts of magnesium aluminum silicate were mixed uniformly, 15 parts of water was added and mixed, then compression molded into a medium plate and dried at room temperature. .
比較例(1)〜(4)
実施例(1)〜(4)を、単純に乾式混合(水及び含水
アルコールを含まない)し成型する。Comparative Examples (1) to (4) Examples (1) to (4) were simply dry mixed (without water and hydrous alcohol) and molded.
上記実施例(1)〜(4)、比較例(1)〜(4)を尋
問パネル1゜名による官能テスト、成型性(肉眼判定)
、耐衝撃性(70cmの高さより落下)を比較した。The above Examples (1) to (4) and Comparative Examples (1) to (4) were subjected to a sensory test by an interrogation panel of 1 person, and moldability (judgment with the naked eye).
, impact resistance (dropped from a height of 70 cm) was compared.
(成型性) (耐衝撃性) (使用性)実施例(1
) ◎ 0 4比較例(1)
X ×’ 2実施例(2)
◎ 0 4比較例(2) ×°×
2
実施例(3)o ○ 4比較例(3
) X X 3実施例(
4)O○ 5
比較例(4) へ × 3、
使用性は下記の様に6点評価でのび、粉っぽさを中心に
一対比較した。(Moldability) (Impact resistance) (Usability) Example (1)
) ◎ 0 4 Comparative example (1)
X ×' 2 Example (2)
◎ 0 4 Comparative example (2) ×°×
2 Example (3) o ○ 4 Comparative example (3
) X X 3 Examples (
4) O○ 5 To comparative example (4) × 3,
Usability was evaluated on a 6-point scale as shown below, with a focus on spreadability and powderiness.
5点・・・非常に良い、4点・・・かなり良い、3点・
・・良い2点・・・普通・1点・・悪い、0点・・・非
常に悪い以上の結果、本発明の粉末化粧料は成型性、耐
衝撃性、使用性において、優れた効果があることが確認
された。5 points...Very good, 4 points...Very good, 3 points.
2 points: good, 1 point, bad, 0 points: very bad The results show that the powder cosmetic of the present invention has excellent effects in moldability, impact resistance, and usability. It was confirmed that there is.
特許出願人 株式会社 資生堂Patent applicant Shiseido Co., Ltd.
Claims (1)
物質の一種又は二種以上と混合し、水及び又は含水アル
コール(炭素数3以下の脂肪族アルコールで含水率は1
0%以上)を加え混練した後、所望の形に成型し乾燥し
て得られる粉末化粧料。(Li) Mix the powder with one or more of water-soluble polymers, water-dispersible polymers, and water-swellable substances,
0% or more), knead it, mold it into a desired shape, and dry it.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19229581A JPS5896009A (en) | 1981-11-30 | 1981-11-30 | Powdery cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19229581A JPS5896009A (en) | 1981-11-30 | 1981-11-30 | Powdery cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5896009A true JPS5896009A (en) | 1983-06-07 |
Family
ID=16288894
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19229581A Pending JPS5896009A (en) | 1981-11-30 | 1981-11-30 | Powdery cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5896009A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0196110A (en) * | 1987-10-07 | 1989-04-14 | Shiseido Co Ltd | Powdery solid cosmetic |
| JP2003261420A (en) * | 2002-03-06 | 2003-09-16 | Pola Chem Ind Inc | Formative makeup cosmetic |
| JP2008174492A (en) * | 2007-01-18 | 2008-07-31 | Kose Corp | Solid powder cosmetic |
| CN103340815A (en) * | 2013-07-23 | 2013-10-09 | 陆飞 | Foundation make-up for eliminating facial edema |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3800034A (en) * | 1970-12-28 | 1974-03-26 | Kolman Labor Inc | Method for preparing pressed powder makeup sticks and product produced |
| JPS5138432A (en) * | 1974-09-24 | 1976-03-31 | Bitsuguei Kk | Bojohifukeshohin no seizohoho |
| JPS5547605A (en) * | 1978-09-29 | 1980-04-04 | Kao Corp | Compressed powder cosmetic |
-
1981
- 1981-11-30 JP JP19229581A patent/JPS5896009A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3800034A (en) * | 1970-12-28 | 1974-03-26 | Kolman Labor Inc | Method for preparing pressed powder makeup sticks and product produced |
| JPS5138432A (en) * | 1974-09-24 | 1976-03-31 | Bitsuguei Kk | Bojohifukeshohin no seizohoho |
| JPS5547605A (en) * | 1978-09-29 | 1980-04-04 | Kao Corp | Compressed powder cosmetic |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0196110A (en) * | 1987-10-07 | 1989-04-14 | Shiseido Co Ltd | Powdery solid cosmetic |
| JP2003261420A (en) * | 2002-03-06 | 2003-09-16 | Pola Chem Ind Inc | Formative makeup cosmetic |
| JP2008174492A (en) * | 2007-01-18 | 2008-07-31 | Kose Corp | Solid powder cosmetic |
| CN103340815A (en) * | 2013-07-23 | 2013-10-09 | 陆飞 | Foundation make-up for eliminating facial edema |
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