JPS59150538A - 担持された触媒を用いた線状ポリエチレンポリアミンの製造方法 - Google Patents

担持された触媒を用いた線状ポリエチレンポリアミンの製造方法

Info

Publication number: JPS59150538A
Authority: JP; Japan
Prior art keywords: catalyst; phosphorus; reaction; metal oxide; group
Prior art date: 1983-01-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP58245593A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0457B2 (fr

Inventor

ステイ−ブン・ヘンリ−・ヴアンダ−プ−ル

ルイス・ウイリアム・ワツツ・ジユニア

ジヨン・マイケル・ラ−キン

テリ−・リ−・レンケン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Texaco Development Corp

Original Assignee

Texaco Development Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-01-03

Filing date

1983-12-28

Publication date

1984-08-28

1983-12-28 Application filed by Texaco Development Corp filed Critical Texaco Development Corp

1984-08-28 Publication of JPS59150538A publication Critical patent/JPS59150538A/ja

1992-01-06 Publication of JPH0457B2 publication Critical patent/JPH0457B2/ja

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims description 162
-1 polyethylene Polymers 0.000 title claims description 39
238000000034 method Methods 0.000 title claims description 27
229920000768 polyamine Polymers 0.000 title claims description 25
239000004698 Polyethylene Substances 0.000 title claims description 23
229920000573 polyethylene Polymers 0.000 title claims description 23
230000008569 process Effects 0.000 title claims description 10
238000011069 regeneration method Methods 0.000 title description 12
230000008929 regeneration Effects 0.000 title description 11
229910052698 phosphorus Inorganic materials 0.000 claims description 62
239000011574 phosphorus Substances 0.000 claims description 62
238000006243 chemical reaction Methods 0.000 claims description 54
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 51
239000000203 mixture Substances 0.000 claims description 44
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 40
239000002245 particle Substances 0.000 claims description 37
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 34
239000008187 granular material Substances 0.000 claims description 28
229910044991 metal oxide Inorganic materials 0.000 claims description 18
150000004706 metal oxides Chemical class 0.000 claims description 18
239000000047 product Substances 0.000 claims description 18
125000002015 acyclic group Chemical group 0.000 claims description 13
239000007795 chemical reaction product Substances 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
239000007788 liquid Substances 0.000 claims description 12
229910052760 oxygen Inorganic materials 0.000 claims description 10
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
239000001301 oxygen Substances 0.000 claims description 9
238000004519 manufacturing process Methods 0.000 claims description 8
238000010924 continuous production Methods 0.000 claims description 7
239000011261 inert gas Substances 0.000 claims description 7
239000007789 gas Substances 0.000 claims description 4
238000005406 washing Methods 0.000 claims description 3
238000001035 drying Methods 0.000 claims description 2
239000003292 glue Substances 0.000 claims 1
238000010926 purge Methods 0.000 claims 1
230000001172 regenerating effect Effects 0.000 claims 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 72
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 48
239000004408 titanium dioxide Substances 0.000 description 35
229910000147 aluminium phosphate Inorganic materials 0.000 description 24
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 20
238000012360 testing method Methods 0.000 description 19
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical class N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
229910019142 PO4 Inorganic materials 0.000 description 15
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 15
150000001875 compounds Chemical class 0.000 description 14
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical class [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 14
XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 14
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 13
238000004458 analytical method Methods 0.000 description 13
235000021317 phosphate Nutrition 0.000 description 12
GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 11
230000000694 effects Effects 0.000 description 11
229910052757 nitrogen Inorganic materials 0.000 description 9
239000010936 titanium Substances 0.000 description 9
ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 8
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 8
239000010452 phosphate Substances 0.000 description 8
229960001124 trientine Drugs 0.000 description 8
238000010438 heat treatment Methods 0.000 description 7
229910052726 zirconium Inorganic materials 0.000 description 7
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 6
CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(iv) oxide Chemical compound O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 6
239000000126 substance Substances 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
238000002441 X-ray diffraction Methods 0.000 description 5
150000003018 phosphorus compounds Chemical class 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
238000004064 recycling Methods 0.000 description 5
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 5
229910000166 zirconium phosphate Inorganic materials 0.000 description 5
LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
238000006555 catalytic reaction Methods 0.000 description 4
238000000151 deposition Methods 0.000 description 4
238000010304 firing Methods 0.000 description 4
239000000843 powder Substances 0.000 description 4
238000012545 processing Methods 0.000 description 4
239000000376 reactant Substances 0.000 description 4
229910052719 titanium Inorganic materials 0.000 description 4
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
230000032683 aging Effects 0.000 description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000011521 glass Substances 0.000 description 3
239000010410 layer Substances 0.000 description 3
IPNPIHIZVLFAFP-UHFFFAOYSA-N phosphorus tribromide Chemical compound BrP(Br)Br IPNPIHIZVLFAFP-UHFFFAOYSA-N 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 3
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
101100025412 Arabidopsis thaliana XI-A gene Proteins 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 2
150000001260 acyclic compounds Chemical class 0.000 description 2
230000002411 adverse Effects 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
238000004587 chromatography analysis Methods 0.000 description 2
RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 2
239000013078 crystal Substances 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
238000004817 gas chromatography Methods 0.000 description 2
239000010439 graphite Substances 0.000 description 2
229910002804 graphite Inorganic materials 0.000 description 2
150000002391 heterocyclic compounds Chemical class 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
239000012535 impurity Substances 0.000 description 2
239000003456 ion exchange resin Substances 0.000 description 2
229920003303 ion-exchange polymer Polymers 0.000 description 2
KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 2
230000007774 longterm Effects 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000008188 pellet Substances 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
231100000572 poisoning Toxicity 0.000 description 2
230000000607 poisoning effect Effects 0.000 description 2
229920001281 polyalkylene Polymers 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
238000010992 reflux Methods 0.000 description 2
238000004626 scanning electron microscopy Methods 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
238000005549 size reduction Methods 0.000 description 2
238000004513 sizing Methods 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
229910052723 transition metal Inorganic materials 0.000 description 2
150000003624 transition metals Chemical class 0.000 description 2
BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 2
IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
239000001226 triphosphate Substances 0.000 description 2
235000011178 triphosphate Nutrition 0.000 description 2
UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 2
125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical class [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
241000380873 Algon Species 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
241000723368 Conium Species 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
239000005909 Kieselgur Substances 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
206010027783 Moaning Diseases 0.000 description 1
240000002380 Rosa carolina Species 0.000 description 1
241000269851 Sarda sarda Species 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
229910052770 Uranium Inorganic materials 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical group [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
238000001354 calcination Methods 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000003518 caustics Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
150000001923 cyclic compounds Chemical class 0.000 description 1
230000006378 damage Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
IFHGGAJXAGWNSX-UHFFFAOYSA-N diethylamino dihydrogen phosphate Chemical compound CCN(CC)OP(O)(O)=O IFHGGAJXAGWNSX-UHFFFAOYSA-N 0.000 description 1
RPXCCPFIMAPSKP-UHFFFAOYSA-N dimethylamino dihydrogen phosphate Chemical compound CN(C)OP(O)(O)=O RPXCCPFIMAPSKP-UHFFFAOYSA-N 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000003546 flue gas Substances 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
238000000227 grinding Methods 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
229910000449 hafnium oxide Inorganic materials 0.000 description 1
WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
125000001183 hydrocarbyl group Chemical group 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000011630 iodine Chemical class 0.000 description 1
229910052740 iodine Chemical class 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910000398 iron phosphate Inorganic materials 0.000 description 1
WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
229910001960 metal nitrate Inorganic materials 0.000 description 1
XMYQHJDBLRZMLW-UHFFFAOYSA-N methanolamine Chemical compound NCO XMYQHJDBLRZMLW-UHFFFAOYSA-N 0.000 description 1
229940087646 methanolamine Drugs 0.000 description 1
239000000178 monomer Substances 0.000 description 1
LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
VVPXMNQHQWODAR-UHFFFAOYSA-N phosphoric acid titanium Chemical compound [Ti].OP(O)(O)=O VVPXMNQHQWODAR-UHFFFAOYSA-N 0.000 description 1
FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
229920000137 polyphosphoric acid Polymers 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
238000004088 simulation Methods 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000000779 smoke Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000005211 surface analysis Methods 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
238000007725 thermal activation Methods 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
229910000348 titanium sulfate Inorganic materials 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
229910000314 transition metal oxide Inorganic materials 0.000 description 1
DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
125000002264 triphosphate group Chemical class [H]OP(=O)(O[H])OP(=O)(O[H])OP(=O)(O[H])O* 0.000 description 1
229940048102 triphosphoric acid Drugs 0.000 description 1
150000003754 zirconium Chemical class 0.000 description 1
ZVWKZXLXHLZXLS-UHFFFAOYSA-N zirconium nitride Chemical compound [Zr]#N ZVWKZXLXHLZXLS-UHFFFAOYSA-N 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts

Landscapes

Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP58245593A 1983-01-03 1983-12-28 担持された触媒を用いた線状ポリエチレンポリアミンの製造方法 Granted JPS59150538A (ja)

Applications Claiming Priority (8)

Application Number	Priority Date	Filing Date
US45515383A	1983-01-03	1983-01-03
US455158		1983-01-03
US455155		1983-01-03
US455156		1983-01-03
US455159		1983-01-03
US455160		1983-01-03
US553333		1983-11-22
US455153		1989-12-22

Publications (2)

Publication Number	Publication Date
JPS59150538A true JPS59150538A (ja)	1984-08-28
JPH0457B2 JPH0457B2 (fr)	1992-01-06

Family

ID=23807617

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP58245593A Granted JPS59150538A (ja)	1983-01-03	1983-12-28	担持された触媒を用いた線状ポリエチレンポリアミンの製造方法

Country Status (2)

Country	Link
JP (1)	JPS59150538A (fr)
CA (1)	CA1207745A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH03118350A (ja) *	1989-08-08	1991-05-20	Union Carbide Chem & Plast Co Inc	縮合構造を有する金属ポリ燐酸塩縮合触媒を用いるアミン類接触反応
JP2011136871A (ja) *	2009-12-28	2011-07-14	Jgc Catalysts & Chemicals Ltd	リン含有金属酸化物微粒子およびその製造方法、該リン含有金属酸化物微粒子を含む透明被膜形成用塗布液ならびに透明被膜付基材

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US431684A (en) *		1890-07-08		Trolley-pole-supporting mechanism
JPS52209A (en) *	1975-06-02	1977-01-05	Texaco Development Corp	Process for preparing polyalkylenepolyamine
JPS57147441A (en) *	1981-01-26	1982-09-11	Ashland Oil Inc	Carrier for catalyst containing phosphate

1983
- 1983-12-28 JP JP58245593A patent/JPS59150538A/ja active Granted
- 1983-12-30 CA CA000444531A patent/CA1207745A/fr not_active Expired

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US431684A (en) *		1890-07-08		Trolley-pole-supporting mechanism
JPS52209A (en) *	1975-06-02	1977-01-05	Texaco Development Corp	Process for preparing polyalkylenepolyamine
JPS57147441A (en) *	1981-01-26	1982-09-11	Ashland Oil Inc	Carrier for catalyst containing phosphate

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH03118350A (ja) *	1989-08-08	1991-05-20	Union Carbide Chem & Plast Co Inc	縮合構造を有する金属ポリ燐酸塩縮合触媒を用いるアミン類接触反応
JP2011136871A (ja) *	2009-12-28	2011-07-14	Jgc Catalysts & Chemicals Ltd	リン含有金属酸化物微粒子およびその製造方法、該リン含有金属酸化物微粒子を含む透明被膜形成用塗布液ならびに透明被膜付基材

Also Published As

Publication number	Publication date
JPH0457B2 (fr)	1992-01-06
CA1207745A (fr)	1986-07-15

Publication	Publication Date	Title
US4806517A (en)	1989-02-21	Method for making pelleted phosphated catalysts derived from group IVB transition metal oxides and catalysts thus prepared
US4588842A (en)	1986-05-13	Catalytic preparation of linear polyethylenepolyamines
EP0115138B1 (fr)	1988-11-02	Procédé régénérateur pour la préparation de polyéthylènepolyamines linéaires utilisant un catalyseur supporté
US4540822A (en)	1985-09-10	Regenerative process for the preparation of linear polyethylenepolyamines using a supported catalyst
US4582650A (en)	1986-04-15	Oxidation with encapsulated co-catalyst
US4584405A (en)	1986-04-22	Activated carbon catalysts and preparation of linear polyethylene polyamines therewith
US4550209A (en)	1985-10-29	Process for the preparation of linear polyethylenepolyamines by reacting monoethanolamine with ethylenediamine in the presence of an intercalatively active catalyst
CN111498853B (zh)	2021-12-07	多晶硅生产副产氯硅烷高沸物的裂解工艺
US4609761A (en)	1986-09-02	Continuous preparation of linear polyethylenepolyamines using novel catalysts derived from titania and a trialkyl phosphate or phosphite
US4524143A (en)	1985-06-18	Catalyst for preparation of linear polyethylenepolyamines
GB1591307A (en)	1981-06-17	Production of maleic anhydride and catalysts therefor
US4578518A (en)	1986-03-25	Catalytic (calcined catalyst and) preparation of linear polyethylenepolyamines (therewith)
US4612397A (en)	1986-09-16	Use of supported phosphate catalysts for preparation of linear polyethylenepolyamines
EP0331396B1 (fr)	1993-03-10	Procédé de fabrication de Ti-Zr-P catalyseurs et leur utilisation dans la préparation de polyéthylènepolyamines linéaires
US4584406A (en)	1986-04-22	Preparation of linear polyethylenepolyamines with modified catalysts
US4578519A (en)	1986-03-25	Catalytic synthesis of linear polyethylenepolyamines (polyethylenepolyamine preparation and catalyst)
JPS61236753A (ja)	1986-10-22	ジエチレントリアミンの製造法
US4555582A (en)	1985-11-26	Catalytic preparation of linear polyethylenepolyamines [with supported catalyst]
JPH0735356B2 (ja)	1995-04-19	非環状のエチレンアミン類の製造法
JPS59150538A (ja)	1984-08-28	担持された触媒を用いた線状ポリエチレンポリアミンの製造方法
JP3332817B2 (ja)	2002-10-07	メソポーラスシリカおよびその製造方法
JP3811205B2 (ja)	2006-08-16	ジメチルアミンの製法
US4040983A (en)	1977-08-09	Oxidation catalysts and process for preparing same
JPS5888342A (ja)	1983-05-26	アリルアミン類の製法
US2535082A (en)	1950-12-26	Acetonitrile production

JPS59150538A - 担持された触媒を用いた線状ポリエチレンポリアミンの製造方法 - Google Patents

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