JPS59152923A - ポリオキシアルキレンジオ−ル−α，ω−ビスアリルポリカ−ボネ−トの製法 - Google Patents

ポリオキシアルキレンジオ−ル−α，ω−ビスアリルポリカ−ボネ−トの製法

Info

Publication number: JPS59152923A
Authority: JP; Japan
Prior art keywords: reaction; diol; manufacturing; polyoxyalkylene; polyoxyalkylene diol
Prior art date: 1983-02-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP59022062A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0526812B2 (2

Inventor

アルベルト　グレーコ

ググリエルモ　ベルトリーニ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Enichimica Secondaria SpA

Original Assignee

Enichimica Secondaria SpA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-02-11

Filing date

1984-02-10

Publication date

1984-08-31

1984-02-10 Application filed by Enichimica Secondaria SpA filed Critical Enichimica Secondaria SpA

1984-08-31 Publication of JPS59152923A publication Critical patent/JPS59152923A/ja

1993-04-19 Publication of JPH0526812B2 publication Critical patent/JPH0526812B2/ja

Status Granted legal-status Critical Current

Links

238000004519 manufacturing process Methods 0.000 title claims description 18
238000006243 chemical reaction Methods 0.000 claims description 58
150000002009 diols Chemical class 0.000 claims description 44
239000003054 catalyst Substances 0.000 claims description 25
JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 claims description 22
238000005809 transesterification reaction Methods 0.000 claims description 21
239000004417 polycarbonate Substances 0.000 claims description 19
-1 polyoxyethylene Polymers 0.000 claims description 19
229920000515 polycarbonate Polymers 0.000 claims description 18
238000000034 method Methods 0.000 claims description 15
229920001451 polypropylene glycol Polymers 0.000 claims description 15
239000000047 product Substances 0.000 claims description 11
229910052783 alkali metal Inorganic materials 0.000 claims description 9
150000001340 alkali metals Chemical class 0.000 claims description 9
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical group [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 claims description 8
239000007795 chemical reaction product Substances 0.000 claims description 8
238000007306 functionalization reaction Methods 0.000 claims description 8
238000001704 evaporation Methods 0.000 claims description 6
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 5
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 4
229920001577 copolymer Polymers 0.000 claims description 3
150000007522 mineralic acids Chemical class 0.000 claims description 3
150000007524 organic acids Chemical class 0.000 claims description 3
230000035484 reaction time Effects 0.000 claims description 3
229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
125000002947 alkylene group Chemical group 0.000 claims description 2
229910044991 metal oxide Inorganic materials 0.000 claims description 2
150000004706 metal oxides Chemical class 0.000 claims description 2
229910052723 transition metal Inorganic materials 0.000 claims description 2
150000003624 transition metals Chemical class 0.000 claims description 2
229920001281 polyalkylene Polymers 0.000 claims 1
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 42
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
125000002887 hydroxy group Chemical group [H]O* 0.000 description 19
230000001476 alcoholic effect Effects 0.000 description 9
239000012467 final product Substances 0.000 description 8
239000000565 sealant Substances 0.000 description 8
239000000463 material Substances 0.000 description 7
239000002585 base Substances 0.000 description 5
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
239000012535 impurity Substances 0.000 description 4
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
238000009826 distribution Methods 0.000 description 3
229920005862 polyol Polymers 0.000 description 3
150000003077 polyols Chemical class 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
235000011089 carbon dioxide Nutrition 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
239000012530 fluid Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
238000005259 measurement Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
CAEWJEXPFKNBQL-UHFFFAOYSA-N prop-2-enyl carbonochloridate Chemical compound ClC(=O)OCC=C CAEWJEXPFKNBQL-UHFFFAOYSA-N 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000005846 sugar alcohols Polymers 0.000 description 2
239000005046 Chlorosilane Substances 0.000 description 1
QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
229910003609 H2PtCl4 Inorganic materials 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
125000000746 allylic group Chemical group 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
239000007809 chemical reaction catalyst Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 description 1
KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
235000009508 confectionery Nutrition 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
239000004210 ether based solvent Substances 0.000 description 1
238000013467 fragmentation Methods 0.000 description 1
238000006062 fragmentation reaction Methods 0.000 description 1
238000001030 gas--liquid chromatography Methods 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000000178 monomer Substances 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
239000003921 oil Substances 0.000 description 1
238000011017 operating method Methods 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
150000003961 organosilicon compounds Chemical class 0.000 description 1
230000003204 osmotic effect Effects 0.000 description 1
229920005606 polypropylene copolymer Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000012812 sealant material Substances 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/18—Block or graft polymers
- C08G64/183—Block or graft polymers containing polyether sequences
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
- C09K2200/0645—Macromolecular organic compounds, e.g. prepolymers obtained otherwise than by reactions involving carbon-to-carbon unsaturated bonds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Polyesters Or Polycarbonates (AREA)
Sealing Material Composition (AREA)
Polyethers (AREA)

JP59022062A 1983-02-11 1984-02-10 ポリオキシアルキレンジオ−ル−α，ω−ビスアリルポリカ−ボネ−トの製法 Granted JPS59152923A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT19532/83A IT1163093B (it)	1983-02-11	1983-02-11	Policarbonato di poliossialchilendiolo-alfa,omega-bisallile utile quale base per sigillanti e procedimento per la sua preparazione
IT19532A/83		1983-02-11

Publications (2)

Publication Number	Publication Date
JPS59152923A true JPS59152923A (ja)	1984-08-31
JPH0526812B2 JPH0526812B2 (2)	1993-04-19

Family

ID=11158834

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP59022062A Granted JPS59152923A (ja)	1983-02-11	1984-02-10	ポリオキシアルキレンジオ−ル−α，ω−ビスアリルポリカ−ボネ−トの製法

Country Status (6)

Country	Link
US (1)	US4518766A (2)
EP (1)	EP0116993B1 (2)
JP (1)	JPS59152923A (2)
AT (1)	ATE31725T1 (2)
DE (1)	DE3468423D1 (2)
IT (1)	IT1163093B (2)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH051012U (ja) *	1991-06-22	1993-01-08	嘉一郎寺浦	コントロールケーブルのライナー
JP2019532164A (ja) *	2016-09-05	2019-11-07	メルツ＋ベンテリアクチェンゲゼルシャフト	イソシアネートフリー及びイソチオシアネートフリーのアルコキシシランポリマーの製造のための反応体としての有機カーボネート変性プレポリマーの使用

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1191846B (it) *	1986-01-15	1988-03-23	Enichem Sintesi	Composizione organosiliconica fluida e procedimento per la sua preparazione
IT1228546B (it) *	1987-07-31	1991-06-20	Enichem Sintesi	Composizione liquida polimerizzabile in vetri organici dotati di elevata stabilita' termica
IT1283314B1 (it) *	1996-03-28	1998-04-16	Enichem Spa	Processo per la preparazione di policarbonati copolieteri polioli
IT1283315B1 (it) *	1996-03-28	1998-04-16	Enichem Spa	Processo a due stadi per la preparazione di policarbonati copolieteridioli.

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1130285B (it) *	1980-03-05	1986-06-11	Anic Spa	Procedimento per la sintesi di allil carbonati di alcoli poliidrici e loro derivati
US4398008A (en) *	1981-12-07	1983-08-09	Ppg Industries, Inc.	Thick polyol (allyl carbonate) polymerizates and method of preparing same

1983
- 1983-02-11 IT IT19532/83A patent/IT1163093B/it active
1984
- 1984-02-03 US US06/576,869 patent/US4518766A/en not_active Expired - Lifetime
- 1984-02-03 DE DE8484200160T patent/DE3468423D1/de not_active Expired
- 1984-02-03 EP EP84200160A patent/EP0116993B1/en not_active Expired
- 1984-02-03 AT AT84200160T patent/ATE31725T1/de not_active IP Right Cessation
- 1984-02-10 JP JP59022062A patent/JPS59152923A/ja active Granted

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH051012U (ja) *	1991-06-22	1993-01-08	嘉一郎寺浦	コントロールケーブルのライナー
JP2019532164A (ja) *	2016-09-05	2019-11-07	メルツ＋ベンテリアクチェンゲゼルシャフト	イソシアネートフリー及びイソチオシアネートフリーのアルコキシシランポリマーの製造のための反応体としての有機カーボネート変性プレポリマーの使用

Also Published As

Publication number	Publication date
ATE31725T1 (de)	1988-01-15
IT8319532A0 (it)	1983-02-11
EP0116993A2 (en)	1984-08-29
IT1163093B (it)	1987-04-08
EP0116993A3 (en)	1985-08-21
EP0116993B1 (en)	1988-01-07
DE3468423D1 (en)	1988-02-11
US4518766A (en)	1985-05-21
JPH0526812B2 (2)	1993-04-19

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JPS59152923A - ポリオキシアルキレンジオ−ル−α，ω−ビスアリルポリカ−ボネ−トの製法 - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (2)

Family

ID=11158834

Family Applications (1)

Country Status (6)

Cited By (2)

Families Citing this family (4)

Family Cites Families (2)

Cited By (2)

Also Published As

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