JPS59161415A - 不飽和ポリマ−中の炭素−炭素二重結合の水素化方法 - Google Patents

不飽和ポリマ−中の炭素−炭素二重結合の水素化方法

Info

Publication number: JPS59161415A
Authority: JP; Japan
Prior art keywords: reaction; weight; copolymer; temperature; unsaturated polymer
Prior art date: 1983-02-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP59032274A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0441161B2 (2

Inventor

ロ−ソン・ギブソン・ワイドマン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Goodyear Tire and Rubber Co

Original Assignee

Goodyear Tire and Rubber Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-02-22

Filing date

1984-02-22

Publication date

1984-09-12

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23861354&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JPS59161415(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1984-02-22 Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co

1984-09-12 Publication of JPS59161415A publication Critical patent/JPS59161415A/ja

1992-07-07 Publication of JPH0441161B2 publication Critical patent/JPH0441161B2/ja

Status Granted legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims description 42
238000005984 hydrogenation reaction Methods 0.000 title claims description 19
239000011203 carbon fibre reinforced carbon Substances 0.000 title claims description 10
238000006243 chemical reaction Methods 0.000 claims description 56
239000004816 latex Substances 0.000 claims description 38
229920000126 latex Polymers 0.000 claims description 38
238000000034 method Methods 0.000 claims description 34
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 28
229910052751 metal Inorganic materials 0.000 claims description 26
239000002184 metal Substances 0.000 claims description 26
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 24
239000011541 reaction mixture Substances 0.000 claims description 14
239000007800 oxidant agent Substances 0.000 claims description 13
239000000178 monomer Substances 0.000 claims description 12
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 11
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
150000001993 dienes Chemical class 0.000 claims description 10
229920001577 copolymer Polymers 0.000 claims description 9
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 8
238000010438 heat treatment Methods 0.000 claims description 8
239000003638 chemical reducing agent Substances 0.000 claims description 7
244000043261 Hevea brasiliensis Species 0.000 claims description 6
239000000203 mixture Substances 0.000 claims description 6
229920003052 natural elastomer Polymers 0.000 claims description 6
229920001194 natural rubber Polymers 0.000 claims description 6
230000008569 process Effects 0.000 claims description 6
239000012190 activator Substances 0.000 claims description 5
229910021645 metal ion Inorganic materials 0.000 claims description 5
238000010992 reflux Methods 0.000 claims description 5
150000003839 salts Chemical class 0.000 claims description 5
239000005062 Polybutadiene Substances 0.000 claims description 4
150000002432 hydroperoxides Chemical class 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 4
229920001195 polyisoprene Polymers 0.000 claims description 4
239000010949 copper Substances 0.000 claims description 3
229920002857 polybutadiene Polymers 0.000 claims description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
150000004677 hydrates Chemical class 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 4
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims 2
229910017052 cobalt Inorganic materials 0.000 claims 2
239000010941 cobalt Substances 0.000 claims 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
229910052802 copper Inorganic materials 0.000 claims 2
229910052742 iron Inorganic materials 0.000 claims 2
239000011133 lead Substances 0.000 claims 2
229910052759 nickel Inorganic materials 0.000 claims 2
229910052709 silver Inorganic materials 0.000 claims 2
239000004332 silver Substances 0.000 claims 2
239000011135 tin Substances 0.000 claims 2
229910052718 tin Inorganic materials 0.000 claims 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
230000009467 reduction Effects 0.000 description 34
150000001336 alkenes Chemical class 0.000 description 25
238000004458 analytical method Methods 0.000 description 25
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 24
229920001971 elastomer Polymers 0.000 description 20
239000003999 initiator Substances 0.000 description 20
239000005060 rubber Substances 0.000 description 20
229920000459 Nitrile rubber Polymers 0.000 description 12
NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 10
IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 10
230000035484 reaction time Effects 0.000 description 10
239000002518 antifoaming agent Substances 0.000 description 8
238000005481 NMR spectroscopy Methods 0.000 description 6
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
239000011521 glass Substances 0.000 description 6
238000003756 stirring Methods 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
-1 alkylstyrene Chemical class 0.000 description 5
239000003054 catalyst Substances 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
239000000243 solution Substances 0.000 description 5
239000002904 solvent Substances 0.000 description 5
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
229920001400 block copolymer Polymers 0.000 description 4
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
229920005604 random copolymer Polymers 0.000 description 4
239000007787 solid Substances 0.000 description 4
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
239000004809 Teflon Substances 0.000 description 3
229920006362 Teflon® Polymers 0.000 description 3
HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
239000007789 gas Substances 0.000 description 3
238000003760 magnetic stirring Methods 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000007720 emulsion polymerization reaction Methods 0.000 description 2
239000006260 foam Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
229910000510 noble metal Inorganic materials 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000010626 work up procedure Methods 0.000 description 2
HZRUTVAFDWTKGD-JEDNCBNOSA-N (2s)-2,6-diaminohexanoic acid;hydrate Chemical compound O.NCCCC[C@H](N)C(O)=O HZRUTVAFDWTKGD-JEDNCBNOSA-N 0.000 description 1
HIACAHMKXQESOV-UHFFFAOYSA-N 1,2-bis(prop-1-en-2-yl)benzene Chemical compound CC(=C)C1=CC=CC=C1C(C)=C HIACAHMKXQESOV-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
ICGLPKIVTVWCFT-UHFFFAOYSA-N 4-methylbenzenesulfonohydrazide Chemical compound CC1=CC=C(S(=O)(=O)NN)C=C1 ICGLPKIVTVWCFT-UHFFFAOYSA-N 0.000 description 1
GBKBSPOXRLCQRW-UHFFFAOYSA-N C1(CC[C-](CC1)C(C)C)C Chemical compound C1(CC[C-](CC1)C(C)C)C GBKBSPOXRLCQRW-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
241000282412 Homo Species 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
239000004472 Lysine Substances 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
239000003570 air Substances 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
229910000071 diazene Inorganic materials 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
238000009905 homogeneous catalytic hydrogenation reaction Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 1
229940005633 iodate ion Drugs 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
238000010525 oxidative degradation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
JRTYPQGPARWINR-UHFFFAOYSA-N palladium platinum Chemical compound [Pd].[Pt] JRTYPQGPARWINR-UHFFFAOYSA-N 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
230000002688 persistence Effects 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
229920000307 polymer substrate Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation

Landscapes

Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP59032274A 1983-02-22 1984-02-22 不飽和ポリマ−中の炭素−炭素二重結合の水素化方法 Granted JPS59161415A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US468816		1983-02-22
US06/468,816 US4452950A (en)	1983-02-22	1983-02-22	Process for hydrogenation of carbon-carbon double bonds in an unsaturated polymer in latex form

Publications (2)

Publication Number	Publication Date
JPS59161415A true JPS59161415A (ja)	1984-09-12
JPH0441161B2 JPH0441161B2 (2)	1992-07-07

Family

ID=23861354

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP59032274A Granted JPS59161415A (ja)	1983-02-22	1984-02-22	不飽和ポリマ−中の炭素−炭素二重結合の水素化方法

Country Status (9)

Country	Link
US (1)	US4452950A (2)
EP (1)	EP0117221B1 (2)
JP (1)	JPS59161415A (2)
AU (1)	AU559579B2 (2)
BR (1)	BR8400562A (2)
CA (1)	CA1216598A (2)
DE (1)	DE3480401D1 (2)
ES (1)	ES529890A0 (2)
MY (1)	MY100004A (2)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5272202A (en) *	1988-12-29	1993-12-21	Nippon Zeon Co., Ltd.	Hydrogenation process of unsaturated, nitrile-group-containing polymer and aqueous emulsion of hydrogenated polymer
JP2002522603A (ja) *	1998-08-11	2002-07-23	ディーエスエムエヌ．ブイ．	不飽和ポリマーの炭素−炭素二重結合を水素化する方法
JP2003523461A (ja) *	2000-01-27	2003-08-05	ディーエスエムエヌ．ブイ．	ジエンモノマー単位及びニトリル基含有モノマー単位から成る水素化されたポリマーの製造法
WO2005056612A1 (ja) *	2003-12-08	2005-06-23	Nitta Corporation	ゴム状製品又はゴム状物質含有製品
JP2005170994A (ja) *	2003-12-08	2005-06-30	Nitta Ind Corp	ゴム状弾性体とその製造法
JP2006063185A (ja) *	2004-08-26	2006-03-09	Nitta Ind Corp	樹脂改質剤及び該樹脂改質剤を含む樹脂組成物
JP2006131807A (ja) *	2004-11-08	2006-05-25	Nitta Ind Corp	変性ラテックス、及び天然ポリイソプレノイド水素添加物又はその変性体含有製品
JP2007169385A (ja) *	2005-12-20	2007-07-05	Sumitomo Rubber Ind Ltd	タイヤ用ゴム組成物およびそれを用いたサイドウォールを有するタイヤ
JP2007277343A (ja) *	2006-04-04	2007-10-25	Bridgestone Corp	ゴム組成物及びそれを用いた空気入りタイヤ。
JP2008184572A (ja) *	2007-01-31	2008-08-14	Bridgestone Corp	変性水添天然ゴムの製造方法、変性水添天然ゴム、ゴム組成物及びそれを用いた空気入りタイヤ
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Also Published As

Publication number	Publication date
EP0117221A1 (en)	1984-08-29
EP0117221B1 (en)	1989-11-08
BR8400562A (pt)	1984-09-25
US4452950A (en)	1984-06-05
AU2477584A (en)	1984-08-30
JPH0441161B2 (2)	1992-07-07
ES8506329A1 (es)	1985-07-01
CA1216598A (en)	1987-01-13
AU559579B2 (en)	1987-03-12
ES529890A0 (es)	1985-07-01
DE3480401D1 (en)	1989-12-14
MY100004A (en)	1988-10-26

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JPH0441161B2 (2)	1992-07-07
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