JPS59232199A - Detergent composition for machines - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a novel i'N R' cutting composition for processing machines containing a specific water-bathable molecular compound.

For example, hot processing of metal is caused by the heat generated during metal processing in cold rolling machines, press machines, cutting/polishing machines, ll1ll pipe manufacturing machines, and other processing machines that use beak or bearing oil. The pressure applied, the temperature of the lubricating oil, l4 of the water supplied to the processing section as an emulsion of commercial lubricant, and many factors before the formation of active metal powder during milling are affected, and the lubricating oil components (e.g. Fats and oils such as beef tallow and palm oil, mineral oil, synthetic esters, fatty acids) change due to chemical reactions, self-decomposition, etc.
It is well known in the industry that so-called scum, a mixture of metal powder, reaction products of smelt and lubricant components, or decomposition products of lubricant components, is generated.

However, it is extremely important to prevent the generation of scum in machining 4844, and due to the accumulation of scum over time, ■ contamination of the broken workpiece due to adhesion of scum to the broken workpiece, ■ lubricant or Changes in sub-lubricity due to scum mixed into oil emulsion, ie, instability of work,
■Certain problems such as environmental change, ■fire outbreaks, etc.

Therefore, the current way to eliminate these problems is to periodically remove the scum that has adhered to the machine using a washing machine.

Conventionally, this cleaning has been carried out by spraying an alkali type, a neutral type mainly composed of a surfactant, or a petroleum solvent shavings mixed with water. However, these (7) detergents had many advantages and disadvantages, and were not able to produce a total of 14%. In other words, petroleum solvents such as kerosene and solvent naphtha are used as emulsions or in the form of emulsions, which are used to remove ignition and mist. The drawback is that there is a major risk of harmful effects on the human body.In addition, the neutral type emulsifies and disperses the oil and gold in the scum, so there is little risk of flammability. However, the cleaning power is low,
However, since it contains a large amount of surfactant, it takes a long time to process the waste water after cleaning. Furthermore, although the alkaline type has stronger cleaning power than the neutral type, it has lower cleaning power than the petroleum-based abrasive type, and contains an alkaline agent that may harm the worker's body (eyes, skin). It has the disadvantage that it is dangerous if it comes into contact with it.

Under such circumstances, the present inventor has made extensive efforts to provide a cleaning agent for processing machines with scum removal properties that does not have the above-mentioned drawbacks, and as a result, the inventors have used a specific water-soluble molecular compound. As a result, we have discovered a cleansing composition that is safe for the belly button (8) and has completed the present invention, which removes mucus by a mechanism different from that of conventional cleansers.

That is, the present invention is directed to (1) a cationic or amphoteric polycondensation product having a basic or ionic nitrogen atom in the molecule having a molecular weight of 10 to 10 million ft, or a salt thereof; Original ionic polycondensate or its salt having amine p) & in it and ■Olefin-maleic acid copolymer salt, acrylic acid or methacrylic acid-
Maleic acid copolymer, homopolymer of acrylic acid or methacrylic acid, or copolymer salt thereof, 5/, is a group consisting of polymers of acrylamide alkylene sulfonic acid.
) A cleaning agent composition for processing machinery containing a water-bathable cylindrical molecular compound having a water bathing property of at least 1 and 2 or more is provided.

Examples of the ionic and zwitterionic Mid compounds of the water-saturated polymer compound used in the present invention include the following.

■ A homopolymer or two or more of nitrogen-containing cumulative monomers or salts thereof represented by the following general formulas (1) to (IK) (9)
- Copolymer of.

CR1 is H or CE (3, R2 and R5, R51 is an alkyl group having 1 to 6 carbon atoms) [ml is 1 to 3, so nl is a number from 1 to 6, R1.

R2 and R3 are the same as in formula (I)] I 4 [R4+XH′i is an alkyl or alkylol group having 1 to 5 carbon atoms, R1 is the same as in formula (1)] 1 (10) [m2 and n2 are Number from 0 to 5, R1+ R2* R3 is the same as formula (1)] I [:Alj, -0-father is -NH-1R1+ 'R21R
3* n Same as 61 formula (1) and (11)] I CR11'R2t Rs + n''X formula (1) and (■
)] I CR1 is the same as formula (1). The 1a substitution of pyridine is at the 2 or 4 position] 1 (R1r R2 is the same as in formula (1). The @ substitution of piperidine is at the 4 position) 1 [R1, R2, R3 are the same as in formula (1)] Specific examples of these monomers include the following.

■ 5-methacryloxy-2-hyroxyderobyl dimethylamine of the formula (1), 3-methacryloxy-2-hyroxyderobyl ethylmethylamine, 5-methacryloxy-2-hydroxypropyl diethylamine, 6-methacryloxy-2 - and roxyderobildiderobylamine, etc.: (n) of the formula N, N-dimethylamino methylene methacrylate, N, N-dimethylamino ethylene glycol methacrylate, N, N-dimethylaminoglopylene capped ethylene glycol methacrylate, N,N-dimethylaminomethylene capped 7″r diethylene glycol methacrylate, N,N-zomethylaminoethylene capped diethylene glycol methacrylate, N,N-dimethylaminopropylene Capped diethylene glycol methacrylate, N, N-
diethylaminoethylene cadde 1 ethylene glycol methacrylate, N, N-diethylaminoethylene capped ethylene glycol methacrylate, N
, N-diethylaminozolobylene-capped ethylene glycol methacrylate, N,N-diethylaminomethylene-gapped V diethylene glycol methacrylate, N,N-diethylaminoethylene-capped diethylene glycol methacrylate, N,N-diethylaminopropylene-capped diethylene glycol methacrylate, etc. =(N-2-Hyloxymethyl-2-α-methylvinyl imitator*l” of the formula [1)”-A/, N-2-Hyloxyethyl-2-α-methylvinyl imitator 11 units, N- 2-hyroxiderobyl-2-α-methyl-nylimida-door, etc.; Dimethyldimethyleneimine methacrylamide V1 N,N-dimethyldiethyleneimine methacrylamide V
1 N,N-diethylmethyleneimine methacrylamide, N,N-diethylethyleneimine methacrylamide r.

N,N-dimethyldimethyleneimine methacrylamide
, N,N-diethyldiethyleneimine methacrylamide
etc. can be exemplified.

Dimethylaminoethyl acrylate of formula (V), diethylaminoethyl acrylate, dimethylaminoethyl methacrylate, zoethylaminoethyl methacrylate, dimethylaminopropylacrylamide r1 diethylaminopropylacrylamide V, dimethylaminopropylmethacrylamide, diethylaminopropylmethacrylamide v etc; (Vl) dimethylaminomethylethylene, diethylaminomethylethylene, dimethylaminomethylpropene, diethylaminomethylpropene stop;
Vinylpyridine of formula (Ml); (vinylpiperidine of formula Vo, vinyl-N-methylhyheridine, etc.; (IX)
Examples include pinylbay cy/I/amine of the formula, vinyl-N, N-dimethylbenzylamine, and the like.

■ One or more nitrogen-containing monomers represented by the above general formulas (1) to <IX) or their derivatives, and α, β1
- dissonant carboxylic acid or its 1M acid or derivative thereof,
A copolymer of a vinyl compound with a sulfonic acid group or one or more vinyl spinning wheels selected from the group consisting of acrylonitrile, vinylpyrrolidone, and h-group olefins having 2 to 2001 carbon atoms. .

As the body of this vinyl spinning wheel, examples include vinyl pyrrolidone, acrylonitrile; acrylate, methacrylate.
The alkali gold 4 salts of these acids, ammonium chloride, amaic compounds, esterification, vinyl sulfone, methallyl sulfonic acid,
Examples include 2-acrylamido-2-methylpro/sulfonic acid, p-styrenesulfonic acid, or alkali metal salts or ammonium salts of these acids.

■ Ethyleneimine: The 4th episode of Ethyleneimine's death.
7y monium salts or their derivatives.

The repeating unit of this V tool weight is the following general formula (XI
), and the average soup density is 10 to 10 million.

[In the formula, n3G represents an integer of 1 to 5, and n'G represents an integer of 0 to 5.] ■ Aliphatic dicarboxylic acid and polyethylene polyamine or polyoxyethylene alkylamine) 14
d M compound salt or quaternary ammonium salt.

Specifically, the repeating single M is a condensed I compound with a polyethylene polyamine represented by the general formula (Xll) and a v6 polymer with a dipolyoxyethylene alkylamine represented by the general formula (XI [)]. The number before the molecule is 1,000 to 1
There are 0,000,000.

(-QC-R7-CONH-(-R'-NH Masu-5R'
-NH-3-(, xll) [wherein, R7+ edimer acid residue or alkylene group having 1 to 10 carbon atoms, R' is -CH
2CH2-1n5 represents an integer of 2 to 7] [In the formula, R9 is the same as the formula (Xll). R8 is a return 1~
8 alkyl group, RQ 'rZ HSl +1 CH3
, R6 and R7 represent integers of 1 to 100] Examples of the aliphatic dicarzenic acid include dimer acid and adipic acid, and examples of the polyethylene polyamine include:
Diethylenetriamine, triethylenetetramine, etc. 1
Can be used for historical purposes.

■ Dihaloalkane-polyalkylenepolyamine sardine polymer.

Specifically, dihaloalkane such as 'z, 1+2-dichloroethane, 1°2-dibromoethane, i,s-dichloropropane, etc., and 2 ++ffi or more 5 in the molecule.
A quaternary polyamine with a polyalkylene polyamine having a grade amino group
It is a Ma compound with an average molecular weight of 10 to 70 million.

Examples of the polyalkylene polyamines mentioned above include the following.

\ ■ Epihalohydrin-amine-polymerization 1 Of course.

Specifically, repeating units represented by the following general formula (XIV) and having an average molecular weight of 10 to 10 million are excluded.

+0-CH20H-1- In the c formula, T(i'o ~ R12GX CH3g+z C
'2H5, Xe indicates a halogen ion] ■ Chitosan salt In the case of starch 51, it is a cationic product of cellulose.

■ Chamber G Molecule obtained by addition of alkylene oxytra to a polyalkylimine 751'/X derivative having 6 to 200 atoms 1 & 600 to 60,000? ') Ether polyol or polyol polyether I transparent conductor.

The polyalkylene polyamine has five or more consecutive skeletons represented by the following formula (XV) in the molecule, and is preferably a polyethyleneimine containing -C'H2CH2
N ( ( Unfortunately, it is a medium rate polyether polyol.

Po ↑ “It is better to be regretful.

The average molecular weight of the above (ω~■) Rd compound is 100
4 is more preferable between 0 and 100 force.

The following formula (X) is used as acrylamizoalkylene sulfonic acid: 5 heat R^ CR, , R6 &
, n2 is the same as in formula (1v)], and its homopolymer, copolymer of two or more structures, or copolymer with other monomers are used.

Kokohisa's (11-(vl)) is used as a counter ion for these water bathing bacterial molecular compounds.

il+ Phosphoric acid, phosphorous acid, or thio or ester compound thereof (11) Alkyl, alkylaryl, mono- or silicic acid ester having 11 or more hydroxyl groups in the allyl group, or thio compound thereof +1111 having 1 to 8 carbon atoms Heptano- or diphosphinic acid having an alkyl, alkylaryl or allyl group or a thio compound thereof or a derivative thereof +1vl Mono- or diphosphinic acid having an alkyl, alkylaryl or shearyl group having 1 to 8 carbon atoms or a thio compound thereof or These derivatives M Mono- or di- or triphosphonic acid containing a nitrogen atom (vl) Boric acid Specific examples of this phosphoric acid compound include the following. Examples of (1) include orthophosphoric acid, monophosphoric acid, mono- or silicic acid esters of aliphatic, alicyclic, or aromatic alcohols having 1 to 8 carbon atoms and orthophosphorus tY&, or thio compounds thereof. , or phosphite esters with the above-mentioned alcohols, or thio compounds thereof. Examples of (11) include 2-hydroxyloxyderovir phosphate; from methylphosphonic acid, dimethylphosphonic acid with a carbon number of 1 to n-octylphosphonic acid, di-n-octylphosphonic acid with a carbon number of 8, 2 -ethylhexylphosphonic acid, di-2-ethylhexylphosphonic acid,
Examples include benzylphosphonic acid, dibenzylphosphonic acid, phenylphosphonic acid, diphenylphosphonic acid, dioxyethanezophosphonic acid, and cholera thiophosphonic acid. Hydroxyethane diphosphonic acid is a compound represented by the following formula.

OH0M OH Acid, for example, methylphosphinic acid with carbon number 1, dimethylphosphine T'S to n-octylphosphinic acid with carbon number 8, di-n-octylphosphinic acid, 2-ethylhexylphosphinic acid, di-2 -ethylhexylphosphinic acid, benzylphosphinic acid, dibenzylphosphinic acid, phenylphosphinic acid, diphenylphosphine r!,
Examples include ilm and these thiophosphinic acids. M
Examples include hexamethylphosphoric mono(or di)amide and trilotris methylenephosphonic acid.

Nitrilotrismethylenephosphone is a compound represented by the following formula.

CHOH 1' HO-P==0 OH 7JO machine tool cleaner composition 9 of the present invention Of course, the above-mentioned water-soluble polymer compound can be dissolved in one or more drops of water and used as an aqueous solution. is preferable. If necessary, 0.01 to 10 or more (hereinafter simply referred to as %) of a known water-soluble rust preventive/Vi corrosion inhibitor may be added.

For example, chromate, nitrite,
Inorganic compounds such as molybdates, undercarriage phosphates; monoamines, diamines or amines, or their ethoxylation, -base ν salts, dibasic acid storms, naphthenates, phosphates, or the above inorganic compounds. salts of amino acids, alkali salts of amino acids, imidate phosphorus derivatives, quaternary ammonium salts, mercaptopene doria, and pen doria.

When using the processing machine cleaning agent composition of the present invention, the concentration of the water-soluble polymer compound is 100 to 100,000 ppm%, especially 3
00 to 50,000 ppm is preferable. Scum and the like can be combated by spraying this composition onto the area to be cleaned or by dipping the TF4 cleaner into the composition.

Although the details of the cleaning action of the cleaning agent composition of the present invention against scum and the like are not clear, it is generally determined that the cleaning action is as follows. In other words, since the surface tension of the aqueous solution of the water-soluble polymer compound used in the present invention is almost the same as that of water, it does not have the effect of emulsifying or dispersing dirt like a surfactant, but it quickly adsorbs to the dirt surface. The surface of the dirt is coated with the heavy or protective colloid characteristic of polymer compounds to make the dirt hydrophilic, reduce the adhesion caused by agglomeration and coalescence of dirt, and give fluidity. It is thought that the dirt can be easily removed by physical force such as spray pressure.

Therefore, the cleaning agent for processing V% of the present invention has the following features.

■ Easily removes dirt with just a little physical force.

- Since the surface of dirt such as scum is covered with a polymer compound, the removed dirt is not sticky and can be easily disposed of.

■ Since the treated dirt does not emulsify or disperse in water, it can be easily separated from water, making wastewater treatment easier.

■ Since there is little dirt mixed into the water, the cleaning power lasts for a long time.

■ Water-soluble polymer compounds act as flocculants, so
Large wastewater treatment capacity.

■ Since it is neutral, it is safe for the human body.

■ There is no risk of fire or other hazards.

Since the cleaning agent composition of the present invention has the above-mentioned excellent characteristics, it can clean the dirt (scum) generated due to the use of Ioka lubricant during mechanical processing of Kin 4, and can also clean the scum that is generated by using Ioka lubricant. It can also be used to remove dirt caused by processes other than grinding, such as crude oil sludge on the walls of crude oil tanks in tankers, and to clean tar pitch sludge in petroleum and manufacturing equipment.

Next, an example will be given and explained.

Water-soluble polymer compound: (A-1) Phosphate of diethylaminomethyl methacrylate polymer (MW=500,000) (A-2)
(MW = 10,000) (A-3)
(MW=2000)(B-
1) +jlef of diethylaminoethyl methacrylate
l F&/vinylpyrrolidone/sodium acrylate=5/
4/1 (shown as a molar ratio. The same applies hereafter on the wood surface),
0> copolymer (Mw=200,000) (B-2)
(MW = 50,000) (B-3) A copolymer (MW =
5000) (B-4) (M
W=1500)(B-5)
(MW=700) (C-1) Phosphorus v of diethylaminoethyl methacrylate! i@C/sodium methacrylate 415 copolymer (yw=20,000) (C-2) (MW=8
000)(Cj,)(M
W = 1000 ) (D) Phosphorus h of ethyleneimine
Female ring-opening polymer (MW, = 100,000) (E) Ethyl phosphinite of dimethylamine ethyl methacrylate 1 unit/sodium acrylate = 5/1
(Mw = 300,000) (F) Ethylphosphophone of dimethylaminoethyl methacrylate! salt/2
Copolymerization of -acrylamino-2-methylpropanesulfonic acid soda = 4/1! Snout (MW=100,000) (G) Copolymer of vinylpyridine phosphate/male pyrolidine/sodium acrylate=6/3/1 (MW=
450,000) (H) Polycondensate of thiophosphorus I'+1 of diethylenetriamine and dimer acid (MW = 800,000) (1) Phosphate of diethylaminoethylmethacrylaminr/sodium acrylate/sodium vinylsulfonate"
1/1/1 copolymer (MW = 400,000) (J) Copolymerization of vinylpyridine with dimethylphosphinic acid of quaternary ammonium/vinyl vinyl 01J r/sodium acrylate = 6/3/1 9 (MW=45
(K) The phosphate of diethylamine ethyl methacrylamine r of the water-soluble polymer compound (1) is used as the #I acid salt.

(L) Quaternary ammonium salt of cationic modified cellulose (MW = 1 million) (M) Polymer fraction of phosphate of 1,2-dichloroethane and hexamethylenetetramine (MW = 50,000) (N ) Polycondensate of ethyl phosphinate of diethylenetriamine and timer acid (MW = 800,000) (0) Monobocyclic polymer of phosphite of trimethylamine quaternary ammonium compound of shrimp chlorohimin (MW = 100,000) (P) Polycondensate of quaternary ammonium salt of tetramethylpropylenediamine with diethylphosphonic acid (M
W=lQ million) (Q) Water-soluble polymer compound (()) vinylpyridine phosphate converted to sulfate (R) Water-bathable bacterial molecule compound (H) diethylene)
Thiophosphate of I7 amine as nitrate (8)
Water-soluble polymer compound (F) dimethylaminoethyl methacrylate ethyl phosphonate as a 14-acid salt (T) Water-soluble polymer compound (E) dimethylaminoethyl methacrylate ethyl phosphite as glycolic acid Salt (U) Water-soluble polymer compound (D) ethyleneimine+7)+7phosphate as acetate (V) Quaternary ammonium salt of vinylpyridine with dimethyl sulfate/vinylpyrroline/acrylic Acid soda = 6/3/1 combination 1 "Compound () bar = 450,000) (W) #Ethylene oxide of Rie Chishinimine 20
Adduct (MW = 50,000) (X) Polyethyleneimine/ethyleneoxy v/propyleneoxy y = 1. [] / 5 / 5 Adduct (MW = 150,000) (Y) N-1 dimethylsulfoethyl acrylamide alone'IT (compound N1113 (MW = 70,000) (z
) N-1 dimethylsulfoethyl acrylamide r
Phosphorus Iv of a salt/dimethylaminoethyl methacrylate
/Salt=1/1 copolymerization@(MW=20,000) (AA) Phosphonate of ethyleneimine/ethyl phosph of dimethylaminoethyl methacrylate,
I” [t4 = 1/1 copolymer (MW = 60,000) (
BB) Phosphate of 5-methacryloxy-2-hyroxyderobyl trimethylammonium/ethylphosphinate of dimethylaminoethyl methacrylate = 2/1
Copolymer of (MW = 50,000) (CC) Phosphonate of methacrylic dimethylaminoethyl ethoxylate/ethyleneimine-1/1 copolymer (MW - 80,000) (DD) Sodium polyacrylate (MW = 10,000)
(EE) Sol methacrylic acid/maleic anhydride = 2
Copolymer of /1 (MW = 50,000) (FF) Formalin condensate of sodium naphthalene sulfonate (MW = 20,000) Kiyoki agent composition: Comparative products in Table 1 in the margin below. i'i(j 2
#Higura 1 item 462 No. 5 Sodium silicate 48% by weight Sodium tripolyphosphate 40 -Ethylenediaminetetraacetic acid (, Naff1) 5#Boryoxyethylene octyl phenyl ether (addition of 10 moles of EO2) 5I lauryl sulfone fused Na
2' Comparative product 1. Pro5 Kerosene 50 weight petroleum sulfonate 25-oleic acid
5I triethanolamine
Cleanliness test: Each cleaning sword composition for processing machines was diluted with water to a predetermined concentration to prepare a broken sample, which was adjusted to 50'C.

The cleanliness test was carried out using cold i; (1 rolled steel plate (
70 x 100 x O, 2n
) was done by doing. <N cleaning was rated 1 by the 5-stage Ahimaki method based on visual judgment, with 5 indicating that almost no scum was removed, and 1 indicating that most of the scum was removed.
I bent it. The results are as shown in Table 2 of Yoshika Q.

2nd table, column 2 Wastewater treatment test, Kamosei WI4i 1171 degrees 5000 ppm water soluble *< 2
i to ngW, .

- Prepare the oil scum 5 times using a cold oil scum.
Add D D Oppm and stir vigorously for 60 minutes at 60"C.
was defined as exploration b(.

After this suction test 1 (Il, pupil acid bread ± 5.91 arbitrary 0, 2
Minute! Add Ca(OH)2 to the mixture and add 7.0
After adjusting the temperature, the mixture was stirred for 10 minutes. Then 50 minutes of silence Ia
Back down! V solution was collected and COD (KMnO, method) was measured. The results are shown in Table 5.

Table 5 (59) (4o) Procedure Amendment (Method) % Formula % 1. Indication of the case Patent Application No. 108382 of 1988 2. Name of the invention Cleaning agent composition for processing machinery 3. Make the amendment Patent applicant address: 1-14, 1-o, Kayaba-cho, Nihonbashi, Chuo-ku, Tokyo Name (091) Kao Soap Co., Ltd. Representative: Maruta Yoshibe Address: 2-1, Marunouchi, Chiyoda-ku, Tokyo Title name
(412) Nippon Kokan Co., Ltd. Representative Minoru Kaneo 4, Agent address 1-3-6 Nihonbashi Ningyocho, Chuo-ku, Tokyo (
103) 5. Date of amendment order: September 27, 1980 (dispatch) 6. Full text of the specification to be amended 7. Engraving of the specification of the contents of the amendment (changes may be made to the contents) 2-

Claims (1)

[Scope of Claims] (1) ■ A single-field ionic or zwitterionic polycondensate or a salt thereof having a basic ionic nitrogen atom in the molecules of 100 to 10 million molecules, ■ Molecules 441000
~10 million polysilicone polymers with amyl groups in the molecules or their clays and olefin-maleic acid copolymer salts, acrylic acid or methacrylic acid-maleic acid copolymers, acrylic acid or one or more water-bathable polymeric compounds selected from the group consisting of homopolymer salts of methacrylic acid or copolymer salts thereof, or polymers of acrylamide alkylene sulfonic acid as essential noodle ingredients. An mθ agent composition for processing shake, characterized by: (2) A counter ion forming a salt of a water bathable polymer compound or a compound group selected from the following 11) to IVD' + flf! F=Water range 7JD water purifier composition as described in item 1. (1) Phosphoric acid, *, phosphorus or these thioesters &
Ester compound (11) Mono- or puric acid esters having one or more hydroxyl groups in alkyl, alkylaryl or & Also, 9 diphosphonic acid or these thio compounds or these derivatives (lv) Charcoal x
Mono- or di-phosphines having number 1 to 8 alkyl, alkylaryl or allyl groups; thio compounds or derivatives thereof (vl mono- or di- or triposphonic acids containing nitrogen atoms (V+l boric acid (3) water bath) The quick-cutting composition for processing machines according to item 1, wherein the polymeric compound is selected from the group consisting of the following general formulas (1) to (IX). ) A homopolymer or a copolymer of two or more nitrogen-containing monomers or salts thereof. 83 [R1 is H or (CH3, R2 and R3 + Group] 1 [ml is a number from 1 to 3, n"fl is a number from 1 to 5, R1゜R21R3 is the same as formula (1)] 1 4 CRa is H, parent is an alkyl or alkylol group having 1 to 3 carbon atoms , R1 is the formula (1), 'same] (3) [m2 &n''& X Q ~ Z, number, R4 + R2
*R3 is the same as formula (1)] I [A is 10- or -NH-1R1# R2* R3, n
” is the same as formula (1) and (It)] 1 CR1+ R2+ R3+ n” G formula (1) and (
Same as ■)] 1 '& CH=C,, (Vll) [R1 is the same as formula (1). Fermentative rearrangement of pyridine is 2 or 4
] 1 °-C CH2= c N-R2 (vl) [R engineering R2
is the same as equation (1). Piperidine position (4) Substitution is at the 2 or 4 position] I CR1+ R2, R3+"1 Same as formula (1)] ■ @6
one or more salts of nitrogen-containing monomers represented by general formulas (1) to (η); and α. A vinyl spinning wheel selected from the group consisting of β-unsaturated trocarboxylic acid or its salts or derivatives thereof, sulfonic acid group-containing compounds or salts, acrylonitrile, vinylpyrrolidine, and aliphatic olefins having 2 to 20 carbon atoms. A copolymer with one or more of the following compounds: ■ Salts of ring-opened polymers of ethyleneimine or quaternary ammonium salts, or derivatives thereof. ■ Aliphatic dicarnic acids and polyethylene polyamines or dipolyoxyethylene. Salts or quaternary ammonium salts of alkyl amine condensates.■ Dihaloalkane-polyalkylenepolyamine silk polymers.■ Ebihalohydarin-amine condensates.■ Chitosan, starch, or cellulose, or cation-modified products thereof.■ Polyether polyol or polyether polyether derivative having a molecular type of 600,000 to 600,000 obtained by adding alkyleneoxy to a polyalkylimine having 6 to 200 nitrogen atoms or its derivative. (4) Water-soluble bacteria The cleaning agent composition for processing machines according to any one of claims 1 to 3, which is an aqueous solution having a molecular compound concentration of 200 to 100,000 ppm.