JPS5930B2 - Pellet pellets - Google Patents
Pellet pelletsInfo
- Publication number
- JPS5930B2 JPS5930B2 JP50089206A JP8920675A JPS5930B2 JP S5930 B2 JPS5930 B2 JP S5930B2 JP 50089206 A JP50089206 A JP 50089206A JP 8920675 A JP8920675 A JP 8920675A JP S5930 B2 JPS5930 B2 JP S5930B2
- Authority
- JP
- Japan
- Prior art keywords
- die
- feed
- carp
- pellet
- hole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000008188 pellet Substances 0.000 title claims description 37
- 241000252233 Cyprinus carpio Species 0.000 claims description 32
- 238000009313 farming Methods 0.000 claims description 17
- 239000001488 sodium phosphate Substances 0.000 claims description 15
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 15
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 14
- 238000000465 moulding Methods 0.000 claims description 11
- 238000001746 injection moulding Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 230000003750 conditioning effect Effects 0.000 claims description 2
- 239000000203 mixture Substances 0.000 description 18
- 239000004466 pelleted feed Substances 0.000 description 7
- 235000013312 flour Nutrition 0.000 description 6
- 239000011782 vitamin Substances 0.000 description 6
- 229940088594 vitamin Drugs 0.000 description 6
- 229930003231 vitamin Natural products 0.000 description 6
- 235000013343 vitamin Nutrition 0.000 description 6
- 241000209140 Triticum Species 0.000 description 5
- 235000021307 Triticum Nutrition 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 5
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 150000003722 vitamin derivatives Chemical class 0.000 description 4
- 235000019750 Crude protein Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- 235000019733 Fish meal Nutrition 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004467 fishmeal Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 230000000384 rearing effect Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 241000442132 Lactarius lactarius Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 235000019764 Soybean Meal Nutrition 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000021050 feed intake Nutrition 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000004455 soybean meal Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Feed For Specific Animals (AREA)
- Fodder In General (AREA)
- Apparatuses For Bulk Treatment Of Fruits And Vegetables And Apparatuses For Preparing Feeds (AREA)
Description
【発明の詳細な説明】
本発明は養鯉用ペレット飼料の製造方法に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing pellet feed for carp farming.
近年、養鯉用配合飼料の実用化が進み、特にペレット飼
料の普及は著しいものがある。In recent years, the practical use of compound feeds for carp farming has progressed, and the spread of pellet feeds in particular has been remarkable.
通常ペレット飼料は飼料原料混合物を加湿、加熱後ペレ
ット成型機のダイとローラーの間に導き、ダイの小孔を
通して射出成型する。Normally, pellet feed is produced by humidifying and heating a feed raw material mixture, which is then introduced between the die and rollers of a pellet molding machine, and then injection molded through small holes in the die.
このようにペレット化された飼料は栄養成分も均一化さ
れ、食いちうしゃ飛散ロスも少なく魚の成長度合がよく
、かつ給餌作業も非常に簡単で長期間の保存にたえるも
ので非常に実用的である。Feed pelleted in this way has a uniform nutritional content, less loss when eaten and scattered, and the fish grow at a good rate. It is also very easy to feed and can be stored for a long time, making it extremely practical. It is true.
しかしながら、ペレット飼料の製造においてはコンディ
ショナーで加湿。However, when producing pelleted feed, it is humidified using a conditioner.
加熱条件を調整しても、ある種の飼料原料あるいは飼料
原料の配合割合によっては、ダイの小孔を通過する際、
多大な負荷がかかり、飼料原料のダイの通過が非常に困
難なものとなる。Even if the heating conditions are adjusted, depending on the type of feed material or the blending ratio of the feed material, when passing through the small hole of the die,
This imposes a large load and makes it very difficult for the feed material to pass through the die.
例えダイを通過しても、無理に押し出すため、摩擦によ
りダイの温度が必要以上にかあり、ダイ通過がさらに困
難になるという悪循環をおこす。Even if it passes through the die, because it is forced out, the temperature of the die becomes higher than necessary due to friction, creating a vicious cycle in which it becomes even more difficult to pass through the die.
またこのような場合、ペレット成型の能力低下を来たす
のみならず、成型されたペレットは無理に押し出される
ため硬度が過度に上がり、そのため魚の摂餌性も悪く、
かつ過度に加熱されるため、栄養成分例えばビタミン類
等が破壊され、栄養的に満足なペレット飼料とならない
などの問題点がある。In such cases, not only will the ability to mold pellets deteriorate, but the hardness of the molded pellets will increase excessively as they are forced out, making it difficult for fish to eat them.
In addition, since the pellets are heated excessively, nutritional components such as vitamins are destroyed, resulting in problems such as not being able to obtain nutritionally satisfactory pelleted feed.
このようにダイの通過に困難を来たす飼料原料としてリ
ン酸ソーダがある。Sodium phosphate is a feed material that is difficult to pass through the die.
リン酸ソーダを養鯉用飼料に添加すると鯉の骨白り病の
防止および成長促進に有効であるが、前述の通り、リン
酸ソーダを添加し、従来の方法でペレット成型すること
は困難であり、粉末飼料への添加のみに止まっていた。Adding sodium phosphate to carp feed is effective in preventing bone whitening disease and promoting growth in carp, but as mentioned above, it is difficult to add sodium phosphate and form pellets using the conventional method. However, it was only added to powdered feed.
すなわちリン酸ソーダを添加してペレット成型すること
は困難とされていた。That is, it has been considered difficult to form pellets by adding sodium phosphate.
そこで本発明者らは鋭意研究を重ねた結果、ダイの貫通
孔入口と出口の断面積比が1:1.05〜1.50で貫
通孔内で段付となるよう形成したダイを通して射出成型
すれば、リン酸ソーダを添加しても養鯉用ペレット飼料
を成型することができることを知見し、本発明を完成し
た。As a result of extensive research, the inventors of the present invention found that injection molding was performed through a die formed so that the cross-sectional area ratio of the through-hole entrance and exit of the die was 1:1.05 to 1.50, and the through-hole was stepped. They found that it was possible to form pelleted feed for carp farming even when sodium phosphate was added, and completed the present invention.
すなわち、本発明は養鯉用飼料原料にリン酸ソーダを添
加混合し、調湿後ペレット成型機のダイの貫通孔入口と
出口との断面積比がl:1.05〜1.50で貫通孔内
で段付となるように形成したダイを通して射出成型する
ことを特徴とする養鯉用ペレット飼料の製造方法であっ
て、その目的とするところはリン酸ソーダを添加した栄
養的、物性的にすぐれた養鯉用ペレット飼料を安価にか
つ大量に製造する方法を提供することにある。That is, in the present invention, sodium phosphate is added and mixed to the feed raw material for carp cultivation, and after conditioning the humidity, the pellet molding machine is formed so that the cross-sectional area ratio between the inlet and outlet of the die is 1:1.05 to 1.50. A method for producing pellet feed for carp, which is characterized by injection molding through a die formed with steps in the hole. To provide a method for manufacturing excellent pellet feed for carp farming at low cost and in large quantities.
次に本発明をさらに具体的に説明する。Next, the present invention will be explained in more detail.
本発明に使用する養鯉用飼料原料としては、魚粉、大豆
粕、酵母等の蚤白源、小麦粉、米粉、米糠等の炭水化物
源、栄養補強としてのビタミン類やミネラル類、その他
の原料等が挙げられ、鯉の成長度合等に応じて適宜選択
したものを用いることができる。Feed materials for carp farming used in the present invention include fishmeal, soybean meal, flea sources such as yeast, carbohydrate sources such as wheat flour, rice flour, and rice bran, vitamins and minerals for nutritional reinforcement, and other raw materials. These can be appropriately selected depending on the growth level of the carp and the like.
養鯉用飼料原料に添加するリン酸ソーダは可溶性のリン
酸ソーダが望ましく、特に無水の第ニリン酸ソーダが好
ましい。The sodium phosphate added to the feed raw material for carp cultivation is preferably soluble sodium phosphate, and particularly preferably anhydrous sodium diphosphate.
そしてその添加量は0.1係以下では鯉に対する成長促
進の効果が少なく、5%以上は効果が下がるので0.1
〜5%が望ましく、特に好ましいのは0.5〜3チの範
囲である。If the amount added is less than 0.1%, the effect of promoting the growth of carp will be small, and if it is more than 5%, the effect will decrease, so 0.1
-5% is desirable, and a range of 0.5-3% is particularly preferred.
養鯉用飼料原料にリン酸ソーダを添加した混合物は、次
によく混合した後水分含量10〜20%、温度30〜1
00℃となるよう加湿、加温する。The mixture obtained by adding sodium phosphate to the raw material for carp culture feed is then mixed well and then heated to a moisture content of 10-20% and a temperature of 30-10%.
Humidify and heat to 00℃.
そして加湿、加温した原料混合物をペレット成型機のダ
イとローラーの間に導き、ダイの貫通孔入口と出口の断
面積比が1:1.05〜1.50で貫通孔内で段付とな
るように形成したダイを通して射出成型する。Then, the humidified and heated raw material mixture is introduced between the die and roller of the pellet molding machine, and the through-hole is stepped with a cross-sectional area ratio of the inlet and outlet of the die of 1:1.05 to 1.50. Injection molding is performed through a die formed to have the following properties.
本発明の方法に用いられるペレット成型機は通常ペレッ
トミルと称するローラー押出し型の成型機あるいはこれ
と実質上類似の構造を有する成型く〉機を使用すること
ができる。As the pellet molding machine used in the method of the present invention, a roller extrusion molding machine commonly called a pellet mill or a molding machine having a structure substantially similar thereto can be used.
そして、ペレット成型機において使用するダイは輪形の
ダイで、その貫通孔の形状は第1図に示されるような形
状のものであって、ダイ貫通孔の入口径aは給餌対象と
する鯉の成長度合に応じて適宜選択すればよく、またダ
イ貫通孔の出口径すは入口径に比し0,2〜0.3rI
an程度大きくシ、入口と出口の断面積比が1:1.0
5〜1.50になるように形成する。The die used in the pellet molding machine is a ring-shaped die, and the shape of the through hole is as shown in Figure 1. It may be selected appropriately depending on the growth degree, and the exit diameter of the die through hole is 0.2 to 0.3 rI compared to the inlet diameter.
The cross-sectional area ratio of the inlet and outlet is 1:1.0.
5 to 1.50.
断面積比が1:1.05以下ではリン酸ソーダを添加し
た養鯉用飼料原料混合物はダイの通過が困難となり、ま
た断面積比が1:1.50以上になると輪形ダイスにお
けるダイ貫通孔数が制限され、しいては能力低下につな
がる。If the cross-sectional area ratio is less than 1:1.05, it will be difficult for the carp farming feed raw material mixture containing sodium phosphate to pass through the die, and if the cross-sectional area ratio is more than 1:1.50, it will be difficult to pass through the die through-hole in the ring die. The number is limited, which in turn leads to a decline in capacity.
そしてまた貫通孔内で段付にすることが肝要であり、貫
通孔を出口に向って次第に口径が犬となるように形成し
たダイ、すなわちテーパ一孔のダイではリン酸ソーダ添
加の養鯉用飼料原料混合物を満足すべき品質のペレット
飼料に成型することができない。It is also important to step the inside of the through hole, and the die is formed so that the diameter of the through hole gradually becomes dog-shaped toward the exit. The feed raw material mixture cannot be formed into pellet feed of satisfactory quality.
貫通孔内で段を付ける寸法としては、輪形ダイの厚さW
によって異なるが、貫通孔入口よりlO〜20rrvn
の位置で段付にすることが望ましい。The thickness W of the ring die is the dimension for forming a step in the through hole.
Although it varies depending on the
It is desirable to have a step at the position.
本発明に使用するダイの貫通孔径、厚さ1段付寸法の使
用例は第1表の通りである。Table 1 shows an example of the through-hole diameter and one-stage thickness of the die used in the present invention.
本発明の方法による養鯉用ペレット飼料はダイ通過時に
、従来のような大きな抵抗がかからないため、リン酸ソ
ーダを添加しても、ダイ貫通孔において目詰りすること
なくペレット成型することができる。The pelleted feed for carp farming produced by the method of the present invention does not experience a large resistance when passing through the die, so even if sodium phosphate is added, the pellet feed can be formed into pellets without clogging the through holes of the die.
従来の方法でリン酸ソーダを添加した場合は、例えペレ
ット成型することができたとしても能力は極端に落ち、
硬度は非常に高くなり、鯉に給餌した場合、摂餌も悪い
ものであるが、本発明により製造した養鯉用ベレット飼
料は硬度も適当であり、かつ粉化率も硬度に比して多く
ならないことが特長である。When adding sodium phosphate using the conventional method, even if it were possible to form pellets, the ability to form them into pellets would be extremely low.
The hardness becomes very high, and when fed to carp, the feed intake is poor, but the pellet feed for carp farming produced by the present invention has an appropriate hardness and a high powdering rate compared to the hardness. The feature is that it does not.
本発明飼料、市販の養鯉用飼料(リン酸ソーダ無添加)
およびリン酸ソーダを添加し従来のダイでペレット成型
した対照飼料の硬度および粉化率を第2表に示す。Inventive feed, commercially available carp feed (no sodium phosphate added)
Table 2 shows the hardness and pulverization rate of the control feed that was pelletized using a conventional die with the addition of sodium phosphate.
次に本発明の養鯉用ペレット飼料を鯉に給与した場合の
飼育結果を第3表に示す。Next, Table 3 shows the rearing results when carp were fed the pellet feed for carp farming of the present invention.
第3表の飼育結果かられかる通り、本発明の養鯉用ペレ
ット飼料は従来の養鯉用ペレット飼料よりも発育成績が
優れていることがわかる。As can be seen from the rearing results in Table 3, it can be seen that the pellet feed for carp farming of the present invention has better growth results than the conventional pellet feed for carp farming.
またペレットの硬度が低く、鯉に対する摂餌性良いのみ
ならず、輸送中における粉化率が低い等の利点がある。In addition, the pellets have low hardness and have the advantage of not only being good for carp to feed on, but also having a low rate of powdering during transportation.
次に本発明の実施例を示す。Next, examples of the present invention will be shown.
実施例 l
ホワイトフィツシュミール 60%
小 麦 粉 35%
ビタミン混合物 2チ
ミネラル混合物 lチ
上記原料に第ニリン酸ソーダ2qlbを添加した後)水
分含量15チになるよう蒸気で調湿し、この混合物をベ
レット成型機のグイとロールの間に導き、呼径3.2m
mでダイ貫通孔入口と出口の断面積比が1:1.20で
、貫通孔内で段付になるよう形成したダイを用い射出成
型し、次に通風乾燥機にて乾燥して養鯉用ペレット飼料
を得た。Example 1 White fish meal 60% Wheat flour 35% Vitamin mixture 2 Mineral mixture 1 After adding 2 qlb of sodium diphosphate to the above raw materials, the moisture content was adjusted with steam to a moisture content of 15 q, and this mixture was Guided between the goo and roll of the pellet forming machine, nominal diameter 3.2m
The cross-sectional area ratio of the inlet and outlet of the die through-hole is 1:1.20, and injection molding is performed using a die formed so that the through-hole is stepped, and then dried in a ventilation dryer to produce carp for cultivation. pelleted feed was obtained.
この得た養鯉用ペレット飼料の硬度は5.9Kddで粗
蛋白質は42、OSであった。The obtained pellet feed for carp farming had a hardness of 5.9 Kdd, a crude protein of 42, and an OS.
実施例 2
ホワイトフィツシュミール 60チ
小 麦 粉 33%
ビタミン混合物 2%
ミネラル混合物 lチ
上記原料に第ニリン酸ソーダ4チを添加した後・水分含
量14%になるよう蒸気で調湿し、この混合物ヲペレッ
ト成型機のグイとロールの間に導き、呼径4.5閣でダ
イ貫通孔入口と出口の断面積比が1:1.07で、貫通
孔内で段付になるよう形成したダイを用い射出成型し、
次に通風乾燥機にて乾燥して養鯉用ペレット飼料を得た
。Example 2 White Fitzmeal 60% Wheat Flour 33% Vitamin Mixture 2% Mineral Mixture 4% Sodium Diphosphate was added to the above raw materials and the humidity was adjusted with steam to a moisture content of 14%. The mixture was introduced between the guide and the roll of the pellet molding machine, and a die was formed with a nominal diameter of 4.5 mm and a cross-sectional area ratio of the entrance and exit of the die through-hole of 1:1.07, so that the through-hole was stepped. Injection molded using
Next, it was dried in a ventilation dryer to obtain pelleted feed for carp farming.
このようにして得た養鯉用ペレット飼料の硬度は6.
I Kti/cmで粗蛋白質は41.7%であった。The hardness of the pellet feed for carp farming thus obtained was 6.
Crude protein was 41.7% at I Kti/cm.
対照例 1
ホワイトフィツシュミール 60%
小 麦 粉 35%
ビタミン混合物 2係
ミネラル混合物 1チ
上記原料に第ニリン酸ソーダ2チを添加した後、水分含
量15%になるよう蒸気で調湿し、この混合物をペレッ
ト成型機のダイとロールの間に導き、従来より用いられ
ている呼径3.2mmでダイ貫通口入口と出口の大きさ
が同ニなダイを用い射出成型した。Comparative Example 1 White Fitzmeal 60% Wheat Flour 35% Vitamin Mixture 2nd Class Mineral Mixture After adding 2 parts of sodium diphosphate to the above raw materials, the humidity was adjusted with steam to a moisture content of 15%. The mixture was introduced between a die and a roll of a pellet molding machine, and injection molded using a conventionally used die with a nominal diameter of 3.2 mm and an inlet and an outlet of the die through-hole of the same size.
しかしすぐに目詰を起し、成型不能となったので、原料
混合物の送り量を極端に少なくし少量を成型し、通風乾
燥機にて乾燥した。However, it quickly became clogged and could not be molded, so the feed rate of the raw material mixture was extremely reduced, a small amount was molded, and it was dried in a ventilation dryer.
得られた養鯉用ペレット飼料の約半分はダイ通過の際の
摩擦熱により焦げた色がつき、養鯉用飼料として不適正
なものとなった。Approximately half of the pelleted feed for carp farming that was obtained had a burnt color due to the frictional heat during passage through the die, making it unsuitable as feed for carp farming.
養鯉用飼料として給与可能なペレットの硬度は13.5
KV/crr1で粗蛋白質は42.0%であった。The hardness of pellets that can be fed as carp feed is 13.5.
The crude protein in KV/crr1 was 42.0%.
対照例 2
ホワイトフィツシュミール 60係
小 麦 粉 33チ
ビタミン混合物 2%
ミネラル混合物 lチ
上記原料に第ニリン酸ソーダ4%を添加し、水分含量1
4%になるよう蒸気で調湿し、この混合物をペレット成
型機のダイとロールの間に導き、呼径4.5mでダイ貫
通孔を出口に向って次第に口径が大となるよう成形した
ダイを用い射出成型した。Control Example 2 White Fitzmeal 60% Wheat Flour 33% Vitamin Mixture 2% Mineral Mixture 4% Sodium Diphosphate was added to the above raw materials and the water content was 1%.
The humidity was adjusted with steam to 4%, and this mixture was introduced between the die and roll of a pellet molding machine, and a die was formed with a nominal diameter of 4.5 m so that the diameter of the die through hole gradually increased toward the exit. It was injection molded using.
しかしながらダイの通過に大きな負荷がかかり、目詰り
を起しやすく、成型不能となった。However, a large load was applied to passing through the die, and clogging easily occurred, making molding impossible.
第1図はダイの貫孔部の断面図である。 FIG. 1 is a cross-sectional view of the through-hole portion of the die.
Claims (1)
後ペレット成型機のダイの貫通孔入口と出口との断面積
比が1:1.05〜1,50で貫通孔内で、段付となる
よう形成したダイを通して射出成型することを特徴とす
る養鯉用ペレット飼料の製造方法。1. Sodium phosphate is added to and mixed with the feed raw material for carp cultivation, and after conditioning the humidity, it is mixed in the through-hole with a cross-sectional area ratio of the through-hole inlet and outlet of the die of a pellet molding machine of 1:1.05 to 1,50, A method for producing pellet feed for carp farming, characterized by injection molding through a die formed so as to be stepped.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP50089206A JPS5930B2 (en) | 1975-07-23 | 1975-07-23 | Pellet pellets |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP50089206A JPS5930B2 (en) | 1975-07-23 | 1975-07-23 | Pellet pellets |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5216396A JPS5216396A (en) | 1977-02-07 |
| JPS5930B2 true JPS5930B2 (en) | 1984-01-05 |
Family
ID=13964233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50089206A Expired JPS5930B2 (en) | 1975-07-23 | 1975-07-23 | Pellet pellets |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5930B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5992394B2 (en) * | 2013-12-20 | 2016-09-14 | ジェックス株式会社 | Solid food for ornamental fish |
| CN105029009A (en) * | 2015-07-03 | 2015-11-11 | 池州清源钓鱼用品有限责任公司 | Rice wine fermented carp feed and preparation method thereof |
-
1975
- 1975-07-23 JP JP50089206A patent/JPS5930B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5216396A (en) | 1977-02-07 |
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