JPS5941726B2 - Filling material for pillows - Google Patents
Filling material for pillowsInfo
- Publication number
- JPS5941726B2 JPS5941726B2 JP4497476A JP4497476A JPS5941726B2 JP S5941726 B2 JPS5941726 B2 JP S5941726B2 JP 4497476 A JP4497476 A JP 4497476A JP 4497476 A JP4497476 A JP 4497476A JP S5941726 B2 JPS5941726 B2 JP S5941726B2
- Authority
- JP
- Japan
- Prior art keywords
- polystyrene
- ammonium salt
- quaternary ammonium
- alkylamide
- filling material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Bedding Items (AREA)
Description
【発明の詳細な説明】
本発明は帯電防止能と放熱電性の優れたポリスチロール
製球状体からなる枕用充填材vc関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a pillow filler VC made of polystyrene spherical bodies with excellent antistatic ability and heat dissipation.
一般にストレスの解消のためには安眠が何にもまして重
要であり、そのためには快適な寝具が必要であるが、そ
の寝具のうちふとんについてはかなり研究が進んでいる
が、安外見過ごされているのが枕である。In general, a good night's sleep is more important than anything else in order to relieve stress, and for that purpose, comfortable bedding is necessary.Although there has been considerable research into futons, they are often overlooked. What is there is a pillow.
安眠のためには枕の大きさ、高さなども重要な要因であ
るが、最も重要なのは頭を冷やして足を暖める効果、即
ち頭寒足熱の効果である。The size and height of the pillow are important factors for a good night's sleep, but the most important is the effect of cooling the head and warming the feet, that is, the effect of cooling the head and warming the feet.
枕用充填材としては従来よりソバガラ、モミガラ、アズ
キなどが使われているが最近に到りパンヤ、合成綿など
も使用されるようになった。Buckwheat hulls, rice hulls, adzuki beans, etc. have traditionally been used as fillers for pillows, but recently, panya, synthetic cotton, etc. have also come into use.
そして風合、放熱性(頭寒足熱性)の点からソバガラが
最もよいとされていた。Buckwheat was considered the best in terms of texture and heat dissipation (keeps the head cold and keeps the feet warm).
しかしながらソバガラはソバの国内生産の減少(はとん
ど中国からの輸入)に加えて圧縮梱包ができないことか
ら輸送上の困難性もあり、ソバガラなみの風合と放熱性
を持った代替品が強く要望されていた。However, in addition to the decline in domestic production of buckwheat (mostly imported from China), there are also transportation difficulties due to the inability to compress buckwheat, so there is no substitute for buckwheat that has the texture and heat dissipation properties of buckwheat. It was strongly requested.
かNる代替品として表面を滑性処理した合成樹脂製小球
が用いられることが知られている(実開昭47−571
7号公報参照)が、単に表面を滑性処理した合成樹脂製
小球は、これを充填して枕とした場合、放熱性が充分で
なくまた重く持ち運びが不便であり、さらに帯電性が大
きいため、使用時に放電を起し人体にショックを与えた
り、塵を吸着し汚れが目立つ等の欠点を持っている。It is known that small balls made of synthetic resin whose surface has been treated to make them slippery can be used as an alternative to this (Utility Model Publication No. 47-571).
(Refer to Publication No. 7) However, when filled with synthetic resin pellets whose surface has been treated to make them slippery, they do not have sufficient heat dissipation, are heavy and inconvenient to carry, and are highly electrostatically charged. Therefore, they have drawbacks such as causing electrical discharge during use, which can cause shock to the human body, and attracting dust, which makes dirt conspicuous.
本発明者はこれら従来の枕用充填材についての欠点を克
服し、放熱性と帯電防止能に優れた合成樹脂小球につい
て研究した結果、特定の発泡倍率と大きさを有する発泡
ポリスチロール製球状体であって、その表面を特定の帯
電防止剤で被覆した球状体が放熱性と帯電防止能に優れ
、持ち運びが容易である枕を与えることを見出し本発明
に到達した。The present inventor overcame the drawbacks of these conventional pillow fillers and researched synthetic resin globules with excellent heat dissipation and antistatic properties. The inventors have discovered that a spherical body whose surface is coated with a specific antistatic agent can provide a pillow that has excellent heat dissipation and antistatic properties and is easy to carry.
即ち本発明は平均発泡倍率が20〜30倍の球状発泡ポ
リスチロールの外側を厚さが0.001〜1.0關の非
発泡ポリスチロールで被覆し、さらにその表面をアルキ
ルドアミド第4級アンモニウム塩で被覆した外径が3〜
10mmのポリスチロール製球状体からなる枚用充填材
である。That is, in the present invention, the outside of spherical expanded polystyrene with an average expansion ratio of 20 to 30 times is coated with non-foamed polystyrene with a thickness of 0.001 to 1.0 times, and the surface is further coated with a quaternary alkylamide. The outer diameter coated with ammonium salt is 3~
This is a sheet filler made of 10 mm polystyrene spheres.
本発明の充填材は頭とのなじみから球状体に構成されて
いることを必要とする。The filler of the present invention needs to have a spherical shape in order to fit in with the head.
即ち球状体であれば就寝時及び寝返り時充填材の移動が
容易であり頭の形に順応する。That is, if the filling material is spherical, it is easy to move when sleeping or turning over, and it adapts to the shape of the head.
本発明において球状発泡ポリスチロールは平均発泡倍率
が5〜30倍好ましくは10〜20倍である。In the present invention, the spherical expanded polystyrene has an average expansion ratio of 5 to 30 times, preferably 10 to 20 times.
平均発泡倍率が5倍より小さくてもまた30倍より大き
くても熱放散性が悪くなる。If the average expansion ratio is smaller than 5 times or larger than 30 times, the heat dissipation property will be poor.
(通常快適な枕として必要な熱放散性は熱伝導率にとし
て3〜5×10−10−4ca1cIrL−1sec−
1deである。(The heat dissipation required for a comfortable pillow is usually 3 to 5 x 10-10-4ca1cIrL-1sec-
It is 1de.
平均発泡倍率がとくK10〜20倍である場合は熱放散
性が良好なうえに破壊強度が高く長期間の使用にも耐え
得る。When the average expansion ratio is particularly K10 to 20 times, the heat dissipation property is good and the breaking strength is high, so that it can withstand long-term use.
本発明においてポリスチロール製球状体は移動及び圧縮
応力に対する安定性の面から外殻構造をなすことが必要
である。In the present invention, it is necessary for the polystyrene spherical body to have an outer shell structure from the viewpoint of stability against movement and compressive stress.
即ち発泡ポリスチロール球状体の外側を厚さが0.00
1〜1.0mmの非発泡ポリスチロールで被覆されてい
る必要がある。That is, the outside of the expanded polystyrene sphere has a thickness of 0.00.
It must be covered with 1-1.0 mm of non-foamed polystyrene.
そしてこの非発泡ポリスチロールで被覆したその上をさ
らにアルキルアミド第4級アンモニウム塩で被覆する。The unfoamed polystyrene is further coated with an alkylamide quaternary ammonium salt.
このようにすることによってポリスチロール製球状体を
充填した枕の帯電防止性を著しるしく改善することがで
きる。By doing so, the antistatic properties of the pillow filled with polystyrene spheres can be significantly improved.
アルキルアミド第4級アンモニウム塩としては例えばス
テアリン酸アミド第4級アンモニウム塩、パルミチン酸
アミド第4級アンモニウム塩があり、これらの塩として
は特に硝酸塩が好ましい。Examples of the alkylamide quaternary ammonium salts include stearic acid amide quaternary ammonium salts and palmitic acid amide quaternary ammonium salts, and nitrates are particularly preferred as these salts.
アルキルアミド第4級アンモニウム塩としてとくにエフ
コール#70(登録商標松本油脂株式会社製)が好適に
用いられる。Efcol #70 (registered trademark, manufactured by Matsumoto Yushi Co., Ltd.) is particularly preferably used as the alkylamide quaternary ammonium salt.
発泡ポリスチロール球状体の球径は3〜10mm好まし
くは4〜8mmである。The spherical diameter of the expanded polystyrene sphere is 3 to 10 mm, preferably 4 to 8 mm.
この球径が3mmより小さくても、また10朋より大き
くてもこれを充填した枕の熱放散は悪くなる。Even if the sphere diameter is smaller than 3 mm or larger than 10 mm, the heat dissipation of the pillow filled with it will be poor.
球径が5〜7mmのときは熱放散性がと(に良好であり
、この球状体を充填した枕は頭を載せたときの感触がよ
く安眠を誘うためには最も適している。When the sphere diameter is 5 to 7 mm, heat dissipation is very good, and a pillow filled with these spheres feels good when you rest your head on it, making it most suitable for inducing a good night's sleep.
本発明の枚用充填材を図面をもって説明すると第1図及
び第2図のごとくである。The sheet filling material of the present invention will be explained with reference to the drawings as shown in FIGS. 1 and 2.
第1図は本発明の性用充填である球状体の側面図で示し
、第2図はその断面図を示す。FIG. 1 shows a side view of a spherical body which is a sexual filler of the present invention, and FIG. 2 shows a cross-sectional view thereof.
1はアルキルアミド第4級アンモニウム塩の塗布層、2
は球状発泡ポリスチロールの外殻部即ち非発泡ポリスチ
ロール層、3は球状発泡ポリスチロールの充実部、4は
球状発泡ポリスチロールの気泡を示す。1 is a coating layer of alkylamide quaternary ammonium salt, 2
3 shows the outer shell part of the spherical expanded polystyrene, that is, the non-expanded polystyrene layer, 3 shows the solid part of the spherical expanded polystyrene, and 4 shows the cells of the spherical expanded polystyrene.
本発明のポリスチロール製球状体を製造するには、ポリ
スチロールのチップな押出機にて成型する際、押出機内
で空気の注入又は発泡材により発泡せしめながらよく混
合して溶融ポリスチロールを冷水中に滴下せしめ瞬間(
急速)冷却することにより表面張力及び凝縮作用により
外殻部即ち非発泡ポリスチロールの層を有する球状体と
する方法を用いるのがよい。In order to produce the polystyrene spherical bodies of the present invention, when molding the polystyrene chips using an extruder, the molten polystyrene is thoroughly mixed while being injected with air or foamed with a foaming material in the extruder. At the moment when it is dripped (
It is preferable to use a method in which the sphere is formed into a spherical body having an outer shell, that is, a layer of unexpanded polystyrene, due to surface tension and condensation by rapid cooling.
そしてこのような方法で得られた球状体にアルキルアミ
ドアンモニウム塩を被覆する。Then, the spherical bodies obtained by such a method are coated with an alkylamide ammonium salt.
この被覆の方法としては球状体をアルキルアミドアンモ
ニウム塩の水溶液又は水分散液中に浸漬後乾燥するか又
は球状体にアルキルアミドアンモニウム塩の水溶液又は
水分散液を吹きつげた後乾燥する方法がある。Methods for this coating include immersing the spherical body in an aqueous solution or dispersion of an alkylamide ammonium salt and then drying it, or spraying an aqueous solution or dispersion of an alkylamide ammonium salt onto the spherical body and then drying it. .
以下実施例を挙げて本発明について詳述する。The present invention will be described in detail below with reference to Examples.
実施例
ポリスチロールのチップを押出機で溶融し攪拌中に空気
を注入して混合する。Example Polystyrene chips are melted in an extruder and mixed by injecting air during stirring.
次いで押出機のノズルより溶融ポリスチロールを冷水中
に滴下せしめることにより表面張力による球状化と同時
に凝縮による外殻即ち非発泡ポリスチロール層を形成を
行わしめて下記の性能のポリスチロール製球状体を製造
した。Next, by dropping the molten polystyrene into cold water from the nozzle of the extruder, it is spheroidized by surface tension and simultaneously formed by condensation to form an outer shell, that is, a non-foamed polystyrene layer, to produce a polystyrene spherical body with the following performance. did.
このポリスチロール製球状体にx 7−1−/l/#
70の水分散液を吹きつげた後乾燥して枚用充填材を得
た。x 7-1-/l/# in this polystyrene spherical body
After spraying an aqueous dispersion of No. 70, it was dried to obtain a sheet filler.
この枚用充填材1.2kgをナイロン織物製袋に入れそ
の上にポリエステル/綿−65/35混紡織物のカバー
(プリント加工)を装着した結果熱放散性の高い、帯電
防止性の優れた枕が得られた。1.2 kg of this sheet filler was placed in a nylon fabric bag and a polyester/cotton 65/35 blend fabric cover (printed) was placed on top of it, resulting in a pillow with excellent heat dissipation and antistatic properties. was gotten.
【図面の簡単な説明】
第1図は本発明の枕用充填材であるポリスチロール製球
状体の側面図を示し、第2図はその断面図を示す。BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 shows a side view of a polystyrene spherical body which is a filling material for a pillow according to the present invention, and FIG. 2 shows a cross-sectional view thereof.
Claims (1)
ルの外側を厚さが0.001〜1.0mmの非発泡ポリ
スチロールで被覆し、さらにその表面をアルキルアミド
第4級アンモニウム塩で被覆した外径が3〜10mmの
ポリスチロール製球状体からなる枕用充填材。 2 アルキルアミド第4級アンモニウム塩がステアリン
酸アミド第4級アンモニウム塩及び/又はパルミチン酸
アミド第4級アンモニウム塩である特許請求の範囲第1
項記載の枕用充填材。 3 アルキルアミド第4級アンモニウム塩がアルキルア
ミド第4級アンモニウム硝酸塩である特許請求の範囲第
1項又は第2項記載の枕用充填剤。 4 平均発泡倍率が10〜20倍である特許請求の範囲
第1項〜第3項記載の枕用充填材。 5 ポリスチロール製球状体の外径が4〜8%である特
許請求の範囲第1項〜第4項記載の枕用充填材。[Claims] 1. The outside of a spherical foamed polystyrene with an average expansion ratio of 5 to 30 times is covered with non-foamed polystyrene with a thickness of 0.001 to 1.0 mm, and the surface is further covered with alkylamide quaternary polystyrene. A filling material for pillows consisting of polystyrene spheres with an outer diameter of 3 to 10 mm coated with grade ammonium salt. 2. Claim 1, wherein the alkylamide quaternary ammonium salt is a stearic acid amide quaternary ammonium salt and/or a palmitic acid amide quaternary ammonium salt.
Filling material for pillows as described in section. 3. The pillow filler according to claim 1 or 2, wherein the alkylamide quaternary ammonium salt is an alkylamide quaternary ammonium nitrate. 4. The pillow filling material according to claims 1 to 3, which has an average expansion ratio of 10 to 20 times. 5. The pillow filler according to claims 1 to 4, wherein the polystyrene spherical bodies have an outer diameter of 4 to 8%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4497476A JPS5941726B2 (en) | 1976-04-22 | 1976-04-22 | Filling material for pillows |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4497476A JPS5941726B2 (en) | 1976-04-22 | 1976-04-22 | Filling material for pillows |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52128756A JPS52128756A (en) | 1977-10-28 |
| JPS5941726B2 true JPS5941726B2 (en) | 1984-10-09 |
Family
ID=12706435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4497476A Expired JPS5941726B2 (en) | 1976-04-22 | 1976-04-22 | Filling material for pillows |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5941726B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58196667U (en) * | 1982-06-24 | 1983-12-27 | 棚橋 胖 | cooling pillow |
| JPS60126066U (en) * | 1984-02-06 | 1985-08-24 | 株式会社 ナツク科学研究所 | pillow |
| JPS60128570U (en) * | 1984-02-08 | 1985-08-29 | 古越 清 | pillow |
| EP2688447A2 (en) * | 2011-03-21 | 2014-01-29 | Polar Generation LLC | Cooling pillow |
-
1976
- 1976-04-22 JP JP4497476A patent/JPS5941726B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS52128756A (en) | 1977-10-28 |
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