JPS5953580A - Cathode-ray tube having high resolving power - Google Patents
Cathode-ray tube having high resolving powerInfo
- Publication number
- JPS5953580A JPS5953580A JP16363382A JP16363382A JPS5953580A JP S5953580 A JPS5953580 A JP S5953580A JP 16363382 A JP16363382 A JP 16363382A JP 16363382 A JP16363382 A JP 16363382A JP S5953580 A JPS5953580 A JP S5953580A
- Authority
- JP
- Japan
- Prior art keywords
- light
- afterglow
- component
- phosphor
- fluorescent substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Luminescent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は高解像度陰極層j管(tC関し、さ1:)に許
しくは長残光性の縁、赤、了jの各51.光成句右′光
体からなる侶光膜を冶I″る高11」・4 f’yζj
及欧トす4Rい管にし’、1−1−るものでス)、ろ3
、周知のように一部の白黒IS、・i l1Ilhl青
υ)螢”A’、 11’;!番オ赤色51.光成’r’
r ’、[1光体、緑色光光成分’1)1)Y:体およ
び青色発光成分螢光体を沼]当な割合で混合した白色)
1′:光混合螢光体の膜であり、また−hルー陰極4’
l:管σ弓1元膜は赤色発光成分螢光体からなる赤色発
光素子、9,1!:色発光成分子t、’ jI=イ1か
もなるH色発光素子オd」−びう11色51)1−成分
り:・光体からノ9「る青色発光素子υ)発光素イトリ
オ(一般に各発光素子はトソト状あイ)(・はスI・ラ
イブM1、に形成される)の規則的fI[繰1jl−に
より構成されていイ)1、
ところで細密な文字や図形の表示が行なわわるコンピュ
ーターの未ψi:′、i表示装置i/、、1i11’1
.空(・・?管制ンステムの表示装置ijj等には高)
す1゛豫IJ’)υ叫(′―極線管の使用か望まれてい
る3、隘極糾管の)1j11″ζ’、+ 1.l’j’
i1向1さ・i)ろための不1力な方θとし2て、1
1r・:(・1・・Kli管υl ′7h’、子糾ビー
ノ・の径を小さくしかつソレーノ・周波数を減少させる
方法か知られて(・zll、すブ、cわち、テレビジョ
ン用[屑(I11□1■管等(])酋ノlijの1窮(
ご)→1・管θ)フレーム周波数い、5511z1)1
1じ:であるか、このフレーム周波数を30 fizセ
、川に下げろことによって114号周波数帯域をと1辿
υ〕陰1ii1(Lh1管の約2イ1ζに拡げるかおる
(・は映f′(;周波μ弗酸’ts、′11’s Jl
l’の15・極線管υ)約1/2倍Itc−t’ii、
’ 、’、ミことかてき、そJlによって角イfツ目庄
を高め<1ノーとかできる。このように1くみ、1MI
441..1’ $iθ)ソ1、−ノ、周波数を減少さ
・1′!ることによ−〕てその1Ilrイ゛H4Ill
: t、、7高めることかて゛きろノ(j−1f歇)i
fiz糾1管(1)i、jiミス回■°1°iの映像周
波粁イi:域かル−l、周波Vどfii’ −r、 J
l’lj波左シ帯域との程・に」:つて決まるか1゛)
てA・)るO
C(/ + 、1 ?lI八高へQイイ2;度1クツ・
、4”1kr1.:”l’4 、’ ””jj+’ )
’(、’膜は長残)’(、+’lのイ1″′1ブr4体
て構成さA1イ)必要がある。こJllll、1ち・、
極線管の仏)0膜が短残)“C;件の螢光体−C構成さ
れると、’jW)’(l膜走査速度か遅(・ために画面
に1:)C・つきか41゛じるためである。−・射にこ
のようブ、C高解像1B川;グ”、 4:(jL K:
・”f’iθ)イを光膜を構成″1−ろイ1:・ブ0杯
は残光11;l、間(不発岨では励、114停止後発光
が1!U〉か励起時の10%まで低[・−1−るσ)に
要−3−ろ1lljr、 li、il 、、、なわち[
l()%残光時間Jを意味するものとづ−る)か普ノ(
Hlの1(・、極わl! ’riの螢光膜をl’i’)
/j!l、1−ろ短残光性螢光体よりも数−1から婆・
・百倍長いことか必2”ユでル・る。DETAILED DESCRIPTION OF THE INVENTION The present invention provides a high-resolution cathode layer tube (with respect to tC) having a long afterglow edge, red, and 51. Light formation phrase right'11", 4 f'yζj
It is a 4R pipe that is used in Europe, 1-1-1), filter 3
, As is well known, some black and white IS, ・i l1Ilhl blue υ) Firefly "A', 11';! No. O red 51. Mitsunari 'r'
r', [1 light body, green light component'1) 1) Y: body and blue light emitting component phosphor mixed in appropriate proportions)
1': A film of a light mixing phosphor, and -hru cathode 4'
l: Tube σ bow 1 element membrane is a red light emitting element consisting of a red light emitting component phosphor, 9,1! : Color light-emitting component element t,' jI=I1 may also be an H-color light-emitting element Od'-biu 11 colors 51) 1-component: - Blue light-emitting element υ) light-emitting element itrio (generally Each light-emitting element has a regular fI [formed in a sliver M1, 1jl-] 1, which displays detailed characters and figures. Computer error ψi:', i display device i/, 1i11'1
.. Sky (...? High for control system display devices ijj, etc.)
1j11''ζ', + 1.l'j'
i1 direction 1 ・i) Let θ be the weaker side for filtration and 2, 1
1r: (・1・・Kli tube υl '7h', Is there any known method to reduce the diameter of the solenoid and reduce the solenoid frequency (・zll, sub, c, for television? [Scrap (I11□1■Pipe etc. ())
Go) → 1・Tube θ) Frame frequency, 5511z1) 1
1st: So, by lowering this frame frequency to 30 fizse, the frequency band 114 is expanded to approximately 2x1ζ of the Lh1 tube. ; Frequency μfluoric acid'ts, '11's Jl
15 of l', polar ray tube υ) about 1/2 times Itc-t'ii,
' , ', You can increase the Kaku Ittsu Mesho by Mi, Kataki, and So Jl and say <1 No. Like this, 1 cup, 1 MI
441. .. 1' $iθ) so1, -no, decrease the frequency・1'! Therefore, the 1Ilr IH4Ill
: t,, 7 to increase the number (j-1f interval) i
fiz 糾 1 tube (1) i, ji miss times■°1°i video frequency 粁ii: area or rule -l, frequency Vdo fii' -r, J
The distance between the l'lj wave and the left band is 1゛)
teA・)ruOC(/ + , 1 ?lI to the eighth high school Qii 2; degree 1 shoes・
, 4"1kr1.:"l'4,'""jj+')
'(,'The membrane remains long)'(,+'l's A1'''1 b r4 body consists of A1 A) It is necessary.This Jllll, 1...
When the phosphor-C of the polar ray tube is configured, 'jW)' (l film scanning speed is slow (because of the 1:) C on the screen. This is for the purpose of reading 41゛.
・"f'iθ)i constitutes a light film" 1-Roi 1: ・B0 cup is afterglow 11;l, between (excitation at non-exposure, after 114 stop, emission is 1!U> or during excitation For low [・−1−σ) up to 10%, −3−1lljr, li, il ,,,i.e.
l () % afterglow time J) or funo (
Hl's 1 (・, extremely! 'ri's fluorescent film l'i')
/j! l, 1-low short afterglow fluorophore from number-1 to
・It must be a hundred times longer.
不出ム!1′[人G」、良好な両f象11丁生を可f1
1シと−J−る高111’l’像度+ip:極f、11
管(以下、枦に陰極糾七と略称才ろ)を]J、1供する
た反ハC、豹l規な長残光青色ジ1」光咎光イ」および
長残光緑色乃全橙色発光イr:九体等をJj、j案[−
1(121願昭57 12866号、同57−2554
5月45)、また輩来公知の長残光赤色発光螢光体木;
よびJ=残光flt色シト−光螢九体σ)改良等も42
.j案した(特開昭56−1.21.258月、体等を
螢光膜に有するlji・、棒かIj管の研死を重ねて来
た(特ル+iI]tf 57 1L867号Q11)+
1とy−71か、1−記)+9 )、(iri糾t″′
1を産業1より実用11−号−ろためシ・−(r、I:
’l’!]5ifのイ1ト光体の劣化(・tよろ色同
゛わか人?イ’/、’c liJ ilJどA[す、こ
の改1〕が本ず区めて中2yてル、ろ1゜
1、記色同−」jか発生ずる原因G土、陰極赫゛管に1
・ji用さjする緑色ヅ1、光成分(’A光体として、
系11成コ(、か7.++28i04 :〜IIT (
As )で表わさ才する珪酸塩糸緑色発)’に ’1.
t:・う°(、体かtl−木用いらA(ろたN〕て゛a
リイ)1、
弔11>1 +、1’、 ′+L+、 ”f’ Atj
ll DJ)J起十&C:tjりろ届’ >’l’、’
イi: C’) 31E)Y; ’j虫瓜の和ミ11.
′l褒化を示J−グラフでル)す、曲線a &;l、土
泥/、n2siU4:l市+(As)係・光イ・i、の
場合を示−”J’u
曲π!Jl ;1かトノわかく)ように、上記Zn25
iO−+ :hl++(As)りI:・)(=体を緑色
う6 )Y; Iル1分づ11元体として陰(、・II
7)雫’liに1史月I した11丁′中、子週・Jj
により著しいメ申1υリノ化7、ど生しる。このため1
い11μ糾t′1′を長期向にわたり−c 1ソ4用l
また場付色−Jれを起し使用に而]え7V−<なろル戸
の向に封かイ1゛じろ3、まプこ」二B己ン、II 2
SiO+ : +\m(As)螢光体は包布11性か良
(なく、仙の発光成分螢光体と711.合使用する」1
.“1合長時間の強いボールミルをか(1゛ないと均一
〕、cイ1:・光膜を形成I−ろことかでき/、Iい3
、gi; 2図は、ボールミル混合11.1間シ(対1
−イ)イ11九体の発光強度の経l、;1変化を示1グ
シフであり、曲線a、bおよびCはそλ1ぞれ(llf
化物系青色発光螢光体、−に記珪醇塩糸緑色発光螢光体
]5;よO・燐11イ塩系赤色発光弥)Y4体の場合を
示ず。Not available! 1′ [Person G”, good both f elephant 11 cloves possible f1
1 shi and -J-ru high 111'l' image resolution +ip: pole f, 11
The tube (hereinafter abbreviated as cathode 糾shichi)] J, 1 provided with a special long afterglow blue color 1 ``Light afterglow light'' and long afterglow green to all orange light emission Ir: Nine bodies etc. Jj, j plan [-
1 (121 Gansho 57 No. 12866, No. 57-2554)
May 45), also a long-afterglow red-emitting phosphor tree known from ancient times;
and J = afterglow flt color sheet - light firefly nine body σ) improvements etc. 42
.. (Japanese Unexamined Patent Application Publication No. 1982-1.21.25, I have been repeatedly grinding the rod or Ij tube with the body etc. in the fluorescent film (Special Le+iI] tf 57 1L867 No. Q11) +
1 and y-71 or 1-note) + 9), (iri
1 from Industry 1 to Practical No. 11-Rotameshi-(r, I:
'l'! ] Deterioration of the light body of 5if (・T different color ゛ Do you know? I'/, 'c liJ ilJ do A [su, this reform 1] is the main difference between the middle 2 years, ro 1゜1, Same coloring - 1 for the cause of the occurrence of G soil, cathode tube
・The green color used for 1, light component ('A as a light body,
System 11 Seiko (,7.++28i04 :~IIT (
As) '1.
t:・U°(, body or tl-Kiyōra A(rotaN)te゛a
li) 1, Funeral 11>1 +, 1', '+L+, "f' Atj
ll DJ) J Kiju & C: tj riro notification'>'l','
Ii: C') 31E)Y; 'j Insect Melon Japanese 11.
``J-graph shows the case of curve a &;!Jl; 1 or tonowakaku), the above Zn25
iO-+ :hl++(As)riI:・)(=makes the body green6)Y;
7) Shizuku'li 1 Fumitsu I, 11th-cho' middle school, child week Jj
Due to the remarkable transformation of Meshin 1υ Reno 7, there is a new life. For this reason 1
11μ t'1' for a long time -c 1 so 4 l
In addition, the place color - J is raised and used] E7V - <Sealed across from the naroru door I1
1
.. 1. Use a strong ball mill for a long time (if not 1, it will be uniform), c1:・Formation of a light film I-rotation/, I3
, gi; Figure 2 shows ball mill mixing 11.1 interval (vs. 1
-A) The curves a, b and C represent the change in luminescence intensity of the 119 bodies over the course of λ1 (llf).
Compound-based blue-emitting phosphor, siliceous salt-based green-emitting phosphor described in - 5; yoO-phosphorus-11-salt-based red-emitting y) The case of the Y4 body is not shown.
第2図か1)わかるように強いホールミルをか(すると
使用さ11るイ1:・光体の中に(」(q”1にイl+
:j化’3il系4ti’九体)、シー21〉1の曲線
aに示−4−如く著l−い輝度劣化な起し、このため陰
極幻!巨1tか色ず、llを生じることになる。Figure 2 or 1) As you can see, a strong hole mill is used.
:J'3il system 4ti' nine bodies), a significant luminance deterioration occurs as shown in curve a of C21〉1 as shown in -4-, and this causes cathode illusion! This will result in a huge amount of damage.
本発明σ)目的it1、製、;’r’j上(l、1土か
L“)ル1ろいは−1コ時間の使用にオ、マいて従来う
ヒ/1′1−4)色ず」1がざ1生しな(・1i′−Φ
)、糸□!盾を提供″うろことに、に、イ)1、色う1
.光成分化・光体と1−る螢光j摸をイ+ −3’ 6
1込(・リシ、fl:l管ν(−より1記目的か達成出
来ることを見出l−で木ヅ1明を完成17た。、
−・1ムわち木シ”1.門の高M IcI ID’、
I東極粕IIT ハ、(1,411+1ν式か
:/、nzSi04Jinx、 Asy、 Mez(但
し、hicはアンチモン:t(5よびビスマスの少な(
とも一方であり、X、yA’6よO・z(,1、そ」1
ぞJ+、 5 X I(1−”≦X≦:3 X 10
”’。The purpose of the present invention σ) The purpose of the invention is to use the conventional method for the use of time on (l, 1 or L). Irozu” 1 gazar 1 life (・1i′−Φ
), thread □! Providing a shield” 1
.. Light componentization/light body and 1-1 fluorescent light simulation + -3' 6
1 included (・Rishi, fl: l pipe ν(-) found out that the 1st objective could be achieved l- and completed Thu 1 Ming 17. High M IcI ID',
I Togoku Kasu IIT Ha, (1,411+1ν formula: /, nzSi04Jinx, Asy, Mez (however, hic is antimony: t (5 and less of bismuth)
On the other hand, X, yA'6 yo O・z(,1, so'1
zo J+, 5 X I (1-"≦X≦:3 X 10
”'.
(1−s y≦5X]0 よ6よびQ (Z≦1×1
0−2 なる条件を411−た1゛数であイ))で表
わさ、IIろ珪1’l・:亜鉛化)′C体を主成分とし
、10つbり〜: )Y、ll、’+間か5〜150ミ
リ秒であるit1’に色ざi’:、 )’i′; IJ
’・1分螢yC4体、(It) I 09゜タレ)Y
、時間か少ノAくとも5ミリ秒以” ” ’ J” +
1: )(: 4i)色乃至赤色9 )’(:、 ”;
(:” 元fイヲー1−成分とし、l O%残光時間か
5〜I 50 ミ’)44゛Q Ai・る赤色51.光
成分化・う°(1体、:tJよぴ(1川 10宇v 9
’:< )’1’; Itろ1111力・5〜150ミ
リ秒であ7:、)1!i色乃至青白色ジし)“t= r
js、・分化・光体がし)なろイ、1尤11W、:を有
1−ろことを114.徴とするものである。(1-s y≦5X]0 yo6 and Q (Z≦1×1
The condition of 0-2 is expressed as 411-1 ゛ number a)), II silica 1'l:zincified)'C isomer is the main component, 10 b~: )Y, ll, IJ
'・1 minute firefly yC4 bodies, (It) I 09゜Tare)Y
, for at least 5 milliseconds or less.
1: ) (: 4i) color to red 9 )'(:, ”;
(:" Original f Iwo-1-component, l O% afterglow time 5 ~ I 50 mi') 44゛Q Ai・ru red 51. Light componentization River 10 u v 9
':<)'1';It's 1111 force/5 to 150 milliseconds 7:,)1! i-colored to bluish-white) "t=r
js,・differentiation・light body) Naroi, 1-11W,: has 1-rokoto 114. It is a sign.
以下、本う・明についてd)述−4−イ)1、子連σ)
とよ5、り本ざ1明しく二月1(・+’+Jlイ)紅色
ざ1光成分螢光イA・は組ル)式か7.o2Si(−1
,+ :八In x 、)〜S)・。Below, regarding Honou and Akira, d) Description-4-B) 1, Child Ren σ)
Toyo 5, Rimotoza 1 Bright February 1 (・+'+Jl I) Crimson Za 1 Light component Fluorescence I A・Ha group Ru) formula 7. o2Si(-1
,+:8Inx,)~S)・.
Mczで゛表わさ、!+ 、八1Cはアンチモンオdよ
O・ヒ゛スマスの少な(とも−力で′あり、”+ y
:+6よびZはそ、lIそJ+、 5 X 10 ≦
1≦:3X]0−2.0≦y≦5 X 10−3および
O<z≦IXHI−2゜なる条件を6111だ′1−珪
酸亜鉛’kl ’I’C4体を斗、成力と1−るもので
A;、るか、4、に、hj1言%”+Yオ(9よびZか
そわそれI X 10 ”≦X≦lXl0−”、1×1
0 ≦y≦2×10 および1×10 ÷Z≦、5X
]Oなろ条件を満た′1−上記珪酸亜鉛も:・光体を用
(・イ)のがさらに好ルしく・(該珪酸伸41ン螢)’
(: 44(、(7)iJq ;<H,−力〃−等G」
、不出j;:li人か先に’l”!l 訂出に1;1シ
た’11+’ /91’i lli’、j 57 34
G20→S let: ii’に #l’l kc
nR’Jl 3わてい2)の゛〔この市狛出に111明
に::l 1Nを1照されたい。)。−J二記録色発5
v、成分イ1.光体とl−ては必璧眞応じて他の緑色系
ざI3光長残光荀光体である硫化前(1)を母体とし、
銅Aりろいは銅オJよυ・、j・(′・+7・−4わが
一力をイ・j活剤とし、カリタス・、11.1、C)・
17/ウノ・θ)/I//1−<とイ、一方を21・1
の共刊話剤とし、j(品詞、臭素、沃諌、弗素才・・よ
ひ)′ルミニウムのうし・σ)少1:I−<ども1棹を
第2 の 共 イ・II占 剤 ど 1− 、 l’
lil ff1l’、イ・1 ン、r(八11. 〜
・、 1 θ)共 イ・j泊剤51.9よびEt−、2
の共伺活剤θ)−ti−1がそJlそれ前:jl :
4−’J体に対しIQ” 〜JO−” i1’ fi;
9o、 10 ’ 〜10“1小]1;τoJ、;
J、び5 X IQ−”〜5XIO”’重f:i: 7
oでA5)るイ1.・光体ル)イ)いは短残光紅色ざ(
3尤な毘で本で・、0、ろ4’Jli目dよ0・アルミ
ニウノ、あろい(i−銅1・よひハロゲン例活(lli
e化亜鉛侭光休を適体d/。Express yourself with Mcz! +, 81C is less than antimony and O.
: +6 and Z is so, lI so J+, 5 X 10 ≦
1≦:3X]0-2.0≦y≦5 1- is A;, ruka, 4, hj1 word%"+Yo (9 and Z or so I X 10 "≦X≦lXl0-", 1
0 ≦y≦2×10 and 1×10 ÷Z≦, 5X
] O satisfies the condition '1- Also the above zinc silicate: It is more preferable to use a light body (・a) (the silicate extension 41-n firefly)
(: 44 (, (7) iJq ; <H, -force〃-etc.G"
, not appeared j;:li first 'l'!l 1;1 shi '11+'/91'illi', j 57 34
G20→S let: ii' to #l'l kc
nR'Jl 3Watei 2) ゛[Please see 111 light::l 1N in this city. ). -J2 recording color development 5
v, component a1. The light body is necessarily based on the pre-sulfurized (1), which is a green light body with a long afterglow of other green color.
Copper A Riroi is Copper O J υ・,j・(′・+7・−4 I use power as I・j activator, Caritas・, 11.1, C)・
17/Uno・θ)/I//1−< and I, one side is 21・1
As a jointly published talking agent, j (part of speech, bromine, ioji, fluorine sais...yohi)'luminium no ushi, σ) Sh1:I- 1-, l'
lil ff1l', i・1 n, r (811. ~
・, 1 θ) both a and j 51.9 and Et-, 2
The co-activating agent θ)-ti-1 is before that: jl:
4-'IQ''~JO-''i1' fi for J body;
9o, 10' ~ 10"1 small] 1; τoJ,;
J, bi5
A5) with o 1.・Light body L) I) Is short afterglow crimson (
3 in the book, 0, ro 4'Jli eyes dyo 0, aluminum Uno, alloy (i-copper 1, yohi halogen example activity (lli
e-zinc tai kokyu d/.
入しl、−4・のても良く、このようにして単イ(も[
<(」−混合イ1:・光体により10%夕(ω’C:
II!1間か5〜I 5(l ミIJ秒でホする糾色ヅ
1′光成分螢光体が本ブ)、1す1にJlll、・ら7
1+る。You can also input l, -4・, and in this way, you can also write a single i (also [
<(''-Mixed A1:・10% evening due to the light body (ω'C:
II! 1 hour or 5 ~ I 5 (l Mi IJ second ho color ㅅ 1' light component phosphor is the main part), 1 to 1 Jllll, et al 7
1+ru.
よた木ヅj:明シ(二用い[)A(ろ赤色発光螢光体3
Y−千4モ4.10%外−5(1lL’I間か少1.r
< ト4) 5 ミ!J秒以上の34残光橙色乃至赤
色ブ〔、先番光体を十D)匁、と−1−イ)もので、こ
θ)井残う°(、橙色乃至赤色発光令、)114体とし
ては例えば組成式か(世し、Al1,1−ツノル7ウム
、ストロンチウノ、。Yotakizuj: Meishi (two uses [) A (red light emitting phosphor 3)
Y - 1,000 4 mo 4.10% outside - 5 (between 1lL'I or a little 1.r
<G4) 5 Mi! 34 afterglow orange to red lights of J seconds or more [, the first light object is 10D] momme, and -1-a), and this θ) well remains ° (, orange to red light emitting order,) 114 bodies For example, the composition formula (Al1,1-thunor7um, strontium, etc.).
バリウム、−\リリウム、ジルコニウム」よび錫(7)
5 t)σ)少ブ5「(ども11」1・、へpcよ1
itL素オ、・よO・釦0)うちの少なくとも1f11
!でル)す、a、b。Barium, -\lillium, zirconium" and tin (7)
5 t) σ) Small 5 ``(Domo 11'' 1., to pc yo 1)
itL soo, yoo, button 0) at least 1f11 of us
! Deru)su, a, b.
CおよびX(よそわぞJl、5 X 101s ;H≦
10−1゜O≦b≦10.0≦C≦10 およびO≦
Xく1なる条件な(1h:、たずトである)で表わされ
、必要に応じてすトリウム、リチウムおよびカリウムσ
)うちの少なくとも1711・の含゛有111が10ガ
ンイ・]活珪酸マグネシウム赤色発光螢光体(1’11
g5i03;へIn)、マンガンおよび鉛旧情珪酸カル
シウノ・((1色発光衡:光体(CaSiO3: 11
.In、円))等〕、マンガン伺旧情化μを酸ノノドミ
ウム橙色発光qt:′)Y;体[:3C(13(i’(
L+ )2− (:(lce2;へIn ) 、 ユー
ロピウム旧情インジウム41111酌塩イ1ニゲ(=
イ4.ユーロピウム旧情希−に類酌化物糸螢光f(〔ユ
ーロピウム旧情希土茨11ωIII酌廓侶光休、ユーロ
ビEu Jリイ)いはLn20:+ : Eta、 l
ly、世し1泪はY、 Gd。C and X (Yosowazo Jl, 5
10-1゜O≦b≦10.0≦C≦10 and O≦
It is expressed by the condition that
), of which at least 1711 contains 111 and is 100% active magnesium silicate red-emitting phosphor (1'11).
g5i03; In), manganese and lead former calcium silicate ((one-color luminescence equivalence: photogen (CaSiO3: 11
.. In, yen)) etc.], manganese oxidation μ is acid nonodium orange luminescence qt:')Y; body [:3C(13(i'(
L+ ) 2- (: (lce2; to In), europium old feelings indium 41111 opium salt i1nige (=
B4. Similar to Europium Kyujoki - similar to the same type of futuristic thread fluorescent f ([Europium Kyujouki Dotsubara 11 ωIII Drunken Priest Mitsukyuu, Eurobi Eu J Lii) or Ln20: + : Eta, l
ly, the first tears of the world are Y, Gd.
1、ハオ、;8LびLt+ 0)うちの少ノ、[(とも
]神でル)ろ)。1, Hao, ;8LbiLt+ 0) My little boy, [(also] Kami deru)ro).
二・−−ITIビウノ、イ=Il古弄、」すj1バナジ
ン酸塩+!I;−>tイ」・。2.--ITI Biuno, I = Il old play, ``suj1 vanadate +! I;->tI"・.
−L−IJビウノ、旧情イ11−1万111※゛f訛化
q勿赤色う1.光螢芳:イ」、 (LnzUz、’;
: l・:u)、 ユーロピウムf]活イ1)土シ、
1(バナジン酊: Jji、A奇、光刊隆’If’ ]
+ マンガン伺凸弗化′1勿諮イr>ン’1′;
4i: Cマンカン伺ン古弗化カリウノ・マf ネンウ
ノ*<CL色’d)’(、’A: )’に体(1\NI
gl’3: NIr+ ) 。-L-IJ Biuno, old love 11-10,111 *゛f accented q of course red color 1. Light Hiroshi: I", (LnzUz,';
: l・:u), europium f] live 1) soil,
1 (Vanadine drunk: Jji, Aki, Takashi Kokan 'If')]
+ Manganese fluoride '1';
4i: C mankan kain old fluoride Kariuno maf neuno *<CL color 'd)' (, 'A: )' to body (1\NI
gl'3: NIr+).
゛マンカンイ・j油井化−ングネシウノ・赤色ツ1ミ光
セ;;光イi・(hlgt”2:へ111)等〕等のイ
t;・光体がk)す、必’)’j k(l応じ−ClJ
、(l残光赤色乃至((テ色’;ii )’CQ、1:
)Y:体を;11::I宜Vこ混合1〜ても良い0、こ
θ)ようにして、Ir体も17< &;l: /J−+
’、合づ1.X体にて10%残光1111間が5〜1.
50 ミリ秒でル1ろ赤色発光IJV分楕、光体か、I
、: 5.(明に用いc)J、tろ。゛Mankanii, j oil well conversion, red Tsu 1 mi light se; ; light i, (hlgt"2: to 111), etc.;, light body k), must')'j k (l according to −ClJ
, (l afterglow red to ((te color';ii)'CQ, 1:
) Y: body; 11:: I G V this mixture 1 ~ may be 0, this θ) In this way, Ir body is also 17 <&; l: /J-+
', Match 1. 10% afterglow 1111 in X body is 5 to 1.
In 50 milliseconds, red light emitted from IJV, light body, I
, : 5. (Used in light c) J, tro.
さ;゛)しこ不発明に用いら11る青色乃至青白色。S;゛) A blue to bluish-white color used in various inventions.
*+1E’(:成分螢)1C7体ハI (、’J %残
:)Y、、; l’Rt間カ5〜150ミリ秒でル)る
も1光什てル1A0.1:いず才lのqt:・)Y;体
でも用いC)」する。こσ)」、うプj−;Ii’・)
Y1体と[〜ては、4Jl /z’j式がZITS :
Alz、 NIx、へpx(イ11シ、へlは釦1ま
たは金の少〕、−くとも一方でル)す、八11はガリウ
ム、インジウムまたはスカンジウム0)51′)の少t
l″くとも1神でル)す、Xは弗素、塩素。*+1E' (: component firefly) 1C7 body HA (, 'J % remaining:) Y,,; qt of talent:・)Y; Also used in the bodyC)". koσ)'', up j-;Ii'・)
Y1 body and [..., 4Jl /z'j formula is ZITS:
Alz, NIx, hepx (I11, hel is button 1 or gold), 811 is gallium, indium or scandium 0) 51')
l''There is at least one god, and X is fluorine and chlorine.
臭素、沃素またはアルミニウノ・のう1:)の少なくと
もI fij−ごル、す、x c=−(+を含むiL’
、 (’) LMてJilろ)で表れさ、l+る長残光
青色乃至青白色発光イ1: 光体 (!1)h;;11
昭 5 6 176]70 号、 56−181
624号、 56−1.80721゛弓、 57−
1133−チJ。At least I of bromine, iodine or aluminium, x c=-(iL' containing +
(') Long afterglow blue to blue-white luminescence 1: Light body (!1)h;;11
176] No. 70, 56-181
No. 624, 56-1.80721゛bow, 57-
1133-Chi J.
56−212278号、 57 12866号騎−参
照)が傷に41(奨さ、+する1、必要に応じて、こわ
に史にケ1.)残光の青色発光螢光体(7,nS :
Ag 、 (、’l、ZnS : AL Ae ’?
) ヲ混合シテも良y−,+1: タ、従来不出願人
カ1iil記′Ijl規フ:Ci!i色’A’、 −L
−IQ残−77,イi:光体を提案1−ろ以前に用い+
:)J+ていた短残光青色発光4.、光体に長残光の緑
色発光令;光体と赤色発光螢光体を混合(〜た所iii
’iライトブル−介j’(、ノル分螢)′1.体(lt
JよりそJlぞわ画素を形JjA: L、本イ1−明の
ツノシー陰極諌り1tかイ1)ら」ll)。また前記:
3色の、:+1’、* 、)l(、体を混合し、’:l
k )’(、膜と1ろど、本発明の白黒1(λ極糾管か
IJらねる3、なオG、コ/トラストを向りさせイ)た
め、必要((一応(−゛こ各発)“’(,1Jly分に
顔イ・1を・加えでもよい3゜本発明(/(ゴナ用され
る緑色発光’i(r ’)’Ill;体である珪(l”
211+i、 @ij螢)“6体は柁1図曲線1〕(イ
11成式か7、n2SiOi :hlno、oos 、
Aso、oos2. 5l)o。t+o2で表わさ
Jlろ珪酸亜鉛螢光体の場合)に示される」:つに従来
の緑色発光螢光体に比べろと著l−2<輝鹿劣化!1)
性か良(・3、また塗布生ν件も良々J’ lj:ため
、他の螢)′C体と混合1−る場合もボールミル等イビ
かける必及カ弓日とんどな(、よつ−’−1)jl j
jL: ’L’l’定の緑色発光成分螢光体、赤色発光
Jノq分イ1;)“C4体および青色発光成分螢光体か
らなる本発明の陰極線管は、長期間便用しても色ず、l
lを示さ/、1:かりた。また視感度に最も影響″4−
ろ緑色発光成分の劣化が少ないため、高いy軍n′支の
画面かイIIらね1、そのために1惧桶も線管の71気
回路等に与えろ効果は摺しし・4、のかル、−)ブこ。No. 56-212278, No. 57 12866) is applied to the wound with 41 (recommended, +1, if necessary, 1.) Afterglow blue-emitting phosphor (7, nS:
Ag, (,'l,ZnS: AL Ae'?
) ヲ Mixed shite also good y-, +1: ta, conventional non-applicant ka 1iiiil'Ijl standard: Ci! i color 'A', -L
-IQ remaining -77, ii: Use light body before suggestion 1-ro+
:) Short afterglow blue emission with J+ 4. , the light body emits green light with a long afterglow; the light body and the red light-emitting phosphor are mixed (to place iii
'I Light Blue Intermediate' (, Norubu Firefly)'1. body (lt
Shape JjA: L, book I1-light horn sea cathode 1t or I1) et al.'ll). Also mentioned:
3 colors, :+1',*,)l(,mix body,':l
k)'(, membrane and 1, black and white 1 of the present invention (lambda pole tube or IJ looking 3, naoG, co/trust ai), it is necessary ((-゛ko) Each emission) "'(, 1 Jly can be added to the face 1. 3゜This invention (/
211+i, @ij 螢) "6 bodies are 柁1 fig. curve 1" (I11 formula 7, n2SiOi: hlno, oos,
Aso, oos2. 5l) o. In the case of a zinc silicate phosphor, expressed as t + o2), there is a significant deterioration of l-2 < brightness compared to a conventional green-emitting phosphor! 1)
The quality is good (・3, and the coating quality is also good.) Even when mixed with other fireflies, it is necessary to use a ball mill etc. tsu-'-1)jl j
The cathode ray tube of the present invention, which is composed of a C4 body and a blue light emitting component phosphor, can be used for a long period of time. Even color, l
Indicates l/, 1: It took. Also, it has the greatest impact on visibility.''4-
Since there is little deterioration of the green light emitting component, it is possible to use a screen with a high y force n' branch. ,-) Buko.
以下実施例にて説明1−る1、
実施例1
r−1(化亜鉛 7.no 7329二順
化珪索 5iU230(By’
三r′4!2化砒素 j\s 20:* 0
. I g三酸化′〕′ンヂモン 5b2C1+
29−1−配属fr+をミキザーミルで充分粉砕混
合し、アルミナルツボに充填し、1.300’C,2時
間空気中で焼成した。It’!’#成後、該焼成物を粉
砕し、史Vこ弗化マンガン375gを冷加し混合した後
百度1300’c:、2時間焼成した。このようにして
得らJlた・焼成物を粉砕、6を浄[7、+tF1 成
式カZ++2Si04: rXlno、oo s As
’o、 ooo2sbo+oozなる本発明に使用さJ
lろ緑色ざt′:光量光体を3Hjだ。この螢光体は残
光時間か70ミリ秒を示した。また同−法で製造さ、!
1だ従来の7.n2SiO+:λ1110.008AS
0,0002チ1;・光体ば、5 llミリ秒の残)°
r、を示した、。The following will be explained in Examples 1-1, Example 1 r-1 (zinc oxide 7.no 7329 disacclimated silica 5iU230(By'3r'4!Arsenic dioxide j\s 20:* 0
.. I g trioxide'〕'ndimon 5b2C1+
29-1-assignment fr+ was thoroughly ground and mixed in a mixer mill, filled into an alumina crucible, and fired in air at 1.300'C for 2 hours. It'! After forming, the fired product was pulverized, and 375 g of manganese fluoride was cooled and mixed, followed by firing at 1300 °C for 2 hours. The thus obtained Jl-fired product was pulverized and purified [7, +tF1 formula Z++2Si04: rXlno, oos As
'o, ooo2sbo+ooz J used in the present invention
lrogreenzat': The amount of light is 3Hj. This phosphor exhibited an afterglow time of 70 milliseconds. Also manufactured using the same method!
1. Conventional 7. n2SiO+:λ1110.008AS
0,0002chi1;・light body, 5 ll milliseconds remaining)°
r, was shown.
l’、 ril−:不冗明に使用されろ、fl盾色発)
°C,螢う“6体35小F1″5、青色発光成分螢)’
(、体どしで残)゛C5時間か:3 (1ミリ秒の立方
晶系を主結晶とする7、nS:)\1y、、 Ci;+
、 C7螢)゛C体l :3 jJi: 、f4j%、
および赤色発光成分’;Ix )’L体として残光時間
か133 、: IJ秒の(′/、Il、N1g)、う
(1”(月)2:へIn 螢9°0体52止i、i、
9会を使用し、これ[°シの螢光体を均一に混合(〜
て白色つ[:元螢)0体を1)だ。l', ril-: used unnecessarily, fl shield color)
°C, firefly "6 bodies 35 small F1" 5, blue luminescent component firefly)'
(Remains in both bodies) ゛C5 time: 3 (7, nS with 1 millisecond cubic system as the main crystal:)\1y,, Ci;+
, C7 firefly)゛C body l :3 jJi: , f4j%,
and red luminescent component';Ix)'Afterglow time as L body 133,: IJ seconds ('/, Il, N1g), U(1" (month) 2: to In firefly 9°0 body 52 stops i ,i,
Mix the fluorescein evenly (~
The white one [: former firefly) 0 body is 1).
この弘′光体を沈降塗布法によりフェースプレー1・上
に均−Qig布し−(螢光膜を形成し、その後従来法の
白黒陰極楠!管製造法により本発明の白黒陰極X、!、
j管を製3:’L L/た。This phosphor was uniformly spread on the face plate 1 by the precipitation coating method (to form a fluorescent film), and then the black and white cathode X,! ,
J tube was made 3:'L L/ta.
本発明の11.ツ極線り17の発光色1−11点は、第
;3図点(゛に/JZされろ(x、y)−(0,277
,0297)てあり、50011,11間の劣化テスト
後の発光色度点it ?jとんど変化1.7エかった。11. of the present invention. The luminescent color 1-11 of the polar line 17 is the 3rd figure point (゛/JZ (x, y) - (0,277
, 0297) and the luminous chromaticity point after the deterioration test between 50011 and 11? The change was 1.7 degrees.
一方1)IJ記従来のべI:光体による従来の1ダミ極
勝′1イは、緑色発光成分の!Iヨ布(tJ、性か良(
無いために、充分ボールミルを使用しなくてはならず、
このため製造さ」また陰極線管ば、点Cに示される発)
’I;色を示−1−べきであるが、硫化物である青色発
光成分かホールミルで劣化12、点(1に示1−(x、
y)・−(0,292,0,324)の発光色を示した
。更にこの陰極線管を500時間の劣化テストにかけた
ところ発光色In点か点(2に示−3−(x、y)・−
(0,303,0,305)を示I−色ず」しを生じた
。On the other hand, 1) IJ Conventional B: Conventional 1 dummy Gokukatsu by light body '1 A is the green luminescent component! I Yofu (tJ, sex or good)
Because there is no such thing, you have to use a ball mill,
For this purpose, a cathode ray tube is also manufactured (the emission shown at point C).
'I; It should show color, but the blue light-emitting component, which is a sulfide, deteriorates in a hall mill.12, point (1-(x,
y)・-(0,292,0,324). Furthermore, when this cathode ray tube was subjected to a deterioration test for 500 hours, the emission color was changed to point In or point (shown in 2 -3-(x,y)・-
(0,303,0,305), resulting in a color change.
実施例2
実施例1と同様の製法により組成式χn2si□+Jl
no、oo、+、 Aso、on、+、 f3io、o
o2テ示すJl−Z+残光時間67 m秒の緑色発光チ
1:光体2471i jJi部しこ7.nS : Co
、 AI緑色発yC体(1ド光体11市i1.i: )
’S、lIを混合l、て緑色発光成分イル・光体とし、
残光時間力30 m 秒0) ZnS : Ag、 C
iン+、 (’d螢う“0体を青色発光成分螢光体とし
、残)10時間] :33 m秒の(Zn 、 Mg
) 3(PO4) 2:へIn螢光体3・1市jA、’
j;1;とY2O2S : I・:【1螢光体14■
吊部を混合して赤色発光成分螢光体とし、こA+らの螢
)’CI、を・フ上 −ス ノ し= −−−1・
1−(5こ 1・ ) 1・ (メ、(・こ 形1+
’/−1,y 1.−後、iイ)((のノノラー1瓜
’X(・(弓1;1管製i省法む(−より本発明のカラ
ー11丁N=第j”I!管を製造した1、木′i、−明
のカシー陰極線ゞ1゛′スは従来のノノラー陰俸晴1゛
″1゛に1しべて長時間の使用νこお←〕ろ色ずれお、
1、び輝度低トは極めて少なかった1、Example 2 The composition formula χn2si□+Jl was obtained by the same manufacturing method as in Example 1.
no, oo, +, Aso, on, +, f3io, o
o2 te shows Jl-Z + green luminous light with afterglow time of 67 ms 1: Light body 2471i jJi section 7. nS: Co
, AI green yC body (1 do light body 11 cities i1.i: )
'S and lI are mixed l, and the green luminescent component illuminant and light body,
Afterglow time 30 m seconds 0) ZnS: Ag, C
10 hours]: 33 msec (Zn, Mg
) 3 (PO4) 2: In phosphor 3.1 city jA,'
j; 1; and Y2O2S: I: [1 fluorophore 14■
The hanging part is mixed to make a red light-emitting component phosphor, and the fireflies of this A + et al.) 'CI, are ・Fu top −Snow shi=−−−1・
1-(5 1・ ) 1・(Me, (・ko form 1+
'/-1, y 1. - after, i i) ((nonorer 1 melon''i, - The bright Cassie cathode rays are used for a long period of time, compared to the conventional non-color shade.
1. There were very few low brightness 1.
第1図は、′由子糺!励起−にに46けるI’r”を光
性の発)“11強)1゛シの経時変化を示−4グラフで
、0〕す、曲i、(jIlaは従来の高M像度陰極彩J
+管に曲用される蒜色発)′(1成分螢光体の1171
合を示し、+li 、?!i! bは本発明の高圧百7
.′1浪陰極k”JL ’I:イに使用さ」1ろ緑色゛
71−光成分・lI′1、弓“C1体の場合を示−1−
、,2C52図(,11、ホールミル混合旧聞にスーJ
−’l−イ螢)゛(7体Uj ’−+1’: )r7強
N’i’、 0) ’qIY) 1llj抄出ヲ示−4
−/’ 97−Cアリ、曲が゛11ン1,1)オ・・よ
ひCはそAtぞ]1イト1を化物系11j色発)’l’
; ;l’i’ )(、体、ilC来の高iす了像度陰
極線管に1・+4用される珪酸塩系緑色発光螢光体およ
び燐1“1221番系赤〔/!、う1−元螢光体の場合
を示−,1l−6ij% ;3図は、CI I;の色j
lJ図にて本開明の高1(イ像腹陰極線管ど何〕[−(
〕)高j+’百3°)1′シ1;ビ極線管())発光色
を示1−図で7tノ、イ2.。
第1図
晴 聞 (hrs)
第 2 図
ボ゛−ルミル′/兄13′日斗朋 (hrs)竿3図
χ 4置
手続補正書
昭和57年+2JI I II
特許J)長官殿
11j(イ!1の表示
昭和、7 年特jI’ #jl、l第163633 ”
2 発明の名称
高1イ像度陰fiil< #翻り(・
3 補止をすると
4代理人
な し
6、 ?di i[ににり増加する発明の数 ft
L4!r ii’l iii?求のfU I/1
1(1)(1)組成式が
、Zll 2 S l 04 : Mll X、As
y、Me Z(但し、MOはアンチ七ンおよびビスマ
スの少なくどb −/j Fあり、X、Vおよびlはイ
れぞれ5xio−5≦×≦3x IQ2. 0≦y≦
5xH)−3おJ、び0<7≦ I X 10−24L
る条件を)6またり数である)
(゛表わされる珪酸亜鉛螢光体を1成分どし、10%残
光時間が5〜150ミリ秒である緑色発光成分螢光体、
(II)10%残光IL’7問が少’cK<ども5ミリ
秒以上の長残光橙色乃至赤色発光螢光体を主成分どじ、
10%残光11.目111が5・〜150ミリ秒である
赤色発光成分螢光体、おJ、び
(Jll > 10%残光時間が5・−H+0 ミリ秒
’Cある青色乃至
青白色発光成分螢光体
からなる螢光膜を右づることを特徴どする高齢(τj1
u陰極線宣。
(2)前記X 、 V tJ3よび′7がそれぞれlX
10−3≦×≦1x 10−2. lx IQ−5≦
y≦2X10−3および?X?0−6 ≦ l :三’
;5X7(l ニニP−−イ;)る条 1′1 を ン
1シ)ノJ リ 数 C′あることを1、!1徴どりる
i’f i!’l R1’i求の範囲>7j i IJ
’i記載の高齢像度陰極線管。
(3)前記最残光lfi色乃至赤色発光螢光体がマンガ
ンイ=J活Aルト燐酸塩系螢光体、マンカン(q活りl
酸塩系螢光体、:’1.− IIビウムf」活希土り’
n酸化物系頒光休体」−−IIピウム(II f’s希
土類硼酸塩螢光体、二I −IIピウム(=J活インジ
ウl\(1j1酸塩i7?光陣、jJ3よびマンカン(
=J活活化化物系螢光体うらの少なくどb ’I fa
n (”あることを特徴とする特8′[8^求の範囲第
1項;1;たは第21ri記載の高齢像1([陰14i
*!it管、。
(/l) i’m ’r+シ1己1邑乃至1°jl’:
l (’!ブを光成分螢光1木が1%i化!u−IIを
111体どし、銀を1・」活剤どし、カリウムj:たは
インジウlオの少イcくと’b−jjを第1のJ((=
J話剤どし、塩素、募素、沃素、弗素お、」、びアルミ
ーウl\のうらの少なくどb ’I fΦをダ12の其
イ」活剤どJる1iWf化亜11)螢光体あるいは該螢
光体に金おJ5び銅の少なくとも一方が更に(=J活さ
れた螢光体を主成分どりることを特it々どづる特許請
求の範囲第11jl、第2項または第3j口1、ピ載の
高解像度陰極線管。
(3))前記MOがノ′ンf ’EンC′あることを特
1ffRどりる1′r訂請求の範囲第1項乃至第4項い
ずれかの」11記載の畠解面度陰極線管。
−6乾−Figure 1 is 'Yuko Tada! In the excitation-4 graph, I'r'' at 46 is the photogenic emission) 11 strong) showing the change over time of 1. Aya J
+ orange light used in tubes)' (1171 of one-component phosphor)
+li, ? ! i! b is the high pressure of the present invention
.. '1 Wave cathode k'JL 'I: Used for A'1 Ro green '71-Light component lI'1, bow 'C1 body case-1-
,,2C52 figure (,11, Su J to whole mill mixed old story
-'l-i firefly) ゛(7 bodies Uj '-+1': ) r7 strong N'i', 0) 'qIY) 1llj extract -4
-/' 97-C ant, song 11-1, 1) O...yohi C is Atzo] 1 it 1 is a monster type 11j color development) 'l'
; ;l'i' ) (, body, silicate-based green-emitting phosphor and phosphor 1 "1221 series red [/!, U Figure 3 shows the case of a 1-element fluorophore.
In the lJ diagram, this Kaimei high 1 (A image of the ventral cathode ray tube) [-(
]) High j+'103°) 1'1; Bipode ray tube ()) Shows the emitted light color 1 - 7t in the figure, A 2. . Figure 1 Haruki (hrs) Figure 2 Ball Mill'/Brother 13' Nito Tomo (hrs) Rod 3 Figure χ 4 Placement Proceedings Amendment 1982 + 2JI I II Patent J) Director-General 11j (I! Display of 1 Showa, 7th year special jI'#jl, l No. 163633”
2 Invention name height 1 image degree fil
L4! r ii'l iii? desired fU I/1
1(1)(1) The composition formula is Zll 2 S l 04 : Mll X, As
y, Me Z (however, MO is at least b − / j F of anti-septane and bismuth, X, V and l are each 5xio-5≦×≦3x IQ2. 0≦y≦
5xH)-3J, and 0<7≦I X 10-24L
(2) 10 (II) 10 % Afterglow IL'7 Questions are low'cK < 5 milliseconds or more Long afterglow orange to red emitting phosphor is the main component,
10% afterglow 11. From a red-emitting component phosphor with an eye 111 of 5.about.150 milliseconds, and from a blue to blue-white luminescent component phosphor with an afterglow time of 5.-H+0 milliseconds (Jll > 10% The elderly (τj1
U cathode ray announcement. (2) The above X, V tJ3 and '7 are each lX
10-3≦x≦1x 10-2. lx IQ-5≦
y≦2X10-3 and? X? 0-6≦l: 3'
;5 I'f i! 'l R1'i range of search>7j i IJ
The aged image quality cathode ray tube described in 'i. (3) The most afterglow lfi color to red emitting phosphor is manganese = J active A phosphate phosphor, manganese (q active l
Acid-based phosphor: '1. - II Bium f "Active Rare Earth"
n oxide-based photoreactive body''--II pium (II f's rare earth borate phosphor, 2I-II pium (=J-active indium\(1j1 acid i7? photon, jJ3 and mankan)
= J activated phosphor backside b 'I fa
n
*! IT tube. (/l) i'm 'r+shi1ki1u~1°jl':
l ('! The light component is fluorescent, 1 wood is 1% i! U-II is 111 bodies, silver is 1.' and 'b−jj as the first J((=
11) Fluorescence Claims 11jl, 2 or 3 each specifically specify that at least one of gold, J5 and copper is further added to the body or the phosphor (=J-activated phosphor). 3j Exit 1, high-resolution cathode ray tube mounted on a pin. A cathode ray tube described in "Kano" 11. -6 dry-
Claims (1)
ZnzSi04 : hlnx、Asy、Nfez(世
し、へ+leは°〕′ンチモノ′A6」−びビスマスθ
)少ノ1:<ども一方で、l))す、X、yお、よび2
はそ、l+そね5 X 、LO” <、x 53xlo
+0≦y≦5〉ぐ10 およOO〈Z≦I X 10
−2なる条件を/111.たづ−hで゛あろ) で表わさJ+ろ珪酸亜りイ冒i:;光体を1−成分と1
7.10つb残光11.’N 141か5〜150ミリ
秒である緑色発光成分螢ゲ(、体、 (++) 1.0τ2・残光11)1間が少/、「く
とも5ミリ秒以上のJ・之残光橙色乃至赤色5b’光イ
1号′光体を主成分ど[7、I O%残)“C2時間か
5〜150ミリ秒である赤色すl−光成分螢光体、およ
γ)・ (1n)1.0%残光時間が5−150ミリ秒である青
色乃至 青白色発うv:ルシ1分螢t’t;体 かもなろ拓′光膜を有−1−ろことを711−徴とする
高解像度陰極細管。 (2)前記X、yおよび2かそコ1ぞわ、]XIO”≦
X≦1. x 、10 、 1. X to >y≦
2XIO’およびl X 10 ’≦Z≦5×10なる
条件を、’ij、1.Jたす数てホ)ることを射像と1
−ろ特n’l’ it’l求の範囲第1項記載の高解f
uj)!旧坑極糾管。 (3) 3i:記長残光橙色乃至赤色発光螢光体がマ
ンガン旧情オルトリ、f酸塩系化九体、マンカン伺活珪
N9堪系li1・光体、ユーロビウノ・旧情希土類酸化
物系螢光体、ユーロビウノ、旧情希土プi’i l1l
Il] l!!”均イ1′、うY、体、ユーロピウノ、
イ・1活インジウム(I’ll rl・?’富(IF
)’(:イ(・5.1< j: ヒ−7ン:/j 7
(1活弗化物系41−光体のうちの少なくとも1(,1
・で゛あることを牛;I徴と1−る’l’1’ S’l
山、求のηすL1ノ1(第1項または第2項記載の高解
像7J’!1(で・9(・鴛ス、t:l、1眉−1、(
4)前記青色乃至青白色発光JJly分5.i、’;光
体がイMe11戸11jη11イ11・1体と1−11
、銀をイ\]活剤とし、ガリウノ、j“かはインジウノ
、0)少な(とも一方をtl・、1の共伺粘剤とし、j
h素、臭素、沃素。 弗素」、1」−び−j′ルミニウノ、のうぢの少なくと
も1(Φケ第2の共伺l占剤と−!IzJ(Iイむ化p
Hi鉛咎う“(: (4・あイ己・目、該螢光体に金4
5、よぴ銅の少なくとも 力か更い一部・)話さ、i[
4た”;k /’L’体を主成分と−J−ろことを重機
と′1″ろ’NJ’ ri’l’ il’l求の範囲第
1が4 、2i”、2項またに1へ・、3項記flip
の高解像1庄1(、(ψ4糾管3、 (5) 前記醋かアンチモンで゛あイ〕ことを特徴と
同一ろ4.1.、 jjl□il’l求の範囲第1項乃
至第4珀いずノ1かの8゛(記1トシ)の高1θJr像
j8陰(枳糺!管3.[Claims] (1) (1) A: ll h It j (, ga ZnzSi04 : hlnx, Asy, Nfez (se, he + le is °]'thimono'A6' - and bismuth θ
) Small number 1: <On the other hand, l)) Su, X, y, and 2
Haso, l+sone5 X, LO” <, x 53xlo
+0≦y≦5〉gu10 OO〈Z≦I X 10
-2 condition /111. It is represented by J + silicic acid salt: ; the light body is 1 - component and 1
7. Afterglow 11. 'N 141 or 5 to 150 milliseconds green luminescent component (, body, (++) 1.0τ2・afterglow 11) 1 period is small/, "J・afterglow of at least 5 milliseconds or more The main component is the orange to red 5b' light component phosphor, and γ) (1n) 1.0% Afterglow time is 5-150 milliseconds Blue to bluish-white emitted v: 1 minute firefly; body also has a luminescent film - 1 - 711 -High-resolution cathode capillaries. (2) Said X, y and 2 or 1 zowa, ]XIO”≦
X≦1. x, 10, 1. X to >y≦
2XIO' and l X 10'≦Z≦5×10, 'ij, 1. J plus number e) is a projection and 1
- High resolution f described in the first term of the range of the lo characteristic n'l'it'l search
uj)! Old mine tube. (3) 3i: Recording afterglow orange to red light-emitting phosphor is manganese old ortho, f-acid based 9 bodies, manganese phosphor N9 resistant li1, light body, eurobiuno old rare earth oxide based fluorescein body, eurobiuno, old love earth pui'i l1l
Il] l! ! ``Unity 1', UY, Body, Europiuno,
I'll RL・?' wealth (IF
)'(:I(・5.1< j: He-7n:/j 7
(1 active fluoride system 41-at least one of the photons (,1
・It is a cow; I sign and 1-'l'1'S'l
Mountain, demand's η L1 no 1 (High resolution 7J'! 1 (described in the first or second term)
4) The blue to blue-white light emission JJly minutes5. i,'; The light body is Me11 11jη11 I11・1 body and 1-11
, silver is used as an active agent, 0) is used as an active agent, and 0) is used as a co-adhesive agent of tl., 1 on one side, and
H, bromine, iodine. Fluorine", 1"-bi-j'luminiumuno, at least one of the two
Hi lead blame “(: (4・Ai・Eyes, gold 4 on the phosphor
5. At least some of the copper's strength/) spoke, i[
4";k/'L' body as main component and -J-roko as heavy machinery and '1'ro' Go to 1., 3. flip
The high resolution of 1 sho 1(, (ψ4 糾管3, (5) The above-mentioned alcohol is the same as that of antimony. High 1θ Jr image of No. 4 Izu No. 1 of 8゛ (note 1 toshi) j8 Yin (continuation! tube 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16363382A JPS5953580A (en) | 1982-09-20 | 1982-09-20 | Cathode-ray tube having high resolving power |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16363382A JPS5953580A (en) | 1982-09-20 | 1982-09-20 | Cathode-ray tube having high resolving power |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5953580A true JPS5953580A (en) | 1984-03-28 |
| JPS6144911B2 JPS6144911B2 (en) | 1986-10-04 |
Family
ID=15777637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16363382A Granted JPS5953580A (en) | 1982-09-20 | 1982-09-20 | Cathode-ray tube having high resolving power |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5953580A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59148058U (en) * | 1983-03-23 | 1984-10-03 | 化成オプトニクス株式会社 | Cathode ray tube equipment for display |
| JPS59191792A (en) * | 1983-04-15 | 1984-10-30 | Hitachi Ltd | cathode ray tube |
-
1982
- 1982-09-20 JP JP16363382A patent/JPS5953580A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59148058U (en) * | 1983-03-23 | 1984-10-03 | 化成オプトニクス株式会社 | Cathode ray tube equipment for display |
| JPS59191792A (en) * | 1983-04-15 | 1984-10-30 | Hitachi Ltd | cathode ray tube |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6144911B2 (en) | 1986-10-04 |
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