JPS60123508A - ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法 - Google Patents

ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法

Info

Publication number: JPS60123508A
Authority: JP; Japan
Prior art keywords: resin; ethylamino; pyridyl; chelate resin; chelate
Prior art date: 1984-05-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP10119184A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6325603B2 (cs

Inventor

Toshiro Yokoyama

敏郎横山

Toshishige Suzuki

敏重鈴木

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-05-19

Filing date

1984-05-19

Publication date

1985-07-02

1984-05-19 Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology

1984-05-19 Priority to JP10119184A priority Critical patent/JPS60123508A/ja

1985-07-02 Publication of JPS60123508A publication Critical patent/JPS60123508A/ja

1988-05-26 Publication of JPS6325603B2 publication Critical patent/JPS6325603B2/ja

Status Granted legal-status Critical Current

Links

229920005989 resin Polymers 0.000 title claims abstract description 49
239000011347 resin Substances 0.000 title claims abstract description 49
239000013522 chelant Substances 0.000 title claims abstract description 21
238000004519 manufacturing process Methods 0.000 title claims description 6
239000002253 acid Substances 0.000 title abstract description 4
-1 2-[2-(2-pyridyl)-ethylamino]ethylamino groups Chemical group 0.000 claims abstract description 8
229910052757 nitrogen Inorganic materials 0.000 claims abstract description 6
125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims abstract description 4
125000004429 atom Chemical group 0.000 claims abstract 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
238000001179 sorption measurement Methods 0.000 abstract description 13
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 6
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract description 5
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract description 4
229920001577 copolymer Polymers 0.000 abstract description 4
229910001385 heavy metal Inorganic materials 0.000 abstract description 4
239000002904 solvent Substances 0.000 abstract description 3
125000001424 substituent group Chemical group 0.000 abstract description 3
229920005990 polystyrene resin Polymers 0.000 abstract description 2
150000003839 salts Chemical class 0.000 abstract 2
IPWSANYYLVGECF-UHFFFAOYSA-N n'-(2-pyridin-2-ylethyl)ethane-1,2-diamine Chemical compound NCCNCCC1=CC=CC=N1 IPWSANYYLVGECF-UHFFFAOYSA-N 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 description 10
125000005843 halogen group Chemical group 0.000 description 7
238000000034 method Methods 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
230000007423 decrease Effects 0.000 description 4
229910021645 metal ion Inorganic materials 0.000 description 4
239000002351 wastewater Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 3
239000003446 ligand Substances 0.000 description 3
229910052750 molybdenum Inorganic materials 0.000 description 3
239000011733 molybdenum Substances 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
239000000126 substance Substances 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 2
CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000000921 elemental analysis Methods 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000000178 monomer Substances 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000013535 sea water Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
YWMAPNNZOCSAPF-UHFFFAOYSA-N Nickel(1+) Chemical compound [Ni+] YWMAPNNZOCSAPF-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229920001328 Polyvinylidene chloride Polymers 0.000 description 1
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
KDPAWGWELVVRCH-UHFFFAOYSA-N bromoacetic acid Chemical compound OC(=O)CBr KDPAWGWELVVRCH-UHFFFAOYSA-N 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
238000005695 dehalogenation reaction Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000003480 eluent Substances 0.000 description 1
235000019441 ethanol Nutrition 0.000 description 1
125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 description 1
239000010842 industrial wastewater Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
239000005033 polyvinylidene chloride Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
QZRBILUOXCKXFR-UHFFFAOYSA-M sodium acetate hydrobromide Chemical compound [Br-].[Na+].C(C)(=O)O QZRBILUOXCKXFR-UHFFFAOYSA-M 0.000 description 1
SESSOVUNEZQNBV-UHFFFAOYSA-M sodium;2-bromoacetate Chemical compound [Na+].[O-]C(=O)CBr SESSOVUNEZQNBV-UHFFFAOYSA-M 0.000 description 1
VRYGRLBNIVQXMY-UHFFFAOYSA-M sodium;acetic acid;chloride Chemical compound [Na+].[Cl-].CC(O)=O VRYGRLBNIVQXMY-UHFFFAOYSA-M 0.000 description 1
238000003756 stirring Methods 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
SFKTYEXKZXBQRQ-UHFFFAOYSA-J thorium(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Th+4] SFKTYEXKZXBQRQ-UHFFFAOYSA-J 0.000 description 1
238000005406 washing Methods 0.000 description 1

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Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP10119184A 1984-05-19 1984-05-19 ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法 Granted JPS60123508A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP10119184A JPS60123508A (ja)	1984-05-19	1984-05-19	ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP10119184A JPS60123508A (ja)	1984-05-19	1984-05-19	ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
JP14009082A Division JPS5939442B2 (ja)	1982-08-11	1982-08-11	新規キレ−ト樹脂の製造方法

Publications (2)

Publication Number	Publication Date
JPS60123508A true JPS60123508A (ja)	1985-07-02
JPS6325603B2 JPS6325603B2 (cs)	1988-05-26

Family

ID=14294061

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP10119184A Granted JPS60123508A (ja)	1984-05-19	1984-05-19	ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法

Country Status (1)

Country	Link
JP (1)	JPS60123508A (cs)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2006328203A (ja) *	2005-05-25	2006-12-07	Hitachi Chem Co Ltd	キレート樹脂

1984
- 1984-05-19 JP JP10119184A patent/JPS60123508A/ja active Granted

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2006328203A (ja) *	2005-05-25	2006-12-07	Hitachi Chem Co Ltd	キレート樹脂

Also Published As

Publication number	Publication date
JPS6325603B2 (cs)	1988-05-26

Publication	Publication Date	Title
RU2141377C1 (ru)	1999-11-20	Гетерогенный комплексообразующий сорбент
JPS587412A (ja)	1983-01-17	キレ−ト樹脂とその製造方法及び吸着処理方法
JPS6315284B2 (cs)	1988-04-04
JPS60123508A (ja)	1985-07-02	ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法
US4277566A (en)	1981-07-07	Chelate resin prepared by aftertreatment of aminated resin with polyfunctional compound and amine
JP2009532551A (ja)	2009-09-10	イオン交換材料、イオン交換カラム、および製造方法
US6153795A (en)	2000-11-28	Ethyleneimine-containing resins, manufacture, and use for chemical separations
JPS5970652A (ja)	1984-04-21	イミノジ酢酸誘導体
JPS6226819B2 (cs)	1987-06-11
US4134861A (en)	1979-01-16	Nitrate selective amidine ion exchange resins
JPS5939442B2 (ja)	1984-09-22	新規キレ−ト樹脂の製造方法
JP2005213477A (ja)	2005-08-11	キレート樹脂及びその製造法
US5356937A (en)	1994-10-18	Resins and processes for preparing them
Warshawsky et al.	2001	1, 2‐Bis (o‐aminophenoxy) ethane‐N, N, N′, N′‐tetraacetic Acid (BAPTA) Covalently Bound to a Polysulfone and to an Insoluble Polystyrene: Synthesis and Applications to the Selective Adsorption of Ca2+ from Mg2+ in Water
AU646889B2 (en)	1994-03-10	Polytetraalkylammonium and polytrialkylamine containing ligands bonded to inorganic supports and processes of using the same for removing and concentrating desired ions from solution
JPS58201804A (ja)	1983-11-24	キレ−ト基を有するスチレン系樹脂とその製造方法及び吸着処理方法
Nishizawa et al.	1986	Preparation and metal-adsorption properties of polystyrene resins functionalized with multidentate ligands having nitrogen and sulfur donor sets
JPS637837A (ja)	1988-01-13	ウラン吸着材
JPS6088008A (ja)	1985-05-17	キレ−ト樹脂の製法
JP5017801B2 (ja)	2012-09-05	キレート樹脂
CA2888176C (en)	2020-02-25	Method for preparing phosphine-based metal binding particles
JPS6052161B2 (ja)	1985-11-18	水銀除去用キレ−ト樹脂の製造方法
JPS62210055A (ja)	1987-09-16	ウラン吸着材
JPH0520445B2 (cs)	1993-03-19
SU1666462A1 (ru)	1991-07-30	Способ получени аминоацилполимеров

JPS60123508A - ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法 - Google Patents

Info

Links

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Related Parent Applications (1)

Publications (2)

Family

ID=14294061

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

Also Published As

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