JPS601752A - Button cell - Google Patents

Button cell

Info

Publication number
JPS601752A
JPS601752A JP58108768A JP10876883A JPS601752A JP S601752 A JPS601752 A JP S601752A JP 58108768 A JP58108768 A JP 58108768A JP 10876883 A JP10876883 A JP 10876883A JP S601752 A JPS601752 A JP S601752A
Authority
JP
Japan
Prior art keywords
sealing plate
negative electrode
sealboard
height
rising section
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58108768A
Other languages
Japanese (ja)
Inventor
Tadashi Sawai
沢井 忠
Masatsugu Kondo
近藤 正嗣
Keigo Momose
百瀬 敬吾
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP58108768A priority Critical patent/JPS601752A/en
Publication of JPS601752A publication Critical patent/JPS601752A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/147Lids or covers
    • H01M50/166Lids or covers characterised by the methods of assembling casings with lids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/147Lids or covers
    • H01M50/166Lids or covers characterised by the methods of assembling casings with lids
    • H01M50/171Lids or covers characterised by the methods of assembling casings with lids using adhesives or sealing agents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

PURPOSE:To improve the leak-proof performance by previously pressing the circumferential rising section of a negative pole sealboard then cutting to predetermined height. CONSTITUTION:A sealboard formed with copper 1, basic material or stainless steel 2 and nickel 3 is pressed such that the circumferential rising section (A) will be longer than the final dimension then said rising section (A) is grinded or cut to predetermined height. The negative pole sealboard 4 produced in such a manner has the rising section made of basic material or stainless steel 2 and maintained vertical to improve the withstandability against the fastening pressure when constructing a cell and to prevent deformation of sealboard 4 resulting in improvement of leak-proof performance.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、アルカリ電解液あるいは有機電解質を用いた
ボタン形電池の改良に関するものである。
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to improvements in button batteries using alkaline or organic electrolytes.

従来例の構成とその問題点 近年の電子技術の進歩によシ、ボタン形電池の形状はま
すます小形、薄形化が要求され、加えて電池の耐漏液特
性は、使用機器の精密化、高額化もあって、高い信頼性
が強く要望されている。
Conventional Structures and Problems Due to advances in electronic technology in recent years, the shape of button batteries has become increasingly smaller and thinner.In addition, the leakage resistance of batteries has improved as the equipment used has become more precise. As they become more expensive, there is a strong demand for high reliability.

2ページ これらの市場の要望にこたえるため、ボタン形電池の総
高さが2.0mmを切り1.6叫あるいは1.0瓢と言
う製品が開発されている。
Page 2 In order to meet these market demands, products with button-shaped batteries whose total height is less than 2.0 mm, called 1.6 mm or 1.0 mm, have been developed.

るいは0.7mmにする必要がある。It is necessary to set the diameter to 0.7 mm.

第1図に総高さが1.6mmの酸化銀電池5R916S
Wの負極封口板の部分断面図を示す。
Figure 1 shows a 5R916S silver oxide battery with a total height of 1.6 mm.
A partial sectional view of the negative electrode sealing plate of W is shown.

この封目板の高さは0 、8 mmで、その素材は銅1
゜ステンレススチール2及びニッケル3の三層クラツド
材よシなり、クラツド材の板厚は0.2mmである。
The height of this sealing plate is 0.8 mm, and its material is copper 1.
゜It is made of a three-layer cladding material of stainless steel 2 and nickel 3, and the thickness of the cladding material is 0.2 mm.

図中Aは周縁立ち上がり部で、その高さは0.3+mn
である。なお、封目板高さ、及び周縁部立ち上がり高さ
、さらにはクラツド材の厚さ等の寸法は薄型電池の一例
として示した。
A in the figure is the rising edge of the periphery, and its height is 0.3+mn
It is. Note that dimensions such as the height of the sealing plate, the rising height of the peripheral edge, and the thickness of the cladding material are shown as an example of a thin battery.

以上のような形状を有する封口板においては、周縁部立
ち上がり部の高さが低いため、基材であるステンレスス
チールを鋭角に立ち上がらせ、立ち上がシ部に垂直性を
確保することが困難であっ3 ページ だ。
In the sealing plate having the shape described above, since the height of the rising part of the peripheral edge is low, it is difficult to make the base material stainless steel rise at an acute angle and ensure verticality in the rising part. Ah, page 3.

このため、第2図に示すように負極封目板の最終プレス
工程において、展延性の良い銅1の層をたたき出し、銅
層によって立ち上がシ部の垂直性及び、垂直部の距離を
長くする試がなされていた。
For this reason, as shown in Figure 2, in the final pressing process of the negative electrode sealing plate, a layer of copper 1 with good malleability is pounded out, and the copper layer increases the verticality of the raised part and the distance between the vertical parts. An attempt was made to do so.

このような負極封目板を用いたボタン形電池においては
、基材であるステンレススチールの周縁立ち上がり部の
形状が垂直になってい々いため、電池を封口締付した場
合に加わる外部よりの圧力に対し、強度が弱く、電池の
耐漏液特性を低下させる原因となっていた。
In a button battery using such a negative electrode sealing plate, the shape of the rising edge of the stainless steel base material becomes vertical, so it is difficult to resist external pressure applied when the battery is sealed. On the other hand, the strength was low, which caused a decrease in the battery's leakage resistance.

発明の目的 本発明は、薄形ボタン形電池の負極封目板を改善するこ
とにより、耐漏液特性の優れた電池を得ることを目的と
しだものである。
OBJECTS OF THE INVENTION The object of the present invention is to obtain a battery with excellent leakage resistance by improving the negative electrode sealing plate of a thin button battery.

発明の構成 上記目的を達成するため、負極封口板の周縁立ち上がシ
部をあらかじめ長くプレス加工した後、立ち上がシ部を
所定の高さとすることで立ち上がり部の垂直性を確保し
たことを特徴とするものである。
Structure of the Invention In order to achieve the above object, the verticality of the rising part is ensured by press-working the rising part of the peripheral edge of the negative electrode sealing plate into a long length in advance, and then setting the rising part to a predetermined height. It is characterized by:

実施例の説明 以下、本発明のボタン形電池に使用する負極封口板を図
により説明する。第3図は銅1.封ロ板の基材であるス
テンレススチール2及びニッケル3からなる3層クラツ
ド板で形成された封口板で、その周縁立ち上が9部Aは
、最終使用時の立ち上が9部寸法よりも長くプレス成型
されたものである。
DESCRIPTION OF EMBODIMENTS Below, the negative electrode sealing plate used in the button-type battery of the present invention will be explained with reference to the drawings. Figure 3 shows copper 1. This is a sealing plate made of a three-layer clad plate made of stainless steel 2 and nickel 3, which is the base material of the sealing plate, and the rising edge 9 A of the sealing plate is larger than the dimension of the rising 9 part at the time of final use. It is long and press-molded.

第4図は、第3図の封目板の周縁立ち上がり部Aの高い
部分を研磨、切削等で、所定の高さに加工したものであ
る。
FIG. 4 shows a high portion of the peripheral rising portion A of the sealing plate shown in FIG. 3 which has been processed to a predetermined height by polishing, cutting, etc.

このようにして得た負極封目板は封口板の基材であるス
テンレススチール2の立ち上がり部形状が垂直に確保さ
れ、電池構成時の締付圧力に対抗する強度が向上し、封
目板の変形を防止して電池としての耐漏液性が向上する
In the negative electrode sealing plate obtained in this way, the shape of the rising part of the stainless steel 2, which is the base material of the sealing plate, is ensured vertically, and the strength against the clamping pressure during battery construction is improved, and the sealing plate is This prevents deformation and improves leakage resistance as a battery.

なお、本発明による負極封口板か否かは、周縁立ち上が
り部を破断して基材であるステンレススチールの垂直度
合を調べることで、容易に判別で5 ページ きる。
It should be noted that whether or not the negative electrode sealing plate according to the present invention is a negative electrode sealing plate according to the present invention can be easily determined by tearing off the rising portion of the peripheral edge and examining the verticality of the stainless steel base material.

次に本発明による負極封口板4を用いた第5図に示す構
造の酸化銀電池5R916SWを作成し、第1図に示し
た従来の負極封目板を使用した同形電池との耐漏液性を
比較したところ次の結果を得た。
Next, a silver oxide battery 5R916SW with the structure shown in FIG. 5 using the negative electrode sealing plate 4 according to the present invention was created, and the leakage resistance was compared with the same type of battery using the conventional negative electrode sealing plate shown in FIG. 1. The comparison yielded the following results.

なお、いずれの電池も封目板の総高さを。、8咽。In addition, the total height of the sealing plate for each battery. , 8 pharynx.

立ち上がり部の高さ0.3mm、3層クラツド材の厚さ
0 、2 mmとし、本発明の封口板の切削前のプレス
成型時の高さは0.6閣とし、これを切削して所定の0
 、3 mmの高さとした。第6図中5は正極ケース、
6は正極合剤、7は正極リング、7,8はセパレータ、
9は亜鉛負極、1oはガスケットである。
The height of the rising part is 0.3 mm, the thickness of the three-layer clad material is 0.2 mm, and the height of the sealing plate of the present invention when press-formed before cutting is 0.6 mm. 0 of
, with a height of 3 mm. 5 in Figure 6 is the positive electrode case;
6 is a positive electrode mixture, 7 is a positive electrode ring, 7 and 8 are separators,
9 is a zinc negative electrode, and 1o is a gasket.

テス)Aは温度45℃、湿度90係中に1000時間放
置後の漏液数、 6ページ テス)Bは温度60℃、湿度9o%中に500時間放置
後の漏液数 以上の通り、本発明電池の耐漏液特性が優れていること
が確認された。
Test) A is the number of leaks after being left at a temperature of 45℃ and humidity of 90% for 1000 hours, page 6Test) B is the number of leakages after being left for 500 hours at a temperature of 60℃ and a humidity of 90%. It was confirmed that the invented battery had excellent leakage resistance.

なお、負極封目板の高さが1.0+mn以上、及び周縁
立ち上がシ部の高さが、0.5mm以上の封口板は、周
縁立ち上がり部の折り曲げ長さが長いため、基材である
ステンレススチールも充分に折り曲げることができ、本
発明の方法を採用する必要がない。
In addition, the negative electrode sealing plate with a height of 1.0+mn or more and a sealing plate with a peripheral edge rising part height of 0.5mm or more have a long bending length at the peripheral edge rising part, so it is difficult to use the base material. Some stainless steels can also be bent well and there is no need to employ the method of the present invention.

発明の効果 以上のように本発明では総高が2瓢以下のボタン形電池
における耐漏液特性を向上させることができる。
Effects of the Invention As described above, the present invention can improve the leakage resistance of a button type battery having a total height of 2 gourds or less.

【図面の簡単な説明】 第1図、第2図は従来のボタン形電池における負極封口
板の部分拡大断面図、第3図は本発明の実施例における
ボタン形電池の周縁立ち上がり部を長くした負極封目板
の部分拡大断面図、第4図は周縁立ち上がり部を所定の
高さとした負極封口板の部分拡大断面°図、第す図は同
負極封口板を備7ページ えたボタン形電池の断面図である。 1・・・・・・銅、2・・・・・・基材であるステンレ
ススチール、3・・・・・・ニッケル、3・・・・・・
負極封口板、A・・・・・・周縁立ち上がり部、6・・
・・・・正極ケース、6・・・・・・正極合剤、9・・
・・・・負極亜鉛。 代理人の氏名 弁理士 中 尾 敏 男 ほか1名第1
図 第2図 3
[Brief Description of the Drawings] Figures 1 and 2 are partially enlarged cross-sectional views of the negative electrode sealing plate in a conventional button-type battery, and Figure 3 is a button-type battery according to an embodiment of the present invention in which the rising edge of the periphery is lengthened. Figure 4 is a partially enlarged cross-sectional view of a negative electrode sealing plate, and Figure 4 is a partial enlarged cross-sectional view of a negative electrode sealing plate with the raised peripheral edge at a predetermined height. FIG. 1... Copper, 2... Stainless steel as base material, 3... Nickel, 3...
Negative electrode sealing plate, A... Peripheral rising portion, 6...
...Positive electrode case, 6...Positive electrode mixture, 9...
...Negative electrode zinc. Name of agent: Patent attorney Toshio Nakao and 1 other person 1st
Figure 2 Figure 3

Claims (2)

【特許請求の範囲】[Claims] (1)負極封口板の周縁立ち上がり部を、あらかじめ長
くプレス加工した後、この立ち上がり部を所定の高さに
研磨、切削等で加工した負極封目板を用いたボタン形電
池。
(1) A button-shaped battery using a negative electrode sealing plate in which the rising edge of the peripheral edge of the negative electrode sealing plate is pressed long in advance, and then the rising edge is polished or cut to a predetermined height.
(2)負極封口板の高さが1.0mm以下で、周縁の立
ち上がり部の高さが0.5mm以下である特許請求の範
囲第1項記載のボタン形電池。
(2) The button-shaped battery according to claim 1, wherein the height of the negative electrode sealing plate is 1.0 mm or less, and the height of the rising portion of the peripheral edge is 0.5 mm or less.
JP58108768A 1983-06-16 1983-06-16 Button cell Pending JPS601752A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58108768A JPS601752A (en) 1983-06-16 1983-06-16 Button cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58108768A JPS601752A (en) 1983-06-16 1983-06-16 Button cell

Publications (1)

Publication Number Publication Date
JPS601752A true JPS601752A (en) 1985-01-07

Family

ID=14492992

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58108768A Pending JPS601752A (en) 1983-06-16 1983-06-16 Button cell

Country Status (1)

Country Link
JP (1) JPS601752A (en)

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