JPS60192716A - 流動床における粒状立体規則性ブテン−１重合体の製造方法 - Google Patents

流動床における粒状立体規則性ブテン−１重合体の製造方法

Info

Publication number: JPS60192716A
Authority: JP; Japan
Prior art keywords: butene; producing; stereoregular; catalyst; polymer
Prior art date: 1983-12-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP59257700A

Other languages

English (en)

Japanese (ja)

Inventor

ナンシー・マリー・ゴレムベスキ

ロバート・ジエイムズ・ジヨルゲンセン

ロバート・ダン・クレランド

アレン・ノスヘイ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Carbide Corp

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-12-20

Filing date

1984-12-07

Publication date

1985-10-01

1984-12-07 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1985-10-01 Publication of JPS60192716A publication Critical patent/JPS60192716A/ja

Status Pending legal-status Critical Current

Links

VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 title claims abstract description 83
229920000642 polymer Polymers 0.000 title claims abstract description 33
238000004519 manufacturing process Methods 0.000 title claims description 7
238000000034 method Methods 0.000 claims abstract description 49
239000007788 liquid Substances 0.000 claims abstract description 10
150000001336 alkenes Chemical class 0.000 claims abstract description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 5
239000003085 diluting agent Substances 0.000 claims abstract description 4
230000000707 stereoselective effect Effects 0.000 claims abstract description 4
239000003054 catalyst Substances 0.000 claims description 29
238000006116 polymerization reaction Methods 0.000 claims description 12
239000000178 monomer Substances 0.000 claims description 11
229920001577 copolymer Polymers 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 7
229910052739 hydrogen Inorganic materials 0.000 claims description 7
150000002902 organometallic compounds Chemical class 0.000 claims description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
150000005673 monoalkenes Chemical class 0.000 claims description 6
239000002245 particle Substances 0.000 claims description 6
150000003623 transition metal compounds Chemical class 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims description 4
239000011261 inert gas Substances 0.000 claims description 4
229920001519 homopolymer Polymers 0.000 claims description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
239000002994 raw material Substances 0.000 claims description 3
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
150000002736 metal compounds Chemical class 0.000 claims 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 13
239000012632 extractable Substances 0.000 abstract description 6
238000009835 boiling Methods 0.000 abstract description 5
239000002685 polymerization catalyst Substances 0.000 abstract description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
238000006243 chemical reaction Methods 0.000 description 10
239000007789 gas Substances 0.000 description 10
239000002904 solvent Substances 0.000 description 8
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 6
239000007787 solid Substances 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 4
238000009826 distribution Methods 0.000 description 4
-1 ethylene, propylene Chemical group 0.000 description 4
150000004820 halides Chemical class 0.000 description 4
239000000463 material Substances 0.000 description 4
229910052723 transition metal Inorganic materials 0.000 description 4
150000003624 transition metals Chemical class 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 3
238000000151 deposition Methods 0.000 description 3
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
150000002431 hydrogen Chemical class 0.000 description 3
239000011236 particulate material Substances 0.000 description 3
239000011347 resin Substances 0.000 description 3
229920005989 resin Polymers 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 2
230000007774 longterm Effects 0.000 description 2
230000000877 morphologic effect Effects 0.000 description 2
229920001748 polybutylene Polymers 0.000 description 2
229920000098 polyolefin Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
241000951471 Citrus junos Species 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
229910010062 TiCl3 Inorganic materials 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
229940100198 alkylating agent Drugs 0.000 description 1
239000002168 alkylating agent Substances 0.000 description 1
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
229920001585 atactic polymer Polymers 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000003426 co-catalyst Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000001514 detection method Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
230000009969 flowable effect Effects 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
239000008187 granular material Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229920001580 isotactic polymer Polymers 0.000 description 1
230000006651 lactation Effects 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
238000012856 packing Methods 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
238000007868 post-polymerization treatment Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000005029 sieve analysis Methods 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
238000012721 stereospecific polymerization Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/908—Containing catalyst of specified particle size

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP59257700A 1983-12-20 1984-12-07 流動床における粒状立体規則性ブテン−１重合体の製造方法 Pending JPS60192716A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/563,470 US4503203A (en)	1983-12-20	1983-12-20	Preparation of granular stereoregular butene-1 polymers in a fluidized bed
US563470		1983-12-20

Publications (1)

Publication Number	Publication Date
JPS60192716A true JPS60192716A (ja)	1985-10-01

Family

ID=24250618

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP59257700A Pending JPS60192716A (ja)	1983-12-20	1984-12-07	流動床における粒状立体規則性ブテン−１重合体の製造方法

Country Status (6)

Country	Link
US (1)	US4503203A (de)
EP (1)	EP0146058B1 (de)
JP (1)	JPS60192716A (de)
AT (1)	ATE44036T1 (de)
CA (1)	CA1233297A (de)
DE (1)	DE3478690D1 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4801672A (en) *	1984-11-01	1989-01-31	Mitsui Petrochemical Industries, Ltd.	Random 1-butene copolymer
US5241024A (en) *	1986-08-21	1993-08-31	Idemitsu Petrochemical Co	Method for producing butene-1 polymer
FI80280C (fi) *	1987-07-15	1990-05-10	Neste Oy	Foerfarande foer framstaellning av poly-1-buten med hoeg kistallinitet och katalysatorkompositions foer dess framstaellning.
US4963311A (en) *	1987-12-17	1990-10-16	Allied-Signal	Polyamide/polyester graft copolymer fibers and method of preparing same
AU744327B2 (en) *	1998-03-05	2002-02-21	Montell Technology Company B.V.	Polybutene-1 (co)polymers and process for their preparation
JP2002256024A (ja) *	2000-12-26	2002-09-11	Mitsui Chemicals Inc	ポリブテン系樹脂、それからなる管材および管
US8299362B2 (en) *	2010-12-23	2012-10-30	Metis Holdings Llc	Cable adapter and adapted system
CN106749789A (zh) *	2016-11-14	2017-05-31	山东省滕州瑞达化工有限公司	高全同聚丁烯‑1连续生产方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US26517A (en) *		1859-12-20		Charles g
NL104893C (de) *	1960-05-20
NL129052C (de) *	1961-11-30
US3580898A (en) *	1968-05-28	1971-05-25	Allied Chem	Vapor phase polymerization of butene-1
DE1948623A1 (de) *	1969-09-26	1971-04-01	Huels Chemische Werke Ag	Verfahren zur Herstellung von frei fliessendem,koernigem,ataktischem Polybuten
FR2207145B1 (de) *	1972-11-17	1975-09-12	Naphtachimie Sa
US3925338A (en) *	1973-03-16	1975-12-09	Monsanto Co	Control of polymer particle size in olefin polymerization
PT69504A (en) *	1978-04-18	1979-05-01	Union Carbide Corp	Process and system for exothermic polymerization in a vertical fluid bed reactor containing cooling means nto

1983
- 1983-12-20 US US06/563,470 patent/US4503203A/en not_active Expired - Fee Related
1984
- 1984-11-30 DE DE8484114587T patent/DE3478690D1/de not_active Expired
- 1984-11-30 EP EP84114587A patent/EP0146058B1/de not_active Expired
- 1984-11-30 AT AT84114587T patent/ATE44036T1/de not_active IP Right Cessation
- 1984-12-03 CA CA000469181A patent/CA1233297A/en not_active Expired
- 1984-12-07 JP JP59257700A patent/JPS60192716A/ja active Pending

Also Published As

Publication number	Publication date
ATE44036T1 (de)	1989-06-15
CA1233297A (en)	1988-02-23
EP0146058A3 (en)	1987-01-14
DE3478690D1 (en)	1989-07-20
EP0146058B1 (de)	1989-06-14
EP0146058A2 (de)	1985-06-26
US4503203A (en)	1985-03-05

Publication	Publication Date	Title
CA1265646A (en)	1990-02-06	PROCESS FOR THE START UP OF POLYMERISATION OR COPOLYMERISATION IN THE GAS PHASE OF .alpha.-OLEFINS IN THE PRESENCE OF A ZIEGLER-NATTA CATALYST SYSTEM
CA1177050A (en)	1984-10-30	Polymerization catalyst and method
US4748221A (en)	1988-05-31	Polymerization of olefins using a ziegler-natta catalyst and two organometallic compounds
CA1140699A (en)	1983-02-01	Process for production of olefin polymer by gas-phase polymerization
JPS5920681B2 (ja)	1984-05-15	重合触媒
CA2103632A1 (en)	1994-02-11	Process for producing ethylene polymers having reduced hexane extractable content
US4097409A (en)	1978-06-27	Preparation of titanium containing catalyst on magnesium support material
CA1257863A (en)	1989-07-25	SOLUTION PROCESS FOR THE PREPARATION OF POLYMERS OF .alpha.-OLEFINS
JP3034219B2 (ja)	2000-04-17	触媒成分と、そのオレフィン重合での利用
CA1297235C (en)	1992-03-10	Method for producing butene-1 polymer
JP3017542B2 (ja)	2000-03-13	エチレンのガス相（共−）重合化方法
US4503203A (en)	1985-03-05	Preparation of granular stereoregular butene-1 polymers in a fluidized bed
US10787526B2 (en)	2020-09-29	Method for startup of a gas phase polymerization reactor
CA1111198A (en)	1981-10-20	Process for the purification of highly crystalline polyolefins
GB2053939A (en)	1981-02-11	Oxide supported vanadium halide catalyst components
JPH0721005B2 (ja)	1995-03-08	エチレンの（共）重合用触媒組成物
EP0083456B1 (de)	1986-02-19	Verfahren zur Äthylencopolymerisation
US4410451A (en)	1983-10-18	Catalyst and process
US4210736A (en)	1980-07-01	Particles of titanium trichlorides which can be used for the stereospecific polymerization of alpha-olefines
FI61500B (fi)	1982-04-30	Foerfarande foer stereospecifik polymerisation av alfa-olefiner med 2-6 kolatomer i naervaro av ett katalytiskt system innehaollande titantrikloridpartiklar och de vid foerfarandet anvaenda titantrikloridpartiklarna
US3897364A (en)	1975-07-29	Process for the preparation of catalysts for the polymerization of olefins
US4211671A (en)	1980-07-08	Olefin polymerization catalyst
GB1559172A (en)	1980-01-16	Supported ziegler catalyst component
KR0177505B1 (ko)	1999-05-15	지글러 촉매계를 사용하여 에틸렌 중합체를 제조하는 방법, 및 이러한 방법으로 제조한 냄새가 적은 에틸렌 중합체
EP1521783B1 (de)	2009-04-22	Verfahren zur (co-)polymerisation von olefinen in der gasphase